ALBERT

Description: New, commensurate members of the fluorite-related Bi 3 Nb 1− x Ta x O 7 family were synthesized and their crystal structures, microstructures, and microwave (MW) dielectric properties were characterized. The incorporation of Ta into the tetragonal Bi 3 Nb 1− x Ta x O 7 solid solution was found to gradually affect the density and the MW dielectric properties. The materials sintered at 870°C exhibited relative permittivities in the range k ′ = 86–72, Q  ×  f values from 793 to 1189 GHz and a positive temperature coefficient of resonant frequency from 88 to 12 ppm/K. The formation of the members of the fluorite-related solid solution along the Bi 3 Nb 1− x Ta x O 7 composition depends on a phase transition, and thus their properties are compared within the compositional range. The correlations between their MW dielectric properties, compositions, crystal structures, and processing parameters were discussed in detail. Optimization of MW properties can be achieved by utilizing the ability of the Bi 3 Nb 1− x Ta x O 7 solid solution that it undergoes a phase transformation from cubic to tetragonal structure which are both characterized by unique properties, under certain synthesis conditions.

Description: Transparent novel glass-ceramics containing Sr 2 YbF 7 :Er 3+ nanocrystals were successfully fabricated by melt-quenching technique. Their structural and up-conversion luminescent properties were systemically investigated by XRD, HRTEM, and a series of spectroscopy methods. The temperature-dependent up-conversion spectra prove that 2 H 11/2 and 4 S 3/2 levels of Er 3+ are thermally coupled energy levels (TCEL). Consequently, the 2 H 11/2 4 I 15/2 and 4 S 3/2 4 I 15/2 emissions of Er 3+ in Sr 2 YbF 7 :Er 3+ glass-ceramics can be used as optical thermometry based on fluorescence intensity ratio (FIR) technique. Combined with low phonon energy and high thermal stability, Er 3+ ions in Sr 2 YbF 7 glass-ceramics present broad operating temperature range (300–500 K), large energy gap of TCEL (786 cm −1 ) and high theoretical maximum value of relative sensitivity (62.14 × 10 −4  K −1 at 560 K), which suggests that Sr 2 YbF 7 :Er 3+ glass-ceramics may be excellent candidates for optical temperature sensors.

Description: The relationship between soil fauna and different fertilizer management practices is of growing concern. The aim of this research was to investigate the response of soil fauna to fertilization regimes, to explore the relationships among the community of soil animals, soil moisture and crop yields. The application of organic fertilizers (i.e., sheep manure or crop residues) increased crop yields and promoted the number of individuals and species of soil fauna owing to the exogenous organic matter that fertilizers provided for the survival and development of soil fauna. Furthermore, the treatments that applied sheep manure (i.e., sheep manure only or nitrogen, phosphorus, potassium and sheep manure plus) were significantly beneficial for increasing crop yields and diversity of soil fauna compared to treatments with crop residues returned (i.e., crop residues returned only or nitrogen, phosphorus, potassium and crop residues returned to the field) (p 〈 0.05) due to the response of soil fauna to diverse exogenous nutrients and the effect of soil fertility. Therefore, the finding that soil fauna abundance is significantly positively correlated with soil moisture and crop yield may mean the effects of fertilizer applications on soil animals were partly masked by the soil moisture and crop yield.

Description: This paper provides an overview of the main manufacturing technologies of displays, focusing on those with low and ultra-low levels of power consumption, which make them suitable for current societal needs. Considering the typified value obtained from the manufacturer’s specifications, four technologies—Liquid Crystal Displays, electronic paper, Organic Light-Emitting Display and Electroluminescent Displays—were selected in a first iteration. For each of them, several features, including size and brightness, were assessed in order to ascertain possible proportional relationships with the rate of consumption. To normalize the comparison between different display types, relative units such as the surface power density and the display frontal intensity efficiency were proposed. Organic light-emitting display had the best results in terms of power density for small display sizes. For larger sizes, it performs less satisfactorily than Liquid Crystal Displays in terms of energy efficiency.

Description: This study forecasts the liquidity gap in China’s pension scheme for urban workers in the context of an ageing population and the possible effects of recent governmental policies by constructing a basic pension model, including “old people”, “middle people” and “new people” and a simulation method. We find, firstly, that China’s liquidity gap of pension will reach its peak of approximately 13.11 trillion yuan in 2038. Subsequently, this gap will gradually decrease with growth in the mortality rate. Secondly, reasonable intervals for the replacement and contribution rates should be set at [0.417, 0.604] and [0.189, 0.262], respectively, to sustain China’s pension system. Thirdly, compared to increasing fiscal subsidies, an income doubling plan, raising the contribution rate, lowering the replacement rate and delaying the retirement age can significantly reduce the liquidity gap, although the policy costs are relatively high. A policy permitting families to have two children will increase the rate of reduction of the liquidity gap, but it cannot effectively narrow the gap at the peak moment.

Description: During the last few years, the issues of energy efficiency and energy saving have dominated the buildings research field. New constructions are based on efficient design and, because of this, the real challenge is to retrofit existing buildings. Italian standards impose thermal transmittance limits for opaque and transparent surfaces, according to the climatic area. In order to understand buildings’ energy behavior, an accurate analysis, carried out by employing advanced calculation codes and instrumental diagnosis—provided by the use of heat flow meter, surface temperature probes and thermal imaging camera—is needed. In this paper, a structure built in the 50 s has been analyzed, by means of a measurement campaign, to investigate the building’s characteristics and its vulnerability. Finally, some retrofit hypotheses have been evaluated by means of a well-known dynamic code. All investments have to be analyzed under a financial point of view, considering materials and installation costs. For this reason, the payback time has been calculated in order to understand how quickly the energy upgrading can be repaid.

Description: Accurate information on the interactions between water and silica is critical to the understanding of its properties including mechanical strength under stress and long-term chemical durability of silica and silicate glasses. In this study, interactions between water and nanoporous amorphous silica models were investigated using density functional theory (DFT) based ab initio molecular dynamics (AIMD) simulations which accurately describe bond breakage and formation as well as chemical reactions. AIMD simulations up to 30 ps were performed for systems containing water and nanoporous silica with a wide range of porosities (31%–67%). Partial removal of defects, such as two-membered rings, was observed during the AIMD runs whereas more reactive coordination defects were removed during the initial geometry optimization. The limited two-membered ring removal can be attributed to restricted water-defect movement or the increased stability of rings located on concave surfaces. Two-membered ring removal mechanisms included the formation of an overcoordinated silicon (Si 5 ) intermediate defect from the dynamic simulations. Si 5 defects continued to develop throughout the simulations, indicating a thermodynamic drive for two-membered ring removal which is kinetically limited. Changes in the electronic structures, such as atomic charges, and bond length-bond angle correlation functions were monitored during the hydroxylation process.

Description: Amorphous calcium polyphosphate (ACPP), an inorganic polymer ceramic, has shown promise as a drug delivery matrix following a repeat gelling protocol. This study described a simple method of preparing ACPP hydrogel in the presence of an excess volume of water. The increased water availability accelerates water molecule ingress and microstructural transformation of ACPP hydrogels. The impact of some experimental settings (soaking time, temperature, stirring, and ACPP particle size) on the physiochemical and rheological natures of ACPP hydrogel were investigated and from which possible hydrogel formation mechanisms were inferred. We believe that the formation of ACPP hydrogel is through the mechanisms of intermolecular ionic interaction and entanglement of polyphosphate chains. The potential application of ACPP hydrogel as a ceramic matrix for sustained drug release warrants further investigation.

Description: Melting gels are hybrid gels that have the ability to soften and flow at around 100°C for some combinations of mono- and di-substituted alkoxysiloxanes, where substitutions are either all aromatic or all aliphatic. In this study, melting gels were prepared using phenyltriethoxysilane (PhTES) and dimethyldiethoxysilane (DMDES), meaning both an aromatic and aliphatic substitution. Differential scanning calorimetry was performed to identify glass-transition temperatures, and thermal gravimetric analysis coupled with differential thermal analysis (TGA-DTA) was performed to measure weight loss. The glass-transition temperatures ( T g ) ranged from −61°C to +5.6°C, which are between the values in the methyl only system, where all T g values are less than 0°C, and those values in the phenyl only system, where T g values are greater than 0°C. The T g decreased with an increase in the DMDES fraction. Below 450°C, the gels lost little weight, but around 600°C there was a drop in weight. This temperature is lower than the temperature for gels prepared with only aromatic substitutions, but higher than that for gels prepared with only aliphatic substitutions. Final heat treatment was carried out at 150°C for the gel with 80%PhTES-20%DMDES (in mol%), and the consolidation temperature increased with increasing DMDES content to 205°C for the gel with 50%PhTES-50%DMDES. After this heat treatment, the melting gels no longer soften.

Description: Direct integration of nanostructures into macroscopic substrates is very important for their practical applications. In this work, we report a simple method that can be introduced for the Sn-catalyzed growth of alumina nanowires on ceramic substrates such as porous disk, monolith, and foam. Our study focuses on the role of the Sn catalysts in the formation mechanisms governing nanowire growth. Using the proposed approach, hair- or grass-like tufts of 20 nm diameter nanowires grow on the surface of the ~3 μm diameter Sn particles, in a tip growth mechanism. The nanowires of α-phased polycrystalline structure grow and are packed via a complex process involving batch-by-batch, branching, and amalgamation growth. The detailed observations reveal that the Sn catalyst is key to tailoring the growth patterns of the nanowires. In addition, cathodoluminescence studies highlight the potential optical applications of the alumina nanowires.

Description: Flash sintering is a nonlinear phenomenon characterized by a sharp increase in the conductivity of the sample and concomitant rapid densification under an electric field in low temperatures in a matter of seconds. Since it is a transient phenomenon, the power dissipation on the sample is not uniform during the process. Thus, a transient analysis is needed to estimate the temperature of the sample during flash sintering due to Joule heating. In this work, the Finite Element Method on a coupled electrothermal nonlinear analysis was used in order to obtain the specimen temperature of 8YSZ after 5 s of flashing. The results agree with the experimental data obtained by the flashing of dense samples and with previous literature.

Description: Temperature-dependent in-situ Raman spectroscopy is used to investigate the phase transformation of zinc metastannate (ZnSnO 3 ) to zinc orthostannate (Zn 2 SnO 4 ) induced upon annealing in the ambient. ZnSnO 3 microcubes (MCs) were synthesized at room temperature using a simple aqueous synthesis process, followed by characterization using electron microscopy, X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, and thermogravimetric analysis (TGA). Annealing of the ZnSnO 3 MCs was carried out up to 1000°C, while recording the Raman spectra in-situ at regular intervals. Phase transformation from metastannate to orthostannate was found to begin around 500°C with an activation energy of ~0.965 eV followed by the recrystallization into the inverse spinel orthostannate phase at ~750°C. Results from this study provide detailed understanding of the phase transformation behavior of perovskite ZnSnO 3 to inverse spinel Zn 2 SnO 4 upon thermal annealing.

Description: Congestion pricing strategy has been recognized as an effective countermeasure in the practical field of urban traffic congestion mitigation. In this paper, a bi-level programming model considering carbon dioxide emission is proposed to mitigate traffic congestion and reduce carbon dioxide emissions. The objective function of the upper level model is to minimize the sum of travel costs and the carbon dioxide emissions costs. The lower level is a multi-modal transportation network equilibrium model. To solve the model, the method of successive averages (MSA) and the shuffled frog leaping algorithm (SFLA) are introduced. The proposed method and algorithm are tested through the numerical example. The results show that the proposed congestion pricing strategy can mitigate traffic congestion and reduce carbon emissions effectively.

Description: The internet and associated Information and Communications Technologies (ICT) are diffusing at an astounding pace. As data centers (DCs) proliferate to accommodate this rising demand, their environmental impacts grow too. While the energy efficiency of DCs has been researched extensively, their water footprint (WF) has so far received little to no attention. This article conducts a preliminary WF accounting for cooling and energy consumption in DCs. The WF of DCs is estimated to be between 1047 and 151,061 m3/TJ. Outbound DC data traffic generates a WF of 1–205 liters per gigabyte (roughly equal to the WF of 1 kg of tomatos at the higher end). It is found that, typically, energy consumption constitues by far the greatest share of DC WF, but the level of uncertainty associated with the WF of different energy sources used by DCs makes a comprehensive assessment of DCs’ water use efficiency very challenging. Much better understanding of DC WF is urgently needed if a meaningful evaluation of this rapidly spreading service technology is to be gleaned and response measures are to be put into effect.

Description: Here, we demonstrate the relationship between glass network topological structure and the chemical state of embedded lanthanide ions. It is revealed that a more dispersed state of lanthanide ions is shown in more constrained 3D rigid network, which delivers valuable information toward homogeneous doping in glasses from the perspective of glass topological structure. The results are believed to be of great significances in the development of advanced optoelectronic devices like high-power laser, efficient fiber amplifier, smaller integrated photonic circuit, etc.

Description: The mechanofusion process, a dry particle coating route, has been successfully applied to coat micrometric SiC particles with submicrometric Ni filaments. In a first step, the mechanofusion parameters were optimized to form a continuous Ni coating onto SiC particles. In a second step, the Ni-coated SiC particles were sintered by hot isostatic pressing. The temperature and pressure cycles were determined to ensure a good densification of the material. Such a densification process leads to the formation of a δ-Ni 2 Si bilayer at the SiC/Ni interface; the inner δ-Ni 2 Si layer in contact with SiC being more rich in carbon than the one in contact with the matrix. From X-ray diffraction, wavelength-dispersive X-ray spectrometry and scanning electron microscopy characterizations, a mechanism is proposed to explain the microstructure of the end-product.

Description: According to the increasing worldwide attention to energy and the environmental performance of the building sector, building energy demand should be minimized by considering all energy uses. In this regard, the development of building components characterized by proper values of thermal transmittance, thermal capacity, and radiative properties is a key strategy to reduce the annual energy need for the microclimatic control. However, the design of the thermal characteristics of the building envelope is an arduous task, especially in temperate climates where the energy demands for space heating and cooling are balanced. This study presents a novel methodology for optimizing the thermo-physical properties of the building envelope and its coatings, in terms of thermal resistance, capacity, and radiative characteristics of exposed surfaces. A multi-objective approach is adopted in order to optimize energy performance and thermal comfort. The optimization problem is solved by means of a Genetic Algorithm implemented in MATLAB®, which is coupled with EnergyPlus for performing dynamic energy simulations. For demonstration, the methodology is applied to a residential building for two different Mediterranean climates: Naples and Istanbul. The results show that for Naples, because of the higher incidence of cooling demand, cool external coatings imply significant energy savings, whereas the insulation of walls should be high but not excessive (no more than 13–14 cm). The importance of high-reflective coating is clear also in colder Mediterranean climates, like Istanbul, although the optimal thicknesses of thermal insulation are higher (around 16–18 cm). In both climates, the thermal envelope should have a significant mass, obtainable by adopting dense and/or thick masonry layers. Globally, a careful design of the thermal envelope is always necessary in order to achieve high-efficiency buildings.

Description: In recent years, global climate change has altered precipitation patterns, causing uneven spatial and temporal distribution of precipitation that gradually induces precipitation polarization phenomena. Taiwan is located in the subtropical climate zone, with distinct wet and dry seasons, which makes the polarization phenomenon more obvious; this has also led to a large difference between river flows during the wet and dry seasons, which is significantly influenced by precipitation, resulting in hydrological drought. Therefore, to effectively address the growing issue of water shortages, it is necessary to explore and assess the drought characteristics of river systems. In this study, the drought characteristics of northern Taiwan were studied using the streamflow drought index (SDI) and Markov chains. Analysis results showed that the year 2002 was a turning point for drought severity in both the Lanyang River and Yilan River basins; the severity of rain events in the Lanyang River basin increased after 2002, and the severity of drought events in the Yilan River basin exhibited a gradual upward trend. In the study of drought severity, analysis results from periods of three months (November to January) and six months (November to April) have shown significant drought characteristics. In addition, analysis of drought occurrence probabilities using the method of Markov chains has shown that the occurrence probabilities of drought events are higher in the Lanyang River basin than in the Yilan River basin; particularly for extreme events, the occurrence probability of an extreme drought event is 20.6% during the dry season (November to April) in the Lanyang River basin, and 3.4% in the Yilan River basin. This study shows that for analysis of drought/wet occurrence probabilities, the results obtained for the drought frequency and occurrence probability using short-term data with the method of Markov chains can be used to predict the long-term occurrence probability of drought/wet events.

Description: Proper lighting is vital to improve, from an artistic point of view, the surface expanse and decorative detailing of architectural heritage buildings considered valuable. When properly lit, monumental buildings can become to onlookers an essential part of the city. Nowadays, for design planners dealing with the improvement of buildings, whose architectural design should be valorized, the real challenge is to combine the lighting artistic requirements with scrupulous economic management in order to limit the energy demand and to respect the environment. For these reasons, this case study examines the lighting of the monumental façade and the cloister of St. Peter in Chains situated in the Faculty of Engineering of Sapienza University of Rome. The present lighting installation, characterized by metal halides, compact fluorescent and halogen lamps, is compared with an alternative scenario presenting LED lamps and scenographic lighting of the monumental façade. Such comparison is based on the evaluation of the lighting levels for different visual tasks and on energy and maintenance issues; the first analysis was performed through the software DIALux Evo 4.0, whereas the second was performed using ecoCALC. This study leads to the conclusion that the lighting levels of the solution presenting LED lamps are better than those of the present solution, and they comply with current standards. Finally, the higher costs of LED lamp installations and the scenographic lighting of the monumental façade are balanced by lower maintenance costs, with a payback period of seven years.

Description: Customer expectations can be extremely nebulous. This research identifies the demographic segmentations and their respective expectations for the spa market. Interviews were conducted and a subsequent questionnaire was employed to gather the voice of the customer and assess the expectations of spa clientele. All of the data was collected from luxury spas in Hawaii, and consisted of respondents from all over the world. Results of the survey suggest that while men want more tangible benefits of a spa, women prefer the experiential qualities of peace and rejuvenation. Additionally, those of lower to middle income focus on the atmosphere more than wealthier clients, who are looking for more long term spa benefits, such as a more youthful appearance.

Description: Any World Heritage Cultural Landscape requires a clear boundary for administration. One of the administrative goals is sustainability. There is no widely identified way to demarcate the boundary of a World Heritage Cultural Landscape. This paper aims to explore a methodology framework to provide a holistic perspective for demarcating boundaries for a World Heritage Cultural Landscape. Honghe Hani Rice Terraces (HHRT) in Yunnan Province is a new World Heritage Cultural Landscape in China. We use it as a research area to illustrate the methodology framework. The framework of methodology is constructed based on four scales of a human-environment system identified by Anne Buttimer. It is used to describe the level of the sustainability of local economy, social organization, natural environment and people’s understanding of the human-environment. Four types of boundaries were investigated in this area. They are the boundary of Malizhai River Basin, the boundary of local water-allocation organization, the boundary of the economic network and the perceptual boundary of the human-environment system. With a comprehensive perspective, we integrated the four types of boundaries to judge the boundary of the core area of HHRT by three criteria, they are: Environmental sustainability, social justice, and the ability to create a new human-environment system. We conclude that some parts of the boundary of the core area of HHRT do not fit the criteria of sustainable development.

Description: The growth economy imposes multiple crises on humanity and the natural world. To challenge this economic growth imperative, the degrowth movement emerges as a dissident response. Although within an economic growth perspective, payments for ecosystem services (PES) have also been proposed to attenuate the negative impacts of capitalism, as a redistributive mechanism that is claimed to deliver equitable conservation and sustainability. Degrowth has notably similar concerns, although it is inclined to argue against PES traditional ideologies and practices, which lead conservation to perceive nature within economic growth and market ideologies, diminishing the relationship between humans and nature. In spite of that, PES are becoming a strong trend in environmental governance. This paper attempts to examine whether PES are, and how they could be suitable for degrowth, through the lens of its main sources. In order to integrate PES and degrowth, it could require a PES reconceptualization. Although we assert that PES are not the most appropriate instrument for conservation, we argue that maybe PES could contribute to degrowth as a transition instrument toward fostering better practices. However, it is important to elucidate how they can be used and under which circumstances they could be appropriate.

Description: This research paper aims at developing and applying a constructive weighting methodology for the elicitation of local stakeholders’ preferences regarding a set of sustainability evaluation criteria during the assessment of low-carbon energy technologies. The overall methodology has been applied and tested for the sustainability evaluation of selected low-carbon energy technologies in Europe from a local stakeholders’ perspective. The researchers applied a constructive weighting methodology based on different Multiple Criteria Analysis (MCA) techniques to test the consistency of stakeholders’ preferences. The methodology was piloted based on a small-scale European local stakeholders’ survey within the framework of Covenant CapaCITY, an Intelligent Energy Europe project that supports the development of Sustainable Energy Action Plans (SEAPs). It became evident that the local stakeholders who participated placed high priorities on aspects such as CO2eq emissions reduction, ecosystem damages reduction, and resilience to climate change during the evaluation of low-carbon energy technologies. Considering the overall energy technologies assessment, wind off-shore, solar PV, hydropower, and wind on-shore achieved the highest scores and better reflected the priorities of local stakeholders considering a large set of multiple sustainability criteria. The high number of criteria led to some inconsistencies of stakeholders’ preferences, confirming the need for consistency checks and/or combining different methods of preference elicitation.

Description: In this study, we allocate Greenhouse gas (GHG) emissions of electricity transmission to the consumers. As an allocation basis, we introduce energy distance. Energy distance takes the transmission load on the electricity energy system into account in addition to the amount of electricity consumption. As a case study, we estimate regional GHG emissions of electricity transmission loss in Chile. Life cycle assessment (LCA) is used to estimate the total GHG emissions of the Chilean electric power system. The regional GHG emission of transmission loss is calculated from the total GHG emissions. We construct the network model of Chilean electric power grid as an undirected network with 466 nodes and 543 edges holding the topology of the power grid based on the statistical record. We analyze the total annual GHG emissions of the Chilean electricity energy system as 23.07 Mt CO2-eq. and 1.61 Mt CO2-eq. for the transmission loss, respectively. The total energy distance for the electricity transmission accounts for 12,842.10 TWh km based on network analysis. We argue that when the GHG emission of electricity transmission loss is estimated, the electricity transmission load should be separately considered. We propose network theory as a useful complement to LCA analysis for the complex allocation. Energy distance is especially useful on a very large-scale electric power grid such as an intercontinental transmission network.

Description: Recently, as more people are concerned with the issues around environment protection, research about how to reduce carbon emissions has drawn increasing attention. Encouraging public transportation is an effective measure to reduce carbon emissions. However, overland public transportation does less to lower carbon because of the gradually increasing pressure of the urban road traffic. Therefore, the waterbus along the coast becomes a new direction of the urban public transport development. In order to optimize the operation plan of the waterbus, a bi-level model considering carbon emissions is proposed in this paper. In the upper-level model, a multiple objective model is established, which considers both the interests of the passengers and the operator while considering the carbon emissions. The lower-level model is a traffic model split by using a Nested Logit model. A NSGA-II (Non-dominated Sorting Genetic Algorithm-II) algorithm is proposed to solve the model. Finally, the city of Zhoushan is chosen as an example to prove the feasibility of the model and the algorithm. The result shows that the proposed model for waterbus operation optimization can efficiently reduce transportation carbon emissions and satisfy passenger demand at the same time.

Description: Multiple doping is widely used to improve the performance of a material, including its electrical transport, mechanical, and photovoltaic properties. In this paper, Sn–Se dual-doped Li 10 GeP 2 S 12 (LGPS, thio-LISICON II analogue) electrolytes were synthesized via ball milling and sintering and compared with those Sn or Se single-doped. Successful Sn and/or Se substitution expanded the unit cell and formed units, which were verified by X-ray powder diffraction, energy-dispersive X-ray spectroscopy, and Raman spectroscopy. In contrast to the limited benefits of Se single doping and the negative effects of Sn single doping, Sn–Se dual doping demonstrated up to 53% enhancement in ionic conductivity. More importantly, Sn–Se dual-doped LGPS showed an extremely low activation energy of 16 kJ/mol, which is one of the lowest known values for lithium ion conductors; as well as one of the widest electrochemical windows of 8 V. Sn–Se dual-doped LGPS is a promising electrolyte for advanced all-solid-state batteries.

Description: In room–corridor building geometry, the corridor smoke temperature is of great importance to fire protection engineering as indoor fires occur. Theoretical analysis and a set of reduced-scale model experiments were performed, and a virtual fire model was proposed, to investigate the correlations between the maximum smoke temperature in corridors and the smoke temperature in rooms. The results show that the dimensionless virtual fire heat release rate (HRR) is characterized by quadratic-polynomial of the dimensionless smoke temperature in fire rooms. The dimensionless distance from a virtual fire source to the corridor ceiling varies linearly with the dimensionless smoke temperature in a room. Results of multiple regression indicate that, at the impingement area of virtual fire, the dimensionless maximum smoke temperature in corridors is only related to the dimensionless virtual fire HRR; in the non-impingement area of a virtual fire, the dimensionless maximum smoke temperature in corridors is a function of the dimensionless virtual fire HRR and dimensionless longitude distance. The viscosity and conduction exhibit an insignificant impact on the maximum temperature in the corridor. Through replacing the parameters of virtual fire with the dimensionless smoke temperature in fire rooms, the correlations between dimensionless maximum temperature in corridors and the dimensionless smoke temperature in fire rooms were proposed.

Description: Changes in agriculture, including simultaneous intensification and abandonment, have significantly shaped the evolution of rural areas. The assessment of resilience in agricultural systems could provide insights into the ability of many rural areas to survive and regain competitiveness following disturbances. The aim of this study is to use the adaptive cycle heuristic as a diagnostic tool to study dynamics of change in two agricultural sectors (durum wheat/sheep and goat farming) in the Basilicata region of Southern Italy over the last seventy years. The heuristic was applied through a participatory approach in a community of stakeholders who have conceived, in collaboration with researchers, the Manifesto “Let’s Think Basilicata” as a regional instrument of analysis and a laboratory of ideas and development of proposals. Despite some methodological difficulties, the adaptive cycle heuristic proved useful to describe processes of change in the socio-ecological system and could have enormous potential in shaping policy instruments for rural areas. However, much greater research is needed, both in terms of theory and methodology, before policy impacts on resilience in socio-ecological systems can be fully understood.

Description: In developing countries, the drinking water supply is still an open issue. In sub-Saharan Africa, only 68% of the population has access to improved sources of drinking water. Moreover, some regions are affected by geogenic contaminants (e.g., fluoride and arsenic) and the lack of access to sanitation facilities and hygiene practices causes high microbiological contamination of drinking water in the supply chain. The Water Safety Plan (WSP) approach introduced by the World Health Organisation (WHO) in 2004 is now under development in several developing countries in order to face up to these issues. The WSP approach was elaborated within two cooperation projects implemented in rural areas of Burkina Faso and Senegal by two Italian NGOs (Non-Governmental Organisations). In order to evaluate its sustainability, a questionnaire based on five different sustainability elements and a cost and time consumption evaluation were carried out and applied in both the case studies. Results demonstrated that the questionnaire can provide a useful and interesting overview regarding the sustainability of the WSP; however, further surveys in the field are recommended for gathering more information. Time and costs related to the WSP elaboration, implementation, and management were demonstrated not to be negligible and above all strongly dependent on water quality and the water supply system complexity.

Description: The development of cities has always had a very close relation with water. However, cities directly impact land use patterns and greatly change natural landscapes, aggravating floods. Considering this situation, this paper intends to discuss lowland occupation and city sustainability in what regards urban stormwater management, fluvial space, and river restoration, aiming at minimizing flood risks and improving natural and built environment conditions. River plains tend to be attractive places for a city to grow. From ancient times, levees have been used to protect lowland areas along major watercourses to allow their occupation. However, urban rivers demand space for temporary flood storage. From a systemic point of view, levees along extensive river reaches act as canalization works, limiting river connectivity with flood plains, rising water levels, increasing overtopping risks and transferring floods downstream. Departing from this discussion, four case studies in the Iguaçu-Sarapuí River Basin, a lowland area of Rio de Janeiro State, Brazil, are used to compose a perspective in which the central point refers to the need of respecting watershed limits and giving space to rivers. Different aspects of low-lying city planning are discussed and analyzed concerning the integration of the built and natural environments.

Description: Polycrystalline Cd 1− x Ba x O (0 ≤  x  ≤ 0.08) ceramics were synthesized via conventional solid-state reaction method, and the effect of Ba 2+ doping on the microstructure as well as the thermoelectric transport properties of the samples were investigated. It was found that doping of Ba 2+ can inhibit the grain growth of CdO, resulting in a considerable reduction in grain size. Moreover, with the increase in Ba 2+ doping content, both the electrical conductivity and the thermal conductivity of Cd 1− x Ba x O decreased, whereas the Seebeck coefficient increased. A high ZT value of 0.47 was achieved for Cd 0.99 Ba 0.01 O at 1000 K, 38% higher than the undoped CdO, mostly due to reduction of the thermal conductivity.

Description: During the last few years, Italian dairy farms, which gather, process and sell milk at the national level, have strengthened their leading market position at the detriment of dairy cooperatives, operating within regional borders. Moreover, decreasing milk prices and increasing production costs have recently induced many farmers to open automatic vending machines, dispensing raw milk for direct sale to local consumers. In order to contribute to the environmental assessment of alternative systems, this study estimated CO2 emissions related to the transport from production farms to point of sale, for three brands of fresh milk currently sold in the Umbria region (Italy), starting from the food miles indicator as a simple concept, easily understood by consumers. These brands differ in the origin of milk (national, regional and local) and distribution channels (large-scale retail channels for national and regional brands and vending machines for the local one). Thus, we estimated the emissions generated by the transport of the fresh milk consumed by regional households. In agreement with previous studies about CO2 emissions of foreign milk supply chains, the analysis showed that the production system of regional-branded milk, sold by retail channels, is the most efficient in terms of the environmental impact of transport.

Description: The need and estimated utility for a structured analysis of the Roşia Montană gold exploitation project have been palpable in the Romanian public sphere during the last 15 years and there is a vast amount of conflicting information and opinions on the benefits and risks involved. This article provides a comprehensive decision analysis of the Roşia Montană project. Over 100 documents from the past years have been gathered regarding the Roşia Montană mining project, which cover the main official, formal and less formal documents covering the case and produced by a wide range of stakeholders. These were then analyzed while designing a multi-criteria tree including the relevant perspectives under which the most commonly discussed four alternatives were analyzed. The result of this can be translated into a valuable recommendation for the mining company and for the political decision-makers. If these stakeholders want the continuation of the project and its acceptance by civil society, the key challenge is to increase the transparency of the process and improve the credibility and legal aspects; if these aspects cannot be met, the decision-makers need to pay attention to the alternatives available for a sustainable development in the area.

Description: Crystalline argon oxygen decarburization slag, in powdery form, was investigated for its hydration potential by alkali activation and curing at 80°C. Na-silicate and K-silicate of the same modulus were used as activators. Isothermal calorimetry at 80°C indicated exothermic reactions in the slag pastes. When the slag mortars were cured under steam at 80°C appreciable gain in compressive strength was measured. This was attributed to C–S–H which was detected in TG, FTIR, and 29 Si NMR analyses. Upon hydration at 90 d, the amount of crystalline phases decreased, whereas the XRD amorphous content in the slag increased. Electron microscopy showed the formation of different morphologies of reaction products depending on the alkaline activator employed. Presence of reaction rims around the crystalline phases with a major presence of Ca, Si, and O in the reacted matrix was observed in elemental maps.

Description: The (1− x )BiFeO 3 - x BaTiO 3 (with x  = 0.1, 0.2, 0.3, and 0.4) ceramics were fabricated successfully by solid-state reaction method. Single-phase perovskite was obtained in all ceramics, as confirmed by XRD technique. It was observed that 0.7BiFeO 3 –0.3BaTiO 3 was the morphotropic phase boundary (MPB) between rhombohedral and cubic phases, as also revealed from ferroelectric and magnetic properties. The simulated and experimental X-Ray Absorption Spectroscopy (XAS) study revealed that BT in 0.75BF-0.25BT is possibly taken a rhombohedral structure. Furthermore, the rounded ferroelectric hysteresis loops observed for 0.9BiFeO 3 –0.1BaTiO 3 and 0.8BiFeO 3 –0.2BaTiO 3 compositions could be attributed to their microstructure and surface charge effects and electron transfer between Fe 3+ and Fe 2+ ions. It was also found that high dielectric constant of 0.9BiFeO 3 –0.1BaTiO 3 composition was a result of grain and grain-boundary effects, as observed in SEM micrographs. In addition, a strong signature of dielectric relaxation behavior was observed in this ceramic system with the activation energy 0.467 eV obtained from the Arrhenius' law. Finally, the local structure investigation with XAS technique provided additional information to better understand the electric and magnetic properties in the BF-BT ceramic system.

Description: We propose an ethical analysis as a method to reflect on how companies’ decisions promote sustainable development. The method proceeds by first identifying the choice according to financial business interests, and by then scrutinizing this choice according to consequentialist and deontological ethics. The paper applies the method to the choice of an Environmental Impact Assessment (EIA) that a consortium of Brazilian companies (EGASUR) delivered as part of their project proposal for the realization of the Inambari hydropower dam in the Peruvian Amazon. We show that if an EIA is chosen based on the attempt to maximize the financial bottom line, it raises ethical issues both from a consequentialist perspective by involving negative consequences for various stakeholder groups, and from a deontological perspective by not complying with relevant rules, guidelines, and principles. The two ethical perspectives hence reveal where the consortium faces impediments to a genuine commitment to sustainability. Building on stakeholder interviews, observations of the project developments, and the executive summary of the actual EIA, we provide indications that EGASUR has indeed made a choice that resembles a decision based on financial interests.

Description: An accurate assessment of a building’s wall performance, defined through the thermal transmittance, is essential to compute the annual energy consumption. Analyzing opaque surfaces, the heat transfer across walls can be modeled by an electro-thermal analogy, based on resistors series, crossed by a one-dimensional heat flow. This analogy is well established and it refers to stratigraphy composed of homogeneous materials. When dealing with inhomogeneous materials, possibly including hollow bricks, the wall’s thermal transmittance is evaluated by means of an effective conductance. However, in order to verify the theoretical models effectiveness, a comparison with in situ measurements is needed. In this paper, three building walls characterized by different stratigraphy have been analyzed; by employing a heat flow meter investigation. Measurements results and estimated thermal transmittance values—calculated applying the standard UNI EN ISO 6946—have been compared.

Description: With an increased awareness of sustainability issues, natural ventilation has become an elegant method for reducing the costs and environmental effects of the energy that is used to maintain comfortable indoor air quality rather than using mechanical ventilation. The windows in many industrial buildings are continuously open to exhaust pollutants and intake fresh air. Though windows are functional and efficient for natural ventilation, rainwater is able to penetrate through the windows during wind-driven rain. For industries in which the moisture content affects the quality of the product, the intrusion of a large amount of rainwater through windows must be prevented without compromising the effective ventilation. The aim of this research is to determine an innovative design for windows to accomplish the optimum of high ventilation and low rain penetration. For this purpose, windows are variously innovated and tested in full-scale measurements, reduced-scale wind-tunnel measurements and computational fluid dynamics (CFD). An artificial rain and wind velocity to mimic the average of the maximum values in Korea are created. The maximum reduction in rain penetration of over 98% compared to basic 90° open windows is attained with only a 4%–9% decrement of ventilation efficiency in the two recommended designs.

Description: The tree-growing sector is considered to be an important supplier of food and raw material for industry worldwide. Increasingly competitive decisions regarding international investment in orchards depend on business analysis. This study compares three apple orchards situated in Cluj-Napoca, on the Eastern limits of the Transylvanian Plain, Romania. While the climatic and soil conditions are relatively consistent among the three orchards, the technical and economic results (expressed in hectares) vary due to the use of three different technological systems of apple production: extensive, intensive, and super-intensive. The study compares the life cycle, starting with age of fructification, production level (quantity and quality), costs (investment and production costs—divided into material costs, mechanical costs, human costs, and overhead costs), income, profit (including rate of profit), and investment efficiency: Net Present Value (NPV), Internal Rate of Return (IRR), and Payback Period (PP). It was observed that the most economically efficient technological system in terms of investments is the super-intensive one, with a higher production level, a higher share of Extra Class apples, and a younger age of initial fructification. However certain inconveniences of this system—such as a more expensive investment, a higher cost of running the business throughout the year, and a reduced life cycle—cannot be ignored.

Description: In this study, ZnS powders with homogeneous morphology were synthesized using a colloidal processing method. Vacuum hot pressing was subsequently applied to consolidate the ZnS powders into infrared transparent ceramics (77.3% transmittance at wavelengths of 6.74 and 9.29 μm). The phase composition of the sintered ZnS suggests the presence of wurtzite as a minor phase in addition to the primary sphalerite phase, and microstructural analysis indicates that the ceramics are highly densified. It has been found that the VHP-sintered ZnS ceramics exhibit blue (450 nm) and green (530 nm) luminescence, which is due to the formation of zinc vacancies and sulfur interstitials, respectively, during the sintering process.

Description: In this study, tribological investigations were carried out on ZTA ceramics with 17 vol% Y-TZP and different stabilizer contents (1, 1.5, and 2 mol% yttria) to analyze the influence of zirconia transformation on wear properties. Samples were tested in a linearly reciprocating ball on flat setup with different applied loads. Raising the fracture toughness by transformation toughening, microcracking, and residual stresses improves the wear resistance only at transition load but increases the wear at high loads. Higher yttria content of 2 mol% and lower zirconia grain size and thus low transformability, decreases fracture toughness but increases the wear resistance at high loads. Therefore the adjustment of stabilizer content on zirconia volume fraction in ZTA plays a decisive role in tribological applications.

Description: Highly (100)-oriented 0.38Bi(Ni 1/2 Hf 1/2 )O 3 -0.62PbTiO 3 relaxor-ferroelectric films were fabricated on Pt(111)/Ti/SiO 2 /Si(111) substrates by introducing a lead oxide seeding layer. A moderate relative permittivity , a low dissipation factor (tan δ 〈 5%), and strong relaxor-like behavior (γ = 0.74) over a broad temperature region were observed. The energy storage density of approximately 45.1 ± 2.3 J/cm 3 was achieved for films with (100) preferential orientation, which is much higher than the value ~33.5 ± 1.7 J/cm 3 obtained from films with random orientation. Furthermore, the PbO-seeded films are more capable of providing larger piezoelectric response (~113 ± 10 pm/V) compared to the films without seeds (~85 ± 8 pm/V). These excellent features indicate that the highly (100)-oriented 0.38Bi(Ni 1/2 Hf 1/2 )O 3 -0.62PbTiO 3 films could be promising candidates for applications in high-energy storage capacitors, high-performance MEMS devices, and particularly for potential applications in the next-generation integrated multifunctional piezoelectric energy harvesting and storage system.

Description: Uniformly dispersed TiC nanoparticle strengthened In 4 Se 2.65 composites have been fabricated by a combined process of mechanical alloying (MA) and hot pressing (HP) successfully. Due to the good electrical conductivity and the extra phonon scattering effect of the TiC nanoinclusions, the electrical resistivity and thermal conductivity decrease with the TiC content up to 0.8 wt%, and a maximum ZT of 0.98 at 723 K was achieved in the sample with 0.8 wt% TiC. Taking account of the measurement uncertainly, the enhancement of ZT value by TiC nanoinclusions is less obvious. On the other hand, the mechanical performance of In 4 Se 2.65 can be effectively improved by TiC nanoinclusions due to the dispersive strengthening effect of the nanoinclusions , and the flexural strength of the sample with 0.8 wt% TiC is improved to 73 MPa, which is over 40% higher than that of the pristine sample.

Description: The radiation damage response of Ti 3 SiC 2 heated from 120°C to 850°C during 700 keV Si + irradiation has been investigated. The samples were analyzed using glancing incidence X-ray diffraction, Rutherford backscattering spectrometry, Raman spectroscopy, and scanning electron microscopy. For the sample at 120°C, irradiation results in a buildup of a heterogeneous surface and the formation of TiC x . Irradiation at 200°C results in maximum microstrain, a maximum in the c lattice parameter, and the appearance of a β phase in addition to the normal α phase of Ti 3 SiC 2. A minimum in the observed damage level near the surface was seen for irradiation at a sample temperature of 300°C but the damaged phase increases at higher temperatures. Differences between the present work and a previous C irradiation study have been ascribed to the enhanced Si defect transport at low temperatures.

Description: Water table control has been successfully tested to improve the sustainability of water management in cranberry production. In the province of Québec (Canada), three sites were investigated to determine the optimum water table depth below soil surface (WTD) using three criteria: (1) increasing yield without decreasing fruit quality; (2) minimizing the amount of water needed by the sprinkler system; and (3) avoiding hypoxic stresses in the rhizosphere. Our results show that the final yield, the berry sugar content, the total number of berries, the number of berries per upright, and the fruit set were maximized when the WTD was 60 cm. Sprinkler water savings of 77% were obtained where the WTD was shallower than 66 cm. In order to avoid hypoxic conditions due to poor drainage, the water level in the canals surrounding the beds should be lowered to 80 cm when a rainfall or a frost protection irrigation is anticipated. All sides of a block of beds must be surrounded by canals to ensure a uniform WTD and to avoid lateral hydraulic gradients that could cause peripheral seepage losses.

Description: Effective change order management is very important in maintaining the financial sustainability of various stakeholders related to construction projects by minimizing cost overruns. In this study, we propose a zero-cost risk management approach based on the collar option model in order to control for the loss caused by change orders, the main cause of cost overruns in construction projects. We apply this model to actual projects for empirical analysis. The analysis, based on 237 projects, indicates that insurance buyers benefit from the collar option model in 46% of the cases, while insurance sellers do so in 53% of the cases. In most cases, the insurance buyer is the owner. According to the model, the owner experiences a loss when the cost overrun caused by change orders is lower than what was expected. In such cases, it is appropriate to conclude that the loss is not caused by the collar option model, but by the absence of additional revenue. However, the insurance seller suffers a loss if the cost overrun is higher than the strike price of the call option. Thus, the insurance seller needs to have expertise in construction management.

Description: This study aimed to investigate the influence of the service encounter expectations of senior customers during wellness tours on customer satisfaction. The organizational attributes of hotels, organizational characteristics and employee characteristics, were adopted as mediating variables. A total of 346 valid questionnaires were retrieved from 50 year-old and above seniors in Taiwan. The results showed that the service encounter expectations of seniors had an indirect influence on customer satisfaction and the organizational attributes mediated the service encounter expectations of seniors and customer satisfaction. The moment of truth in the interactions between service staff members and seniors represents the pivotal management implication of this study.

Description: In higher education there is a growing demand for graduates with the competence to transform our society toward a sustainable future. Part of this competence in sustainability is anticipatory competence, the ability to engage with multiple futures, manage uncertainty and hold a worldview that the future can and should be steered toward a more just sustainable path. In order to further examine and operationalise anticipatory competence, a course “Sustainability and the Future” was developed and run in the University of Vechta, Germany, as part of an action research cycle exploring key competencies for sustainability in higher education. Reflective journaling was used to explore the competence acquisition process along with focus groups with students after the course. The analysis of this programme shows that while certain subject areas such as values, transport and population models provoke more critical reflection on the future, skills such as the ability to work with emotional aspects of the future, for instance hope, were perceived to be necessary for anticipatory competence.

Description: Smart cards are able to store and protect relatively large amounts of data. When applied in universities, they can act as multi-purpose, multi-function and smart ID cards. This would avoid the waste of resources and maintain environmental sustainability. This study proposes a model that integrates Technology Acceptance Model and Theory of Reasoned Action into a framework incorporating the notion of environmental concern in order to explore the factors that affect students’ behavioral intention to use University Smart Cards. This study employs a quantitative method for primary data collection via a structured questionnaire for university students. The findings indicated that the perceived usefulness and subjective norm of university smart card systems have the most significant predictive power on potential users’ attitudes and intentions of adopting the card.

Description: Tourism is perceived as an appropriate solution for pursuing sustainable economic growth due to its main characteristics. In the context of sustainable tourism, gamification can act as an interface between tourists (clients), organisations (companies, NGOs, public institutions) and community, an interface built in a responsible and ethical way. The main objective of this study is to identify gamification techniques and applications used by organisations in the hospitality and tourism industry to improve their sustainable activities. The first part of the paper examines the relationship between gamification and sustainability, highlighting the links between these two concepts. The second part identifies success stories of gamification applied in hospitality and tourism and reviews gamification benefits by analysing the relationship between tourism organisations and three main tourism stakeholders: tourists, tourism employees and local community. The analysis is made in connection with the main pillars of sustainability: economic, social and environmental. This study is positioning the role of gamification in the tourism and hospitality industry and further, into the larger context of sustainable development.

Description: Traditional rural landscapes emerged from the long term interaction of the natural and anthropogenic environment. These landscapes are now threatened by drastic social-ecological changes. Recent international trends on sustaining cultural landscapes place great emphasis on understanding of multiple values, presented in the landscape, by considering various stakeholder perspectives. It is now recognized that strong community engagement with the landscape should be translated into conservation and management practices. This paper aims to examine the recent conservation activities around endangered traditional rural landscapes in Korea through a case study of Gacheon village. In this village, since 2000, a series of central administrative measures have been implemented to revive the local community, and to conserve its distinctive landscape. By analyzing challenges to the site, by discussing conservation experience and lessons, and by recommending future strategies for sustaining its cultural landscapes, this paper is expected to provide a basis for future policy-making for safeguarding traditional rural landscapes.

Description: Greenhouse gas emissions have serious impacts on the natural environment. Therefore, the restrictions imposed on carbon emission force enterprises to take carbon emission into consideration when making production decisions. In this paper, in the context of allowing emission trading and investment of emission reduction technology, models were presented for a two-stage supply chain to analyze the optimal investment and pricing decisions. The results indicate that manufacturer’s endurance capacity of reduction difficulty is higher in the cooperation model than in the Stackelberg game model, and that perfect coordination of supply chains can be realized by a revenue sharing contract. From the perspective of a consumer, low-carbon products mean higher price, so that subsidies or tax exemptions should be provided to keep low prices. Meanwhile, the government can promote investment in emission-reduction technologies and achieve its emission reduction targets by controlling emission trading price, strengthening emission reduction publicity and providing technology investment subsidies.

Description: Electronic paper (e-paper) is a major sector of Taiwan’s Optoelectronic industry. It has paid much attention on the development of flexible displays. Even though the market is booming, the future is still unclear for business development. No research has yet forecasted the future market size of the e-paper industry. In addition, proposing an appropriate forecasting model to understand the trend of this industry plays a crucial role for market players and government’s authorities in formulating correct strategies. Therefore, in this paper, the future market size of Taiwan’s e-paper industry is predicted by an effective combined grey model. Two combinations of DGM(2,1) and Verhulst model with Fourier series and Markov chain, namely FM-Verhulst and FMDGM(2,1), were presented. Based on the annual data of Taiwan’s e-paper industry, the results show that the forecasting performances of two FM-Verhulst and FMDGM(2,1) models are highly accurate compared with other grey models. Precision is 96.36% and 97.77%, respectively. However, for long-term prediction, the FMDGM(2,1) model obtains the best performance in all proposed grey models. With obtained forecasting results in Taiwan’s e-paper industry by the FMDGM(2,1) model, it can be pointed out that the future market size of Taiwan’s e-paper would slowly increase in the next few years.

Description: ising global energy needs and limited fossil fuel reserves have led to increased use of renewable energies. In Germany, this has entailed massive exploitation of agricultural biomass for biogas generation, associated with unsustainable farming practices. Organic agriculture not only reduces negative environmental impacts, organic farmers were also prime movers in anaerobic digestion (AD) in Germany. This study’s aim was to identify the structure, development, and characteristics of biogas production associated with organic farming systems in order to estimate further development, as well as energetic and associated agronomic potentials. Surveys were conducted among organic farms with AD technology. 144 biogas plants could be included in the analysis. Total installed electrical capacity was 30.8 MWel, accounting for only 0.8% of the total installed electrical capacity in the German biogas sector. Recently, larger plant types (>250 kWel) with increased use of (also purchased) energy crops have emerged. Farmers noticed increases in yields (22% on average) and quality of cash crops in arable farming through integrated biogas production. In conclusion, although the share of AD in organic farming is relatively small it can provide various complementary socio-ecological benefits such as the enhancement of food output through digestate fertilization without additional need for land, while simultaneously reducing greenhouse gas emissions from livestock manures and soils. However, to achieve this eco-functional intensification, AD systems and their management have to be well adapted to farm size and production focus and based primarily on residue biomass.

Description: Research from a variety of disciplines suggests that online technologies (i.e., Web 2.0 and social media) have considerable potential for spurring proenvironmental action; however, relatively little work examines how to effectively capitalize on these communication and organization tools. This review paper describes the Technologies for Proenvironmental Action Model (TPAM), a conceptual framework that explicates how different functions of Web 2.0 and social media (i.e., informational, relational, and experiential) can generate and/or facilitate personal, social, and contextual pathways to environmentally responsible behaviors. As derived from the TPAM, the likelihood of achieving practical goals of increasing proenvironmental behaviors is enhanced when technological functions are matched to the different pathways to proenvironmental action. For example, the relational function of technologies, as exemplified by Social Networking Sites (SNSs), should be particularly effective in communicating social norms supportive of environmentally responsible behaviors. The TPAM is intended as a guide to develop novel approaches, research questions, and methodologies in leveraging Web 2.0 and social media technologies to promote proenvironmental action. Results will contribute to basic theory development and work in applied settings (e.g., local environmental organizations) in order to effectively communicate and organize with different segments of the population to increase sustainable behaviors.

Description: Sustainability reports are tools for disseminating information to stakeholders and the public, serving the organizations in the dual purpose of communicating CSR and being accountable. The production of these reports has recently become more prevalent in the food industry, despite the fact this practice has received heavy criticism on two fronts: The quality of the tool for communication, and the extent of accountability. In addition to these criticisms, organizations must overcome the additional challenge of publishing sustainability reports that successfully meet the demands of a multi-stakeholder audience. In light of the importance of this practice, this paper presents a method to assess the communication and accountability characteristics of Spanish food companies’ sustainability reports. This method is based on the method Analytic Network Process (ANP) and adopts a multi-stakeholder approach. This research, therefore, provides a reference model for improving sustainability reports, with the aim of successfully meeting their communication objectives and the demands of all stakeholders.

Description: This research is the first attempt of a carbon emission investigation of tourism-based farms. A total of 36 cases were investigated. The result reveals that each tourist returns an average revenue of 28.6 USD and generates an average 10.9 kg-CO2eq per visit of carbon emissions. The average carbon emission density for each land area is 8.2 t/ha·year and is 245 kg/m²·year for each floor area. It is estimated that the overall carbon emissions reach 321,751 tons annually. The tourism-based farms were clustered into five categories, based on their business characteristics. It was found that high-end vacation leisure farms produce 2.46 times the carbon emissions than natural eco-conservation farms. Carbon emissions were 42% higher than the annual average in July and August. A secondary high season is in February, but it is merely higher than the annual average by 8% because of the mild climate. Two significant models for predicting carbon emissions were constructed by stepwise regression. As agriculture administrative authorities in Taiwan gradually have begun admitting the cultivated lands for multi-purpose usage, tourism-based farms have been increasing drastically. This study provides references for both public authorities and farm managers in exploring the issues with regard to carbon emissions and farm sustainability.

Description: The metropolitan city of Istanbul is becoming overcrowded and the demand for clean water is steeply rising in the city. The use of analytical approaches has become more and more critical for forecasting the water supply and demand balance in the long run. In this research, Istanbul’s water supply and demand data is collected for the period during 2006 and 2014. Then, using an autoregressive integrated moving average (ARIMA) model, the time series water supply and demand forecasting model is constructed for the period between 2015 and 2018. Three important sustainability metrics such as water loss to supply ratio, water loss to demand ratio, and water loss to residential demand ratio are also presented. The findings show that residential water demand is responsible for nearly 80% of total water use and the consumption categories including commercial, industrial, agriculture, outdoor, and others have a lower share in total water demand. The results also show that there is a considerable water loss in the water distribution system which requires significant investments on the water supply networks. Furthermore, the forecasting results indicated that pipeline projects will be critical in the near future due to expected increases in the total water demand of Istanbul. The authors suggest that sustainable management of water can be achieved by reducing the residential water use through the use of water efficient technologies in households and reduction in water supply loss through investments on distribution infrastructure.

Description: Most studies explored green-roof thermal effects on a few hot summer days based on short-term monitoring data. Few studies investigated the seasonal and diurnal patterns of thermal performance and associated weather effects. This research aims to address the following two questions: (1) how green-roof thermal performance varies with different season and time; and (2) to what extent can thermal performance be predicted by background weather parameters? A retrofitted extensive green roof was established on the top of a railway station in subtropical Hong Kong. Monitoring data covering a two-year period, one year before roof greening and one year after, were collected and analyzed. Results indicated notable seasonal and diurnal patterns of green-roof thermal performance. It exhibited cooling effects in spring, summer and fall, but warming effects in winter. The cooling effects were more pronounced in summer than spring and fall, on sunny days than rainy and cloudy days, and in nighttime than daytime. Air temperature, relative humidity, wind speed, solar radiation, and soil moisture could explain 83.6%–86% of the thermal effects’ variation. The multiple-regression models based on the five weather variables established in this study provide an uncomplicated and direct approach to predict the thermal performance of similar extensive green roofs in subtropical areas.

Description: The study presents a cost effective electricity generation portfolio for six island states for a 20-year period (2015–2035). The underlying concept investigates whether adding sizeable power capacities of renewable energy sources (RES) options could decrease the overall costs and contribute to a more sustainable, indigenous electricity generation at the same time. Often, island states rely on fossil fuels which, apart from dependence on foreign resources, also includes an additional, significant transport cost. This is an extra motive to study the extent in which island states represent primary locations for RES technologies. For the aims of the present study an optimization model has been developed and following numerous runs the obtained results show that installing PV and battery capacities can delay-reduce the huge investments in fossil options in early periods. Thus, investment on RES can have a positive, long-term effect on the overall energy mix. This prompt development can happen without adding new subsidies but there is a need to address the existing socio-economic barriers with intelligent design of financing and economic instruments and capacity building as discussed in the conclusions.

Description: We have developed a visualized 3-D model of a City Sustainability Index (CSI) based on our original concept of city sustainability in which a sustainable city is defined as one that maximizes socio-economic benefits while meeting constraint conditions of the environment and socio-economic equity on a permanent basis. The CSI is based on constraint and maximization indicators. Constraint indicators assess whether a city meets the necessary minimum conditions for city sustainability. Maximization indicators measure the benefits that a city generates in socio-economic aspects. When used in the policy-making process, the choice of constraint indicators should be implemented using a top-down approach. In contrast, a bottom-up approach is more suitable for defining maximization indicators because this technique involves multiple stakeholders (in a transdisciplinary approach). Using different materials of various colors, shapes, sizes, we designed and constructed the visualized physical model of the CSI to help people evaluate and compare the performance of different cities in terms of sustainability. The visualized model of the CSI can convey complicated information in a simple and straightforward manner to diverse stakeholders so that the sustainability analysis can be understood intuitively by ordinary citizens as well as experts. Thus, the CSI model helps stakeholders to develop critical thinking about city sustainability and enables policymakers to make informed decisions for sustainability through a transdisciplinary approach.

Description: The temperature distribution in copper and martensitic steel spheres has been investigated for the initial stage of field-activated sintering (FAST)/spark plasma sintering (SPS) using capacitor discharges (CD) with applied voltages from one to 15 V as model experiments. At first, the evolution of the contact resistance between the spheres has been studied. The results show the reduction in the contact resistance after discharge with increasing electrical load, yet no significant dependence on the length or number of the discharge pulses. Thereby the initial resistance is only decreased distinctly if at least a certain minimal voltage was applied. Subsequently, the melting of thin coatings of different metals on copper spheres has been studied and the occurrence of molten phase and its melting point were assigned to the corresponding discharge current. Extrapolation from the currents necessary to melt the coating layers in the CD experiments to lower values typical for FAST was used to estimate the contact overtemperature in the latter case. Resulting values for copper range from 0.05 K for normal heating with 100 K/min to 5 K for maximum current output.

Description: In this study, we report on the microstructure of SiO 2 -coated Al-doped ZnO nanoparticles densified by spark plasma sintering(SPS), using a multiscale approach. Our observations show that it is possible to successfully prepare dense pellets while keeping the nanostructure with well-defined Si-rich grain boundaries. Although a very limited partial solubility of Si in the ZnO matrix has been observed, Si is mostly concentrated at the grain boundaries. More surprisingly, we evidenced some areas with nanoscale inhomogeneity of the Al concentration, which can locally strongly exceed the average composition of the matrix. It could explain the apparent discrepancy observed in the literature between the simultaneous presence of ZnAl 2 O 4 in Al-doped ZnO, which should be the signature of the doping level exceeding the solubility limit, and the concentration of carriers that still depends on the nominal Al concentration in ZnO even in the presence of ZnAl 2 O 4 .

Description: This study examines the factors that influence individual intentions towards the adoption of full electric vehicles. A sample including 308 respondents was collected on the streets of Macau. The collected data were analysed by confirmatory factor analysis and structural equation modelling. The results demonstrate that environmental concerns and the perception of environmental policy are antecedent factors of the perception of full electric vehicles, which influences the behavioural intention to purchase full electric vehicles. This study also finds that the perception of economic benefit is one of the key factors influencing the adoption of full electric vehicles. Vehicle operators seek economic benefits from future long-term fuel savings, high energy efficiency, and cheap electricity. Thus, a government striving to promote low-carbon transportation needs to scale up its efforts to enhance citizens’ environmental concerns and to establish proper environmental policy as well as to provide long-term financial and strategic support for electric vehicles.

Description: Building owners are encouraged to reduce energy use in order to both contribute to national energy-saving goals and reduce the costs of heating and operation. It is important to choose the most optimal renovation measures available so as to achieve cost-effective energy use while maintaining excellent indoor environments, without sacrificing architectural quality or negatively affecting the environment. Building owners and managers often have neither the time nor the expertise required to properly evaluate the available renovation options before making a final decision. Renovation measures are often calculated to repay investments in a short time, rather than taking into account life-cycle costs (LCC), despite the fact that a thoughtful, comprehensive renovation is often more cost-effective in the long run. This paper presents a systematic approach for evaluating different renovation alternatives based on a number of sustainability criteria. The methodology has been verified using three multi-family apartment buildings in Sweden. The benefit of using the proposed methodology is made clear through a comparison between the different renovation alternatives from a sustainability perspective, and will hopefully serve as encouragement to choose renovation measures which involve marginally increased investments but lead to significant environmental and social benefits in the long-term.

Description: A survey was conducted of the wastewater treatment systems and related sludge handling practices on the island of Yap, in the Federated States of Micronesia, to assist in identifying areas where further work would be merited to improve on effectiveness and sustainability. A detailed inventory was made of communal septic tanks as found at health centers and schools. Though most of these septic tanks appeared to be functional, there were concerns due to some units being positioned within the tidal zone, covered over with vegetation, or out of reach of the pump truck. Furthermore, the centralized wastewater treatment plant on Yap provides only primary treatment consisting of a limited removal of suspended solids. Thus, only partially treated sewage is being discharged to the bay. Excess sludge is drawn from the treatment plant on a quarterly basis, which local farmers regularly make use of as fertilizer for crop application without adequate treatment. As an immediate target for further study and pilot testing, exploring the use of an attached-growth process as an inexpensive retrofit to enhance the effectiveness of the treatment plant is proposed. In addition, the benefits of implementing a composting program for recycle of waste sludge in a safe manner and developing a framework for management of septic tanks are discussed.

Description: Soil degradation is a global problem caused by many factors including excessive tillage, inappropriate crop rotations, excessive grazing or crop residue removal, deforestation, mining, construction and urban sprawl. To meet the needs of an expanding global population, it is essential for humankind to recognize and understand that improving soil health by adopting sustainable agricultural and land management practices is the best solution for mitigating and reversing current soil degradation trends. This research editorial is intended to provide an overview for this Special Issue of Sustainability that examines the global problem of soil degradation through reviews and recent research studies addressing soil health in Africa, Australia, China, Europe, India, North and South America, and Russia. Two common factors—soil erosion and depletion of soil organic matter (SOM)—emerge as consistent indicators of how “the thin layer covering the planet that stands between us and starvation” is being degraded. Soil degradation is not a new problem but failing to acknowledge, mitigate, and remediate the multiple factors leading to it is no longer a viable option for humankind. We optimistically conclude that the most promising strategies to mitigate soil degradation are to select appropriate land uses and improve soil management practices so that SOM is increased, soil biology is enhanced, and all forms of erosion are reduced. Collectively, these actions will enable humankind to “take care of the soil so it can take care of us”.

Description: Urban development bestows a great opportunity to increase sustainability in the built environment as cities are responsible for the majority of environmental impacts. However, the urban development process is fragmented and sub-optimization leads to unsustainable life cycle outcomes. The purpose of this study is to examine the urban development process from a life cycle perspective and identify how different actors understand life cycle management. By utilizing an inductive qualitative research design, 38 in-depth thematic interviews were conducted within the Finnish urban development industry including a case study and independent interviews from different phases of the urban development life cycle. The theoretical perspective is a combination of the ecosystem construct and life cycle management. Results show that there is no clear responsible actor for life cycle management in urban development. All actors claim that there is value to be added, mostly in economic, but also environmental and social terms. This study reveals that investors should be the responsible actor in the urban development process. By claiming responsibility and focusing on life cycle leadership we can improve sustainability in urban development, and respond to the urban sustainability challenge, thus improving the quality of life and welfare in our urban society.

Description: Compared with previous studies that have focused on customers’ behavioral intentions or the factors that influence purchase behaviors on blogs or discussion boards, in this study, we examine the factors of independent food blogs or discussion boards that influence users’ customer citizenship behaviors. Six food blogs were selected based on the flow rate and food diaries. 323 Subjects were chosen from the blog user population and then interviewed to develop the data needed for this study. The results indicate that psychological needs, customer satisfaction, and customer-company identification positively affect customer citizenship behaviors. High satisfaction of customer-orientation is a critical management strategy on food blogs. This study adapts physically existing organizational behavior theory through appropriate inference and modification for virtual community. Unlike past studies that focused on customer purchase intention, this study emphasizes customer value and social media of the virtual community.

Description: Among renewable energy resources, wind energy became more attractive in the last decade. Wind farm installations dramatically increased in areas where climatic conditions, topography, and environment have allowed their development. The installation of wind turbines, usually carried out in remote areas, recently began to cover areas identified by a complex terrain such as urban and suburban zones. Although these new plant choices are characterized by lower productivity, there is increasing interest in wind energy production in both urban and suburban areas. In this work the authors have carried out an energy analysis developed from a sample of small wind turbines available on the market. This study shows how variable the energy production of a small wind turbine can be according to many design and context parameters: wind profiles, installation height, land use, and characteristics of the turbine.

Description: The primary objective of this paper is to analyse households’ adaptation measures to the impacts of repeated extreme weather events, specifically floods, which belong amongst the most serious manifestation of ongoing climate change in Europe. The case study focuses on a rural area in the north-east part of the Czech Republic, in the catchment basin of the Bečva River. A total of 605 households were addressed within the framework of the questionnaire survey. On the basis of the conducted research, we determined that the total amount of adaptation measures adopted by those dwelling in residential homes within the investigated catchment area was relatively low. In contrast, however, one of the most important adaptation measures—house elevation—was applied by 46.94% of the houses (up to 1 m) and by 21.16% houses (elevated more than 1 m) respectively. We also found that the amount and scope of adaptation measures realized by households were influenced by certain socio-demographic factors of the inhabitants. The most statistically significant factors included households with more residents or families with more children living in the household, as well as those with a higher level of education. Flood experience, the level of damage, and individual flood risk perception also played an important role.

Description: The field of eco-innovation is included in the area of sustainable development being closely related with ecological planning. In this context, this paper aims to evaluate Romanian eco-innovation performance during the period 2003–2013 by constructing a composite index and to also identify the main eco-innovation poles at the European level using multidimensional analysis techniques based on the eco-innovation specific indicators for the year 2013. This approach used the methodology of constructing composite indices proposed by Organization for Economic Co-operation and Development (OECD) in 2008. The index measured the eco-innovation dimensions in 27 countries over the period 2003–2013. The empirical analysis revealed the conclusion that in Romania, the eco-innovation level is low compared with other countries, thus Romania cannot emphasize its eco-innovation performance. The empirical results of the study highlighted that eco-innovation represents a phenomenon leading to significant progress in achieving the objective of sustainable development in Romania, and also at the European level, only if the importance of this area is awarded and eco-innovation measures are enforced through adequate policies, leading to economic growth.

Description: The effects of increasing concentrations of oregano (Origanum vulgare L.) and rosemary (Rosmarinus officinalis L.) essentials oil (EO) on ruminal gas emissions were tested in vitro using 50 mL serum bottles. Each bottle contained a 200 mg substrate (alfalfa hay and corn meal 1:1) and a 20 mL solution composed of a buffered medium and rumen fluid (1:2). The percentage of ruminal fermentation products was quantified by an infrared analyzer. The reduction of total gas production was 6% and 9% respectively when using the 1.5 and 2.0 g/L oregano EO measurements. The reduction of methane production was 55%, 72% and 71% respectively with regard to the 1.0, 1.5 and 2.0 g/L oregano EO doses, while rosemary EO (2.0 g/L) reduced the methane production by 9%. The production of ammonia was significantly reduced (59%–78%) by all treatments with the exception of rosemary EO at the lowest dose. Dry matter and neutral detergent fiber degradability was reduced by most of the treatments (respectively 4%–9% and 8%–24%). The total volatile fatty acids (VFA) concentration was markedly decreased by oregano EO and was not affected by rosemary EO. Both EOs mitigated rumen fermentations, but oregano EO gave rise to the highest reduction in methane and ammonia production. However, further research is needed to evaluate the use of these essential oils as dietary supplements by taking into account the negative effects on feed degradability.

Description: Background: This study aims to find diets with low price and low climate impact, yet fulfilling all nutritional requirements. Methods: Optimization by linear programming. The program constrains 33 nutrients to fulfill Dutch dietary requirements. In a second cycle, the upper boundary for climate impact through greenhouse gas emissions (GHGE) is set to 1.6 kg carbon dioxide equivalents/day (CO2eq). In a third cycle, the costs are set on €2.50 as a constraint. The objective function of the optimization maximized the most consumed food products (n = 206) for male and female adults separately (age 31–50). Results: A diet of 63 popular and low priced basic products was found to deliver all required nutrients at an adequate level for both male and female adults. This plant-based, carbohydrate and fiber-rich diet consists mainly of wholegrain bread, potatoes, muesli, open-field vegetables and fruits. The climate impact of this diet is very low (1.59 kg CO2eq/day) compared to the average Dutch diet. By constraining costs, a low carbon diet of €2.59/day is possible. Conclusions: A two-person diet consisting of 63 products and costing €37 per week can simultaneously be healthy and yet have half the average climate impact. Linear programming is a promising tool to combine health and sustainability on both societal and individual levels.

Description: Infrastructure has long been a priority in development policy, but there is debate over infrastructure impacts. Whereas economic studies show reductions in poverty, social research has documented growing income inequality. We suggest that a focus on livelihoods permits a bridge between the two literatures by highlighting decisions by households that may capture economic benefits but also yield social inequalities. We therefore take up two questions. First is whether new infrastructure allows households to diversify their livelihoods, where diversity begets resilience and thus affords livelihood sustainability. Second is whether households with more diverse livelihoods exhibit greater increases in livelihood diversity, which would widen livelihood inequalities. We take up the case of the Inter-Oceanic Highway, a trans-boundary infrastructure project in the southwestern Amazon. Findings from a rural household survey for the first question show a strong effect of accessibility on increasing livelihood diversity in areas receiving infrastructure upgrades, an indication that infrastructure fosters household resilience. However, results regarding the second question indicate that households with more diversified livelihoods also exhibit larger increments in diversity, which implies growing livelihood inequality. There remains a need to account for inequalities in livelihood diversity, since less diversified households benefit less from new infrastructure and remain more exposed to risks to their livelihoods.

Description: Hybrid renewable energy systems (HRES) are a trendy alternative to enhance the renewable energy deployment worldwide. They effectively take advantage of scalability and flexibility of these energy sources, since combining two or more allows counteracting the weaknesses of a stochastic renewable energy source with the strengths of another or with the predictability of a non-renewable energy source. This work presents an optimization methodology for minimum life cycle cost of a HRES based on solar photovoltaic, wind and biomass power. Biomass power seeks to take advantage of locally available forest wood biomass in the form of wood chips to provide energy in periods when the PV and wind power generated are not enough to match the existing demand. The results show that a HRES combining the selected three sources of renewable energy could be installed in a rural township of about 1300 dwellings with an up-front investment of US $7.4 million, with a total life cycle cost of slightly more than US $30 million. Such a system would have benefits in terms of energy autonomy and environment quality improvement, as well as in term of job opportunity creation.

Description: Several challenges regarding the European tourism industry were recently identified at EU level which the experts of the European Commission tried to meet, thus formulating several priorities within the newest Tourism Action Framework: Stimulate long-term competitiveness in the European tourism sector, promote the development of sustainable and high-quality tourism, and consolidate the image and promotion of European tourist destinations. Due to the new generational context, information and communications technology ICT and innovation became keywords within the most recent European Tourism Policy. Considering the symbiotic relationship that exists at the European tourism level between sustainable development, innovative ICT solutions, and long-term competitiveness, the decision-makers in European destinations should focus on identifying innovative ways to implement the new Tourism Action Framework adopted by the European Commission, through ICT applications, in order to support long-term competitiveness achievement. Two such authentic proposals are formulated within the present discussion paper: the creation of a decision support system for the management of sustainable European destinations and the development of a trip-planner for quality-sensitive tourists based on an umbrella European certification/labeling system for tourism quality. There is still a fertile field in these areas and, therefore, more innovative ICT tools to support the long-term competitiveness of European tourist destinations can be developed.

Description: Pressureless sintering is a well-established powder metallurgical route for processing and consolidation of mixed materials. Especially materials exhibiting a high melting point could be densified without tool abrasion by this sintering technique. As the sintering temperatures are often higher compared to pressure-assisted techniques care must be taken by means of grain growth. In our studies we used a ternary compound mixture to obtain Mo-based alloys. Consolidation applying pressure-assisted methods (hot pressing, spark plasma sintering) and pressureless sintering were used, respectively. The densities reached and the microstructures obtained were compared. These Mo–Si–B alloys were processed using a nitride-powder-based route offering lower impurity contents due to short processing times by avoiding time consuming mixing / milling steps. The sintering conditions depending on the powder particle size as well as the sample shape will be presented in detail. The composition investigated in this article offered a continuous α-Mo matrix with intermetallic islands consisting of Mo 3 Si and Mo 5 SiB 2 (T2) phases. The combination of a ductile α-Mo matrix and intermetallic phases embedded within offered an enhanced mechanical behavior at room temperature compared to MoSi 2 or other intermetallic alloys. Moreover, the intermetallic compounds as well as Mo are candidates for high-temperature applications. As the high-temperature behavior could be strongly influenced by the respective microstructure we present here the processing and the microstructure obtained.

Description: As the most promising candidate of the solid electrolyte materials for future lithium batteries, oxide electrolytes with high–lithium-ion conductivity have experienced a rapid development in the past few decades. Existing oxide electrolytes are divided into two groups, i.e., crystalline group including NASICON, perovskite, garnet, and some newly developing structures, and amorphous/glass group including Li 2 O–MO x (M = Si, B, P, etc.) and LiPON-related materials. After a historical perspective on the general development of oxide electrolytes, we try to give a comprehensive review on the oxide electrolytes with high–lithium-ion conductivity, with special emphasis on the aspect of materials selection and design for applications as solid electrolytes in lithium batteries. Some successful examples and meaningful attempts on the incorporation of oxide electrolytes in lithium batteries are also presented. In the conclusion part, an outlook for the future direction of oxide electrolytes development is given.

Description: Dual-phase oxygen transport membranes are fast-growing research interest for application in oxyfuel combustion process. One such potential candidate is CGO-FCO (60 wt% Ce 0.8 Gd 0.2 O 2−δ –40 wt% FeCo 2 O 4 ) identified to provide good oxygen permeation flux with substantial stability in harsh atmosphere. Dense CGO-FCO membranes of 1 mm thickness were fabricated by sintering dry pellets pressed from powders synthesized by one-pot method (modified Pechini process) at 1200°C for 10 h. Microstructure analysis indicates presence of a third orthorhombic perovskite phase in the sintered composite. It was also identified that the spinel phase tends to form an oxygen deficient phase at the grain boundary of spinel and CGO phases. Surface exchange limitation of the membranes was overcome by La 0.6 Sr 0.4 Co 0.2 Fe 0.8 O 3−δ (LSCF) porous layer coating over the composite. The oxygen permeation flux of the CGO-FCO screen printed with a porous layer of 10 μm thick LSCF is 0.11 mL/cm 2 per minute at 850°C with argon as sweep and air as feed gas at the rates of 50 and 250 mL/min.

Description: Two-step sintering (TSS) in a reducing atmosphere has been employed to obtain fine-grain BaTiO 3 ceramics with a core-shell microstructure, a more uniform grain-size distribution, and superior reliability for multilayer ceramic capacitor applications. Compared to ceramics of the same composition conventionally sintered for about the same time, TSS ceramics feature a thinner shell thickness thus a stronger dopant localization, which leads to a lower concentration, higher internal resistance and more dopant- association. Improved reliability is manifest in a 50% higher breakdown strength at ambient temperature and a 400% longer endurance time to withstand DC stress at 185°C, in addition to a less field-and-temperature-dependent capacitance. A scaling analysis of the redistribution and endurance dynamics identifies transmission across the shell-grain-boundary region as the critical element beneficially impacted by core-shell structure and two-step sintering.

Description: (Ba, Ca)(Ti, Zr)O 3 ceramics have been considered as a potential lead-free alternative to commonly used lead-based piezoelectric ceramics due to their high piezoelectric performance at room temperature. In this study, the bipolar fatigue behavior of this material is investigated at room temperature. Two compositions were cycled with a bipolar electric field signal at 10 Hz with a maximum of three times the coercive field for up to approximately 10 7 cycles. Both investigated compositions exhibited high bipolar fatigue resistance compared to other ceramics reported in the literatures. The high fatigue resistance originates from the lack of mechanical damage and a weak domain wall pinning effect due to their location in the phase transition region. It was also found that pore morphology affected bipolar fatigue behavior.

Description: 0.94(Na 0.5 Bi 0.5+ x )TiO 3 –0.06BaTiO 3 ( x  = −0.04, 0, 0.02; named NB 0.46 T-6BT, NB 0.50 T-6BT, NB 0.52 T-6BT, respectively) lead-free piezoelectric ceramics were prepared via the solid-state reaction method. Effects of Bi 3+ nonstoichiometry on microstructure, dielectric, ferroelectric, and piezoelectric properties were studied. All ceramics show typical X-ray diffraction peaks of ABO 3 perovskite structure. The lattice parameters increase with the increase in the Bi 3+ content. The electron probe microanalysis demonstrates that the excess Bi 2 O 3 in the starting composition can compensate the Bi 2 O 3 loss induced during sample processing. The size and shape of grains are closely related to the Bi 3+ content. For the unpoled NB 0.50 T-6BT and NB 0.52 T-6BT, there are two dielectric anomalies in the dielectric constant–temperature curves. The unpoled NB 0.46 T-6BT shows one dielectric anomaly accompanied by high dielectric constant and dielectric loss at low frequencies. After poling, a new dielectric anomaly appears around depolarization temperature ( T d ) for all ceramics and the T d values increase with the Bi 3+ amount decreasing from excess to deficiency. The diffuse phase transition character was studied via the Curie–Weiss law and modified Curie–Weiss law. The activation energy values obtained via the impedance analysis are 0.69, 1.05, and 1.16 eV for NB 0.46 T-6BT, NB 0.50 T-6BT and NB 0.52 T-6BT, respectively, implying the change in oxygen vacancy concentration in the ceramics. The piezoelectric constant, polarization, and coercive field of the ceramics change with the variation in the Bi 3+ content. The Rayleigh analysis suggests that the change in electrical properties of the ceramics with the variation in the Bi 3+ amount is related to the effect of oxygen vacancies.

Description: Despite technological improvements in its production process, the sanitary ware industry inevitably generates a certain volume of discards, products whose quality is not up to standard. The present paper is the first to scientifically explore clay-based sanitary ware waste (SW) with a view to its valorization as an addition in the design of new, more environmentally friendly cements. The focus is on characterization of the waste and its pozzolanicity, as well as the structural and microstructural changes taking place in the pozzolan/Ca(OH) 2 system in the first 90 d of reaction. The findings show that pozzolanicity in clay-based waste is comparable to the activity observed in silica fume (SF) and higher than that found in other clay-based materials and fly ash (FA). The microstructural study of the clay-based waste/Ca(OH) 2 system, in turn, reveals that the proportion of C–S–H gels rises with hydration time. These gels are characterized by long mean chain lengths (MCL) and low Ca/Si ratios. The intrinsic characteristics of this thermally activated clay-based waste qualify it as a type Q pozzolans as defined in the European cement standards, making it apt for use in the manufacture of CEM II, IV, and V cements.

Description: High-Energy Ball Milling (HEBM) is proposed as a cost effective and environmental friendly technique to produce Co- and Mn- based oxides suitable for application as protective coating. Mixtures of manganese and cobalt oxides in different molar ratio (Co:Mn = 1:1 and Co:Mn = 2:1) were subjected to mechanochemical treatment up to 100 h and morpho-structural evolution was evaluated. XRD analysis results show that the HEBM treatment promotes the solid-state reaction of the starting compounds, with the formation of different crystalline phases when compared to high-temperature solid-state synthesis. SEM obs erv ations and N 2 adsorption measurements suggest that all processed powders are composed by aggregates of nanometric particles. While long milling time is required to complete the reaction, 10 hours are enough to activate the powders to obtain the desired phases after a mild thermal treatment, as evidenced by in situ thermal XRD analysis. Electrical conductivity measures performed with the Van der Pauw method on sintered pellets evidence a significant difference between the two compositions, related to the dual-phase nature of Co:Mn = 1:1 material at intermediate temperatures (i.e., T  〈 700°C), Co:Mn = 2:1 sample showing higher conductivity values in the whole tested range (500°C–800°C).

Description: The Na–SrSiO 3 as a potential high-conductivity ionic conductor for intermediate temperature solid oxide electrochemical cells (SOECs) has drawn much attention recently. Some of these studies questioned the feasibility of Na doping and therefore the creation of oxygen vacancies, while others suggested an alternative phase responsible for the ionic conduction. In this study, a systematic investigation was carried out to understand the ionic conduction in Na–SrSiO 3 . Through in situ high-temperature X-ray diffraction, thermal analysis, microstructural characterization, and electrical conductivity measurement, Na–SrSiO 3 was shown as a two-phase material, one being slightly Na-doped SrSiO 3 and another being amorphous Na 2 Si 2 O 5 . The former was an electrical insulator whereas the latter was a good ionic conductor. It was also found that the amorphous Na 2 Si 2 O 5 phase was unstable at the temperature ≥500°C, crystallizing into the insulating polycrystalline Na 2 Si 2 O 5 which causes conductivity to “bend-over” at higher temperatures. A preliminary Ab Initio Molecular Dynamics (AIMD) simulation suggested that the amorphous Na 2 Si 2 O 5 be predominantly a Na + conductor.

Description: This study investigated the influence of codoping with Ge and GeO 2 on the nonlinear coefficient α and the breakdown voltage E B of TiO 2 –Nb 2 O 5 –SrCO 3 varistor ceramics. Ge–GeO 2 codoping notably changed the microstructure of the TiO 2 –Nb 2 O 5 –SrCO 3 ceramics, increased α, and decreased E B . When the doping contents of Nb 2 O 5 and SrCO 3 were 0.1 and 0.2 mol%, respectively, the optimum doping content of 0.25 mol% Ge and 0.75 mol% GeO 2 exhibited high α (11.6), low E B (13.8 V/mm), and high grain-boundary barrier Φ B (0.96 eV). These results are superior to previous findings. In addition, Ge and GeO 2 , which function as sintering aids, reduced the sintering temperature caused by the low melting point. The optimal sintering temperature was 1260°C for the TiO 2 –Nb 2 O 5 –SrCO 3 ceramics doped with Ge and GeO 2 .

Description: Pure perovskite K 0.5 Na 0.5 NbO 3 – x SrTiO 3 ( x  =   0.16, 0.17, 0.18, and 0.19) ceramics were prepared by using a solid-state reaction process. The ceramics were optically transparent for visible and near-infrared wavelengths. Then, high tunability (24.1%) and low dielectric loss (0.016) for the x  =   0.18 sample indicated the transparent ceramics could be used in tunable devices. The Lorentz-type relation fitting for the temperature dependence of dielectric permittivity showed that these ceramics had a typical relaxor behavior, and the polar nanoregions were related to the tunable dielectric properties. The nonlinear dielectric behavior was further explored by the Johnson model combined with Langevin terms, which revealed that the polar nanoregions contributed to the nonlinear ε( E ) dependencies with contributions of 12.3%, 11.6%, 5.9%, and 3.6% for x  =   0.16, 0.17, 0.18, and 0.19, respectively.

Description: The effect of Cr 3+ on the electrical properties of SnO 2 -based films deposited by electrophoresis on Si/Pt substrate was considered. The films were sintered in a microwave oven at 1000°C/40 min and then the surface was modified with deposition of Cr 3+ ions by electrophoresis. The diffusion of Cr 3+ contributes to the modification of the potential barrier formed on the grain boundary improving the electrical properties due to electron acceptor species adsorption on the grain boundary. The influence on the properties of grain boundary was verified by I versus V characterization in as a function of temperature. The films showed nonlinear coefficient over 9, potential barrier height over 0.5 eV and resistivity greater than 10 7  Ω·cm. 4 samples were prepared at same conditions and presented similar electrical behavior, showing the efficiency of technique on reproducibility to varistor properties control. Thereby the nonlinear coefficient increases while decreasing the conductivity of the system is noticed.

Description: The plasmonic effects of infiltrated silver (Ag) nanoparticles, with different contents, inside a nanostructured TiO 2 film on the photovoltaic performance of dye-sensitized solar cells (DSSCs) are explored. The synthesized Ag nanoparticles are immobilized onto deposited TiO 2 nanoparticles by a new strategy using 3-mercaptopropionic acid (MPA), a bifunctional linker molecule. Transmission electron microscope (TEM) images show that monodispersed Ag and polydispersed TiO 2 nanoparticles have an average diameter of 12 ± 3 nm and 5 ± 1 nm, respectively. Moreover, Fourier transform infrared spectroscopy (FTIR) analysis reveals that Ag nanoparticles were successfully functionalized and capped with MPA. Optical studies on the MPA-capped Ag nanoparticles inside TiO 2 film show an increase in the total absorbance of the electrode. Moreover, EIS measurements confirm that MPA-capped Ag nanoparticles inhibit the charge recombination and improve the stability of nanoparticles in I 3 − / I − electrolyte. The DSSC assembled with optimal content of MPA-capped Ag nanoparticles demonstrated an enhanced power conversion efficiency (8.82% ± 0.07%) compared with the pure TiO 2 (7.30% ± 0.05%). The increase in cell efficiency was attributed to the enhanced dye light absorption in strength and spectral range due to the surface plasmon resonance of MPA-capped Ag nanoparticles in the photoanode.

Description: A large and stable shape memory effect has been observed in 0.6 wt% Mn-doped (Pb 0.99 Nb 0.02 )[(Zr 0.70 Sn 0.30 ) 0.52 Ti 0.48 ] 0.98 O 3 (Mn:PNZST) ceramics after being poled at high temperature. A maximum shape memory of 0.41% was achieved. This effect is related to the preferentially oriented defect dipoles along the poling direction after poling at high temperature and electric field. Furthermore, the shape memory effect is stable after 10 4 electric cycles at 30 kV/cm. The shape memory piezoelectric actuator may be fabricated using this kind of material.

Description: Glassmelting efficiency largely depends on heat transfer to reacting glass batch (melter feed), which in turn is influenced by the bulk density (ρ b ) and porosity (ϕ) of the reacting feed as functions of temperature ( T ). Neither ρ b ( T ) nor ϕ( T ) functions are readily accessible from direct measurements. For the determination of ρ b , we monitored the profile area of heated feed pellets and calculated the pellet volume using numerical integration. For the determination of ϕ, we measured the material density of feeds quenched at various stages of conversion via pycnometry and then computed the feed density at heat-treatment temperature using thermal expansion values of basic feed constituents.

Description: Spray-drying is an effective method for producing powder aggregates with controlled size and morphology. Here, we report on a systematic study aimed at determining how spray-drying parameters such as nozzle temperature, gas flow, salt concentration and solution feed rate, influence the characteristics of BaCl 2 granules prepared from aqueous solutions. We correlate the granule characteristics to these conditions through the use of processing maps and modeling. It is found that well-dispersed, high density and spherical aggregates, which are favorable for subsequent powder compaction and sintering, can be obtained within a limited range of processing conditions.

Description: When the sample temperature is warm enough so that the Joule heating takes over the environment's radiation heating as the dominant heating means, thermal runaway follows and flash sintering is triggered. This condition accurately predicts the reported onset temperature T on of all the constant-field ( E ) experiments on flash sintering, performed under a constant heating rate. The predicted linear ln( E 2 / T on 4 ) versus T on −1 relation determines the activation energy and the relative ranking of the electrical conductivity of the tested materials.

Description: In recent years, kaolinite-based wastes are focusing the attention of researchers to obtain recycled metakaolinite, with consequent environmental and socioeconomic benefits. One of these lines of research is based on coal mining waste, which once activated thermally, it becomes a highly pozzolanic product (ACM). This study reports the influence of activated carbon mining waste on the formation and evolution of the mineralogical phases in the ACM/cement system as well as their influence on the microstructure up to 90 d of reaction. Mineralogical analyses clearly show that the addition of ACM modified mineralogical compounds of blended cements. The C 4 AH 13 and C 4 A H 12 were the predominant phases in this type of cements; while in the ordinary portland cement cements, portlandite, ettringite, and carboaluminate were main hydrated phases. Two differential zones in the pore size distribution of the C–S–H gels at 12 and 4.5 nm were observed, predominating the formation of C–S–H gels at 12 nm when 20% of ACM was added to the cement.

Description: Ce 3+ , Nd 3+ codoped (Sr 0.6 Ca 0.4 ) 3 (Al 0.6 Si 0.4 )O 4.4 F 0.6 phosphors were synthesized through the high-temperature solid-state reaction method. Luminescence spectra, absorption spectra, and decay lifetimes of these samples have been measured to prove the energy-transfer process from Ce 3+ to Nd 3+ . Under UV and blue light excitation, (Sr 0.6 Ca 0.4 ) 3 (Al 0.6 Si 0.4 )O 4.4 F 0.6 :Ce 3+ ,Nd 3+ phosphors exhibit near-infrared (NIR) emission, mainly peaking at 1093 nm and secondarily at 916 nm. The NIR emission matches well with the band gap of c-Si. Results of this work suggest that the (Sr 0.6 Ca 0.4 ) 3 (Al 0.6 Si 0.4 )O 4.4 F 0.6 :Ce 3+ , Nd 3+ phosphors have potential application as down-shifting luminescent convertor for enhancing the photoelectric conversion efficiency of c-Si solar cell.

Description: It was determined that the mean grain boundary radius of curvature in 3 mol% yttria-stabilized zirconia isothermally annealed without and with a DC electric field  = 18 V/cm was uniquely proportional to the mean linear intercept grain size , the proportionality constant α   = 3/2 being in accord with the Rios-Fonseca stereological model.

Description: The electric-field-driven phase transition in (K, Na, Li)(Nb, Ta, Sb)O 3 lead-free piezoelectric ceramics was investigated by X-ray diffraction, Raman spectra, and the temperature dependences of permittivity spectra. After poling under different electric fields, phase of the ceramics transformed gradually from orthorhombic–tetragonal coexisting phase to orthorhombic phase, indicating that the crystal structure of ceramics was strongly sensitive to electric field as an external stimulus. A secondary phase K 3 Li 2 Nb 5 O 15 induced by electric field was detected in the ceramics with Li content of 7 mol%, which was close to the solubility limit of lithium. This field-induced secondary phase resulted from the movement of Li ions and the structural deformation induced by electric field. Moreover, piezoelectric constant d 33 increased with the increasing poling field strength and the enhancement can be attributed to the field-triggered domain switching. This study implied that in addition to temperature and composition, which has been reported in previous researches, electric field might be an effective way for inducing phase transition in lead-free piezoelectric ceramics and improving the electrical performances simultaneously.

Description: In this study, we introduce a simple and effective seed-mediated growth method (SMGM) for the controlled synthesis of boron suboxide powder. By employing starting powders with different concentrations and adding boron suboxide seeds with a star-like morphology, we demonstrate that B 6 O ceramics that exhibit high-level crystallinity can be synthesized using SMGM at ambient pressure conditions. The formation of multilayered star-shaped B 6 O particles via SMGM is reported for the first time.

Description: In this study, thermal radiation was employed for sintering silicon carbide foams that achieved a gradient porous structure. The simultaneous use of graphite and carbon fiber reinforced carbon composite ( C f / C ) radiators resulted in an axial temperature gradient of ~600°C along the cylindrical sample, as confirmed by both numerical simulation and experimental measurement. By sintering the cylinder top at 1600°C for 5 min, the porous SiC body achieved an axial pore size gradient from ~106 ± 36 μm to ~250 ± 84 μm and an open porosity from 41.4 to 79.8 vol%. This work indicates the potential of sintering by intense thermal radiation technique for rapid manufacturing functionally graded materials through asymmetric assembly of thermal radiators.