Publication Date:
2018-07-05
Description:
Laser has dual role in mineralogy; minerals are used as a source of laser radiation and laser is employed in mineral analytical study. Therefore, we used spectroscopic methods to study Cr-bearing minerals, which are potential laser sources. Chemical composition was determined by XRF analysis, and shows that ruby is enriched in Fe, Ti and Cr, alexandrite contains Ti, Cr, Fe, Mg, Ca, and Si, spinel has increased Si, Cr, V, Fe, and Ca, and uvarovite contains Ti, V, Fe, and Mn along with major Cr. The luminescence spectra of ruby samples measured by Raman spectrometer have two very narrow and intense bands between 690 and 698 nm. Alexandrite has a broad luminescence band in the 640 – 780 nm region and has two intense bands at 680 and 710 nm. The spinel luminescence bands occur in the region ranged from 673 to 725 nm, are broader than in ruby, but still intensive. Uvarovite has a broad band in the region between 655 and 950 nm. Strong luminescence emission in ruby at about 695 nm and in alexandrite between 640 and 780 nm can be attributed to the laser effect – spontaneous emission due to the energy transition from metastable E to basic A2 state. This is also manifested in the optical spectra; there is an intensive transmission in the spectral region, where the luminescence laser effect occurred.Laser has dual role in mineralogy; minerals are used as a source of laser radiation and laser is employed in mineral analytical study. Therefore, we used spectroscopic methods to study Cr-bearing minerals, which are potential laser sources. Chemical composition was determined by XRF analysis, and shows that ruby is enriched in Fe, Ti and Cr, alexandrite contains Ti, Cr, Fe, Mg, Ca, and Si, spinel has increased Si, Cr, V, Fe, and Ca, and uvarovite contains Ti, V, Fe, and Mn along with major Cr. The luminescence spectra of ruby samples measured by Raman spectrometer have two very narrow and intense bands between 690 and 698 nm. Alexandrite has a broad luminescence band in the 640 – 780 nm region and has two intense bands at 680 and 710 nm. The spinel luminescence bands occur in the region ranged from 673 to 725 nm, are broader than in ruby, but still intensive. Uvarovite has a broad band in the region between 655 and 950 nm. Strong luminescence emission in ruby at about 695 nm and in alexandrite between 640 and 780 nm can be attributed to the laser effect – spontaneous emission due to the energy transition from metastable E to basic A2 state. This is also manifested in the optical spectra; there is an intensive transmission in the spectral region, where the luminescence laser effect occurred.
Print ISSN:
1338-0044
Electronic ISSN:
1338-5674
Topics:
Geosciences
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