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  • Springer  (4,139)
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  • 1
    Publication Date: 2011-06-09
    Description:    Selenium-containing nanosystems based on nonionic polymers (polyvinylpyrrolidone, oxyethyl cellulose), a cationic polyelectrolyte (poly- N,N,N,N -trimethylmethacryloyloxyethylammonium methyl sulfate), and anionic polyelectrolytes (poly-2-acrylamido-2-methylpropanesulfonic and polymethacrylic acids) were studied. Content Type Journal Article Pages 661-665 DOI 10.1134/S1070427211040173 Authors S. V. Valueva, Institute of Macromolecular Compounds, Russian Academy of Sciences, St. Petersburg, Russia L. N. Borovikova, Institute of Macromolecular Compounds, Russian Academy of Sciences, St. Petersburg, Russia N. A. Matveeva, Institute of Macromolecular Compounds, Russian Academy of Sciences, St. Petersburg, Russia Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 4
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  • 2
    Publication Date: 2011-06-09
    Description:    Structure of the crystalline component of a polyacrylonitrile fiber was studied in isothermal thermomechanical treatment by comparing X-ray diffraction data at various temperatures and mechanical loads of thermal stabilization. Content Type Journal Article Pages 701-707 DOI 10.1134/S1070427211040252 Authors A. G. Fazlitdinova, State Educational Enterprise for Higher Professional Education, Chelyabinsk State University, Chelyabinsk, Russia V. A. Tyumentsev, State Educational Enterprise for Higher Professional Education, Chelyabinsk State University, Chelyabinsk, Russia E. P. Mayanov, State Educational Enterprise for Higher Professional Education, Chelyabinsk State University, Chelyabinsk, Russia S. A. Podkopaev, State Educational Enterprise for Higher Professional Education, Chelyabinsk State University, Chelyabinsk, Russia Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 4
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  • 3
    Publication Date: 2011-06-09
    Description:    Equation relating the physicochemical properties of a material being ground to technological parameters of the process is derived. The equation makes it possible to evaluate the energy expenditure for grinding. Content Type Journal Article Pages 628-631 DOI 10.1134/S1070427211040124 Authors O. S. Ivanov, Institute for Problems of Chemical-Energetic Technologies, Siberian Branch, Russian Academy of Sciences, Biisk, Altai krai, Russia M. S. Vasilishin, Institute for Problems of Chemical-Energetic Technologies, Siberian Branch, Russian Academy of Sciences, Biisk, Altai krai, Russia Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 4
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  • 4
    Publication Date: 2011-06-09
    Description:    Catalytic activity exhibited by a mixed-valent film of ruthenium oxideruthenium cyanide deposited on the surface of a glassy-carbon electrode in electrooxidation of paracetamol and acetylsalicylic acid was used to develop a high-sensitivity selective method for determination of these compounds in the case of their joint presence under flow-injection conditions. Content Type Journal Article Pages 620-627 DOI 10.1134/S1070427211040112 Authors L. G. Shaidarova, Kazan State University, Kazan, Tatarstan, Russia A. V. Gedmina, Kazan State University, Kazan, Tatarstan, Russia I. A. Chelnokova, Kazan State University, Kazan, Tatarstan, Russia G. K. Budnikov, Kazan State University, Kazan, Tatarstan, Russia Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 4
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  • 5
    Publication Date: 2011-06-09
    Description:    Possibility of synthesis of 1-adamantyl phenyl ethers by one stage without use of a catalyst was researched. Content Type Journal Article Pages 730-731 DOI 10.1134/S1070427211040318 Authors G. M. Butov, Volzhskii Polytechnic Institute of Volgograd State Technical University, Volzhskii, Volgogradckaya oblast, Russia E. A. Kamneva, Volzhskii Polytechnic Institute of Volgograd State Technical University, Volzhskii, Volgogradckaya oblast, Russia K. R. Saad, Volzhskii Polytechnic Institute of Volgograd State Technical University, Volzhskii, Volgogradckaya oblast, Russia Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 4
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  • 6
    Publication Date: 2011-06-09
    Description:    The possibility to synthesize polyamidines in melt from dinitriles and diamines in the presence of aluminum chloride was explored. Content Type Journal Article Pages 510-511 DOI 10.1134/S1070427211030311 Authors B. Ch. Kholkhoev, Baikal Institute of Nature Management, Siberian Branch, Russian Academy of Sciences, Ulan-Ude, Buryat Republic, Russia V. F. Burdukovskii, Baikal Institute of Nature Management, Siberian Branch, Russian Academy of Sciences, Ulan-Ude, Buryat Republic, Russia D. M. Mognonov, Baikal Institute of Nature Management, Siberian Branch, Russian Academy of Sciences, Ulan-Ude, Buryat Republic, Russia Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 3
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  • 7
    Publication Date: 2011-06-09
    Description:    Results of numerical modeling of the kinetics of reaction of binding of nitrogen at mechanochemical disintegration of water solutions are illustrated. Experimental data of kinetics of more than fifty reactions which in many cases are different from Arrhenius kinetics were used in calculations. It is found that the main channel of nitrogen fixation is the formation of nitrocompounds, but in the presence of small amount of hydrogen the change to the channel of ammonia formation becomes possible. Content Type Journal Article Pages 559-564 DOI 10.1134/S1070427211030396 Authors Z. S. Salimov, Institute of General and Inorganic Chemistry, Academy of Sciences of Republic of Uzbekistan, Tashkent, Uzbekistan U. S. Baltaev, Institute of General and Inorganic Chemistry, Academy of Sciences of Republic of Uzbekistan, Tashkent, Uzbekistan A. M. Khurmamatov, Institute of General and Inorganic Chemistry, Academy of Sciences of Republic of Uzbekistan, Tashkent, Uzbekistan N. Kh. Yuldashev, Institute of General and Inorganic Chemistry, Academy of Sciences of Republic of Uzbekistan, Tashkent, Uzbekistan O. R. Obdurakhmonov, Institute of General and Inorganic Chemistry, Academy of Sciences of Republic of Uzbekistan, Tashkent, Uzbekistan Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 3
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  • 8
    Publication Date: 2011-06-09
    Description:    X-ray diffraction and differential-thermal analyses were used to study the phase relations in the subsolidus region of the system Li 2 MoO 4 -BaMoO 4 -R 2 (MoO 4 ) 3 . The temperature dependence of the conductivity of Li 3 Ba 2 R 3 (MoO 4 ) 8 phases (R = Y, Eu, Sm, La) was examined. Content Type Journal Article Pages 384-387 DOI 10.1134/S1070427211030086 Authors N. M. Kozhevnikova, Baikal Institute of Nature Management, Siberian Branch, Russian Academy of Sciences, Ulan-Ude, Buryatia, Russia O. A. Kopylova, Baikal Institute of Nature Management, Siberian Branch, Russian Academy of Sciences, Ulan-Ude, Buryatia, Russia Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 3
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  • 9
    Publication Date: 2011-06-09
    Description:    Effect of hydrodynamic conditions on the electrodeposition of copper from water-isopropyl alcohol solutions of CuSO 4 was studied. The experimental data obtained were analyzed in terms of the diffusion kinetics equation for a rotating disk electrode. Electron microscopy and X-ray diffraction analysis were used to examine the chemical and granulometric composition of copper-containing electrolytic powders. Content Type Journal Article Pages 615-619 DOI 10.1134/S1070427211040100 Authors A. V. Noskov, Institute of Solution Chemistry, Russian Academy of Sciences, Ivanovo, Russia S. A. Chulovskaya, Institute of Solution Chemistry, Russian Academy of Sciences, Ivanovo, Russia A. V. Balmasov, Ivanovo State University of Chemical Engineering, Ivanovo, Russia V. I. Parfenyuk, Institute of Solution Chemistry, Russian Academy of Sciences, Ivanovo, Russia Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 4
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  • 10
    Publication Date: 2011-06-09
    Description:    Initiated oxidation of cumene by oxygen in the presence of ascorbic acid was studied. Content Type Journal Article Pages 427-430 DOI 10.1134/S1070427211030165 Authors O. V. Smirnova, Litvinenko Institute of Physicoorganic Chemistry, National Academy of Sciences of Ukraine, Donetsk, Ukraine I. V. Efimova, Litvinenko Institute of Physicoorganic Chemistry, National Academy of Sciences of Ukraine, Donetsk, Ukraine I. A. Opeida, Litvinenko Institute of Physicoorganic Chemistry, National Academy of Sciences of Ukraine, Donetsk, Ukraine Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 3
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  • 11
    Publication Date: 2011-06-09
    Description:    Method for evaluation of the efficiency of photoresist adhesion promoters is suggested. The method is based on a thermodynamic simulation of the reactivity of organosilicon compounds with respect to hydroxycontaining derivatives. The adequacy of the chosen technique was verified experimentally. Content Type Journal Article Pages 431-436 DOI 10.1134/S1070427211030177 Authors V. A. Titov, Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia V. I. Rakhlin, Favorskii Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, Irkutsk, Russia E. E. Grinberg, State Research Institute of Chemical Reagents and Special-Purity Chemical Substances, Federal State Unitary Enterprise, Moscow, Russia Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 3
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  • 12
    Publication Date: 2011-06-09
    Description:    An efficient procedure was developed for preparation of ( E )- and ( Z )-3-chloroprop-2-ne-1-ylamines from commercially available 1,3-dichloropropene. Content Type Journal Article Pages 504-506 DOI 10.1134/S1070427211030293 Authors A. U. Takhautdinova, Ufa State Petroleum Technological University, Ufa, Bashkortostan, Russia E. R. Mindiyarova, Ufa State Petroleum Technological University, Ufa, Bashkortostan, Russia R. N. Shakhmaev, Ufa State Petroleum Technological University, Ufa, Bashkortostan, Russia V. V. Zorin, Ufa State Petroleum Technological University, Ufa, Bashkortostan, Russia Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 3
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  • 13
    Publication Date: 2011-06-09
    Description:    Cooling of polymer granules and strands in air and water was examined. The greatest effect of a turbulence of air flow on the cooling rate of granules was revealed in the starting period. An analysis of the cooling of granules in water demonstrated that the rate of heat transfer from a volume of thermoplastic material to its surface was a rate-limiting step and, thus, an effect of turbulization of a water flow on the cooling was negligible. We showed that it would be appropriate to install partitions destroying a heated boundary layer of water for intensifying process in a cooling bath since an actual cooling of the strands in the water bath longer corresponds to the case when water moves together with strand. Content Type Journal Article Pages 550-558 DOI 10.1134/S1070427211030384 Authors I. O. Mikulionok, Ukrainian Technical University “Kyiv Polytechnical Institute”, Kiev, Ukraine L. B. Rodchenko, Ukrainian Technical University “Kyiv Polytechnical Institute”, Kiev, Ukraine Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 3
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  • 14
    Publication Date: 2011-06-09
    Description:    Results of experiments on evaluation of velocity fields in the apparatus of diameter 98 mm loaded with irregular ring nozzle of different type so that the ratio of the diameter of the apparatus to the diameter of the packing D/d = 10 are analyzed in the article. The significant influence of the walls limiting the layer of packing on the uniformity of distribution of the velocity field in the cross-section of the apparatus with packing is shown. Raschig rings, rings of MS type and rings of N1 type of dimensions 10 × 10 × 0.9 mm made of metal were used as packing. The data obtained on Raschig rings were compared with published data. Content Type Journal Article Pages 533-538 DOI 10.1134/S1070427211030359 Authors A. S. Pushnov, Moscow State University of Environmental Engineering, Moscow, Russia E. N. Petrashova, Moscow State University of Environmental Engineering, Moscow, Russia M. G. Lagutkin, Moscow State University of Environmental Engineering, Moscow, Russia Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 3
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  • 15
    Publication Date: 2011-06-09
    Description:    Ion exchange properties of carbon fibers obtained by heat treatment in a temperature range of 200–600°C in an inert atmosphere of cellulose-regenerated impregnated by 0.3–3.0 M ammonium chloride were examined. Content Type Journal Article Pages 368-371 DOI 10.1134/S1070427211030050 Authors N. K. Luneva, Institute of General and Inorganic Chemistry, National Academy of Sciences of Belarus, Minsk, Belarus M. Z. Gavrilov, Institute of General and Inorganic Chemistry, National Academy of Sciences of Belarus, Minsk, Belarus Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 3
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  • 16
    Publication Date: 2011-06-09
    Description:    An effect of ammonium hydrofluoride treatment of silica-containing raw material was examined. We described thermodynamics and kinetics of caking raw materials and their crushed materials, ammonium hexafluorosilicate sublimation, and amorphous silica formation. Constants of rate and activation energy of the chemical reactions were calculated. Content Type Journal Article Pages 345-350 DOI 10.1134/S1070427211030013 Authors V. S. Rimkevich, Institute of Geology and Nature Management, Far Eastern Branch, Russian Academy of Sciences, Blagoveshchensk, Amur oblast, Russia A. A. Pushkin, Institute of Geology and Nature Management, Far Eastern Branch, Russian Academy of Sciences, Blagoveshchensk, Amur oblast, Russia Yu. N. Malovitskii, Institute of Geology and Nature Management, Far Eastern Branch, Russian Academy of Sciences, Blagoveshchensk, Amur oblast, Russia I. V. Girenko, Institute of Geology and Nature Management, Far Eastern Branch, Russian Academy of Sciences, Blagoveshchensk, Amur oblast, Russia Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 3
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  • 17
    Publication Date: 2011-06-09
    Description:    Results of numerical modeling of the kinetics of reaction of binding of nitrogen at mechanochemical disintegration of water solutions are illustrated. Experimental data of kinetics of more than fifty reactions which in many cases are different from Arrhenius kinetics were used in calculations. It is found that the main channel of nitrogen fixation is the formation of nitrocompounds, but in the presence of small amount of hydrogen the change to the channel of ammonia formation becomes possible. Content Type Journal Article Pages 542-549 DOI 10.1134/S1070427211030372 Authors V. B. Oshurko, Association “Technologies and Materials of Nuclear Science and Engineering,”, Moscow, Russia K. G. Poltevskii, Association “Technologies and Materials of Nuclear Science and Engineering,”, Moscow, Russia P. P. Poluetkov, Association “Technologies and Materials of Nuclear Science and Engineering,”, Moscow, Russia Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 3
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  • 18
    Publication Date: 2011-06-09
    Description:    Deep hydrogenation of products of cyclohexane condensation, dianons: 2-cyclohexylidene cyclohexanone and 2-cyclohexylene cyclohexanone, containing in waste of caprolactam manufacture, to saturated alcohol, 2-cyclohexyl cyclohexanol that can be used in synthesis of ester plasticizers for polymer compositions. Content Type Journal Article Pages 655-660 DOI 10.1134/S1070427211040161 Authors V. A. Pozdeev, Samara State Technical University, Samara, Russia S. V. Levanova, Samara State Technical University, Samara, Russia E. L. Krasnykh, Samara State Technical University, Samara, Russia Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 4
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  • 19
    Publication Date: 2011-06-09
    Description:    Mutual solubility was studied for the components of pseudoquaternary system water-isopropanolkerosene-ethyl silicate-40, and the compositions of the system in the critical solubility points were determined. Content Type Journal Article Pages 582-587 DOI 10.1134/S1070427211040045 Authors S. A. Demakhin, Ekokhim Research and Production Enterprise, Limited Liability Company, Saratov, Russia K. K. Il’in, Chernyshevskii Saratov State University, Saratov, Russia A. G. Demakhin, Ekokhim Research and Production Enterprise, Limited Liability Company, Saratov, Russia Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 4
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  • 20
    Publication Date: 2011-06-09
    Description:    Initiated oxidation of tridecane in chlorobenzene solution with molecular oxygen in the presence of a series of phenol derivatives was studied by chemiluminescence and gas-volumetric methods. The kinetic parameters of the antiradical and antioxidant activity of the compounds were determined. Content Type Journal Article Pages 649-654 DOI 10.1134/S107042721104015X Authors A. N. Nikolaevskii, Donetsk National University, Donetsk, Ukraine V. V. Morenko, Donetsk National University, Donetsk, Ukraine O. P. Kniga, Donetsk National University, Donetsk, Ukraine T. N. Ivleva, Donetsk National University, Donetsk, Ukraine Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 4
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  • 21
    Publication Date: 2011-06-09
    Description:    Isotherm of ion exchange of Co 2+ and Na + cations on iron-manganese concretions is thermodynamically described using a modified Langmuir equation. The thermodynamic characteristics of the ion exchange are determined. Content Type Journal Article Pages 588-591 DOI 10.1134/S1070427211040057 Authors D. E. Chirkst, St. Petersburg State Mining Institute, St. Petersburg, Russia O. V. Cheremisina, St. Petersburg State Mining Institute, St. Petersburg, Russia M. V. Ivanov, St. Petersburg State Mining Institute, St. Petersburg, Russia I. I. Ivanov, St. Petersburg State Mining Institute, St. Petersburg, Russia I. T. Zhadovskii, St. Petersburg State Mining Institute, St. Petersburg, Russia A. A. Chistyakov, St. Petersburg State Mining Institute, St. Petersburg, Russia Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 4
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  • 22
    Publication Date: 2011-06-09
    Description:    The optimum conditions for the formation of amorphous silicon dioxide from wastes formed in ferroalloy production containing more than 99% of the main substance were determined and its physicochemical properties were studied. Content Type Journal Article Pages 565-571 DOI 10.1134/S107042721104001X Authors L. A. Zemnukhova, Institute of Chemistry, Far East Branch, Russian Academy of Sciences, Vladivostok, Russia G. A. Fedorishcheva, Institute of Chemistry, Far East Branch, Russian Academy of Sciences, Vladivostok, Russia E. D. Shkorina, Institute of Chemistry, Far East Branch, Russian Academy of Sciences, Vladivostok, Russia T. A. Kaydalova, Institute of Chemistry, Far East Branch, Russian Academy of Sciences, Vladivostok, Russia N. N. Barinov, Institute of Chemistry, Far East Branch, Russian Academy of Sciences, Vladivostok, Russia Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 4
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  • 23
    Publication Date: 2011-06-09
    Description:    Sorption of methyl acetate, ethyl acetate, propyl acetate, butyl acetate, and diethyl ether on thin films of esters: poly(ethylene glycol) sebacate and phthalate, dinonyl phthalate, tween-40, pentaerythritol tetrabenzoate, triphenyl phosphate, Triton X-305, and stearic acid was studied. The mass of sorbent films was optimized, the sensitivity and selectivity of modifiers toward analytes was evaluated, and the time of maximum sorption was determined. Content Type Journal Article Pages 592-596 DOI 10.1134/S1070427211040069 Authors S. I. Niftaliev, Voronezh State Technological Academy, Voronezh, Russia S. E. Plotnikova, Voronezh State Technological Academy, Voronezh, Russia N. Ya. Mokshina, Voronezh Institute of Air Force Engineering, Voronezh, Russia Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 4
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  • 24
    Publication Date: 2011-06-09
    Description:    Electrolytic composites of iron sulfides FeS and Fe 3 S 4 with natural graphites of GAK and EUZ-3 brands and Chinese graphite were synthesized in thin layers and studied in a prototype lithium battery. Content Type Journal Article Pages 607-614 DOI 10.1134/S1070427211040094 Authors R. D. Apostolova, Ukrainian State University of Chemical Engineering, Dnepropetrovsk, Ukraine O. V. Kolomoets, Ukrainian State University of Chemical Engineering, Dnepropetrovsk, Ukraine M. E. Shembel, Ukrainian State University of Chemical Engineering, Dnepropetrovsk, Ukraine Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 4
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  • 25
    Publication Date: 2011-06-09
    Description:    Lightfast of red xanthene and blue azine and triphenylmethane dyes in mixtures with azo dyes of 1-phenyl-3-methyl-5-pyrazolone in the polymer films from cellulose acetobutirate were studied. Content Type Journal Article Pages 670-675 DOI 10.1134/S1070427211040197 Authors N. B. Sokolova, St. Petersburg State Technological Institute, St. Petersburg, Russia I. V. Lisina, St. Petersburg State Technological Institute, St. Petersburg, Russia N. A. Tamoshauskas, St. Petersburg State Technological Institute, St. Petersburg, Russia Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 4
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  • 26
    Publication Date: 2011-06-09
    Description:    The possibility to prepare pH-sensitive hydrogels based on polyhexamethyleneguanidine hydrochloride was explored. The equilibrium swelling rate of the hydrogels obtained at different monomer ratios was examined in relation to pH of the medium. Content Type Journal Article Pages 724-726 DOI 10.1134/S107042721104029X Authors M. N. Grigor’eva, Baikal Institute of Nature Management, Siberian Division, Russian Academy of Sciences, Buryat Republic, Ulan-Ude, Russia S. A. Stel’makh, Baikal Institute of Nature Management, Siberian Division, Russian Academy of Sciences, Buryat Republic, Ulan-Ude, Russia L. U. Bazaron, Baikal Institute of Nature Management, Siberian Division, Russian Academy of Sciences, Buryat Republic, Ulan-Ude, Russia D. M. Mognonov, Baikal Institute of Nature Management, Siberian Division, Russian Academy of Sciences, Buryat Republic, Ulan-Ude, Russia Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 4
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    Topics: Chemistry and Pharmacology
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  • 27
    Publication Date: 2011-06-10
    Description:    The concentration of polycyclic aromatic hydrocarbons (PAHs) was determined in seawater, sediment, and Rock oyster Saccostrea cucullata collected from four sampling sites in the inter-tidal areas of Bushehr province. The total concentrations of 14 PAHs varied from 1.5 to 3.6 ng/L in seawater, 41.7 to 227.5 ng/g dry weight in surface sediment, and 126 to 226.1 ng/g dry weight in oyster tissue. In comparing PAH concentrations among the three matrices in Bushehr province, data showed that the pattern of individual PAHs in seawater, oyster, and sediment were different. The oysters tended to accumulate the lower molecular weight and the more water-soluble PAHs. Sediment samples were distinguished from the sea water and oyster samples by the presence of high molecular weight PAHs, especially six-ring PAHs. Three- and four-ring PAHs were the most abundant compounds among the 14 PAHs investigated in surface seawater, sediment, and oyster samples. As expected, differences in octanol/water partition coefficient among individual PAHs and the greater persistence of the higher molecular weight PAHs contributed to the accumulation patterns in oyster and sediment. The results of the study suggested that the main sources of PAHs in the seawater and sediment in the region were mixed pyrolitic and petrogenic inputs. Content Type Journal Article Pages 1-10 DOI 10.1007/s11270-011-0850-5 Authors Roozbeh Mirza, Department of Marine Biology, Faculty of Marine Sciences, Khoramshahr Marine Science and Technology University, Khoramshahr, Iran Mehdi Mohammadi, Department of Marine Biotechnology and Environment, Persian Gulf Research and Studies Center, Persian Gulf University, Bushehr, 75169 Iran Ali Dadolahi Sohrab, Department of Environment, Faculty of Natural Sciences, Khoramshahr Marine Science and Technology University, Khoramshahr, Iran Alireza Safahieh, Department of Marine Biology, Faculty of Marine Sciences, Khoramshahr Marine Science and Technology University, Khoramshahr, Iran Ahmad Savari, Department of Marine Biology, Faculty of Marine Sciences, Khoramshahr Marine Science and Technology University, Khoramshahr, Iran Pavaneh Hajeb, Department of Fisheries, Persian Gulf Research and Studies Center, Persian Gulf University, Bushehr, 75169 Iran Journal Water, Air, & Soil Pollution Online ISSN 1573-2932 Print ISSN 0049-6979
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  • 28
    Publication Date: 2011-06-11
    Description:    Red lead (Pb 3 O 4 ) has been used extensively in the past as an anti-corrosion paint for the protection of steel constructions. Prominent examples being some of the 200,000 high-voltage pylons in Germany which have been treated with red lead anti-corrosion paints until about 1970. Through weathering and maintenance work, paint compounds and particles are deposited on the soils beneath these constructions. In the present study, six such “pylon soils” were investigated in order to characterize the plant availability and plant uptake of Pb, Cd, and Zn. For comparison, three urban soils with similar levels of heavy metal contamination were included. One phase extractions with 1 M NH 4 NO 3 , sequential extractions (seven steps), and extractions at different soil pH were used to evaluate the heavy metal binding forms in the soil and availability to plants. Greenhouse experiments were conducted to determine heavy metal uptake by Lolium multiflorum and Lactuca sativa var. crispa in untreated and limed red lead paint contaminated soils. Concentrations of Pb and Zn in the pylon soils were elevated with maximum values of 783 mg Pb kg −1 and 635 Zn mg kg −1 while the soil Cd content was similar to nearby reference soils. The pylon soils were characterized by exceptionally high proportions of NH 4 NO 3 -extractable Pb reaching up to 17% of total Pb. Even if the relatively low pH of the soils is considered (pH 4.3–4.9), this appears to be a specific feature of the red lead contamination since similarly contaminated urban soils have to be acidified to pH 2.5 to achieve a similarly high Pb extractability. The Pb content in L. multiflorum shoots reached maximum values of 73 mg kg −1 after a cultivation time of 4 weeks in pylon soil. Lime amendment reduced the plant uptake of Pb and Zn significantly by up to 91%. But L. sativa var. crispa cultivated on soils limed to neutral pH still contained critical Pb concentrations (up to 0.6 mg kg −1 fresh weight). Possible mechanisms for the exceptionally high plant availability of soil Pb derived from red lead paint are discussed. Content Type Journal Article Pages 1-15 DOI 10.1007/s11270-011-0851-4 Authors Marcel Brokbartold, Department of Soil Science and Soil Ecology, Institute of Geography, Ruhr-University Bochum, Universitätsstr. 150, 44780 Bochum, Germany Mareike Wischermann, Department of Soil Science and Soil Ecology, Institute of Geography, Ruhr-University Bochum, Universitätsstr. 150, 44780 Bochum, Germany Bernd Marschner, Department of Soil Science and Soil Ecology, Institute of Geography, Ruhr-University Bochum, Universitätsstr. 150, 44780 Bochum, Germany Journal Water, Air, & Soil Pollution Online ISSN 1573-2932 Print ISSN 0049-6979
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  • 29
    Publication Date: 2011-06-22
    Description:    Magnetosensitive composites were prepared on the basis of biocompatible polymers using Elmore reaction. The structure of the composites and the morphology of the metal-containing component were examined. The magnetic characteristics of the materials were studied. Content Type Journal Article Pages 847-853 DOI 10.1134/S1070427211050181 Authors Yu. N. Bol’bukh, Chuiko Institute of Surface Chemistry, National Academy of Sciences of Ukraine, Kiev, Ukraine V. A. Tertykh, Chuiko Institute of Surface Chemistry, National Academy of Sciences of Ukraine, Kiev, Ukraine G. Yu. Yurkov, Baikov Institute of Metallurgy and Materials Science, Russian Academy of Sciences, Moscow, Russia E. A. Ovchenkov, Lomonosov Moscow State University, Moscow, Russia Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 5
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    Topics: Chemistry and Pharmacology
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  • 30
    Publication Date: 2011-06-22
    Description:    A thermotropic mesogenic alkylene-aromatic poly(ether ester) was prepared by phase-transfer polycondensation of the azomethine derived from 5-amino-2-phenylbenzoxazole and 3,4-dihydroxybenzaldehyde with 1,6-bis(4-chlorocarbonylphenoxy)hexane in the presence of a phase-transfer catalyst, trimethylhexadecylammonium bromide. The intramolecular orientation order parameters and the angle formed by the pendant 5-imino-2-phenylbenzoxazole substituent relative to the backbone were estimated by methods of molecular hydrodynamics and optics. Content Type Journal Article Pages 832-839 DOI 10.1134/S1070427211050168 Authors S. V. Bushin, Institute of Macromolecular Compounds, Russian Academy of Sciences, St. Petersburg, Russia L. N. Andreeva, Institute of Macromolecular Compounds, Russian Academy of Sciences, St. Petersburg, Russia I. A. Strelina, Institute of Macromolecular Compounds, Russian Academy of Sciences, St. Petersburg, Russia L. I. Rudaya, Institute of Macromolecular Compounds, Russian Academy of Sciences, St. Petersburg, Russia A. V. Chernienko, Institute of Macromolecular Compounds, Russian Academy of Sciences, St. Petersburg, Russia S. M. Ramsh, Institute of Macromolecular Compounds, Russian Academy of Sciences, St. Petersburg, Russia V. V. Shamanin, Institute of Macromolecular Compounds, Russian Academy of Sciences, St. Petersburg, Russia Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 5
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  • 31
    Publication Date: 2011-06-22
    Description:    Effect of the composition of copolymers of methyl methacrylate with methacrylic acid and methacrylamide on their heat resistance and thermooxidative stability was studied. Content Type Journal Article Pages 859-866 DOI 10.1134/S107042721105020X Authors L. P. Krul’, Belarussian State University, Minsk, Belarus L. B. Yakimtsova, Belarussian State University, Minsk, Belarus E. L. Egorova, Research Institute for Physicochemical Problems, Belarussian State University, Minsk, Belarus Yu. I. Matusevich, Research Institute for Physicochemical Problems, Belarussian State University, Minsk, Belarus A. P. Polikarpov, Institute of Physicoorganic Chemistry, National Academy of Sciences of Belarus, Minsk, Belarus Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 5
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    Topics: Chemistry and Pharmacology
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  • 32
    Publication Date: 2011-06-22
    Description:    Previous research in agricultural catchments showed that past inputs of nitrate continue to influence present observations and future characteristics of nitrate concentrations in stream water for a long period of time. This persistence manifests itself as a “memory effect” with a prolonged response of stream water nitrate levels to reductions of nitrate inputs on the catchment scale. The question we attempt to resolve is whether such a memory effect also exists in mountainous catchments with a snowmelt-dominated runoff regime. We analyzed long-term records (∼20 years) of nitrate-nitrogen concentrations measured in stream at three stations on the upper Váh River (Slovakia). Applying spectral analysis and detrended fluctuation analysis, we found a varying degree of persistence between the three analyzed sites. With increasing catchment area, the fluctuation scaling exponents generally increased from 0.77 to 0.93 (fluctuation exponents above 0.5 are usually considered as a proof of persistence while values close to 0.5 indicate “white” uncorrelated noise). The nitrate-nitrogen signals temporally scaled as a power-low function of frequency (1/ f noise) with a strong annual seasonality. This increase in persistence might be attributable to the catchment areas upstream the sampling sites. These results have important implications for water quality management. In areas where reduction of nitrate in surface waters is imposed by legislation and regulatory measures, two catchments with different persistence properties may not respond to the same reduction of sources of nitrogen at the same rate. Content Type Journal Article Pages 1-12 DOI 10.1007/s11270-011-0854-1 Authors Milan Onderka, Department of Environment and Agro-biotechnologies, Centre de Recherche Public—Gabriel Lippmann, 41, rue du Brill, 4422 Belvaux, Luxembourg Lea Mrafková, Slovak Hydrometeorological Institute, Jeséniova 17, Bratislava, 833 15 Slovakia Andreas Krein, Department of Environment and Agro-biotechnologies, Centre de Recherche Public—Gabriel Lippmann, 41, rue du Brill, 4422 Belvaux, Luxembourg Lucien Hoffmann, Department of Environment and Agro-biotechnologies, Centre de Recherche Public—Gabriel Lippmann, 41, rue du Brill, 4422 Belvaux, Luxembourg Journal Water, Air, & Soil Pollution Online ISSN 1573-2932 Print ISSN 0049-6979
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  • 33
    Publication Date: 2011-06-23
    Description:    Lime was physically blended with Waste Activated Sludge (W.A.S) in various proportions. These blends were hydrated, dried, ground, and sieved to size of utmost 200 μm. The sorbents were then used in fixed-bed reactor for dry desulfurization tests. It was found that the blends had higher sorption capacities than lime alone which means that W.A.S augmented lime's sorption capacity. Higher surface area and porosity of the blended sorbents compared to lime was the main cause of the improved sorption capacity, a conclusion supported by Brunauer–Emmett–Teller surface area analysis (surface area increment with sorption capacity) and scanning electron microscopy imaging (rough morphology being formed). This higher surface area and porosity was caused by pozzolanic reaction between lime and the alumina silicate constituents of W.A.S. The products of this reaction are high surface area, complex calcium alumina silicates. Content Type Journal Article Pages 1-7 DOI 10.1007/s11270-011-0856-z Authors Paul Maina, Tshwane University of Technology, P.O Box Private Bag X680, Pretoria, 0001 South Africa Makame Mbarawa, Tshwane University of Technology, P.O Box Private Bag X680, Pretoria, 0001 South Africa Journal Water, Air, & Soil Pollution Online ISSN 1573-2932 Print ISSN 0049-6979
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  • 34
    Publication Date: 2011-06-25
    Description:    The sorption of four endocrine disruptors, bisphenol A (BPA), estrone (E1), 17β-estradiol (E2), and 17α-ethinylestradiol (EE2) in tropical sediment samples was studied in batch mode under different conditions of pH, time, and sediment amount. Data obtained from sorption experiments using the endocrine disruptors (EDs) and sediments containing different amounts of organic matter showed that there was a greater interaction between the EDs and organic matter (OM) present in the sediment, particularly at lower pH values. The pseudosecond order kinetics model successfully explained the interaction between the EDs and the sediment samples. The theoretical and experimentally obtained q e values were similar, and k values were smaller for higher SOM contents. The k F values, obtained from the Freundlich isotherms, varied in the ranges 4.2–7.4 × 10 −2 (higher OM sediment sample, S 2 ) and 1.7 × 10 −3 –3.1 × 10 −2 (lower OM sediment sample, S 1 ), the latter case indicating an interaction with the sediment that increased in the order: EE2 〉 〉 E2 〉 E1 〉 BPA. These results demonstrate that the availability of endocrine disruptors may be directly related to the presence of organic material in sediment samples. Studies of this kind provide an important means of understanding the mobility, transport, and/or reactivity of this type of emergent contaminant in aquatic systems. Content Type Journal Article Pages 1-8 DOI 10.1007/s11270-011-0861-2 Authors Bruno B. Cunha, Department of Analytical Chemistry, Institute of Chemistry, São Paulo State University (UNESP), CP 355, 14801-970 Araraquara, SP, Brazil Wander Gustavo Botero, Federal University of Alagoas (UFAL), CP 61, 57309-005 Arapiraca, Alagoas, Brazil Luciana Camargo Oliveira, Federal University of São Carlos (UFSCar), 18052-780 Sorocaba, São Paulo, Brazil Viviane M. Carlos, Department of Environmental Engineering, São Paulo State University (UNESP), 18087-180 Sorocaba, SP, Brazil Marcelo L. M. Pompêo, Institute of Biosciences, University of São Paulo (USP), 05508–900 São Paulo, São Paulo, Brazil Leonardo F. Fraceto, Department of Environmental Engineering, São Paulo State University (UNESP), 18087-180 Sorocaba, SP, Brazil André H. Rosa, Department of Environmental Engineering, São Paulo State University (UNESP), 18087-180 Sorocaba, SP, Brazil Journal Water, Air, & Soil Pollution Online ISSN 1573-2932 Print ISSN 0049-6979
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  • 35
    Publication Date: 2011-06-25
    Description:    Understanding the acid-base chemistry of soil and the soil processes related to the release or retention of sulfate and nitrate is important in order to predict watershed recovery from long-term acid deposition. Soils were sampled from the Noland Divide Watershed (NDW), a small, high-elevation watershed in the Great Smoky Mountains National Park receiving high rates of acid deposition over several decades. Soil samples were measured for chemical properties related to acidification and used to conduct sulfate adsorption and nitrogen (N) incubation experiments. Shallow soil was higher in acidic and basic ions than deeper soils, and the mean effective cation exchange capacity was 8.07, 5.06, and 3.57 cmol c  kg −1 in the A, Bw, and Cb horizons, respectively. In all three soil horizons, the base saturation was equal to or below 7% and the ratio of Ca/Al was below 0.01, indicating that the NDW is very sensitive to acid deposition. Based on results from sulfate adsorption isotherms, the NDW has not reached its maximum sulfate adsorption saturation and is likely able to retain further additions of sulfate. Desorption of sulfate from NDW soils is expected if sulfate concentrations in soil solution drop below 50 μeq L −1 but is highly dependent on soil pH and organic carbon content. Total soil organic N was 500 times greater than inorganic N in the A soil horizon, and net N mineralization and nitrification remained constant during a 28-day incubation indicating a large reservoir of N substrate for soil microbes. Nitrogen experiment results suggest that nitrate export from the watershed is largely controlled by biological processes rather than by nitrate deposition flux. Soil data collected in this study contributes to our understanding of biogeochemical processes affecting the response of acid-impacted ecosystems such as the NDW to future changes in atmospheric deposition. Content Type Journal Article Pages 1-15 DOI 10.1007/s11270-011-0858-x Authors Meijun Cai, Department of Civil and Environmental Engineering, University of Tennessee, Knoxville, TN 37996, USA Amy M. Johnson, Department of Biosystems Engineering and Soil Science, University of Tennessee, Knoxville, TN 37996, USA John S. Schwartz, Department of Civil and Environmental Engineering, University of Tennessee, Knoxville, TN 37996, USA Steve E. Moore, US Department of Interior, National Park Service, Great Smoky Mountains National Park, Gatlinburg, TN 37738, USA Matt A. Kulp, US Department of Interior, National Park Service, Great Smoky Mountains National Park, Gatlinburg, TN 37738, USA Journal Water, Air, & Soil Pollution Online ISSN 1573-2932 Print ISSN 0049-6979
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  • 36
    Publication Date: 2011-06-25
    Description:    The modification effects of hematite with aluminum hydroxide were investigated on the removal of fluoride ions from water using batch experiments. The effects of pH, contact time, fluoride concentration, and the dose of sorbent on the sorption of fluoride ions by a modified hematite were studied. Characterization of hematite before and after the modification with aluminum hydroxide was studied by X-ray diffraction, scanning electron microscope, and Brunauer–Emmett–Teller. Equilibrium was reached in 48 h of contact time and the maximum sorption of fluoride was found in the pH eq range between 2.34 and 6.26. The Elovich model described the kinetic sorption processes and the Langmuir–Freundlich model, the sorption isotherm process. These results indicated that the sorption mechanism was chemisorption on a heterogeneous material. Content Type Journal Article Pages 1-9 DOI 10.1007/s11270-011-0860-3 Authors A. Teutli-Sequeira, Departamento de Química, Instituto Nacional de Investigaciones Nucleares, A. P. 18-1027, Col. Escandón, Delegación Miguel Hidalgo, C.P. 11801 México, DF, Mexico Marcos Solache-Ríos, Departamento de Química, Instituto Nacional de Investigaciones Nucleares, A. P. 18-1027, Col. Escandón, Delegación Miguel Hidalgo, C.P. 11801 México, DF, Mexico P. Balderas-Hernández, Facultad de Química, Universidad Autónoma del Estado de México, Paseo Colón y Tollocan s/n., C.P. 50000 Toluca Estado de México, Mexico Journal Water, Air, & Soil Pollution Online ISSN 1573-2932 Print ISSN 0049-6979
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  • 37
    Publication Date: 2011-06-25
    Description:    Perchlorate (ClO 4 − ), a thyroid hormone disruptor, is both naturally occurring and a man-made contaminant increasingly found in a variety of terrestrial environments. The environmental presence of ClO 4 − is considered to be the result of atmospheric formation and deposition processes. The ultimate processes, particularly heterogeneous-based reactions, leading to natural ClO 4 − formation are not well understood. Oxidation of chlorine species by an energetic source such as lightning is considered to be one of the potential heterogeneous sources of natural ClO 4 − . Currently, there is very little information available on lightning-induced ClO 4 − . We designed a laboratory electrical discharge reactor capable of evaluating ClO 4 − formation by the oxidation of “dry” sodium chloride (NaCl) aerosols (relative humidity (RH) 〈70%) in electrical discharge plasma at voltages and energies up to 24 kV and 21 kJ, respectively. Similar to other non-electrochemical ClO 4 − production processes, the amount of ClO 4 − produced (0.5–4.8 μg) was 3 orders of magnitude lower than the input Cl − (7.1–60.1 mg). The amount of ClO 4 − generated increased with peak voltage (V) and theoretical maximum discharge energy with ΔClO 4 − /ΔV = 0.28 × 10 −3  μg V −1 ( R 2  = 0.94) and ΔClO 4 − /ΔE = 0.44 × 10 −3  μg J −1 ( R 2  = 0.83). The total ClO 4 − generated decreased with an increase in relative humidity from 2.8 ± 0.1 μg (RH ∼46%) to 0.9 ± 0.1 μg (RH ∼62%) indicating that the presence of moisture inhibits the formation of ClO 4 − . Additional modifications to the reactor support the hypothesis of ClO 4 − formation due to the action of plasma on Cl − aerosols as opposed to direct oxidation on the surface of the electrodes. Finally, the contribution of lightning-induced ClO 4 − in North America is calculated to have a wide range from 0.006 × 10 5 to 5 × 10 5  kg/year and is within the range of the measured ClO 4 − depositional flux in precipitation samples obtained across the USA (0.09 × 10 5 –1.2 × 10 5  kg/y). Content Type Journal Article Pages 1-13 DOI 10.1007/s11270-011-0857-y Authors Balaji Rao, Department of Civil and Environmental Engineering, Texas Tech University, Lubbock, TX 79409-1023, USA Suhas Mohan, Department of Civil and Environmental Engineering, Texas Tech University, Lubbock, TX 79409-1023, USA Andreas Neuber, Department of Electrical and Computer Engineering, Texas Tech University, Lubbock, TX 79409-3102, USA William Andrew Jackson, Department of Civil and Environmental Engineering, Texas Tech University, Lubbock, TX 79409-1023, USA Journal Water, Air, & Soil Pollution Online ISSN 1573-2932 Print ISSN 0049-6979
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  • 38
    Publication Date: 2011-06-09
    Description:    Modification of AG-OV-1 activated carbon with an ozone-oxygen mixture was studied. Changes in the porosity, state of the surface, and adsorption capacity of ozonized samples were examined in relation to the oxidation duration. Explanation are suggested for the patterns obtained. Content Type Journal Article Pages 597-601 DOI 10.1134/S1070427211040070 Authors O. V. Belyaeva, Kemerovo Technological Institute of Food Industry, Kemerovo, Russia T. A. Krasnova, Kemerovo Technological Institute of Food Industry, Kemerovo, Russia S. A. Semenova, Kemerovo Technological Institute of Food Industry, Kemerovo, Russia Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 4
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  • 39
    Publication Date: 2011-06-09
    Description:    The available published data on thermodynamic properties of liquid arsenic-lead alloys were analyzed and mathematically treated on which basis the limiting activity coefficients of arsenic in liquid lead were calculated for several temperatures. Content Type Journal Article Pages 602-606 DOI 10.1134/S1070427211040082 Authors A. G. Morachevskii, St. Petersburg State Polytechnical University, St. Petersburg, Russia T. V. Butukhanova, St. Petersburg State Polytechnical University, St. Petersburg, Russia Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 4
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  • 40
    Publication Date: 2011-06-09
    Description:    The effect of organic solvents miscible with water (acetone, methyl ethyl ketone, 2-propanol, 2-ethoxyethanol, dimethylformamide) on the composition, structure, and crystal transformations of polyborasiloxanes formed by hydrolytic polycocondensation of tetraethoxysilane with boric acid under the conditions of base catalysis (NH 4 OH) was studied. Content Type Journal Article Pages 696-700 DOI 10.1134/S1070427211040240 Authors V. V. Malyshev, Engineering-Technological Institute, Ukraine Open International Institute for Human Development, Kiev, Ukraine M. G. Voronkov, Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, St. Petersburg, Russia S. V. Klimenko, Engineering-Technological Institute, Ukraine Open International Institute for Human Development, Kiev, Ukraine V. S. Klimenko, Engineering-Technological Institute, Ukraine Open International Institute for Human Development, Kiev, Ukraine Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 4
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  • 41
    Publication Date: 2011-06-09
    Description:    A procedure was developed for preparing a new heterocyclically substituted chelating aminopolymer, N-2-(2-pyridyl)ethyl chitosan, by direct addition of 2-vinylpyridine to chitosan under the conditions of synthesis in gel. The resulting polymer has the degree of substitution of up to 1. The ability of the samples obtained to sorb transition and noble metal ions was evaluated. Content Type Journal Article Pages 713-718 DOI 10.1134/S1070427211040276 Authors A. V. Pestov, Postovskii Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences, Yekaterinburg, Russia S. Yu. Bratskaya, Institute of Chemistry, Far-Eastern Branch, Russian Academy of Sciences, Vladivostok, Russia Yu. A. Azarova, Institute of Chemistry, Far-Eastern Branch, Russian Academy of Sciences, Vladivostok, Russia M. I. Kodess, Postovskii Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences, Yekaterinburg, Russia Yu. G. Yatluk, Postovskii Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences, Yekaterinburg, Russia Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 4
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  • 42
    Publication Date: 2011-06-09
    Description:    The solvent effect on the kinetic features of the synthesis and molecular characteristics of the copolymers in homogeneous radical copolymerization of sodium 2-acrylamido-2-methylpropanesulfonate with sodium acrylate in water and water-dimethyl sulfoxide mixtures (75: 25, 50: 50, 25: 75) at pH 9 and 60°C in the presence of potassium persulfate was studied Content Type Journal Article Pages 679-684 DOI 10.1134/S1070427211040215 Authors V. F. Kurenkov, Kazan State University of Technology, Kazan, Tatarstan, Russia A. V. Kurenkov, Kazan State University of Technology, Kazan, Tatarstan, Russia Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 4
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  • 43
    Publication Date: 2011-06-09
    Description:    Condensation of a vapor-air mixture and boiling in a flowing down water film in an upright tubular evaporator was examined. We studied techniques to intensify heat exchange by installation of turbulators in a form of coil on a heat transfer surface of pipes and developed dependencies to estimate values of heat transfer coefficient in condensation and boiling. Content Type Journal Article Pages 539-541 DOI 10.1134/S1070427211030360 Authors N. A. Voinov, Siberian State Technological University, Krasnoyarsk, Russia O. P. Zhukov, Siberian State Technological University, Krasnoyarsk, Russia A. N. Voinov, Siberian State Technological University, Krasnoyarsk, Russia Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 3
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  • 44
    Publication Date: 2011-06-09
    Description:    Deformation-strength, sorption, and operation properties of composite materials made from polyvinyl alcohol and coproducts of diesel biofuel production (rape-cake and glycerin) were studied with the aim to apply them for agricultural needs. Content Type Journal Article Pages 719-723 DOI 10.1134/S1070427211040288 Authors V. Grazhulevichene, Lithuanian Agricultural University, Kaunas, Lithuania L. Augulis, Lithuanian Agricultural University, Kaunas, Lithuania M. Gumbite, Lithuanian Agricultural University, Kaunas, Lithuania V. Makarevichene, Lithuanian Agricultural University, Kaunas, Lithuania Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 4
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  • 45
    Publication Date: 2011-06-09
    Description:    Effect of parameters of the ion exchange of Na + cations for La 3+ in Y zeolites with SiO 2 /Al 2 O 3 molar ratios of 5.1 and 6.0 on the degree of exchange and physicochemical properties of the resulting LaNaY samples was studied. The conditions in which deeply substituted La-forms of a Y zeolite with high degree of crystallinity can be obtained were determined. Content Type Journal Article Pages 577-581 DOI 10.1134/S1070427211040033 Authors A. N. Khazipova, Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, Ufa, Bashkortostan, Russia R. R. Il’yasova, Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, Ufa, Bashkortostan, Russia A. A. Tantseva, Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, Ufa, Bashkortostan, Russia B. I. Kutepov, Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, Ufa, Bashkortostan, Russia Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 4
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  • 46
    Publication Date: 2011-06-09
    Description:    The conditions of emulsification of imported analogs of Russian epoxy resins in the presence of nonionic surfactants were studied. The curing kinetics and the hardness of coatings formed from compounds containing epoxy emulsions and EPILINK 701 and Waterpoxy 751 curing agents were examined. Content Type Journal Article Pages 479-485 DOI 10.1134/S1070427211030256 Authors E. V. Shinkareva, Institute of General and Inorganic Chemistry, National Academy of Sciences of Belarus, Minsk, Belarus V. D. Koshevar, Institute of General and Inorganic Chemistry, National Academy of Sciences of Belarus, Minsk, Belarus Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 3
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  • 47
    Publication Date: 2011-06-09
    Description:    Hydroxylation of phenol with a 25% aqueous solution of hydrogen peroxide in polar protic and aprotic solvents on TS-1 heterogeneous catalyst under various conditions was studied. The major reaction products (hydroquinone, pyrocatechol) and their ratio were determined. A kinetic model describing the hydroxylation in accordance with the Rideal-Eley mechanism was chosen. Content Type Journal Article Pages 640-648 DOI 10.1134/S1070427211040148 Authors V. V. Potekhin, Himtek Engineering Private Joint-Stock Company, St. Petersburg, Russia V. A. Kulikova, St. Petersburg State Institute of Technology, St. Petersburg, Russia V. V. Vasil’ev, St. Petersburg State Engineering and Economic University, St. Petersburg, Russia E. G. Kohina, St. Petersburg State Institute of Technology, St. Petersburg, Russia V. M. Potekhin, St. Petersburg State Institute of Technology, St. Petersburg, Russia Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 4
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  • 48
    Publication Date: 2011-06-10
    Description:    Elevated emissions of nitrogen oxides (NO x ) in the Athabasca Oil Sands Region, Alberta and higher foliar nitrogen (N) concentrations in jack pine ( Pinus banksiana ) needles close to major emission sources has led to concerns that the surrounding boreal forest may become N-saturated. Despite these concerns, N deposition and impacts on upland forests in the region is poorly quantified. The objective of this study was to characterize N cycling in five plots representing the two dominant upland forest types (jack pine and trembling aspen, Populus tremuloides ) close (〈30 km) to the largest mining operations in the region, during a 2-year period. Despite the high level of NO x emissions, bulk throughfall and deposition measured at both study sites were surprisingly very low (〈2 kg N ha −1  year −1 ). Internal N cycling was much greater in aspen stands; annual N input in litterfall was ten times greater, and net N mineralization rates were two to five times greater than in jack pine stands. Nitrogen use efficiency (NUE) was much greater in jack pine when calculated based on N litterfall indices, but not when N pools in biomass were considered. Despite differences in internal cycling among forest types, nitrate leaching from mineral soil in both forest types was negligible (〈0.1 kg N ha −1  year −1 ) and patterns of 15 N in roots, foliage, and mineral soil were typical of N-limited ecosystems, and both sites show no evidence of N saturation. Content Type Journal Article Pages 1-13 DOI 10.1007/s11270-011-0833-6 Authors Dayna L. Laxton, Environmental and Life Sciences, Trent University, 1600 West Bank Drive, Peterborough, ON K9J 7B8, Canada Shaun A. Watmough, Environmental and Life Sciences, Trent University, 1600 West Bank Drive, Peterborough, ON K9J 7B8, Canada Julian Aherne, Environmental and Life Sciences, Trent University, 1600 West Bank Drive, Peterborough, ON K9J 7B8, Canada Journal Water, Air, & Soil Pollution Online ISSN 1573-2932 Print ISSN 0049-6979
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  • 49
    Publication Date: 2011-06-15
    Description:    Alberta’s oil sands are located in the boreal forest where surface mining requires reconstruction of these landscapes using waste saline and sodic overburden (SSOB) piles. The impact of these SSOB materials, however, on root development of planted boreal species is unknown. The objective of this study was to examine the effect of SSOB material on the root distributions of planted boreal species. Root distributions for planted mixedwood stands were measured using soil cores and compared with soil physical and chemical properties on three reclaimed sites. Soil pH ranged from 6.1 to 7.5 across all three reclaimed sites. Sodium adsorption ratio ranged from 〈30 in the SSOB at the youngest site to 〈4 at the oldest site while soil electrical conductivity ranged from 〈12 and 〈4 dS m −1 in the SSOB at the youngest and oldest site, respectively. Root length distributions were concentrated in the upper 30 cm of the soil profile and ranged from 0.96 to 7.99 cm cm −3 . The roots were observed in the SSOB and accounted for 1.3% to 2.2% of the total root length in the profile. The root length density was also negatively correlated with Na and EC at all sites. The root distributions on these young reclaimed sites were similar to those from undisturbed boreal forest stands overlying saline soils, suggesting that root distributions on these reclaimed sites appear to be unaffected by the SSOB; however, further monitoring will be required as the stand matures to determine future impacts of the SSOB on forest productivity. Content Type Journal Article Pages 1-17 DOI 10.1007/s11270-011-0852-3 Authors Heidi Lazorko, Department of Soil Science, University of Saskatchewan, 51 Campus Drive, Saskatoon, SK, Canada S7N 5A8 Ken C. J. Van Rees, Department of Soil Science, University of Saskatchewan, 51 Campus Drive, Saskatoon, SK, Canada S7N 5A8 Journal Water, Air, & Soil Pollution Online ISSN 1573-2932 Print ISSN 0049-6979
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  • 50
    Publication Date: 2011-06-15
    Description:    Phosphorus (P) delivered by urban rainfall–runoff partitions and speciates during the transport process. This study examines transport and speciation of P in rainfall and runoff across 15 wet weather events from a paved source area dominated by biogenic loads and to a lesser degree, anthropogenic loads. The mean and median event-based source area total phosphorus is 3.6 and 3.5 mg/l, respectively. The mean and median event-based source area dissolved fraction ( f d ) are 0.31 and 0.32 illustrating that P is predominately bound to particulate matter fractions. The majority of events across the monitoring campaign produce a weak mass-limited transport of dissolved phosphorus (DP). With respect to the DP fraction in runoff (pH range of 6.4 to 8.6), the dominant species are orthophosphates (HPO 4 −2 and H 2 PO 4 − ) which account for more than 90% of DP mass. The order of species predominance is consistently HPO 4 −2  ≈ H 2 PO 4 −  〉〉 CaHPO 4  〉 MgHPO 4 . With rainfall pH ranging from 4.2 to 4.9 and a f d  ≈ 1.0, H 2 PO 4 − accounts for 95% to 99% of DP in rainfall. Despite the inherent variability of a large dataset (362 samples across 15 events) the speciation of DP is influenced primarily by pH, with a range from 4.2 (rainfall) up to 8.6 (runoff) that results in an order of magnitude change in P species concentration and determines the order between the dominant orthophosphate species. For this source area, the role of alkalinity, dissolved organic carbon and partitioning on DP speciation are minor compared to the influence of pH. Content Type Journal Article Pages 1-15 DOI 10.1007/s11270-011-0829-2 Authors Christian Berretta, Environmental Engineering Sciences, University of Florida, 114 Black Hall, Gainesville, FL 32611, USA John Sansalone, Environmental Engineering Sciences, University of Florida, 114 Black Hall, Gainesville, FL 32611, USA Journal Water, Air, & Soil Pollution Online ISSN 1573-2932 Print ISSN 0049-6979
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  • 51
    Publication Date: 2011-06-22
    Description:    Corrosion resistance of tantalum, titanium, and a number of carbon materials in a NaOH melt in the atmosphere of argon was studied in the temperature range 400–700°C. Content Type Journal Article Pages 854-858 DOI 10.1134/S1070427211050193 Authors N. A. Medvedeva, Bashkir State University, Ufa, Bashkortostan, Russia R. Kh. Yumagulova, Institute of Organic Chemistry, Ufa Scientific Center, Russian Academy of Sciences, Ufa, Bashkortostan, Russia I. A. Ionova, Institute of Organic Chemistry, Ufa Scientific Center, Russian Academy of Sciences, Ufa, Bashkortostan, Russia S. I. Kuznetsov, Institute of Organic Chemistry, Ufa Scientific Center, Russian Academy of Sciences, Ufa, Bashkortostan, Russia S. V. Kolesov, Institute of Organic Chemistry, Ufa Scientific Center, Russian Academy of Sciences, Ufa, Bashkortostan, Russia Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 5
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    Topics: Chemistry and Pharmacology
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  • 52
    Publication Date: 2011-06-22
    Description:    Sorption properties of the weakly basic complex-forming sorbent bis-1,3,5-dithiazinane-5-yl-ethane with respect to Pd(II), Ag(I), and Hg(II) were studied. The sorbent was prepared from ethylenediamine, formic aldehyde, and H 2 S by a single-reactor procedure. Content Type Journal Article Pages 786-791 DOI 10.1134/S1070427211050089 Authors G. R. Anpilogova, Institute of Organic Chemistry, Ufa Scientific Center, Russian Academy of Sciences, Ufa, Russia N. S. Akhmadiev, Institute of Organic Chemistry, Ufa Scientific Center, Russian Academy of Sciences, Ufa, Russia G. R. Khabibullina, Institute of Organic Chemistry, Ufa Scientific Center, Russian Academy of Sciences, Ufa, Russia V. R. Akhmetova, Institute of Organic Chemistry, Ufa Scientific Center, Russian Academy of Sciences, Ufa, Russia Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 5
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  • 53
    Publication Date: 2011-06-22
    Description:    The mechanism of methyl methacrylate polymerization in the presence of 1,3,5-trithiane was studied. Content Type Journal Article Pages 873-876 DOI 10.1134/S1070427211050223 Authors E. I. Yarmukhamedova, Institute of Organic Chemistry, Ufa Scientific Center, Russian Academy of Sciences, Ufa, Bashkortostan, Russia Yu. I. Puzin, Institute of Organic Chemistry, Ufa Scientific Center, Russian Academy of Sciences, Ufa, Bashkortostan, Russia I. A. Ionova, Institute of Organic Chemistry, Ufa Scientific Center, Russian Academy of Sciences, Ufa, Bashkortostan, Russia Yu. B. Monakov, Institute of Organic Chemistry, Ufa Scientific Center, Russian Academy of Sciences, Ufa, Bashkortostan, Russia Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 5
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  • 54
    Publication Date: 2011-06-22
    Description:    Changes in the redox and antiradical properties of humic acids upon exposure to monochromatic UV light of an excilamp and polychromatic light of a helium lamp were studied. Content Type Journal Article Pages 820-825 DOI 10.1134/S1070427211050144 Authors N. V. Yudina, Institute of Oil Chemistry, Siberian Branch, Russian Academy of Sciences, Tomsk, Russia O. N. Chaikovskaya, Tomsk State University, Tomsk, Russia I. V. Sokolova, Tomsk State University, Tomsk, Russia E. V. Mal’tseva, Institute of Oil Chemistry, Siberian Branch, Russian Academy of Sciences, Tomsk, Russia L. V. Nechaev, Tomsk State University, Tomsk, Russia Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 5
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  • 55
    Publication Date: 2011-06-22
    Description:    Protective efficiency of preservation materials based on spent motor oil and unrefined rapeseed oil with a zinc filler and additions of micrographite or multilwalled carbon nanotubes was studied. Content Type Journal Article Pages 803-810 DOI 10.1134/S1070427211050119 Authors N. V. Shel’, Tambov State Technical University, Tambov, Russia A. O. Golovchenko, Tambov State Technical University, Tambov, Russia V. I. Vigdorovich, Tambov State Technical University, Tambov, Russia L. E. Tsygankova, Derzhavin State University, Tambov, Russia Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 5
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  • 56
    Publication Date: 2011-06-22
    Description:    The specific surface area, micropore volume, and pore size distribution for the Zr(IV), Sn(IV), and Ti(IV) oxyhydrates and double hydrates of the composition M x Mn 1− x O y · n H 2 O and M x Al1 − x O y · n H 2 O [M = Zr(IV), Sn(IV), Ti(IV), x = 0.5–0.9 were calculated. The specific surface charge and zero-charge point in 0.12 M KNO 3 were determined. Content Type Journal Article Pages 756-761 DOI 10.1134/S107042721105003X Authors T. V. Mal’tseva, Vernadsky Institute of General and Inorganic Chemistry, National Academy of Sciences of Ukraine, Kiev, Ukraine T. V. Yatsenko, Vernadsky Institute of General and Inorganic Chemistry, National Academy of Sciences of Ukraine, Kiev, Ukraine E. O. Kudelko, Vernadsky Institute of General and Inorganic Chemistry, National Academy of Sciences of Ukraine, Kiev, Ukraine V. N. Belyakov, Vernadsky Institute of General and Inorganic Chemistry, National Academy of Sciences of Ukraine, Kiev, Ukraine Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 5
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  • 57
    Publication Date: 2011-06-22
    Description:    Heat of mixing of binary systems was studied formed by acrylic acid with hexane, benzene, acetonitrile, 1,2-dichloroethane and acetic acid at 293.15 K and atmospheric pressure. Content Type Journal Article Pages 898-901 DOI 10.1134/S1070427211050284 Authors V. V. Sergeev, Lviv Polytechnic National University, Lviv, Ukraine V. N. Dibrivnyi, Lviv Polytechnic National University, Lviv, Ukraine Yu. Ya. Van-Chin-Syan, Lviv Polytechnic National University, Lviv, Ukraine Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 5
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  • 58
    Publication Date: 2011-06-22
    Description:    A procedure was developed for preparation of lithium and sodium hypothiophosphates from the corresponding alkali-metal and phosphorus sulfides in ethanol. The possibility was explored for preparation of tin(II) hypothiophosphate in an alcoholic solution by an exchange reaction between sodium hypothiophosphate and tin(II) chloride. Content Type Journal Article Pages 762-765 DOI 10.1134/S1070427211050041 Authors S. N. Svirskaya, Southern Federal University, Rostov-on-Don, Russia T. G. Lupeiko, Southern Federal University, Rostov-on-Don, Russia A. S. Pakhomov, Southern Federal University, Rostov-on-Don, Russia E. S. Medvedeva, Southern Federal University, Rostov-on-Don, Russia Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 5
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  • 59
    Publication Date: 2011-06-23
    Description:    Arsenic occurs in the earth's crust in various chemical forms as a result of both natural and anthropogenic sources. Soil chemical extractions may help understand As availability, as well as the possibility of As entry into the food chain. Phytoextraction has been proposed as a technology for remediation of As-contaminated soils. The study was carried out to assess the bioavailability of As by extractants and to compare the performance of castor bean and sunflower for As removal from soils. Two soils were contaminated with Na 2 HAsO 4 .7H 2 O adding 35 and 150 mg As dm −3 soil. Arsenic availability was assessed using the following extractants: tri-distilled water, ammonium sulfate, ammonium phosphate, ammonium oxalate + oxalic acid, organic acids mixture, Mehlich-1, and United States Environmental Protection Agency 3051. The roots and shoots of 35-day-old plants were collected and dry matter yield as well as As concentration were determined. The accumulation of As in shoot was also calculated in order to evaluate the plants potential for As phytoextraction. The extractants tested were efficient to assess the concentration of available As in soil. Addition of As to the soils did not cause severe toxicity in plants, although the dose 150 mg As dm −3 soil decreased shoot and root yield in both species. Castor bean was less sensitive to As than sunflower, but none of the species had hyperaccumulation characteristics. These species can be used for revegetation of areas contaminated with As up to safe limit of 150 mg As dm −3 soil, as proposed by CONAMA for industrial areas in Brazil. Content Type Journal Article Pages 1-8 DOI 10.1007/s11270-011-0853-2 Authors Évio E. C. Melo, Department of Engineering and the Environment, Federal University of Paraíba, Rio Tinto, Paraíba, Brazil CEP-58297-000 Luiz R. G. Guilherme, Department of Soil Science, Federal University of Lavras, Lavras, Minas Gerais, Brazil CEP 37200-000 Clistenes W. A. Nascimento, Department of Agronomy, Rural Federal University of Pernambuco, Recife, Pernambuco, Brazil CEP 52171-900 H. G. V. Penha, Department of Soil Science, Federal University of Lavras, Lavras, Minas Gerais, Brazil CEP 37200-000 Journal Water, Air, & Soil Pollution Online ISSN 1573-2932 Print ISSN 0049-6979
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  • 60
    Publication Date: 2011-06-25
    Description:    Emissions of methane (CH 4 ), carbon dioxide (CO 2 ), and nitrous oxide (N 2 O) from a forested watershed (160 ha) in South Carolina, USA, were estimated with a spatially explicit watershed-scale modeling framework that utilizes the spatial variations in physical and biogeochemical characteristics across watersheds. The target watershed (WS80) consisting of wetland (23%) and upland (77%) was divided into 675 grid cells, and each of the cells had unique combination of vegetation, hydrology, soil properties, and topography. Driven by local climate, topography, soil, and vegetation conditions, MIKE SHE was used to generate daily flows as well as water table depth for each grid cell across the watershed. Forest-DNDC was then run for each cell to calculate its biogeochemistry including daily fluxes of the three greenhouse gases (GHGs). The simulated daily average CH 4 , CO 2 and N 2 O flux from the watershed were 17.9 mg C, 1.3 g C and 0.7 mg N m −2 , respectively, during the period from 2003–2007. The average contributions of the wetlands to the CH 4 , CO 2 and N 2 O emissions were about 95%, 20% and 18%, respectively. The spatial and temporal variation in the modeled CH 4 , CO 2 and N 2 O fluxes were large, and closely related to hydrological conditions. To understand the impact of spatial heterogeneity in physical and biogeochemical characteristics of the target watershed on GHG emissions, we used Forest-DNDC in a coarse mode (field scale), in which the entire watershed was set as a single simulated unit, where all hydrological, biogeochemical, and biophysical conditions were considered uniform. The results from the field-scale model differed from those modeled with the watershed-scale model which considered the spatial differences in physical and biogeochemical characteristics of the catchment. This contrast demonstrates that the spatially averaged topographic or biophysical conditions which are inherent with field-scale simulations could mask “hot spots” or small source areas with inherently high GHGs flux rates. The spatial resolution in conjunction with coupled hydrological and biogeochemical models could play a crucial role in reducing uncertainty of modeled GHG emissions from wetland-involved watersheds. Content Type Journal Article Pages 1-13 DOI 10.1007/s11270-011-0855-0 Authors Zhaohua Dai, CSRC, EOS, University of New Hampshire, 8 College Rd., Durham, NH 03824, USA Carl C. Trettin, CFWR, USDA Forest Service, 3734 Highway 402, Cordesville, SC 29434, USA Changsheng Li, CSRC, EOS, University of New Hampshire, 8 College Rd., Durham, NH 03824, USA Harbin Li, CFWR, USDA Forest Service, 3734 Highway 402, Cordesville, SC 29434, USA Ge Sun, EFETAC, SRS, USDA Forest Service, 920 Main Campus Dr., Raleigh, NC 27606, USA Devendra M. Amatya, CFWR, USDA Forest Service, 3734 Highway 402, Cordesville, SC 29434, USA Journal Water, Air, & Soil Pollution Online ISSN 1573-2932 Print ISSN 0049-6979
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  • 61
    Publication Date: 2011-06-25
    Description:    Air pollutants emissions from traffic are very closely connected to urban air quality, in a local scale, as well as to global problems like climate change, in a large scale. Road transport air pollutants emissions represent, in most cases, a critical parameter for a comprehensive and successful understanding of the mechanisms governing the air pollutants concentrations. Hence, reliable estimations and comprehension of road transport emissions are indispensable in order to set reliable strategies in the direction of air pollution abatement and management of air pollutants and greenhouse gases emissions. In this framework, in the present work, the emissions of air pollutants from road transport in Greece will be presented for the whole period 1990–2009 as it was found that a detailed, accurate and reliable emissions inventory was missing. The whole period emissions variation has clarified the impact of the change in the vehicle fleet, the engine technologies and the fuel quality. The calculated results have revealed that the age of the vehicles and the corresponding engine technology are the critical parameters determining the amount of the pollutants emitted. This was mainly observed in both passenger cars and heavy duty vehicles demonstrating the importance of a renewal programme of the old circulating vehicles in order to set an effective air pollution abatement strategy. Passenger cars were found to be responsible for the major part of most air pollutants emissions except from nitrogen oxides and particulates emissions. Heavy duty vehicles contribute more than 66% to nitrogen oxides and particulates emissions. For the whole time period, all calculated pollutants present a decreasing trend, with the exception of carbon dioxide and nitrous oxide which increase constantly, ranging from −96% for sulphur dioxide to −1% for PM10. Content Type Journal Article Pages 1-13 DOI 10.1007/s11270-011-0859-9 Authors Athena Progiou, AXON Enviro-Group Ltd, 18 Troias str, 11257 Athens, Greece Ioannis Ziomas, Laboratory of Process Analysis and Design, School of Chemical Engineering, National Technical University of Athens, 9 Heroon Polytehneiou str., Zografou Campus, 15780 Athens, Greece Journal Water, Air, & Soil Pollution Online ISSN 1573-2932 Print ISSN 0049-6979
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  • 62
    Publication Date: 2011-06-28
    Description:    The clinoptilolite which was modified with sodium and potassium chloride was found to have adsorption capacity for rhodium. To evaluate the adsorption capacity and characteristics, the effects of solution pH, dose of clinoptilolite loading, contact time, temperature, and initial rhodium concentration were investigated in a batch mode. Adsorption was decreased with the increasing temperature for both modified clinoptilolites. The Langmuir and Freundlich adsorption models were used for mathematical description of the adsorption equilibrium. Equilibrium data were fitted to the Langmuir model in the concentrations of 2–60 mg l −1 at 293 and 313 K. Based on the Langmuir isotherm plots, the maximum adsorption capacity value was calculated to be 0.415 mg g −1 at 293 K. Various thermodynamic parameters such as ∆ G °, ∆ H °, and ∆ S ° were evaluated with results indicating that this system was an exothermic spontaneous reaction and kinetically suited to the pseudo-second-order model. Content Type Journal Article Pages 1-9 DOI 10.1007/s11270-011-0869-7 Authors Ömer Saltabaş, Ceha Jewellery & Chemistry Co., Molla Fenari Mah., Gazi Sinan Paşa Sok, No: 18/1, Cağaloğlu-Fatih, 34420 Istanbul, Turkey Murat Teker, Department of Chemistry, Sakarya University, 54100 Sakarya, Turkey Aslı Döver, Department of Chemistry, Sakarya University, 54100 Sakarya, Turkey Eylem Serpil Atay, Department of Chemistry, Sakarya University, 54100 Sakarya, Turkey Journal Water, Air, & Soil Pollution Online ISSN 1573-2932 Print ISSN 0049-6979
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  • 63
    Publication Date: 2011-06-09
    Description:    The method of colorimetric analysis based on the formation of colored β-silicon-molybdenum complex was used to study the formation kinetics of solutions of alkali metal silicates in the course of sol depolimerization. Content Type Journal Article Pages 351-356 DOI 10.1134/S1070427211030025 Authors N. A. Shabanova, Mendeleev Russian University of Chemical Engineering, Moscow, Russia Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 3
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  • 64
    Publication Date: 2011-06-09
    Description:    The effect of temperature factor on the efficiency of absorption of fluorine- and chlorine gas by a chemical absorbent, marble chips of a grade CA-MC, was researched. The degree of absorption of fluoride compounds at room temperature was 91%. The degree of recovery of total chlorine was 47.3%, that is because the low reactivity of the absorbent and an increase in an amount of Cl 2 in gases due to displacement of it by the fluorides from formed CaCl 2 . Calculation of thermodynamic characteristics of the processes showed that the equilibrium constant for the reaction of chlorine with CaCO 3 increased with a temperature growth, which proved larger intensity of the chlorine absorption by the hot absorbent. According to the suggested method, the gases containing chlorine fluorides successively passed through three distinct temperature zone of calcium carbonate: 230–600°C, 25–35°C and 300–600°C. In this case, the degree of recovery of fluorine compounds was 99%, and 98% of elemental chlorine was absorbed. Content Type Journal Article Pages 526-532 DOI 10.1134/S1070427211030347 Authors O. B. Gromov, JSC “Leading Research Institute of Chemical Technology”, Moscow, Russia Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 3
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  • 65
    Publication Date: 2011-06-09
    Description:    New linear and branched oligodialkylalkylhydrosiloxanes were prepared by hydrolytic cocondensation of various functional organosilanes with diethyl(dimethyl-)dichlorosilane, ethylhydro-(methylhydro-) dichlorosilane, and trimethylchlorosilane, followed by catalytic rearrangement in the presence of an electrophilic catalyst. The products are of interest as hydrophobizing agents and starting compounds for replacement of hydrogen atoms at silicon by other substituents. Content Type Journal Article Pages 491-496 DOI 10.1134/S107042721103027X Authors S. N. Natsyuk, State Research Institute of Chemistry and Technology of Organoelement Compounds, State Scientific Center of the Russian Federation, Moscow, Russia M. B. Lotarev, State Research Institute of Chemistry and Technology of Organoelement Compounds, State Scientific Center of the Russian Federation, Moscow, Russia T. V. Koroleva, State Research Institute of Chemistry and Technology of Organoelement Compounds, State Scientific Center of the Russian Federation, Moscow, Russia L. B. Skvortsova, State Research Institute of Chemistry and Technology of Organoelement Compounds, State Scientific Center of the Russian Federation, Moscow, Russia A. V. Kisin, State Research Institute of Chemistry and Technology of Organoelement Compounds, State Scientific Center of the Russian Federation, Moscow, Russia D. A. Cheshkov, State Research Institute of Chemistry and Technology of Organoelement Compounds, State Scientific Center of the Russian Federation, Moscow, Russia A. V. Kovalenko-Gorodetskaya, Lomonosov Moscow State Academy of Fine Chemical Technology, Moscow, Russia Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 3
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  • 66
    Publication Date: 2011-06-09
    Description:    Surface activity, capability for micelle formation of sodium and calcium salts of succinic acid monoalkyl esters and monoalkyl amides in aqueous solutions, and their waterproofing action in the microflotation of the calcium-containing mineral apatite were studied. The results obtained have been compared with similar data for saturated monocarboxylic acids. Content Type Journal Article Pages 361-367 DOI 10.1134/S1070427211030049 Authors G. V. Mitrofanova, Mining Institute, Kola Scientific Center, Russian Academy of Sciences, Apatity, Russia V. A. Ivanova, Mining Institute, Kola Scientific Center, Russian Academy of Sciences, Apatity, Russia Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 3
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  • 67
    Publication Date: 2011-06-09
    Description: Abstarct   The possibility was explored of synthesizing trans -isomers of 2-(4-hydroxystyryl)quinoline, 2-(4-hydroxystyryl)-7-chloroquinoline, 3-(4-hydroxystyryl)benzo[ f ]quinoline, and 6-(4-hydroxystyryl)-2,2′-bipyridine under uncatalyzed and solvent-free conditions using microwave irradiation. Content Type Journal Article Pages 507-509 DOI 10.1134/S107042721103030X Authors T. N. Gavrishova, Institute of Chemical Physics Problems, Russian Academy of Sciences, Chernogolovka, Moscow oblast, Russia V. M. Lee, Institute of Chemical Physics Problems, Russian Academy of Sciences, Chernogolovka, Moscow oblast, Russia K. V. Gor’kov, Institute of Chemical Physics Problems, Russian Academy of Sciences, Chernogolovka, Moscow oblast, Russia M. F. Budyka, Institute of Chemical Physics Problems, Russian Academy of Sciences, Chernogolovka, Moscow oblast, Russia Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 3
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  • 68
    Publication Date: 2011-06-09
    Description:    The heat resistance of copolymers of alkyl methacrylates with o -allylphenol was studied. The possibility of preparing viscosity additives that would be more resistant to heat than alkyl methacrylate homopolymers was examined. Content Type Journal Article Pages 676-678 DOI 10.1134/S1070427211040203 Authors A. I. Akhmedov, Kuliev Institute of Chemistry of Additives, National Academy of Sciences of Azerbaijan, Baku, Azerbaijan E. I. Gasanova, Kuliev Institute of Chemistry of Additives, National Academy of Sciences of Azerbaijan, Baku, Azerbaijan T. Kh. Akchurina, Kuliev Institute of Chemistry of Additives, National Academy of Sciences of Azerbaijan, Baku, Azerbaijan D. Sh. Gamidova, Kuliev Institute of Chemistry of Additives, National Academy of Sciences of Azerbaijan, Baku, Azerbaijan E. I. Isakov, Kuliev Institute of Chemistry of Additives, National Academy of Sciences of Azerbaijan, Baku, Azerbaijan Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 4
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  • 69
    Publication Date: 2011-06-09
    Description:    Mono- and diesters of N -benzoylaminoacetic acid, which exhibit high wear-preventive properties in a synthetic ester oil, were synthesized. Content Type Journal Article Pages 732-734 DOI 10.1134/S107042721104032X Authors A. A. Makhmudova, Azerbaijan State Pedagogical University, Baku, Azerbaijan N. S. Kyazimova, Azerbaijan State Pedagogical University, Baku, Azerbaijan V. S. Gasanov, Azerbaijan State Pedagogical University, Baku, Azerbaijan R. S. Mamedova, Azerbaijan State Pedagogical University, Baku, Azerbaijan Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 4
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  • 70
    Publication Date: 2011-06-09
    Description:    Kinetics of radiation-initiated polymerization of tetrafluoroethylene in acetone was studied at various initial concentrations (pressures) of the monomer in the reactor, which remain constant in the course of synthesis. Concentrated solutions of tetrafluoroethylene telomers were obtained and their properties were examined. Content Type Journal Article Pages 691-695 DOI 10.1134/S1070427211040239 Authors A. I. Bol’shakov, Institute for Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow oblast, Russia G. A. Kichigina, Institute for Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow oblast, Russia A. M. Kolesnikova, Institute for Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow oblast, Russia D. P. Kiryukhin, Institute for Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow oblast, Russia Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 4
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  • 71
    Publication Date: 2011-06-09
    Description:    The effect exerted by different extractants (cyclohexanone, dimethylamides of carboxylic acids C 10 -C 13 , and octanol-1), which are used for preparation of potassium heptafl uorotantalate, on its purity and characteristics of sodium-reduced tantalum powders was studied experimentally. Content Type Journal Article Pages 572-576 DOI 10.1134/S1070427211040021 Authors V. N. Kolosov, Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials, Kola Scientific Center, Russian Academy of Sciences, Apatity, Russia S. M. Masloboeva, Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials, Kola Scientific Center, Russian Academy of Sciences, Apatity, Russia T. Yu. Prokhorova, Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials, Kola Scientific Center, Russian Academy of Sciences, Apatity, Russia V. M. Orlov, Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials, Kola Scientific Center, Russian Academy of Sciences, Apatity, Russia M. N. Miroshnichenko, Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials, Kola Scientific Center, Russian Academy of Sciences, Apatity, Russia Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 4
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  • 72
    Publication Date: 2011-06-09
    Description:    Extraction of copper, nickel, zinc, and chromium from galvanic sludges by various complexons (pyrocatechol, phenanthroline, disodium ethylendiaminetetraacetate, and nitrilotrimethylenephosphonic acid) was considered. Content Type Journal Article Pages 727-729 DOI 10.1134/S1070427211040306 Authors M. V. Buzaeva, Ulyanovsk State Engineering University, Ulyanovsk, Russia O. A. Zaval’tseva, Ulyanovsk State Engineering University, Ulyanovsk, Russia O. A. Davydova, Ulyanovsk State Engineering University, Ulyanovsk, Russia V. V. Dubrovina, Ulyanovsk State Engineering University, Ulyanovsk, Russia E. S. Klimov, Ulyanovsk State Engineering University, Ulyanovsk, Russia Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 4
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  • 73
    Publication Date: 2011-06-09
    Description:    The product of condensation of tetraethoxysilane with diphenylsilanediol was studied by gel permeation chromatography, 29 Si NMR, and IR spectroscopy, and its structure was suggested. Content Type Journal Article Pages 685-690 DOI 10.1134/S1070427211040227 Authors A. V. Kalinin, Lebedev Research Institute of Synthetic Rubber, Federal State Unitary Enterprise, St. Petersburg, Russia D. M. Kostycheva, Lebedev Research Institute of Synthetic Rubber, Federal State Unitary Enterprise, St. Petersburg, Russia G. A. Nikolaev, Lebedev Research Institute of Synthetic Rubber, Federal State Unitary Enterprise, St. Petersburg, Russia L. V. Agibalova, Lebedev Research Institute of Synthetic Rubber, Federal State Unitary Enterprise, St. Petersburg, Russia B. Z. Volchek, Institute of Macromolecular Compounds, Russian Academy of Sciences, St. Petersburg, Russia Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 4
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  • 74
    Publication Date: 2011-06-15
    Description:    The homogeneity ranges with respect to the content of metal components in air were determined for yttrium and holmium manganites, based on X-ray phase analysis data for homogeneous solid solutions and heterogeneous compositions with the general formula Ln 2− x Mn x O 3±δ (Ln = Y, Ho) prepared by ceramic synthesis procedure in air at 900–1400°C. The results were presented as fragments of the composition-temperature phase diagrams of the Ln-Mn-O (Ln = Y, Ho) systems in air. Content Type Journal Article Pages 512-514 DOI 10.1134/S1070427211030323 Authors O. M. Fedorova, Institute of Metallurgy, Ural Branch, Russian Academy of Sciences, Yekaterinburg, Russia Yu. V. Golikov, Institute of Metallurgy, Ural Branch, Russian Academy of Sciences, Yekaterinburg, Russia Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 3
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  • 75
    Publication Date: 2011-06-22
    Description:    Corrosion resistance of tantalum, titanium, and a number of carbon materials in a NaOH melt in the atmosphere of argon was studied in the temperature range 400–700°C. Content Type Journal Article Pages 811-814 DOI 10.1134/S1070427211050120 Authors V. P. Yurkinskii, St. Petersburg State Polytechnic University, St. Petersburg, Russia E. G. Firsova, St. Petersburg State Polytechnic University, St. Petersburg, Russia L. P. Baturova, St. Petersburg State Polytechnic University, St. Petersburg, Russia Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 5
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  • 76
    Publication Date: 2011-06-22
    Description:    The behavior of asymmetric dimethylhydrazine was studied in helium and air-helium media with and without passage of electric current through the discharge unit of the reactor. The products of the corresponding transformations of asymmetric dimethylhydrazine were identified by the gas chromatography/mass-spectrometry technique. Content Type Journal Article Pages 826-831 DOI 10.1134/S1070427211050156 Authors M. V. Khmeleva, Research Institute of Chemistry, Lobachevsky Nizhi Novgorod State University, Nizhni Novgorod, Russia V. I. Faerman, Research Institute of Chemistry, Lobachevsky Nizhi Novgorod State University, Nizhni Novgorod, Russia A. D. Zorin, Research Institute of Chemistry, Lobachevsky Nizhi Novgorod State University, Nizhni Novgorod, Russia V. F. Zanozina, Research Institute of Chemistry, Lobachevsky Nizhi Novgorod State University, Nizhni Novgorod, Russia Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 5
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  • 77
    Publication Date: 2011-06-22
    Description:    Most widely occurring classes of carbon nanoparticles used to create polymeric composite systems are considered. The possibility is demonstrated of using “polymer-carbon nanoparticles” composites for raising the level of mechanical properties of polymeric materials, creating friction units with improved tribological characteristics, developing new electrochemical, microelectronic, and optical devices, and modifying barrier properties of polymeric membranes. Methods for treatment of nanoparticles to provide their compatibility with polymeric matrices and preclude their aggregation are discussed. Content Type Journal Article Pages 735-750 DOI 10.1134/S1070427211050016 Authors A. M. Valenkov, Belyi Institute for Mechanics of Metal-Polymer Systems, State Research Institution, National Academy of Sciences of Belarus, Gomel, Belarus I. V. Gofman, Institute of Macromolecular Compounds, Russian Academy of Sciences, St. Petersburg, Russia K. S. Nosov, Belyi Institute for Mechanics of Metal-Polymer Systems, State Research Institution, National Academy of Sciences of Belarus, Gomel, Belarus V. M. Shapovalov, Belyi Institute for Mechanics of Metal-Polymer Systems, State Research Institution, National Academy of Sciences of Belarus, Gomel, Belarus V. E. Yudin, Institute of Macromolecular Compounds, Russian Academy of Sciences, St. Petersburg, Russia Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 5
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  • 78
    Publication Date: 2011-06-22
    Description:    By visual-polythermal method in the range 5–25°C we studied phase equilibria and critical phenomena in a ternary system potassium nitrate-water-triethylamine, where its component, binary liquid system, is stratified at the lower critical solution temperature. Content Type Journal Article Pages 798-802 DOI 10.1134/S1070427211050107 Authors D. G. Cherkasov, Saratov State University, Saratov, Russia K. K. Il’in, Saratov State University, Saratov, Russia Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 5
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  • 79
    Publication Date: 2011-06-22
    Description:    Effect of type and consumption of fluorine reagents (HF, NH 4 F·HF, NH 4 F and NaF) on the deposition of rare earth elements from the wet-process phosphoric acid of the dihydrate process was examined. Content Type Journal Article Pages 773-781 DOI 10.1134/S1070427211050065 Authors E. P. Lokshin, Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials, Kola Scientific Center, Russian Academy of Sciences, Apatity, Russia O. A. Tareeva, Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials, Kola Scientific Center, Russian Academy of Sciences, Apatity, Russia I. R. Elizarova, Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials, Kola Scientific Center, Russian Academy of Sciences, Apatity, Russia Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 5
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  • 80
    Publication Date: 2011-06-22
    Description:    The oxidation resistance of polyethylene films in which the antioxidant is concentrated exclusively in the surface layer of the polymer or in the layer contacting with the support was studied. Specific features of oxidation of polyethylene films with heterogeneous distribution of an amine (Neozon D) or phenolic (Irganoks 1010) antioxidant on a catalytically active copper support were examined in relation to the kind of the antioxidant. Content Type Journal Article Pages 877-881 DOI 10.1134/S1070427211050235 Authors D. G. Lin, Skorina Gomel State University, Gomel, Belarus E. V. Vorob’eva, Skorina Gomel State University, Gomel, Belarus Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 5
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  • 81
    Publication Date: 2011-06-22
    Description:    The flocculating performance of a cationic polyelectrolyte, copolymer of N,N -dimethyl- N,N -diallylammonium chloride with acrylamide, in the recovery of butadiene-styrene rubber from latex was studied in relation to the concentrations of the dispersed phase and acidifying agent and to the temperature. Content Type Journal Article Pages 882-887 DOI 10.1134/S1070427211050247 Authors S. S. Nikulin, Voronezh State Academy of Technology, Voronezh, Russia T. N. Poyarkova, Voronezh State University, Voronezh, Russia V. M. Misin, Institute of Biochemical Physics, Russian Academy of Sciences, Moscow, Russia Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 5
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  • 82
    Publication Date: 2011-06-22
    Description:    New polymeric guanidinium and phosphonium salts derived from amino acids and polysulfones were prepared. Content Type Journal Article Pages 867-872 DOI 10.1134/S1070427211050211 Authors M. N. Gorbunova, Institute of Technical Chemistry, Ural Branch, Russian Academy of Sciences, Perm, Russia Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 5
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  • 83
    Publication Date: 2011-06-22
    Description:    Maleopimar adducts of tall colophony esters with alcohols-telomers 1 H ,1 H ,5 H -perfluoropentane-1-ol, 1 H ,1 H ,7 H -perfluoroheptane-1-ol, and 1 H ,1 H ,9 H -perfluorononane-1-ol were synthesized in conditions of Diels-Alder reaction. Content Type Journal Article Pages 895-897 DOI 10.1134/S1070427211050272 Authors L. M. Popova, St. Petersburg State Technological University of Vegetative Polymers, St. Petersburg, Russia Yu. A. Dmitrieva, St. Petersburg State Technological University of Vegetative Polymers, St. Petersburg, Russia S. V. Vershilov, St. Petersburg State Technological University of Vegetative Polymers, St. Petersburg, Russia Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 5
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  • 84
    Publication Date: 2011-06-28
    Description:    Since swine wastewater is used by farmers for soil fertilization, evaluation of toxic compounds or micro-contaminants of separate streams is required. This paper uses the toxicity identification evaluation (TIE) procedure for the physicochemical and ecotoxicological characterization of swine wastewater. To distinguish the most important toxic compounds, a physicochemical characterization and phase I-TIE procedure were performed. The acute toxic effect of swine wastewater and treated fractions (phase II-TIE) were evaluated using Daphnia magna determining 48-h LC 50 . Results show a high level of conductivity (23.5 μS cm −1 ), which is explained as due to the concentration of ions, such as ammonium (NH 4 + –N 1.6 g L −1 ), sulfate (SO 4 2−  397.3 mg L −1 ), and chlorine (Cl −  1,230.0 mg L −1 ). The acute toxicity of the swine wastewater was evaluated on D. magna (48-h LC 50  = 3.4%). Results of the different water treatments indicate that anionic exchange treatments could reduce 22.5% of swine wastewater’s acute toxicity by reducing chlorine (to around 51%) and conductivity (8.5%). On the other hand, cationic exchange treatment increased acute toxicity on D. magna (% RT = −624.4%), by reducing NH 4 + –N (around 100%) and total nitrogen (95.5%). This finding suggests that part of the toxicity comes from anionic compounds, such as chlorine. Content Type Journal Article Pages 1-7 DOI 10.1007/s11270-011-0864-z Authors C. Alejandra Villamar, Engineering and Biotechnology Environmental Group, Environmental Science Center EULA—Chile, University of Concepción, P.O. Box 160-C, Concepción, Chile Teresa Cañuta, Engineering and Biotechnology Environmental Group, Environmental Science Center EULA—Chile, University of Concepción, P.O. Box 160-C, Concepción, Chile Marisol Belmonte, Engineering and Biotechnology Environmental Group, Environmental Science Center EULA—Chile, University of Concepción, P.O. Box 160-C, Concepción, Chile Gladys Vidal, Engineering and Biotechnology Environmental Group, Environmental Science Center EULA—Chile, University of Concepción, P.O. Box 160-C, Concepción, Chile Journal Water, Air, & Soil Pollution Online ISSN 1573-2932 Print ISSN 0049-6979
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    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 85
    Publication Date: 2011-06-28
    Description:    The objective of this study was to investigate the effects of adding different rates of diethylenetriamine pentaacetate (DTPA) at different concentrations (0, 0.5, 1, and 5 mmol kg −1 ) and ethylenediamine disuccinate (EDDS) at 0, 5, 7.5, and 10 mmol kg −1 on the capacity of Brussels sprouts plants to take up Se from soils contaminated with 0, 5, 10, and 15 mg kg −1 NaSeO 4 , under a greenhouse conditions. Results indicated that the application of DTPA and EDDS to Se-contaminated soils significantly affect plant Se concentration, Se uptake, and dry matter yield of plants. Se concentration in the plant leaves, stems, and roots increased with increase in DTPA and EDDS application doses, but total Se uptake increased from 0 to 1.0 and 7.5 mmol kg −1 DTPA and EDDS application doses, respectively, and decreased after those levels due to toxic Se concentration for plant. Most plant available fractions and the carbonate, metal oxide, and organic matter-bound fractions increased linearly with Se application. At all DTPA and EDDS application rates, the Se concentrations in the leaves were about two to three times higher than those in the roots and about three to four times higher than those in the stems. This study suggests that the above-ground organs like leaf and shoots of Brussels sprouts can effectively be used in the removal of Se from soils contaminated with Se. Under the conditions in this experiment, Brussels sprouts were capable of removing 0.9–1.8 mg Se pot −1 when harvested at maturity without any chelating agent take into consideration one growing season per year. Based on the data of present experiment, it would be necessary to approximately 57–67 growing seasons without EDDS and EDTA to remove all total Se from polluted soil. Selenium removal can be further increased 12- to 20-fold with 7.5 mmol kg −1 EDDS and 1.0 mmol kg −1 DTPA application, respectively. Content Type Journal Article Pages 1-12 DOI 10.1007/s11270-011-0863-0 Authors Aslıhan Esringü, Department of Soil Science, Faculty of Agriculture, Ataturk University, Erzurum, 25240 Turkey Metin Turan, Department of Soil Science, Faculty of Agriculture, Ataturk University, Erzurum, 25240 Turkey Journal Water, Air, & Soil Pollution Online ISSN 1573-2932 Print ISSN 0049-6979
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  • 86
    Publication Date: 2011-06-09
    Description:    The mechanism of photoreduction of silver particles from colloidal solutions in 2-hydroxyethyl methacrylate, followed by its photopolymerization for preparing antirefl ection coatings, is considered. Content Type Journal Article Pages 666-669 DOI 10.1134/S1070427211040185 Authors P. A. Muzalev, Saratov State Technical University, Saratov, Russia I. D. Kosobudskii, Saratov State Technical University, Saratov, Russia D. M. Kul’batskii, Saratov State Technical University, Saratov, Russia N. M. Ushakov, Saratov Branch, Kotel’nikov Institute of Radio Engineering and Electronics, Russian Academy of Sciences, Saratov, Russia V. Ya. Podvigalkin, Saratov Branch, Kotel’nikov Institute of Radio Engineering and Electronics, Russian Academy of Sciences, Saratov, Russia Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 4
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  • 87
    Publication Date: 2011-06-09
    Description:    Cationic polymerization of dicyclohexylpropane diglycidyl ether in the presence of boron trifluoride was studied with the aim to prepare hybrid coatings. Content Type Journal Article Pages 708-712 DOI 10.1134/S1070427211040264 Authors N. G. Leonova, Donetsk National University, Donetsk, Ukraine V. M. Mikhal’chuk, Donetsk National University, Donetsk, Ukraine V. I. Rybachenko, Litvinenko Institute of Physical Organic and Coal Chemistry, National Academy of Sciences of Ukraine, Donetsk, Ukraine R. G. Semenova, Litvinenko Institute of Physical Organic and Coal Chemistry, National Academy of Sciences of Ukraine, Donetsk, Ukraine V. A. Beloshenko, Galkin Donetsk Physicotechnical Institute, National Academy of Sciences of Ukraine, Donetsk, Ukraine Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 4
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    Topics: Chemistry and Pharmacology
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  • 88
    Publication Date: 2011-06-09
    Description:    Reaction of ethylene oxide with methyl mercaptan in the presence of a catalyst, a solution of potassium hydroxide in methyl(β-oxyethyl) sulfide, was studied. Various technological procedures for synthesis of methyl(β-oxyethyl) sulfide were analyzed. The process conditions providing a 98–99% conversion of the starting reagents at a selectivity of 97–98% were suggested. Content Type Journal Article Pages 632-639 DOI 10.1134/S1070427211040136 Authors O. I. Tuzhikov, Volgograd State Technical University, Volgograd, Russia T. V. Khokhlova, Volgograd State Technical University, Volgograd, Russia S. B. Zotov, Volgograd State Technical University, Volgograd, Russia S. A. Orlova, Volgograd State Technical University, Volgograd, Russia Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 4
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    Topics: Chemistry and Pharmacology
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  • 89
    Publication Date: 2011-06-10
    Description:    Field experiments were conducted to assess the influence of plant growth and amendment addition on phytostabilisation of copper (Cu), lead (Pb), manganese (Mn) and zinc (Zn) along highway soil in southwest British Columbia, Canada. The plant species tested were Lolium perenne L (perennial rye grass), Festuca rubra L. (creeping red fescue) and Poa pratensis L. (Kentucky blue grass) and the amendments, lime and phosphate. The treatment efficiencies were assessed during different seasons as a completely randomized factorial experiment in split plot design. The research tasks involved: (1) quantifying the seasonal extent of metal accumulation in soil and assessing the seasonal impact on metal speciation for different soil amendments and plant species; (2) determining seasonal accumulation differences between sampling periods in plant parts; and (3) assessing the influence of root–soil interactions on metal dynamics. The amendments decreased the exchangeable fraction and plant uptake of all four metals. The lowest mobile fractions (exchangeable and carbonate bound) were found in soils growing Festuca for Cu, Lolium for Mn and a Lolium/Poa/Festuca combination for Pb and Zn. Metal accumulation and metal dynamics in the rhizosphere soil are compared with those of the bulk soil. The final outcome was the development of a remediation strategy for all four metals involving suitable plants and amendments and incorporating seasonal and rhizosphere influences. Content Type Journal Article Pages 1-18 DOI 10.1007/s11270-011-0843-4 Authors Prabha K. Padmavathiamma, Faculty of Land and Food Systems, University of British Columbia, 2357 Main Mall, Vancouver, BC V6T 1Z4, Canada Loretta Y. Li, Department of Civil Engineering, University of British Columbia, 6250 Applied Science Lane, Vancouver, BC V6T 1Z4, Canada Journal Water, Air, & Soil Pollution Online ISSN 1573-2932 Print ISSN 0049-6979
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    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 90
    Publication Date: 2011-06-10
    Description:    One of the main environmental impacts of concentrated animal feeding operations is the soil degradation in vicinity with the livestock breeding facilities due to substances such as ammonia emitted from the various stages of the process. Owing to the high temperatures of the Mediterranean ecosystems, the evolution of gasses is more extensive and the soil degradation is consequently more severe than those obtained in northern Europe. In this research, the soil degradation effects of a large meat-producing, processing, and packaging unit have been investigated. The investigated intensive hog farming operation (IHFO) is located at a limestone soil coastal area with sea to the north and hills to the south. Soil samples of the upper mineral soil were taken in various distances and directions from the IHFO boundaries. Thirteen experimental cycles were carried out in the duration of 1.5 years starting in March 2009 until October 2010. The soil samples were analyzed on pH and electrical conductivity (EC) values as well as NH 4 + and NO 3 − concentrations. Significantly higher concentrations of the two nitrogen forms were observed on samples at increasing proximity downwind from the farm (south). Southern soil average NH 4 + and NO 3 − concentrations ranged between 0.4–118 μg NH 4 + -N g −1 soil and 6.1–88.4 μg NO 3 − -N g −1 soil, respectively. The variation of emitted gasses depositions was clearly reflected in the average pH and EC values. Average pH and EC values downwind from IHFO boundaries varied between 7.1–8.2 and 140–268 μS/cm, respectively. Content Type Journal Article Pages 1-11 DOI 10.1007/s11270-011-0848-z Authors Stylianos Liodakis, Laboratory of Inorganic and Analytical Chemistry, Department of Chemical Engineering, National Technical University of Athens (N.T.U.A.), 9 Iroon Polytechniou Street, Athens, 157 80 Greece Charalampos Michalopoulos, Laboratory of Inorganic and Analytical Chemistry, Department of Chemical Engineering, National Technical University of Athens (N.T.U.A.), 9 Iroon Polytechniou Street, Athens, 157 80 Greece Elpida Efthymiou, Laboratory of Inorganic and Analytical Chemistry, Department of Chemical Engineering, National Technical University of Athens (N.T.U.A.), 9 Iroon Polytechniou Street, Athens, 157 80 Greece Georgios Katsigiannis, Laboratory of Inorganic and Analytical Chemistry, Department of Chemical Engineering, National Technical University of Athens (N.T.U.A.), 9 Iroon Polytechniou Street, Athens, 157 80 Greece Journal Water, Air, & Soil Pollution Online ISSN 1573-2932 Print ISSN 0049-6979
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  • 91
    Publication Date: 2011-06-15
    Description:    Tributyltin (TBT) is a very effective biocide and an active ingredient in antifouling paints. Screening along the Indian coast yielded 49 bacterial isolates capable of TBT assimilation. The screening was done based on the ability of bacteria to grow in mineral salt medium (MSM) containing TBT as the sole source of carbon. All the isolates produced exopolysaccharides (biosurfactants) in the medium which aid in emulsification and thus ease bioavailability of TBT. Five isolates were identified as potent TBT degraders (namely, Pseudomonas pseudoalcaligenes , Pseudomonas stutzeri , Pseudomonas mendocina , Pseudomonas putida , and Pseudomonas balearica ) based on their biomass production in MSM containing TBT as the sole source of carbon. In addition to evaluating the potential of individual bacterial strains, the study also focused on using a consortium of bacteria to explore their synergistic effect when grown on TBT. Further tests like growth profile, rhamnolipid secretion profile, extracellular protein secretion profile, and detection of siderophores were performed on these isolates when grown in MSM supplemented with 2 mM TBT concentration. Emulsification activity of the crude extracellular polysaccharides against kerosene was evaluated. It can be therefore inferred that TBT degradation by these marine pseudomonads is a two-step process: (a) dispersion of TBT in the aqueous phase and (b) tin–carbon bond cleavage by siderophores affecting debutylation of TBT. The consortium of bacteria may be effective in the treatment of TBT-contaminated waste water in dry docks. Content Type Journal Article Pages 1-8 DOI 10.1007/s11270-011-0842-5 Authors Ramya Sampath, National Institute of Ocean Technology (NIOT), Velachery-Tambaram Main Road, Pallikaranai, Chennai, 600100 India Harish Venkatakrishnan, National Institute of Ocean Technology (NIOT), Velachery-Tambaram Main Road, Pallikaranai, Chennai, 600100 India Vijaya Ravichandran, National Institute of Ocean Technology (NIOT), Velachery-Tambaram Main Road, Pallikaranai, Chennai, 600100 India Rajat Roy Chaudhury, National Institute of Ocean Technology (NIOT), Velachery-Tambaram Main Road, Pallikaranai, Chennai, 600100 India Journal Water, Air, & Soil Pollution Online ISSN 1573-2932 Print ISSN 0049-6979
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  • 92
    Publication Date: 2011-06-22
    Description:    Separation of aqueous isopropanol solutions by pervaporation using membranes based on composites of a polyimide with an aniline-anthranilic acid copolymer was studied. Content Type Journal Article Pages 840-846 DOI 10.1134/S107042721105017X Authors A. Yu. Pulyalina, St. Petersburg State University, St. Petersburg, Russia G. A. Polotskaya, St. Petersburg State University, St. Petersburg, Russia L. M. Kalyuzhnaya, Institute of Macromolecular Compounds, Russian Academy of Sciences, St. Petersburg, Russia I. G. Sushchenko, Institute of Macromolecular Compounds, Russian Academy of Sciences, St. Petersburg, Russia T. K. Meleshko, Institute of Macromolecular Compounds, Russian Academy of Sciences, St. Petersburg, Russia A. V. Yakimanskii, Institute of Macromolecular Compounds, Russian Academy of Sciences, St. Petersburg, Russia M. V. Chislov, St. Petersburg State University, St. Petersburg, Russia A. M. Toikka, St. Petersburg State University, St. Petersburg, Russia Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 5
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    Topics: Chemistry and Pharmacology
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  • 93
    Publication Date: 2011-06-22
    Description:    Dissolution of copper in organic media in the presence of complexons, whose role is played by spatially hindered ortho -quinones with electron-acceptor substituents and acetylacetone, is considered. Content Type Journal Article Pages 892-894 DOI 10.1134/S1070427211050260 Authors M. V. Buzaeva, Ul’yanovsk State Technical University, Ul’yanovsk, Russia V. V. Dubrovina, Ul’yanovsk State Technical University, Ul’yanovsk, Russia O. A. Davydova, Ul’yanovsk State Technical University, Ul’yanovsk, Russia E. S. Klimov, Ul’yanovsk State Technical University, Ul’yanovsk, Russia Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 5
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  • 94
    Publication Date: 2011-06-22
    Description:    Adsorption capacities for water, carbon(IV) oxide, benzene, and linear hexane were determined for samples of X zeolite whose grains are entire aggregation of crystals with the maximum degree of exchange of sodium cations for cations of calcium, magnesium, potassium, and hydrogen. Content Type Journal Article Pages 782-785 DOI 10.1134/S1070427211050077 Authors I. N. Pavlova, Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, Ufa, Bashkortostan, Russia R. S. Ilibaev, Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, Ufa, Bashkortostan, Russia O. S. Travkina, Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, Ufa, Bashkortostan, Russia Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 5
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    Topics: Chemistry and Pharmacology
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  • 95
    Publication Date: 2011-06-22
    Description:    Specific features of adsorption-desorption of water vapor on the initial samples of valley-bog and raised-bog peat and on the samples modified with iron and aluminum salts were studied and interpreted in terms of the model of a process with two types of sorption sites. Content Type Journal Article Pages 792-797 DOI 10.1134/S1070427211050090 Authors L. B. Naumova, Tomsk State University, Tomsk, Russia T. S. Minakova, Tomsk State University, Tomsk, Russia E. B. Chernov, Surgut State University, Surgut, Khanty-Mansi autonomous okrug, Russia N. P. Gorlenko, Surgut State University, Surgut, Khanty-Mansi autonomous okrug, Russia I. A. Ekimova, Tomsk State University, Tomsk, Russia Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 5
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    Topics: Chemistry and Pharmacology
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  • 96
    Publication Date: 2011-06-22
    Description:    A layered magnesium silicate, an analog to natural talc, was synthesized by mechanical treatment of a mixture of magnesium hydroxide and hydrated silicic acid powders, as well as by heat treatment of aqueous dispersions containing magnesium hydroxide particles and silica sols prepared from different precursors. Content Type Journal Article Pages 751-755 DOI 10.1134/S1070427211050028 Authors B. N. Dudkin, Institute of Chemistry, Komi Scientific Center, Ural Division, Russian Academy of Sciences, Syktyvkar, Komi Republic, Russia O. A. Vasyutin, Institute of Chemistry, Komi Scientific Center, Ural Division, Russian Academy of Sciences, Syktyvkar, Komi Republic, Russia Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 5
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  • 97
    Publication Date: 2011-06-22
    Description:    The binding properties of the baddeleyite concentrate mechanically treated with the use of Portland cement and alumina clinkers as activator were studied. Content Type Journal Article Pages 766-772 DOI 10.1134/S1070427211050053 Authors B. I. Gurevich, Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw, Kola Scientific Center, Russian Academy of Sciences, Apatity, Murmansk oblast, Russia A. M. Kalinkin, Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw, Kola Scientific Center, Russian Academy of Sciences, Apatity, Murmansk oblast, Russia V. V. Tyukavkina, Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw, Kola Scientific Center, Russian Academy of Sciences, Apatity, Murmansk oblast, Russia E. V. Kalinkina, Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw, Kola Scientific Center, Russian Academy of Sciences, Apatity, Murmansk oblast, Russia Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 5
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  • 98
    Publication Date: 2011-06-22
    Description:    The properties of quaternary ammonium salts in water and in a dispersion of a film-forming agent were studied by viscometry, conductometry, and pH-metry. The colloidal particle sizes, critical micelle concentrations, and coagulation thresholds were determined. Content Type Journal Article Pages 888-891 DOI 10.1134/S1070427211050259 Authors E. N. Makarewicz, University of Technology and Life Sciences, Bydgoszcz, Poland A. V. Shiichuk, University of Technology and Life Sciences, Bydgoszcz, Poland I. D. Syrotyns’ka, National Medical University, Ivano-Frankovsk, Ukraine Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 5
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  • 99
    Publication Date: 2011-06-22
    Description:    The kinetics of low-temperature graft copolymerization of triethylene glycol dimethacrylate with Krasol LBH-3000 oligobutadiene rubber was studied in relation to the initial mixture composition at 20°C. The experimental kinetic data were compared with the results of calculation by the suggested equation. The copolymer compositions were calculated from the extraction data in relation to the initial mixture compositions. The binary copolymerization constants were calculated by the analytical and graphical methods. Content Type Journal Article Pages 902-905 DOI 10.1134/S1070427211050296 Authors Yu. A. Anisimov, Mechnikov Odessa National University, Odessa, Ukraine O. N. Nikolova, Mechnikov Odessa National University, Odessa, Ukraine Yu. N. Anisimov, Mechnikov Odessa National University, Odessa, Ukraine Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 5
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    Topics: Chemistry and Pharmacology
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  • 100
    Publication Date: 2011-06-22
    Description:    Kinetics of the reaction of 4-nitrobenzoic acid with ammonia, catalyzed by the system constituted by boric acid and PEG-400 poly(ethylene glycol), was studied. A catalysis mechanism was suggested, which consists in original synthesis of incomplete polyethylene glycol borate esters, formation on their basis of 4-nitrobenzoic acid borate esters, and their further amidation with ammonia. Content Type Journal Article Pages 815-819 DOI 10.1134/S1070427211050132 Authors L. Ya. Shteinberg, Institute of Chemical Technology and Industrial Ecology, Scientific and Technical Institution, Rubezhnoe, Lugansk oblast, Ukraine Journal Russian Journal of Applied Chemistry Online ISSN 1608-3296 Print ISSN 1070-4272 Journal Volume Volume 84 Journal Issue Volume 84, Number 5
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    Topics: Chemistry and Pharmacology
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