ALBERT

Description: Forests, Vol. 9, Pages 544: Contrasting Responses of Soil Respiration Components in Response to Five-Year Nitrogen Addition in a Pinus tabulaeformis Forest in Northern China Forests doi: 10.3390/f9090544 Authors: Bo Zhao Yan Geng Jing Cao Lu Yang Xiuhai Zhao Increasing atmospheric nitrogen (N) deposition has profound effects on carbon (C) cycling in forest ecosystems. As an important part of belowground C dynamics, soil respiration is potentially affected by changing N availability. However, the responses of total soil respiration (RST) and its three components, soil respiration derived from plant roots (RSR), root-free soil (RSS) and the litter layer (RSL), to such N enrichment remains poorly understood. To assess the effects of N enrichment on soil respiration components, three levels of N addition, namely low (LN, 50 kg N ha−1 year−1), medium (MN, 100 kg N ha−1 year−1) and high (HN, 150 kg N ha−1 year−1), were conducted over five growing seasons from 2011 to 2015 in a temperate Chinese pine (Pinus tabulaeformis) forest in northern China. A control plot without N addition (CK) was also established. The five-year mean annual rate of RST was 2.18 ± 0.43 μmol m−2 s−1, and the contributions of RSR, RSS and RSL were 8.8 ± 3.1%, 82.2 ± 4.5% and 9.0 ± 5.5%, respectively. Compared with CK, RST was significantly increased by 16.5% in the HN plots, but not in the LN or MN treatments. RSS was significantly decreased by 18.1%, 26.6% and 18.4% in the LN, MN and HN plots, respectively, due to the reduction of both microbial biomass carbon (MBC) and enzyme activity. In contrast, RSR was increased by more than twice under the MN treatment, which promoted root growth and activity (higher fine root biomass and N concentration). A significant elevation in RSL was only detected in the HN plots, where the increased litter input enhanced litter decomposition and hence RSL. Our findings clearly demonstrated that N addition of different intensities had different effects on soil components. In particular, the above- and belowground components of heterotrophic respiration, RSL and RSR, showed contrasting responses to high level addition of N. Thus, we highlight that the response of soil respiration components to N addition should be examined individually. Our results may contribute to a better understanding of soil respiration dynamics under future N scenarios, and have important implications in forest management.

Description: Minerals, Vol. 8, Pages 389: Induration Process of MgO Flux Pellet Minerals doi: 10.3390/min8090389 Authors: Qiangjian Gao Xin Jiang Haiyan Zheng Fengman Shen The induration process of oxidized pellet, containing the oxidation of magnetite phase (Fe3O4) and the sintering of oxidized magnetite phase (hematite–Fe2O3), is significant to obtain sufficient pellet strength. The current study focuses on the induration mechanisms of MgO flux pellet in terms of the oxidation process of Fe3O4 and densification process of the pellet. It is found that MgO dosage negatively affects the oxidation of Fe3O4 into Fe2O3. The number of recrystallized grain of Fe2O3 in the MgO flux pellet is less than that in the Non-MgO flux pellet. Additionally, an unreacted core model was applied to consider and clarify the oxidation of Fe3O4. According to the verification experiments, the experimental data and calculated results fit well. Therefore, the unreacted core model can describe the oxidation of Fe3O4 in the pellet induration process. Moreover, based on the development of pore parameters during the pellet induration process, a new index, the so-called oxide densification index (ODI) was defined to profoundly specify the densification degree of the pellet. The results show that the ODI of the MgO flux pellet maintains at a lower level compared with that of the Non-MgO flux pellet. It illustrates that MgO can substantially restrain the pellet densification process.

Description: Minerals, Vol. 8, Pages 388: Ore-Forming Processes at the Xiajinbao Gold Deposit in Eastern Hebei Province: Constraints from EPMA and LA-ICPMS Analysis Minerals doi: 10.3390/min8090388 Authors: Cheng Wang Yongjun Shao Kuanxin Huang Haodi Zhou Jianguo Zhang Zhongfa Liu Qingquan Liu The Xiajinbao gold deposit is located at the northern margin of the North China Craton. Hydrothermal pyrites belonging to three stages were identified: Py1; Py2; and Py3. Geochemical study of these pyrites was conducted using electron probe microanalysis and laser ablation inductively coupled plasma mass spectrometry to investigate the distributions of minor and trace elements, constrain pyrite genesis, and to obtain an improved understanding of the ore-forming processes. Py1 and Py2 contain high concentrations of Au and are interpreted to have been deposited from fluids from a dominantly magmatic source. Py3 grains have the lowest Co/Ni ratios. All generations of pyrite were deposited by mixing of meteoric waters with magmatic-hydrothermal fluids. Boiling of early ore-forming fluids led to the precipitation of Py1 and gold. Decreasing fO2 in the ore-forming system resulted in the formation of Py2 and gold. Fluid mixing was the dominant controlling factor for the precipitation of Py3 together with small amounts of gold.

Description: Minerals, Vol. 8, Pages 383: Towards Greener Lixiviants in Value Recovery from Mine Wastes: Efficacy of Organic Acids for the Dissolution of Copper and Arsenic from Legacy Mine Tailings Minerals doi: 10.3390/min8090383 Authors: Richard A. Crane Devin J. Sapsford In many cases, it may be possible to recover value (e.g., metals, land) from legacy mine wastes and tailings when applying leaching-based remediation such as dump/heap leaching or in-vessel soil washing. However, if the lixiviant used has the potential to cause environmental damage upon leakage, then this approach will have limited practicability due to actual or perceived risk. This study focused on comparing the efficacy of organic acids, namely methanesulfonic (CH3SO3H) and citric (C6H8O7) acid, with mineral acids, namely sulfuric (H2SO4) and hydrochloric (HCl) acid, for the dissolution of Cu and As from mine tailings. The advantage of the former acid type is the fact that its conjungate base is readily biodegradable which should thereby limit the environmental impact of accidental spill/leakage (particularly in non-carbonate terrain) and might also be directly useful in capture/recovery systems coupled with percolation leaching (e.g., as an electron donor in sulphate-reducing bioreactors). The operational factors acid concentration, leaching time, mixing intensity and solid–liquid ratio, were tested in order to determine the optimum conditions for metal dissolution. HCl, H2SO4, and CH3SO3H typically exhibited a relatively similar leaching ability for As despite their different pKa values, with dissolutions of 58%, 56%, 55%, and 44% recorded for H2SO4, HCl, CH3SO3H, and C6H8O7, respectively, after 48 h when using 1 M concentrations and a 10:1 L:S ratio. For the same conditions, H2SO4 was generally the most effective acid type for Cu removal with 38% compared to 32%, 29% and 22% for HCl, CH3SO3H and C6H8O7. As such, CH3SO3H and C6H8O7 demonstrated similar performances to strong mineral acids and, as such, hold great promise as environmentally compatible alternatives to conventional mineral acids for metal recovery from ores and waste.

Description: Minerals, Vol. 8, Pages 381: Effects of Superplasticizer on the Hydration, Consistency, and Strength Development of Cemented Paste Backfill Minerals doi: 10.3390/min8090381 Authors: Jian Zhang Hongwei Deng Abbas Taheri Junren Deng Bo Ke The strength and consistency of cemented paste backfill (CPB) are of key concerns in the stope stability and cost control for underground mines. It is common practice to use additives, such as superplasticizer, to improve the performance of CPB. This study mainly focuses on the effects of superplasticizer on the hydration, consistency, and strength of CPB. In this study, a polynaphtalene sulfonate was used as the superplasticizer. The binder is a mix of 33.3% ordinary Portland cement and 66.7% fly ash. The CPB specimens with a tailings-binder ratio of 3:1 and a solid concentration of 70% were then tested by a low field nuclear magnetic resonance system after different hydration times. Effects of polynaphtalene sulfonate on the hydration, fluidity, and strength were investigated. Results showed that the polynaphtalene sulfonate has a strong influence on short-duration hydration, which may contribute to the strength increase of CPB. It has been demonstrated that the polynaphtalene sulfonate improved the fluidity of the CPB mixture. With the increased dosage of polynaphtalene sulfonate, the slump increased. It was also found that the polynaphtalene sulfonate dosage has a negligible effect on the 1 day (d) strength while it has a strengthening effect on the 7 d, 14 d, and 28 d strength of CPB specimens.

Description: Minerals, Vol. 8, Pages 382: Synchrotron Radiation Based Study of the Catalytic Mechanism of Ag+ to Chalcopyrite Bioleaching by Mesophilic and Thermophilic Cultures Minerals doi: 10.3390/min8090382 Authors: Zhenyuan Nie Weiwei Zhang Hongchang Liu Jinlan Xia Wei Zhu Duorui Zhang Lei Zheng Chenyan Ma Yidong Zhao Wen Wen The catalytic mechanism of Ag+ for chalcopyrite bioleaching by mesophilic culture (at 30 °C) and thermophilic culture (at 48 °C) was investigated using synchrotron radiation-based X-ray diffraction (SR-XRD) and S K-edge and Fe L-edge X-ray absorption near edge structure (XANES) spectroscopy. Bioleaching experiments showed that copper extraction from chalcopyrite bioleaching by both cultures was promoted significantly by Ag+, with more serious corrosion occurring on the minerals surface. SR-XRD and XANES analyses showed that the intermediates S0, jarosite and secondary minerals (bornite, chalcocite and covellite) formed for all bioleaching experiments. For these secondary minerals, the formation of bornite and covellite was promoted significantly in the presence of Ag+ for both cultures, while Ag+ has almost no effect on the formation of chalcocite. These results provided insight into the catalytic mechanisms of Ag+ to chalcopyrite bioleaching by the mesophilic and thermophilic cultures, which are both probably due to the rapid formation of bornite by Ag+ and the conversion of bornite to covellite.

Description: Minerals, Vol. 8, Pages 391: Interpretation of Hydrophobization Behavior of Dodecylamine on Muscovite and Talc Surface through Dynamic Wettability and AFM Analysis Minerals doi: 10.3390/min8090391 Authors: Hao Jiang Ya Gao Sultan Ahmed Khoso Wanying Ji Yuehua Hu In this study, a new approach, “dynamic wettability”, and atomic force microscopy (AFM) imaging analysis techniques were successfully used to characterize the hydrophobization mechanism of the collector dodecylamine (DDA) on muscovite and talc surfaces. The attachment of bubbles to the minerals was studied through the dynamic contact angle to gain a detailed understanding of the hydrophobization mechanism of DDA on a muscovite and talc surface. AFM imaging and interaction forces were performed to explain the DDA adsorption mechanism on both minerals. Finally, flotation tests were performed to verify the effectiveness of these techniques. After treatments with DDA, the contact angles became much larger compared to initial angles, particularly for muscovite, and the attachment of bubbles on the talc surface was much easier than muscovite due to its natural hydrophobicity. From AFM imaging, both the muscovite and talc showed a similar tendency; the higher the DDA concentration, the more the adsorbed amount. However, the adsorbed amount of DDA on talc surface was obviously more than that on muscovite. As far as interaction forces are concerned, the maximum attractions occurred at certain different concentrations respectively for muscovite and talc and agreed well with the AFM-imaging results. Moreover, results obtained from flotation tests were promising and quite in agreement with the phenomenon of these techniques.

Description: Forests, Vol. 9, Pages 548: CO2 Footprint of the Seeds of Rubber (Hevea brasiliensis) as a Biodiesel Feedstock Source Forests doi: 10.3390/f9090548 Authors: Moritz Wagner Melvin Lippe Iris Lewandowski Mirko Salzer Georg Cadisch Crude rubber seed oil (CRSO) is a promising but currently underutilized biodiesel feedstock alternative, extracted by pressing the seeds of the rubber tree (Hevea brasiliensis). Rubber trees are cultivated across more than 11.4 million hectares worldwide, mainly in Southeast Asia. Despite their suitability as a biodiesel feedstock source, rubber seeds are currently treated as waste in the monocultural plantation system. To date, no assessments have been performed to examine the potential impact of rubber seed-based biodiesel production on GHG emissions. This study analyses the global warming potential of rubber seed methyl ester (RSME) production in Southeast Asia. The functional unit used is 1 MJ of biodiesel. A sensitivity analysis assesses the influence of key parameters (e.g., rubber seed yield) on the GHG mitigation potential. A scenario analysis evaluates the effect of using RSME by-products for energy generation. In comparison to fossil diesel, RSME has a carbon mitigation potential of 67 g CO2.eq. MJ−1, based on allocation by mass. On the condition of compliance with international sustainability standards that call for deforestation-free value chains, the generation of RSME biodiesel on rubber tree plantations in Southeast Asia would have a total mitigation potential of around 2.8 million tonnes of CO2 eq. per year.

Description: Forests, Vol. 9, Pages 558: Phenology and Synchrony of Scymnus coniferarum (Coleoptera: Coccinellidae) with Multiple Adelgid Species in the Puget Sound, WA, USA Forests doi: 10.3390/f9090558 Authors: Molly N. Darr Rachel K. Brooks Nathan P. Havill E. Richard Hoebeke Scott M. Salom The hemlock woolly adelgid (HWA), Adelges tsugae, is an invasive pest of Tsuga spp. in eastern North America. Scymnus coniferarum is a predaceous beetle that was collected from HWA in the western United States. Limited knowledge of this insect in its native habitat led to studies to evaluate its potential for biological control of HWA. Seasonal abundance was sampled at six sites in Tacoma, WA, twice monthly, for one year on different host trees of potential adelgid prey. Tree species included Pseudotsuga menziesii, Pinus contorta, Pinus monticola, and Tsuga heterophylla. Scymnus coniferarum adults were found on all conifer species, except P. menziesii. Each conifer species supported a different adelgid species, suggesting S. coniferarum feeds on multiple adelgid species. More S. coniferarum were found on pine than hemlock. DNA barcoding of S. coniferarum found two distinct clusters that differed by 6% divergence. Beetles in each cluster were co-habiting the same conifer species, and they could not be distinguished morphologically. Further taxonomic studies are needed to understand the significance of DNA barcode sequence divergence. Because S. coniferarum was more frequently associated with pine adelgids than HWA, and because of remaining taxonomic uncertainty, S. coniferarum may not be suitable for HWA biological control.

Description: Forests, Vol. 9, Pages 557: Surface Changes of Selected Hardwoods Due to Weather Conditions Forests doi: 10.3390/f9090557 Authors: Ivan Kubovský Eliška Oberhofnerová František Kačík Miloš Pánek The study is focused on the surface changes of five hardwoods (oak, black locust, poplar, alder and maple) that were exposed to natural weathering for 24 months in the climatic conditions of Central Europe. Colour, roughness, visual and chemical changes of exposed surface structures were examined. The lowest total colour changes (ΔE*) were found for oak (23.77), the highest being recorded for maple (34.19). Roughness differences after 24-month exposure (ΔRa) showed minimal changes in poplar wood (9.41); the highest changes in roughness were found on the surface of alder (22.18). The presence of mould and blue stains was found on the surface of maple, alder and poplar. Chemical changes were characterized by lignin and hemicelluloses degradation. Decreases of both methoxy and carbonyl groups, cleavage of bonds in lignin and hemicelluloses, oxidation reaction and formation of new chromophores were observed. In the initial phases of the degradation process, the discoloration was related to chemical changes; in the longer period, the greying due to settling of dust particles and action of mould influenced the wood colour. The data were confirmed by confocal laser scanning microscopy. The obtained results revealed degradation processes of tested hardwood surfaces exposed to external environmental factors.

Description: Forests, Vol. 9, Pages 556: Changes in Phylogenetic Community Structure of the Seedling Layer Following Hurricane Disturbance in a Human-Impacted Tropical Forest Forests doi: 10.3390/f9090556 Authors: Liza S. Comita María Uriarte Jimena Forero-Montaña W. John Kress Nathan G. Swenson Jill Thompson María Natalia Umaña Jess K. Zimmerman Disturbance plays a key role in shaping forest composition and diversity. We used a community phylogeny and long-term forest dynamics data to investigate biotic and abiotic factors shaping tropical forest regeneration following both human and natural disturbance. Specifically, we examined shifts in seedling phylogenetic and functional (i.e., seed mass) community structure over a decade following a major hurricane in a human-impacted forest in Puerto Rico. Phylogenetic relatedness of the seedling community decreased in the first five years post-hurricane and then increased, largely driven by changes in the abundance of a common palm species. Functional structure (based on seed mass) became increasingly clustered through time, due to canopy closure causing small-seeded, light-demanding species to decline in abundance. Seedling neighbor density and phylogenetic relatedness negatively affected seedling survival, which likely acted to reduce phylogenetic relatedness within seedling plots. Across the study site, areas impacted in the past by high-intensity land use had lower or similar phylogenetic relatedness of seedling communities than low-intensity past land use areas, reflecting interactive effects of human and natural disturbance. Our study demonstrates how phylogenetic and functional information offer insights into the role of biotic and abiotic factors structuring forest recovery following disturbance.

Description: Forests, Vol. 9, Pages 550: Investigations on the Effects of Seasonal Temperature Changes on the Electrical Resistance of Living Trees Forests doi: 10.3390/f9090550 Authors: Xiaoquan Yue Lihai Wang Xiaolong Shi Mingxian Xu Zhiming Zhu In order to use the electrical resistance method to accurately and timely detect and evaluate the internal decay defects of living trees, the effects of the seasonal temperature and moisture content on the electrical resistance of standing trees were investigated. At the Northeast Forestry University Experimental Forest Farm, Harbin, Heilongjiang Province of China, Populus simonii Populus simonii Carr. and Larix gmelinii (Rupr.) Rupr. were selected as the objects and the electrical resistance of standing trees was tested through different seasons from December 2016 to December 2017. Meanwhile, the effects of changes in the seasonal temperatures (−20 to −10 °C, −10 to −5 °C, −5 to 0 °C, 0 to 5 °C, 5 to 10 °C, 10 to 15 °C, 15 to 25 °C) as well as changes in the moisture content (MC) (Populus simonii, MC ≥ 103%; Larix gmelinii, MC ≥ 77.5%) on the electrical resistance in the cross-sections of living trees were studied. The influence of temperature at different moisture contents, the moisture content at different temperatures, and their combined effects on electrical resistance were analyzed, following which a regression model was also established. The obtained results indicated that ambient temperature had a significant effect on the average value of electrical resistance in the cross-section of living trees when temperatures were below the freezing point. There was a sudden discontinuity near the freezing point, and logR (logarithm value of electrical resistance) in the cross-sections of sound trees and decayed trees changed in a similar trend with variations in the temperature. While the effect of moisture content on logR in the cross-sections of threes was insignificant at different temperatures because of the moisture content above FSP (fiber saturation point). It indicated that the temperature and moisture content had interactive effects on logR in the cross-sections. The binary linear regression model between moisture content, temperature, and logR was highly fitted with a correlation coefficient (R2) higher than 0.8. The outcome of this investigation indicates that when non-destructive testing is performed on living trees using electrical resistance at different seasonal temperatures, the measured results need to consider both the temperature and moisture content. For practical work, it is not recommended to consider testing living trees near the freezing point temperature using the electrical resistive tomography. Below the freezing point, the electrical resistance changes with temperature greatly relative to the normal temperature. Therefore, when performing the detection of electrical resistance, it is necessary to calibrate the effects of temperature

Description: Forests, Vol. 9, Pages 549: Effect of Fertilization on Growth and Mortality of Jack Pine Growing on Poor, Sandy Soils in Michigan, USA: Implications for Sustainable Management Forests doi: 10.3390/f9090549 Authors: David E. Rothstein Our understanding of nutrient limitations to jack pine (Pinus banksiana Lamb.) growth is lacking across the Lake States of the USA (Michigan, Wisconsin and Minnesota), where this species makes up an important forest cover type on nutrient poor sands. Currently this cover type is managed using whole-tree harvesting (WTH) across large areas of state and federal forestland, which raises concerns for long-term declines in soil fertility and future productivity. In this study, I carried out a factorial fertilization experiment to better understand potential nutrient limitations to jack pine growth on excessively drained sandy soils in northern Lower Michigan. Treatments were nitrogen (N), phosphorus (P) and base cations applied singly and in all factorial combinations. In addition, I constructed input-output nutrient budgets for jack pine management in northern Lower Michigan using existing data on atmospheric deposition, weathering and harvest nutrient removals. In no case did I observe an increase in tree growth rate to fertilization, instead I observed an overall decline in growth rates, and an increase in mortality rates, in trees fertilized with N. Nitrogen-induced imbalances of foliar N: potassium (K) were strongly correlated with decreased growth in N amended plots. Together with nutrient budget analysis, which indicated that harvest removals of K greatly exceed inputs over the planned rotation, this suggests that WTH may not be sustainable over multiple rotations. Furthermore, the impacts of WTH on ecosystem K status are likely to be exacerbated over time by anthropogenic N deposition.

Description: Forests, Vol. 9, Pages 551: 70 Years of Land Use/Land Cover Changes in the Apennines (Italy): A Meta-Analysis Forests doi: 10.3390/f9090551 Authors: Francesco Malandra Alessandro Vitali Carlo Urbinati Matteo Garbarino Land use science usually adopts a case study approach to investigate landscape change processes, so we considered a meta-analysis an appropriate tool for summarizing general patterns and heterogeneous findings across multiple case studies over a large geographic area. Mountain landscapes in the Apennines (Italy) have undergone significant variations in the last century due to regional and national socio-economic changes. In this work, we reviewed 51 manuscripts from different databases and examined 57 case studies. We explored heterogeneous data sets, adopting a stepwise approach to select the case studies: Step 1, a general overview of the main studies; Step 2, an analysis of the features of the study sites and of land-use/cover transitions; Step 3, a landscape pattern analysis. We standardized the processing methods to obtain a new set of homogeneous data suitable for comparative analysis. After some pre-processing of the selected paper due to the broad heterogeneity of the data, we calculated common landscape metrics ex novo. We obtained digital images used to perform automatic segmentation with eCognition Developer 64 software. Our review indicated that most case studies were in Central and Southern Italy, 83% were examined at local scale, 77% carried out change detection, but only 38% included both change detection and landscape spatial pattern analysis. The results revealed a clear trend of forest expansion (+78%) and the reduction of croplands (−49%) and grasslands (−19%). We did not find significant changes in the landscape spatial patterns.

Description: Diversity, Vol. 10, Pages 100: Divergence, Convergence and Phenotypic Diversity of Neotropical Frugivorous Bats Diversity doi: 10.3390/d10030100 Authors: Oscar E. Murillo-García Maria E. De la vega Knowing how adaptation shapes morphological evolution is fundamental to understanding the processes that promote biological diversity. However, there is a lack of empirical evidence on the effects of adaptive radiations on phenotypic diversity, which is related to processes that promote phenotypic divergence and convergence. We applied comparative methods to identify shifts in adaptive peaks and to detect divergence and convergence in skull morphology of frugivorous bats (Phyllostomidae: Stenodermatinae and Carollinae), an ecologically diverse group with strong association between skull morphology, feeding performance and diet that suggests adaptive diversification through morphological innovation. We found divergence and convergence for skull morphology. Fifteen peak shifts were found for jaws, which result in four convergent and four divergent regimes. For skull, nine peak shifts were detected that result in three convergent and three divergent regimes. Furthermore, convergence was significant and strong for skull morphology since distantly related organisms converged to the same adaptive optima. Results suggest that convergence indicates the effect of restriction on phenotypes to keep the advantages provided by the skull phenotype that played a central role in the evolution of strict frugivory in phyllostomids. We conclude that convergence has limited phenotypic diversity of functional traits related to feeding in phyllostomid frugivores.

Description: Forests, Vol. 9, Pages 555: Generalized Nonlinear Mixed-Effects Individual Tree Crown Ratio Models for Norway Spruce and European Beech Forests doi: 10.3390/f9090555 Authors: Ram P. Sharma Zdeněk Vacek Stanislav Vacek Tree crowns are commonly measured to understand tree growth and stand dynamics. Crown ratio (CR—crown depth-to-total height ratio) is significantly affected by a number of tree- and stand-level characteristics and other factors as well. Generalized mixed-effects CR models were developed using a large dataset (measurements from 14,669 trees of Norway spruce (Picea abies (L.) Karst.) and European beech (Fagus sylvatica (L.)) acquired from permanent research plots in various parts of the Czech Republic. Among several tree- and stand-level variables evaluated, diameter at breast height, height to crown base, dominant height, basal area of trees larger in diameter than a focal tree, relative spacing index, and variables describing the effects of species mixture and canopy height differentiation significantly contributed to CR variation. We included sample-plot-level variations caused by randomness in the data and other stochastic factors into the CR models using the mixed-effects modeling approach. The logistic function, which predicts the values between 0 and 1, was chosen to develop the generalized CR mixed-effects model. A large proportion of the CR variation (R2adj ≈ 0.63 (Norway spruce); 0.72 (European beech)) was described by generalized mixed-effects model without significant residual trends. Testing the CR model against a part of the model fitting dataset confirmed its high prediction precision. Our CR model can be useful for growth simulation using inventory databases that lack crown measures. Other potential implications of our CR models in forest management are mentioned in the article.

Description: Forests, Vol. 9, Pages 554: Identification, Prioritization and Mapping of Ecosystem Services in the Panchase Mountain Ecological Region of Western Nepal Forests doi: 10.3390/f9090554 Authors: Shankar Adhikari Himlal Baral Craig R. Nitschke Ecosystem services (ES) are critical to human well-being, especially in developing countries. Improved understanding of the status of ES is required to help people improve their quality of life. The status of ES is largely unknown in many regions of Nepal. This study was carried out in one of Nepal’s biodiversity hotspots, the Panchase Mountain Ecological region (PMER), to identify, prioritize and map the major ES in the region. Primary data for the study were collected through key informant interviews, focus group discussions, a transect walk, and field observations. Similarly, secondary data were obtained from published and unpublished reports and satellite images of the study area. The data were analyzed both qualitatively and quantitatively. Thirty-seven ES were identified from the study landscape. Among them, nine were provisioning services, thirteen regulating services, nine cultural services, and six supporting services. Interestingly, the prioritization of ES among stakeholders differed on the basis of their background, particular features of their landscape, professional engagement, and individual interests. For instance, forest users prioritized provisioning services for their daily needs whereas forest managers prioritized regulating and cultural services for overall ecosystem management and aesthetic values. Mapping of the ES from the landscape for 1995 and 2015 identified that forest area and associated ES have likely increased, especially in the upland regions, while agricultural land and their associated ES have decreased. The study can be used as a reference by planners and policy makers in managing ES in the PMER to increase synergies and reduce trade-off among various services.

Description: Minerals, Vol. 8, Pages 397: The Saint-Honoré Carbonatite REE Zone, Québec, Canada: Combined Magmatic and Hydrothermal Processes Minerals doi: 10.3390/min8090397 Authors: Alexandre Néron Léo Paul Bédard Damien Gaboury The Saint-Honoré carbonatite complex hosts a rare earth element (REE) deposit traditionally interpreted as being produced by late-stage hydrothermal fluids that leached REE from apatite or dolomite found in the early units and concentrated the REE in the late-stage units. New evidence from deeper units suggest that the Fe-carbonatite was mineralized by a combination of both magmatic and hydrothermal crystallization of rare earth minerals. The upper Fe-carbonatite has characteristics typical of hydrothermal mineralization—polycrystalline clusters hosting bastnäsite-(Ce), which crystallized radially from carbonate or barite crystals, as well as the presence of halite and silicification within strongly brecciated units. However, bastnäsite-(Ce) inclusions in primary magmatic barite crystals have also been identified deeper in the Fe-carbonatite (below 1000 m), suggesting that primary crystallization of rare earth minerals occurred prior to hydrothermal leaching. Based on the intensity of hydrothermal brecciation, Cl depletion at depth and greater abundance of secondary fluid inclusions in carbonates in the upper levels, it is interpreted that hydrothermal activity was weaker in this deepest portion, thereby preserving the original magmatic textures. This early magmatic crystallization of rare earth minerals could be a significant factor in generating high-volume REE deposits. Crystallization of primary barite could be an important guide for REE exploration.

Description: Forests, Vol. 9, Pages 563: Distribution Changes of Phosphorus in Soil–Plant Systems of Larch Plantations across the Chronosequence Forests doi: 10.3390/f9090563 Authors: Fanpeng Zeng Xin Chen Bin Huang Guangyu Chi Phosphorus (P) is one of the most important factors influencing the growth and quality of larch plantations. A systematic knowledge of the dynamic changes of P in soil–plant systems can provide a theoretical basis for the sustainable development of larch plantations. We determined the concentration, biomass, and accumulation of P in five tree components (i.e., leaf, branch, bark, stem, and root), and the concentrations of various soil P fractions of larch plantations in 10-, 25-, and 50-year-old stands in northeast China. Our results showed that the N:P ratio and P concentration in leaves increased with stand age, indicating that the growth of larch plantations might be limited by P in the development of stands. The N:P ratio and P concentration in roots, and P resorption efficiency, increased with stand age, indicating the use efficiency of P could be enhanced in older stands. The concentrations of soil-labile P fractions (Resin-P, NaHCO3-Pi, and NaHCO3-Po) in 25- and 50-year-old stands were significantly lower than those in 10-year-old stands, indicating the availability of soil P decreases with the development of larch plantations.

Description: Forests, Vol. 9, Pages 562: Fine-Root Responses of Populus tomentosa Forests to Stand Density Forests doi: 10.3390/f9090562 Authors: Huijuan Bo Chunyan Wen Lianjun Song Yatao Yue Lishui Nie Stand density directly affects the distribution of ecological factors such as light, heat, and water in forest communities and changes the diversity and structure of undergrowth species, thereby affecting soil health. Fine roots can provide water and nutrients to plants rapidly in the fierce competition of soil resources, so as to get rid of environmental factors. This study examined the fine-root responses of the Populus tomentosa clone S86 to three stand densities (plant × row spacing: 2 × 2 m, 4 × 3 m, 4 × 5 m). We measured the biomass, morphology, and nitrogen content of lower- (1–3 order) and higher-order (>3 order) fine roots, and analyzed soil chemical properties in 10–30 cm. The soil from the density (2 × 2 m) stands showed lower soil organic matter content, available nitrogen, available phosphorous, and available potassium than others. Obviously, lower and higher-order fine roots were different: biomass of the >3 order accounted for 77–87% of the total biomass, 1–3-order fine-root diameter around 0.28–0.38 mm, while >3-order fine root were 1.28–1.69 mm; the length of 1–3-order fine root was longer than the >3 order, and root length density, specific root length, and nutrient content between the 1–3 and >3 orders were different. At 2 × 2 m, 1–3-order fine-root biomass was the highest, 132.5 g/m3, and the 1–3-order fine-root length, diameter, surface, root length density was also the highest; at the same time, the 1–3-order fine-root total nitrogen and organic matter content was also the highest, while the >3 order was highest under 4 × 3 m or 4 × 5 m. The findings of this study show that stand density affected the available nutrient content of the soil. When soil resources were poor, the biomass, morphology, and chemical content of fine roots were adjusted to increase the nutrient absorption rate, particularly in the lower-order roots.

Description: Forests, Vol. 9, Pages 564: Drought-Affected Populus simonii Carr. Show Lower Growth and Long-Term Increases in Intrinsic Water-Use Efficiency Prior to Tree Mortality Forests doi: 10.3390/f9090564 Authors: Shoujia Sun Lanfen Qiu Chunxia He Chunyou Li Jinsong Zhang Ping Meng The Three-North Shelter Forest (TNSF) is a critical ecological barrier against sandstorms in northern China, but has shown extensive decline and death in Populus simonii Carr. in the last decade. We investigated the characteristics—tree-ring width, basal area increment (BAI), carbon isotope signature (13Ccor), and intrinsic water-use efficiency (iWUE)—of now-dead, dieback, and non-dieback trees in TNSF shelterbelts of Zhangbei County. Results from the three groups were compared to understand the long-term process of preceding drought-induced death and to identify potential early-warning proxies of drought-triggered damage. The diameter at breast height (DBH) was found to decrease with the severity of dieback, showing an inverse relationship. In all three groups, both tree-ring width and BAI showed quadratic relationships with age, and peaks earlier in the now-dead and dieback groups than in the non-dieback group. The tree-ring width and BAI became significantly lower in the now-dead and dieback groups than in the non-dieback group from 17 to 26 years before death, thus, these parameters can serve as early-warning signals for future drought-induced death. The now-dead and dieback groups had significantly higher δ13Ccor and iWUEs than the non-dieback group at 7–16 years prior to the mortality, indicating a more conservative water-use strategy under drought stress compared with non-dieback trees, possibly at the cost of canopy defoliation and long-term shoot dieback. The iWUE became significantly higher in the now-dead group than in the dieback group at 0–7 years before death, about 10 years later than the divergence of BAI. After the iWUE became significantly different among the groups, the now-dead trees showed lower growth and died over the next few years. This indicates that, for the TNSF shelterbelts studied, an abrupt iWUE increase can be used as a warning signal for acceleration of impending drought-induced tree death. In general, we found that long-term drought decreased growth and increased iWUE of poplar tree. Successive droughts could drive dieback and now-dead trees to their physiological limits of drought tolerance, potentially leading to decline and mortality episodes.

Description: Minerals, Vol. 8, Pages 406: Comparative Analysis of Attachment to Chalcopyrite of Three Mesophilic Iron and/or Sulfur-Oxidizing Acidophiles Minerals doi: 10.3390/min8090406 Authors: Qian Li Baojun Yang Jianyu Zhu Hao Jiang Jiaokun Li Ruiyong Zhang Wolfgang Sand Adhesion plays an important role in bacterial dissolution of metal sulfides, since the attached cells initiate the dissolution. In addition, biofilms, forming after bacterial attachment, enhance the dissolution. In this study, interactions between initial adhesion force, attachment behavior and copper recovery were comparatively analyzed for Acidithiobacillus ferrooxidans, Acidithiobacillus thiooxidans, and Leptospirillum ferrooxidans during bioleaching of chalcopyrite. The adhesion forces between bacteria and minerals were measured by atomic force microscopy (AFM). L. ferrooxidans had the largest adhesion force and attached best to chalcopyrite, while A. ferrooxidans exhibited the highest bioleaching of chalcopyrite. The results suggest that the biofilm formation, rather than the initial adhesion, is positively correlated with bioleaching efficiency.

Description: Minerals, Vol. 8, Pages 409: The Lengenbach Quarry in Switzerland: Classic Locality for Rare Thallium Sulfosalts Minerals doi: 10.3390/min8090409 Authors: Thomas Raber Philippe Roth The Lengenbach quarry is a world-famous mineral locality, especially known for its rare and well-crystallized Tl, Pb, Ag, and Cu bearing sulfosalts. As of June 2018, it is the type locality for 44 different mineral species, making it one of the most prolific localities worldwide. A total of 33 thallium mineral species have been identified, 23 of which are type minerals. A brief description of several thallium species of special interest follows a concise and general overview of the thallium mineralization.

Description: Minerals, Vol. 8, Pages 408: Structural Control on Clay Mineral Authigenesis in Faulted Arkosic Sandstone of the Rio do Peixe Basin, Brazil Minerals doi: 10.3390/min8090408 Authors: Ingrid B. Maciel Angela Dettori Fabrizio Balsamo Francisco H.R. Bezerra Marcela M. Vieira Francisco C.C. Nogueira Emma Salvioli-Mariani Jorge André B. Sousa Clay minerals in structurally complex settings influence fault zone behavior and characteristics such as permeability and frictional properties. This work aims to understand the role of fault zones on clay authigenesis in arkosic, high-porosity sandstones of the Cretaceous Rio do Peixe basin, northeast Brazil. We integrated field, petrographic and scanning electron microscopy (SEM) observations with X-ray diffraction data (bulk and clay-size fractions). Fault zones in the field are characterized by low-porosity deformation bands, typical secondary structures developed in high-porosity sandstones. Laboratory results indicate that in the host rock far from faults, smectite, illite and subordinately kaolinite, are present within the pores of the Rio do Peixe sandstones. Such clay minerals formed after sediment deposition, most likely during shallow diagenetic processes (feldspar dissolution) associated with meteoric water circulation. Surprisingly, within fault zones the same clay minerals are absent or are present in amounts which are significantly lower than those in the undeformed sandstone. This occurs because fault activity obliterates porosity and reduces permeability by cataclasis, thus: (1) destroying the space in which clay minerals can form; and (2) providing a generally impermeable tight fabric in which external meteoric fluid flow is inhibited. We conclude that the development of fault zones in high-porosity arkosic sandstones, contrary to other low-porosity lithologies, inhibits clay mineral authigenesis.

Description: Diversity, Vol. 10, Pages 103: Sonar Surveys for Bat Species Richness and Activity in the Southern Kalahari Desert, Kgalagadi Transfrontier Park, South Africa Diversity doi: 10.3390/d10030103 Authors: Rick A. Adams Gary Kwiecinski Kgalagadi Transfrontier Park is located in northwestern South Africa and extends northeastward into Botswana. The park lies largely within the southern Kalahari Desert ecosystem where the Auob and Nassob rivers reach their confluence. Although these rivers run only about once every 100 years, or shortly after large thunderstorms, underground flows and seeps provide consistent surface water for the parks sparse vegetation and diverse wildlife. No formal studies on bats have previously occurred at Kgalagadi. We used SM2 + BAT ultrasonic detectors to survey 10 sites along the Auob and Nassob rivers from 5–16 April 2016. The units recorded 3960 call sequences that were analyzed using Kaleidoscope software for South African bats as well as visual determinations based on call structure attributes (low frequency, characteristic frequency, call duration, and bandwidth). We identified 12 species from four families: Rhinolophidae: Rhinolophus fumigatus. Molossidae: Chaerephon pumilus, and Sauromys petrophilus, Tadarida aegyptiaca; Miniopteridae: Miniopteris schreibersi (natalensis), Vespertilionidae: Laephotis botswanae, Myotis tricolor, Neoromicia capensis, N. nana, Pipistrellus hesperidus, Scotophilus dinganii, and S. viridus. The most abundant species during the survey period was N. capensis. We also used paired-site design to test for greater bat activity at water sources compared to dry sites, with dry sites being significantly more active. We conclude that species richness is much higher than previously known from this region and that more species may be present during the warmer months of the year. In addition, activity of bats during the dry season in Kgalagadi would likely be more concentrated around drinking opportunities, thus allowing for better detection of species richness in the area.

Description: Forests, Vol. 9, Pages 574: Effects of Forest Management Practices on Moth Communities in a Japanese Larch (Larix kaempferi (Lamb.) Carrière) Plantation Forests doi: 10.3390/f9090574 Authors: Mi Young Moon Sung-Soo Kim Dae-Seong Lee Hee Moon Yang Chan-Woo Park Hyun Seop Kim Young-Seuk Park Biodiversity in forests is strongly affected by forest management practices, such as clearcutting and aggregated retention. Therefore, the assessment of the effects of forest management on biodiversity is a major concern in forest ecology. In the present study, we aimed to characterize the effects of forest management practices, after one year, on the abundance, species richness, community composition, and functional groups of moths in forests. The moths were sampled in four different forest stands: three stands (clearcutting, aggregated retention, and no cutting) in a planted Japanese larch forest and one stand in a natural Mongolian oak forest. The results revealed that the moth communities changed in response to the changes in vegetation after the implementation of forest management practices, and clearcutting increased the abundance and species richness of herbivorous and warm-adapted species. The structure and function of moth communities were affected by the forest management practices such as clearcutting and aggregated retention, which were reflected by a decrease in community indices and change in moth community composition with changes in vegetation.

Description: Forests, Vol. 9, Pages 577: Contribution of Harvest Residues to Nutrient Cycling in a Tropical Acacia mangium Willd. Plantation Forests doi: 10.3390/f9090577 Authors: Nguyen Van Bich Alieta Eyles Daniel Mendham Tran Lam Dong David Ratkowsky Katherine J. Evans Vo Dai Hai Hoang Van Thanh Nguyen Van Thinh Caroline Mohammed Harvest residues can play a crucial role in conserving nutrients for recycling in forests, but little is known about the rates of decomposition and nutrient release from these residues following logging in tropical acacia plantations. In this study, we examined the biomass and nutrient content of harvest residue components (bark, leaves, and branches) using the litterbag technique for a 1.5-year-period following harvest of a seven-year-old Acacia mangium plantation in Northern Vietnam. At harvest, the total dry biomass of harvest residues was 18 t ha−1 comprising bark (8.9 t ha−1), branches (6.6 t ha−1), and leaves (2.5 t ha−1). The retained bark on site conserved 51% N, 29% P, 32% K, 64% Ca, and 24% Mg content from harvest residues for recycling. Decomposition rate of the leaves was the most rapid (k = 1.47 year−1; t0.5 = 0.47 year), then branches (k = 0.54 year−1; t0.5 = 1.29 year), and bark (k = 0.22 year−1; t0.5 = 3.09 year). During decomposition, the loss of nutrients from harvest residues was K ≈ Ca > N > P> Mg. Decomposition of harvest residues and the associated rate of nutrient release can potentially supply a significant amount of nutrients required for stand development in the next rotation.

Description: Minerals, Vol. 8, Pages 413: Infra Red Spectroscopy of the Regulated Asbestos Amphiboles Minerals doi: 10.3390/min8090413 Authors: Giancarlo Della Ventura Ruggero Vigliaturo Reto Gieré Simone Pollastri Alessandro F. Gualtieri Gianluca Iezzi Vibrational spectroscopies (Fourier Transform Infra Red, FTIR, and Raman) are exceptionally valuable tools for the identification and crystal–chemical study of fibrous minerals, and asbestos amphiboles in particular. Raman spectroscopy has been widely applied in toxicological studies and thus a large corpus of reference data on regulated species is found in the literature. However, FTIR spectroscopy has been mostly used in crystal–chemical studies and very few data are found on asbestos amphiboles. This paper is intended to fill this gap. We report new FTIR data collected on a suite of well-characterized samples of the five regulated amphibole species: anthophyllite, amosite, and crocidolite, provided by the Union for International Cancer Control (UICC) Organization, and tremolite and actinolite, from two well-known occurrences. The data from these reference samples have been augmented by results from additional specimens to clarify some aspects of their spectroscopic features. We show that the FTIR spectra in both the OH-stretching region and in the lattice modes region can be effective for rapid identification of the asbestos type.

Description: Minerals, Vol. 8, Pages 414: Supergene Uranyl Mineralization of the Rabejac Deposit, Lodève, France Minerals doi: 10.3390/min8090414 Authors: Fabrice Dal Bo Frédéric Hatert Simon Philippo The Rabejac uranium deposit that is located in the Lodève region, France, is the type locality for three uranyl minerals species (fontanite, seelite, and rabejacite). In addition, this deposit shows an extraordinary supergene uranyl mineralization characterized by the presence of many rare secondary uranyl species. In the present study, a mineralogical description as well as new chemical and crystallographic data are reported on (meta)zeunerite, (meta)nováčekite, (meta)uranospinite, heinrichite, nováčekite-I, arsenuranospathite, umohoite, calcurmolite, becquerelite, billietite, and liebigite. The chemical data indicate that the arsenate members of the autunite/meta-autunite group incorporate a significant amount of phosphorus. Moreover, the uranospinite samples usually exhibit high Mg content, thus moving toward the nováčekite end-member composition. The refined unit-cell parameters for all of the investigated mineral species are in agreement with the previous data reported in the literature. Finally, a model describing the alteration of the primary uraninite and the formation of secondary uranyl minerals is proposed in agreement with the observed mineral assemblages.

Description: Minerals, Vol. 8, Pages 412: Intracrystalline Reaction-Induced Cracking in Olivine Evidenced by Hydration and Carbonation Experiments Minerals doi: 10.3390/min8090412 Authors: Romain Lafay German Montes-Hernandez François Renard Pierre Vonlanthen In order to better understand the microtextural changes associated with serpentinization reactions, natural millimeter-sized olivine grains were experimentally reacted with alkaline NaOH and NaHCO3 solutions at a temperature of 200 °C and for durations of 3 to 12 months. During hydration experiments, dissolution and precipitation were intimately correlated in time and space, with reaction products growing in situ, either as layered veins or as nearly continuous surface cover. In contrast, carbonation experiments showed a strong decoupling between both processes leading to essentially delocalized precipitation of the reaction products away from dissolution sites. Textural analyses of the samples using scanning electron microscopy, Raman spectroscopy, and X-ray synchrotron microtomography provided experimental evidence for a cause-and-effect relationship between in situ precipitation and intracrystalline reaction-induced cracking in olivine. Juvenile cracks typically nucleated at the tip of dissolution notches or on diamond-shaped pores filled with reaction products, and propagated through the olivine crystal lattice during the course of the reaction. The occurrence of new cracks at the tip of diamond-shaped pores, but also of tiny subspherical pores lining up along microcracks, indicated that fracturation and porosity networks were mutually driven, making serpentinization an extremely efficient alteration process over time. Alternatively, our data suggested that some form of porosity also developed in absence of fracturation, thus further highlighting the remarkable efficiency and versatility of serpentinization processes.

Description: Minerals, Vol. 8, Pages 411: Chemical Stability and Leaching Behavior of One-Part Geopolymer from Soil and Coal Fly Ash Mixtures Minerals doi: 10.3390/min8090411 Authors: April Anne S. Tigue Roy Alvin J. Malenab Jonathan R. Dungca Derrick Ethelbhert C. Yu Michael Angelo B. Promentilla Aluminosilicate minerals have become an important resource for an emerging sustainable material for construction known as geopolymer. Geopolymer, an alkali-activated material, is becoming an attractive alternative to Portland cement because of its lower carbon footprint and embodied energy. However, the synthesis process requires typically a two-part system for alkali activation wherein the solid geopolymer precursor is mixed with aqueous alkali solutions. These alkali activators are corrosive and may be difficult to handle in the field-scale application. In this study, a one-part geopolymer in which coal fly ash was mixed with solid alkali activators such as sodium hydroxide and sodium silicate to form a powdery cementitious binder was developed. This binder mixed with soil only requires water to form the soil-fly ash (SO-CFA) geopolymer cement, which can be used as stabilized soil for backfill/foundation. This geopolymer product was then evaluated for chemical stability by immersing the material with 5% by weight of sulfuric acid solution for 28 days. Indication suggests that the geopolymer exhibited high resistance against acid attack with an observed increase of unconfined compressive strength even when the immersion time in acidic solution was increased to 56 days. The mineralogical phase, microstructure, and morphology of the material were characterized by X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, and scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDX), respectively. Results not only confirmed the formation of gypsum due to acid attack but also indicated the dissolution of anorthite and albite that may have caused the microstructure to be composed of sodium aluminosilicate hydrate (N–A–S–H) and calcium (alumino) silicate hydrate (C(–A)–S–H) with poly(ferro-sialate-siloxo) and poly(ferro-sialate-disiloxo) networks. A column leaching test with deionized water was also performed on the soil-fly ash geopolymer to study the leachability of metals in the material. Results showed that arsenic exhibits higher mobility in the geopolymer as compared to that of cadmium, chromium, and lead.

Description: Forests, Vol. 9, Pages 584: The Concept of Landscape Structure, Forest Continuum and Connectivity as a Support in Urban Forest Management and Landscape Planning Forests doi: 10.3390/f9100584 Authors: Janez Pirnat David Hladnik Close-to-nature urban forests and remnants of natural vegetation represent an important opportunity for urban residents to experience daily perception of and access to the natural environment. Despite there being a high percentage of forest cover (59%) and a favorable structure of the prevailing forested landscapes in Slovenia, urban expansion and infrastructure-driven development has severely weakened the connectivity and conservation of urban and suburban forests. The majority of urban settlements lie within walking distance of the surrounding forests (<1 km). However, only close-to-nature forests with relatively low silvicultural inputs offer ecosystem services sufficient to fulfil the supply and demand of the expanding urban population. In order to estimate the conservation of forests in the open space of Slovenian settlements, we used a spatial model of landscape structure and forest connectivity. The model can be enhanced with patterns of corridors and stepping stones of natural vegetation in the landscape matrix to provide support in the decision-making process of landscape planning and the conservation of urban and suburban forests.

Description: Forests, Vol. 9, Pages 585: Optimizing the Location of Biomass Energy Facilities by Integrating Multi-Criteria Analysis (MCA) and Geographical Information Systems (GIS) Forests doi: 10.3390/f9100585 Authors: Heesung Woo Mauricio Acuna Martin Moroni Mohammad Sadegh Taskhiri Paul Turner Internationally forest biomass is considered to be a valuable renewable energy feedstock. However, utilization of forest harvesting residues is challenging because they are highly varied, generally of low quality and usually widely distributed across timber harvesting sites. Factors related to the collection, processing and transport impose constraints on the economic viability of residue utilization operations and impact their supply from dispersed feedstock locations. To optimize decision-making about suitable locations for biomass energy plants intending to use forest residues, it is essential to factor in these supply chain considerations. This study conducted in Tasmania, Australia presents an investigation into the integration of Multi-criteria analysis (MCA) and Geographical Information systems (GIS) to identify optimal locations for prospective biomass power plants. The amount of forest harvesting biomass residues was estimated based on a non-industrial private native resource model in Tasmania (NIPNF). The integration of MCA and a GIS model, including a supply chain cost analysis, allowed the identification and analysis of optimal candidate locations that balanced economic, environmental, and social criteria within the biomass supply. The study results confirm that resource availability, land use and supply chain cost data can be integrated and mapped using GIS to facilitate the determination of different sustainable criteria weightings, and to ultimately generate optimal candidate locations for biomass energy plants. It is anticipated that this paper will make a contribution to current scientific knowledge by presenting innovative approaches for the sustainable utilization of forest harvest residues as a resource for the generation of bioenergy in Tasmania.

Description: Forests, Vol. 9, Pages 582: Estimation of Forest Above-Ground Biomass by Geographically Weighted Regression and Machine Learning with Sentinel Imagery Forests doi: 10.3390/f9100582 Authors: Lin Chen Chunying Ren Bai Zhang Zongming Wang Yanbiao Xi Accurate forest above-ground biomass (AGB) is crucial for sustaining forest management and mitigating climate change to support REDD+ (reducing emissions from deforestation and forest degradation, plus the sustainable management of forests, and the conservation and enhancement of forest carbon stocks) processes. Recently launched Sentinel imagery offers a new opportunity for forest AGB mapping and monitoring. In this study, texture characteristics and backscatter coefficients of Sentinel-1, in addition to multispectral bands, vegetation indices, and biophysical variables of Sentinal-2, based on 56 measured AGB samples in the center of the Changbai Mountains, China, were used to develop biomass prediction models through geographically weighted regression (GWR) and machine learning (ML) algorithms, such as the artificial neural network (ANN), support vector machine for regression (SVR), and random forest (RF). The results showed that texture characteristics and vegetation biophysical variables were the most important predictors. SVR was the best method for predicting and mapping the patterns of AGB in the study site with limited samples, whose mean error, mean absolute error, root mean square error, and correlation coefficient were 4 × 10−3, 0.07, 0.08 Mg·ha−1, and 1, respectively. Predicted values of AGB from four models ranged from 11.80 to 324.12 Mg·ha−1, and those for broadleaved deciduous forests were the most accurate, while those for AGB above 160 Mg·ha−1 were the least accurate. The study demonstrated encouraging results in forest AGB mapping of the normal vegetated area using the freely accessible and high-resolution Sentinel imagery, based on ML techniques.

Description: Minerals, Vol. 8, Pages 418: Authigenic Mg-Clay Minerals Formation in Lake Margin Deposits (the Cerro de los Batallones, Madrid Basin, Spain) Minerals doi: 10.3390/min8100418 Authors: Juan Emilio Herranz Manuel Pozo The Madrid Basin contains large and well developed deposits of Mg-clays of Miocene age. These were developed in an environment controlled by a lacustrine saline-alkaline environment with an arid or semi-arid climate, leading to large deposits of Mg-clays. This paper summarizes the study about the formation of Mg-clay minerals in the transition from mudflat lithofacies made-up of Mg-smectite to palustrine lithofacies where sepiolite is predominant. The samples collected in the field were characterized by XRD (X-Ray Diffaction) (bulk sample and clay fraction), examined using SEM (Scanning Electron Microscopy) and analyzed by XRF (X-Ray Fluorescence) and FTIR (Fourier Transform Infrared Spectroscopy). The results suggest that during the formation of these materials dissolution-precipitation, direct precipitation and recrystallization mechanisms intervened. The type of water present (runoff, lake and/or groundwater) is a key factor for the development of the different mineral phases. In the case of the study, the analyzed series goes from mudflat conditions with influence of runoff water to a palustrine environment. During this evolution, the influence of groundwater increases with time. This is reflected in the affinity between the samples analyzed and the presence of certain elements that could serve as indicators of changes between different media.

Description: Forests, Vol. 9, Pages 580: The Effect of Combined Herbivory by Wild Boar and Small Ruminants on the Regeneration of a Deciduous Oak Forest Forests doi: 10.3390/f9090580 Authors: Eleni M. Abraham Paraskevi Sklavou Aikaterini Loufi Zoi M. Parissi Apostolos P. Kyriazopoulos The multiple agroforestry land uses of oak forests are of great ecological and economic interest as they contribute to the improvement of animal husbandry, wildlife, and environment. However, herbivory by wildlife and livestock highly affects the structure and the dynamic of forest ecosystems including its regeneration. The aim of this study was to investigate the comparative effect of wild boar and small ruminants herbivory on the regeneration of a deciduous oak forest in northern Greece. Eight sites were selected in an even aged stand of similar canopy cover and forest site quality: four sites with long-time use mainly by wild boar and four sites with long-time grazing by sheep and browsing by goats. A plot of 150 m2 in each of the sites was fenced in order to be protected from herbivory. The plant cover and number of oak seedlings and acorns was measured in both grazed and protected plots for four consecutive years. The plant cover increased in the protected plots independent of the type of animals. The seedling cover decreased about 29% and 9% in sites where small ruminants and wild boars foraged respectively. Similarly, the number and the weight of acorns significantly decreased in the sites grazed by small ruminants mainly during the mast year of the oaks. Forest management has to control the small ruminants grazing in terms of intensity, timing, and duration in order to ensure the sustainability of the ecosystem.

Description: Forests, Vol. 9, Pages 581: Effect of Vegetation Management and Site Conditions on Volume, Biomass and Leaf Area Allometry of Four Coniferous Species in the Pacific Northwest United States Forests doi: 10.3390/f9090581 Authors: Carlos A. Gonzalez-Benecke Herman N. Flamenco Maxwell G. Wightman Allometric equations are useful tools for calculating tree and stand-level attributes, such as above-ground biomass or stem volume, using simple measurements that can be obtained from stand inventory data. These equations tend to be species-specific and can be affected by site conditions and silvicultural treatments. Forest vegetation management treatments (VM) are an important component of reforestation programs in the Pacific Northwest of the United States; however, no study has investigated the impact of these treatments on crop tree allometry. In this study we assessed the long-term effects of two contrasting VM treatments on the allometry of sixteen-year-old Douglas-fir, western hemlock, western redcedar, and grand fir trees growing in Oregon’s central Coast Range (CR) and fifteen-year-old Douglas-fir and western redcedar trees growing in Oregon’s Cascade foothills (CF). The VM treatments included a control which received only a pre-planting herbicide application and a VM treatment consisting of five consecutive years of vegetation control after planting. The equations developed in this study were species-specific and were not affected by VM with the exception of western redcedar foliage biomass. For western redcedar, tress of similar diameter had more foliage biomass when growing on plots without VM after planting. The allometry of Douglas-fir and western redcedar was also found to be affected by site, such that trees of similar diameter and height had larger stem volume when growing at the CR site than the CF site. This difference in stem volume was found to be the result of differences in stem tapering. There was a strong relationship between stand basal area and leaf area index that was the same for all species tested and was unaffected by site. The equations presented in this study are useful for calculating stem volume, leaf area and individual tree and component biomass for stands of the studied species that are of similar age.

Description: Minerals, Vol. 8, Pages 416: Rare Earth and Phosphorus Leaching from a Flotation Tailings of Florida Phosphate Rock Minerals doi: 10.3390/min8090416 Authors: Haijun Liang Patrick Zhang Zhen Jin David W. DePaoli Phosphorite, or phosphate rock, is the raw material of phosphoric acid production. It has also been regarded as the most important secondary rare earth element (REE) resource due to low contents of rare earth elements contained in the ore. In Florida, there is about 19 Mt of phosphate rock mined annually. After beneficiation, the phosphate rock concentrate is utilized to produce phosphoric acid via a wet-process in which sulfuric acid is used to digest phosphate. During these processes, REEs and some phosphorus get lost in the byproducts including phosphatic clay, flotation tailings, phosphogypsum (PG), and phosphoric sludge. Recovering REEs and phosphorus from these wastes is beneficial to maximize the utilization of these valuable resources. This study focused on the effects of wet-process operating conditions on REE and phosphorus leaching from a kind of flotation tailing of Florida phosphate rock. The tailings were first beneficiated with a shaking table, and then a series of leaching tests were conducted on the shaking table concentrate. The results indicated that REEs had similar trends of leaching efficiency to those of phosphorus. Under the conditions of 16% phosphoric acid concentration in the initial pulp, a temperature of 75 °C, a stoichiometric ratio of sulfuric acid (H2SO4) to calcium oxide (CaO) of 1.1, and a weight ratio of liquid to solid of 3.5, REE and phosphorus leaching efficiencies reached relatively high values of approximately 61% and 91%, respectively. Analyses indicated that the phosphate ions (PO43−) in the leaching solution tended to combine with REE ions to form REE phosphates which precipitated into PG, but the other large amount of anions such as sulfate ions (SO42−) and fluoride ions (F−) took effect of steric hindrance to prevent PO43− from combining with REE cations. These two opposite effects determined the REE distribution between the leaching solution and PG.

Description: Forests, Vol. 9, Pages 589: Assessing the Progress of REDD+ Projects towards the Sustainable Development Goals Forests doi: 10.3390/f9100589 Authors: Charlotte Milbank David Coomes Bhaskar Vira Almost a decade since the establishment of Reducing Emissions from Deforestation and Degradation (REDD+), this study investigates the extent to which REDD+ projects are delivering on the promise of co-benefits and the elusive ‘triple-win’ for climate, biodiversity, and local communities. The Climate, Community and Biodiversity Alliance (CCB) is among several leading REDD+ certification standards that are designed to support the delivery of social and environmental co-benefits, and ‘socially-just’ carbon. This study uses an in-depth content analysis of 25 subnational REDD+ project documents to assess the extent to which REDD+ project objectives align with Sustainable Development Goals (SDG) targets, and evaluates the reporting of progress towards meeting these objectives. Currently the CCB standards address a relatively small subset of SDG targets. Despite this, we find that REDD+ projects aspire to work on a much broader set of SDG target objectives, thus going beyond what the CCB Standards require for REDD+ validation. However, although reviewed REDD+ projects have these aspirations, very few are actively monitoring impact against the goals. There is a gap between aspiration and reported progress at the goal level, and for each project: on average, only a third of SDGs that are being targeted by REDD+ projects are showing ‘improvement’. The analysis shows which global goals are most frequently targeted, and which are the least. It also allows an analysis of which projects are following through most effectively in terms of monitoring progress towards the SDGs. This assessment provides insights into the priorities of REDD+ project proponents, suggesting that REDD+ has unfulfilled potential to elicit positive change in relation to the SDGs. Our analysis also shows that there is considerable potential for the safeguarding bodies to do more to ensure that real improvements are made, and reported against, aligning REDD+ projects more strongly with global development agendas.

Description: Forests, Vol. 9, Pages 587: Tree- and Stand-Level Biomass Estimation in a Larix decidua Mill. Chronosequence Forests doi: 10.3390/f9100587 Authors: Andrzej M. Jagodziński Marcin K. Dyderski Kamil Gęsikiewicz Paweł Horodecki Carbon pool assessments in forests is one of the most important tasks of forest ecology. Despite the wide cultivation range, and economical and traditional importance, the aboveground biomass of European larch (Larix decidua Mill.) stands is poorly characterized. To increase knowledge about forest biomass accumulation and to provide a set of tools for aboveground biomass estimation, we studied a chronosequence of 12 larch forest stands (7–120 years old). From these stands, we measured the biomass of 96 sample trees ranging from 1.9 to 57.9 cm in diameter at breast height. We provided age-specific and generalized allometric equations, biomass conversion and expansion factors (BCEFs) and biomass models based on forest stand characteristics. Aboveground biomass of stands ranged from 4.46 (7-year-old forest stand) to 445.76 Mg ha−1 (106-year-old). Stand biomass increased with increasing stand age, basal area, mean diameter, height and total stem volume and decreased with increasing density. BCEFs of the aboveground biomass and stem were almost constant (mean BCEFs of 0.4688 and 0.3833 Mg m−3, respectively). Our generalized models at the tree and stand level had lower bias in predicting the biomass of the forest stands studied, than other published models. The set of tools provided fills the gap in biomass estimation caused by the low number of studies on larch biomass, which allows for better estimation of forest carbon pools.

Description: Forests, Vol. 9, Pages 588: Relationships between Tree Vigor Indices and a Tree Classification System Based upon Apparent Stem Defects in Northern Hardwood Stands Forests doi: 10.3390/f9100588 Authors: Edouard Moreau Steve Bédard Guillaume Moreau David Pothier Many northern hardwood stands include several low-vigor trees as a result of past management. To restore these degraded stands, partial cuts are applied with partly validated tree classification systems that are based upon apparent stem defects. We sampled 214 sugar maple (Acer saccharum Marsh.) and 84 yellow birch (Betula alleghaniensis Britt.) trees from six sites covering the northern hardwood forest zone of the Province of Quebec, Canada. We evaluated their vigor with a four-class system, and quantified the growth efficiency index and several indices that were based solely upon radial growth. The growth efficiency index increased non-significantly with increasing tree vigor class. The five-year basal area increment (BAI-1-5) was significantly different between the lowest and highest tree vigor classes. Yet, temporal changes in BAI-1-5 helped classify correctly only 16% of high-vigor trees that became poorly vigorous 8–10 years later. Overall, these results suggest that the tree classification system is weakly related to actual tree vigor and its application likely generates few significant gains in future stand vigor. Modifying and simplifying the tree vigor system must be considered to facilitate the tree marking process that is required to improve the vigor of degraded stands.

Description: Forests, Vol. 9, Pages 590: Influential Actors’ Perceptions of Facilitators and Instruments for Solving Future Forest Land-Use Disputes in Europe Forests doi: 10.3390/f9100590 Authors: Peter K. Aurenhammer Špela Ščap Nike Krajnc Jorge Olivar Pablo Sabin Sílvia Nobre Francesco Romagnoli Despite strong expectations regarding the role that forestry, with its multitude of potential benefits, could and should play in the ‘bio-economy’, little research has been done on the actual perceptions of influential actors on how to best address future forest land-use disputes. We want to shed light on whether and in which contexts expectations regarding the bio-economy, e.g., the strong role of markets, are likely. The paper analyses influential actors’ core values and beliefs about the primary facilitators and the most appropriate instruments for resolving disputes over future forest land use. We used Social Network Analysis-based sampling and a quantitative semi-structured questionnaire, which included a preference analysis with twelve items covering broad issues and disputes related to future forest land use, to identify actors’ beliefs about and preferences for facilitators and policy instruments within key issues for future land use. The respondents were asked to identify one of five ‘primary facilitators’ (state, market, society, individual citizens/owners, leave it to nature) and distribute six points to a maximum of three preferred instruments (eight items, covering a broad set of instruments, from dictates or bans to awareness raising). The results are based on the perceptions of the influential or most important actors from various innovative government and private forest initiatives in Bavaria (Germany), Slovenia, Castilla y León (Spain), Nordeste (Portugal), and Latvia (481 actor responses, 109 initiatives). The initiatives included participatory mountain forest initiatives, forest intervention zones, afforestation projects, forest owner associations, and model forest and labelling initiatives. The results provide insight into the similarities and differences between European countries and actor groups regarding the preferred facilitators and instruments for solving future forest problems. In light of disagreement in the literature on the role of the state or markets in future forest land use and the bio-economy, our results show that the market and its instruments are considered to play a dominant role in wood mobilisation. With respect to all other issues (socio-ecological, societal, other), the state or other institutions and their instruments gain priority. The state is considered to play a stronger role in developing new markets, e.g., for energy transition or new uses of wood, contrary to liberal market expectations. Ecological and social problems are considered to be outside of the market domain. Here, the state is called in, e.g., to steer recreational issues, the provision of ecosystem services, or the improvement of the protective function. The clearest preference across all regions is for the state to secure the provision of ecosystem services, in contrast to calls for future markets to regulate this field.

Description: Forests, Vol. 9, Pages 591: Productivity, Costs, and Selected Environmental Impacts of Remote-Controlled Mini Forestry Crawlers Forests doi: 10.3390/f9100591 Authors: Ferréol Berendt Mathieu Fortin Christian Suchomel Janine Schweier An effective way to reduce off-road traffic in forests is to implement greater distances between skid trails. However, this implies that trees beyond the boom reach of the harvester need to be felled motor manually before being winched to the skid trail, for example using a remote-controlled mini forestry crawler (MFC). They are only a few local studies which have evaluated the performance of such MFCs. The use of MFCs for wood extraction operations in mixed soft- and hardwood stands is presented in this study conducted in Southwestern Germany. The aim of this study was to analyze the productivity, costs, and selected environmental impacts of mini forestry crawlers during winching operations through a time study. Using statistical regression, time consumption was analyzed in order to determine significant explanatory variables. Environmental impacts were evaluated using the life cycle assessment (LCA) methodology with Umberto software. The mean net cycle time was 4.82 min and the net productivity rate was 7.77 m3 by productive machine hour (PMH0). Explanatory variables which significantly affected the net cycle time were the winched volume, the number of trees per load, and winching distance. Environmental analysis showed that inputs of fossil energy were mostly due to diesel and lubricant consumption. Raw materials for machine manufacture and maintenance showed the highest impact in human toxicity potential category. The MFCs showed good environmental performances, but the harvesting system should become more productive in order to be more cost effective.

Description: Minerals, Vol. 8, Pages 421: A Study on the Flocculation and Sedimentation of Iron Tailings Slurry Based on the Regulating Behavior of Fe3+ Minerals doi: 10.3390/min8100421 Authors: Tao Yue Xiqing Wu Xiao Chen Tianyu Liu Based on the regulating behavior of Fe3+, flocculation and sedimentation tests of iron tailings slurry flocculated using 2 mg/L anionic polyacrylamide (APAM) were studied, including the tests of Fe3+ dosage, regulating time, and pH. Flocculation–sedimentation tests showed that: a recommended addition of 56 mg/L Fe3+ produced a surprisingly bad flocculation effect; sedimentation ability decreased with the increase of regulating time, however, the regulating ability during the first 1 min was low; Fe3+ displayed a high regulating effect at pH 6–7, and then decreased with the increase of slurry pH. Size analysis demonstrated that the regulating ability of Fe3+ was related to the change of floc size, which increased with the decrease of size. Zeta potential analysis and calculation showed that small concentrations of Fe3+ and certain hydroxyl complex ions (such as Fe(OH)2+ and Fe(OH)2+) adsorbed onto the APAM molecular chains, resulting in a decreased charge density of the APAM molecules, and this electrostatic adsorption was able to make the polymer curl more easily. Fourier Transform Infrared Spectroscopic (FTIR) indicated the APAM on the hematite was slightly degraded into a monomer-like short-chain polymer while adding certain concentration of Fe3+. Scanning Electron Microscope (SEM) imaging showed that the network structure of APAM molecules treated by Fe3+ collapsed, and the APAM adsorption amount on hematite was significantly reduced. Therefore, the effect of Fe3+ on the APAM could be recommended as a new method for desorption and degradation of the APAM contained in the tailings slurry or flocs.

Description: Minerals, Vol. 8, Pages 420: Cerromojonite, CuPbBiSe3, from El Dragόn (Bolivia): A New Member of the Bournonite Group Minerals doi: 10.3390/min8100420 Authors: Hans-Jürgen Förster Luca Bindi Günter Grundmann Chris J. Stanley Cerromojonite, ideally CuPbBiSe3, represents a new selenide from the El Dragόn mine, Department of Potosí, Bolivia. It either occurs as minute grains (up to 30 µm in size) in interstices of hansblockite/quijarroite intergrowths, forming an angular network-like intersertal texture, or as elongated, thin-tabular crystals (up to 200 μm long and 40 μm wide) within lath-shaped or acicular mineral aggregates (interpreted as pseudomorphs) up to 2 mm in length and 200 μm in width. It is non-fluorescent, black, and opaque, with a metallic luster and black streak. It is brittle, with an irregular fracture, and no obvious cleavage and parting. In plane-polarized incident light, cerromojonite is grey to cream-white, and weakly pleochroic, showing no internal reflections. Between crossed polarizers, cerromojonite is weakly anisotropic, with rotation tints in shades of brown and grey. Lamellar twinning on {110} is common. The reflectance values in air for the COM standard wavelengths (R1 and R2) are: 48.8 and 50.3 (470 nm), 48.2 and 51.8 (546 nm), 47.8 and 52.0 (589 nm), and 47.2 and 52.0 (650 nm). Electron-microprobe analyses yielded a mean composition of: Cu 7.91, Ag 2.35, Hg 7.42, Pb 16.39, Fe 0.04, Ni 0.02, Bi 32.61, Se 33.37, total 100.14 wt %. The empirical formula (based on 6 atoms pfu) is (Cu0.89Hg0.11)Σ = 1.00(Pb0.56Ag0.16Hg0.15 Bi0.11Fe0.01)Σ = 0.99Bi1.00Se3.01. The ideal formula is CuPbBiSe3. Cerromojonite is orthorhombic (space group Pn21m), with a = 8.202(1) Å, b = 8.741(1) Å, c = 8.029(1) Å, V = 575.7(1) Å3, Z = 4. Calculated density is 7.035 g·cm−3. The five strongest measured X-ray powder diffraction lines (d in Å (I/I0) (hkl)) are: 3.86 (25) (120), 2.783 (100) (122), 2.727 (55) (212), 2.608 (40) (310), and 1.999 (25) (004). Cerromojonite is a new member of the bournonite group, representing the Se-analogue of součekite, CuPbBi(S,Se)3. It is deposited from strongly oxidizing low-T hydrothermal fluids at a fSe2/fS2 ratio >1, both as primary and secondary phase. The new species has been approved by the IMA-CNMNC (2018-040) and is named for Cerro Mojon, the highest mountain peak closest to the El Dragón mine.

Description: Forests, Vol. 9, Pages 592: Strategies for Climate-Smart Forest Management in Austria Forests doi: 10.3390/f9100592 Authors: Robert Jandl Thomas Ledermann Georg Kindermann Alexandra Freudenschuss Thomas Gschwantner Peter Weiss We simulated Austrian forests under different sustainable management scenarios. A reference scenario was compared to scenarios focusing on the provision of bioenergy, enhancing the delivery of wood products, and reduced harvesting rates. The standing stock of the stem biomass, carbon in stems, and the soil carbon pool were calculated for the period 2010–2100. We used the forest growth model Câldis and the soil carbon model Yasso07. The wood demand of all scenarios could be satisfied within the simulation period. The reference scenario led to a small decrease of the stem biomass. Scenarios aiming at a supply of more timber decreased the standing stock to a greater extent. Emphasizing the production of bioenergy was successful for several decades but ultimately exhausted the available resources for fuel wood. Lower harvesting rates reduced the standing stock of coniferous and increased the standing stock of deciduous forests. The soil carbon pool was marginally changed by different management strategies. We conclude that the production of long-living wood products is the preferred implementation of climate-smart forestry. The accumulation of carbon in the standing biomass is risky in the case of disturbances. The production of bioenergy is suitable as a byproduct of high value forest products.

Description: Forests, Vol. 9, Pages 593: Macronutrient Stocks in Scots Pine Stands of Different Densities Forests doi: 10.3390/f9100593 Authors: Andrzej Węgiel Ernest Bielinis Krzysztof Polowy A positive nutrient balance is crucial to sustaining forest productivity. Differences in stand densities usually mean different aboveground biomass stocks and different proportions of tree compartments. These differences can be reflected in the different macronutrient stocks between stands of different densities, because various tree compartments have different element concentrations. In this study, 82-year-old stands of Scots pine were compared, and specifically, the concentrations of the elements in tree compartments and the amounts of macronutrients in aboveground biomass were compared. The nutrients considered in this study were nitrogen, phosphorus, potassium, calcium, magnesium, and sulfur. A positive correlation between stand density and the level of stored macronutrients was found for nitrogen, phosphorus, and potassium. This result means that forest managers can influence nutrient balances by regulating stand densities or by harvesting methods (SOH: stem-only harvesting or WTH: whole-tree harvesting).

Description: Minerals, Vol. 8, Pages 422: Effect of Acidithiobacillus ferrooxidans on Humic-Acid Passivation Layer on Pyrite Surface Minerals doi: 10.3390/min8100422 Authors: Hongying Yang Wenjie Luo Ying Gao The effect of Acidithiobacillus ferrooxidans on the humic-acid passivation layer on pyrite surfaces was studied by atomic-force microscopy, leaching experiments, and adsorption experiments. Atomic-force-microscopy results showed that humic-acid was adsorbed onto the pyrite surface. The bacteria grew and reproduced on the humic-acid layer. Leaching experiments showed that the humic-acid passivation layer prevented the oxidation of pyrite by Fe3+ under aseptic conditions. Bacteria destroyed the humic-acid layer, promoted pyrite oxidation, and increased the oxidation of pyrite from 1.64% to 67.9%. Bacterial adsorption experiments showed that the humic-acid passivation layer decreased the speed of bacterial adsorption on the pyrite surface but had no effect on the number of bacteria adsorbed on the pyrite surface. The maximum number of bacteria adsorbed by pyrite with and without the humic-acid layer was 4.17 × 1010 cells∙mL−1 and 4.4 × 1010 cells∙mL−1, respectively. Extracellular polymeric stratum layer of bacteria cultured at different concentrations of humic-acid was extracted and analyzed. This layer could destroy the humic-acid layer and promote pyrite oxidation.

Description: Minerals, Vol. 8, Pages 423: Petrogenesis of Heavy Rare Earth Element Enriched Rhyolite: Source and Magmatic Evolution of the Round Top Laccolith, Trans-Pecos, Texas Minerals doi: 10.3390/min8100423 Authors: Brent A. Elliott The Round Top rhyolite located in Trans-Pecos Texas is enriched in Be, F, Li, Nb, Rb, Sn, Th, U, Y, Zr, and rare earth elements (REEs). REE-bearing minerals are mainly ubiquitous nano-scale accessory phases throughout the groundmass, incorporated in synchysite-group minerals, xenotime-(Y), Y- and Ce-rich fluorite, and zircon. The rhyolite is peraluminous, high-silica, alkaline (not peralkaline), with elevated heavy rare earth element concentrations and anonymously negative Eu values. Pervasive spongy groundmass and recrystallization textures are consistent with the elevated and remobilized Zr, Th, and Y + HREE (heavy rare earth element) concentrations and a high field strength element (HFSE) soluble, sub-alkalic, F-rich, magmatic system. REE-bearing minerals are present as late-magmatic, interstitial phases and attributed with closed-system, post-magmatic, hydrothermal alteration. Petrogenetic modeling provides scenarios that explain the geochemical evolution and REE complexing behavior in evolved rhyolite magmas, and determines possible source compositions and evolution. Trace element models suggest a system typical of having extensive magmatic differentiation. The resulting rhyolite magma is indicative of a silica-rich magmatic system enriched in H2O, Li, and/or F that could be considered transitional between pure silicate melt and hydrothermal fluid, where fluorine-ligand complexing was prevalent through late magmatic cooling and crystallization processes. Thorough differentiation and high fluorine activity contributed to the late stage crystallization of REE-bearing minerals in the Round Top rhyolite.

Description: Forests, Vol. 9, Pages 594: Screening Potential Bioenergy Production of Tree Species in Degraded and Marginal Land in the Tropics Forests doi: 10.3390/f9100594 Authors: Nils Borchard Medha Bulusu Ann-Michelle Hartwig Matthias Ulrich Soo Min Lee Himlal Baral Bioenergy can produce at least 25% of the global energy demand to combat climate change through reducing emissions in the energy sector. However, information on the bioenergy production potential of woody species and their suitability for silviculture on various soils in the humid tropics is limited. This review aims to identify tree species suitable for bioenergy production under these conditions. Data were compiled from 241 publications and nine freely available databases to assess environmental and silvicultural information on tropical tree species. Energy outputs were derived from the estimated productivity of the reviewed species and ranged from 0.2 to 24.0 Mg biomass ha−1 yr−1, 0.1 to 9.0 Mg bio-oil ha−1 yr−1, and 0.2 to 20.0 Mg sugar ha−1 yr−1, equivalent to an energy yield between 2 and 444 GJ ha−1 yr−1. As such, these bioenergy yields are within the range reported for the lignocellulosic biomass of energy crops cultivated in Europe, the USA, and Brazil. Our review identified some high-yielding species (e.g., Dyera polyphylla (Miq.) Steenis, Metroxylon sagu (Rottb.), Pongamia pinnata (L.)) and leguminous species that could be beneficial in mixed stands (e.g., Elaeis oleifera (Kunth) and Pongamia pinnata) or are suitable species to grow on wet or re-wetted peatland (Dyera polyphylla). However, there are limitations to cultivate woody bioenergy species on wet peatland. Sustainable methods for managing and harvesting forests, particularly on wet or re-wetted peatland, need to be developed.

Description: Minerals, Vol. 8, Pages 419: The Synthesis of Secondary Iron Minerals Induced by Quartz Sand during the Bioleaching Process Improves the Dewaterability of Municipal Sewage Sludge Minerals doi: 10.3390/min8100419 Authors: Yingying Ma Heru Wang Yongwei Song Yiqian Wu Zehao Guo This study elucidated the mechanisms during the bioleaching process when optimizing the dewaterability of municipal sludge using quartz sand. The experiment was conducted with a shaking table and a series of controlled trials designed to investigate the influence of quartz sand on sludge dewaterability. Scanning electron microscopy and X-ray diffraction were applied to explore the quartz sand’s action mechanism. Results indicated that quartz sand could improve the sludge bioleaching efficiency. The optimal reaction time was between 24–48 h and 48–72 h with and without 10 g·L−1 of quartz sand, and a minimum sludge specific resistance to filtration was 1.2 × 1012 and 2.4 × 1012 m·kg−1, respectively. Quartz sand could provide nucleating sites for secondary iron minerals and overcome the unfavorable influence of a low Fe3+ supply rate in the initial bioleaching stage (0–24 h). Because it was conducive to accelerating the initial mineral precipitation, quartz sand could improve bioleaching efficiency. The X-ray diffraction spectrum showed that quartz sand induced changes in the synthesis pathway of secondary iron minerals when the concentration of Fe2+ ≥ 4 g·L−1. This then promoted the transformation of schwertmannite into jarosite during the mineralization process, which immobilizes nutrients such as K+ and NH4+ in the form of jarosite. Accordingly, bioleached sludge dewaterability and its utilization value can be improved. These results provide theoretical reference for improving bioleaching techniques in the treatment of municipal sludge.

Description: Minerals, Vol. 8, Pages 417: Optimizing Flotation Circuit Recovery by Effective Stage Arrangements: A Case Study Minerals doi: 10.3390/min8100417 Authors: Vahid Radmehr Sied Ziaedin Shafaei Mohammad Noaparast Hadi Abdollahi Recovery is one of the most important metallurgical parameters in designing and evaluating flotation circuits. The present study used the recovery arrangement for two and three stage circuits to evaluate the effect of stage recovery on the overall circuit recovery and flotation circuit configuration. The results showed that mainly the highest recovery value should be assigned to the rougher stage in order to achieve the maximum overall circuit recovery. Countercurrent rougher-cleaner and rougher-scavenger circuits, in which recycling streams step back one stage at a time, follow a general rule for the assignment of recovery. Finally, a flotation plant containing six flotation banks was examined as a case study. A program for calculating total circuit recovery, for all possible combinations of recovery was developed in MATLAB software. 720 recovery combinations were evaluated. The results showed that optimal recovery allocation in stages could be effective in achieving overall circuit recovery. It was shown that the use of a large number of stages in some of the flotation circuits leads to the loss of equipment and additional costs. The proposed approach can be employed as an effective tool for designing and optimizing various flotation circuits and their operational parameters.

Description: Forests, Vol. 9, Pages 583: An Integer Linear Programming Model to Select and Temporally Allocate Resources for Fighting Forest Fires Forests doi: 10.3390/f9100583 Authors: Jorge Rodríguez-Veiga María José Ginzo-Villamayor Balbina Casas-Méndez Optimal planning of the amount and type of resources needed for extinguishing a forest fire is a task that has been addressed in the literature, using models obtained from operational research. In this study, a general integer linear programming model is proposed, which addresses the allocation of resources in different time periods during the planning period for extinguishing a fire, and with the goal of meeting Spanish regulations for the non-negligence of fronts and periods of rest for pilots and brigades. A computer program and interface were developed using the R language. By means of an example using historical data, we illustrate the model at work and its exact resolution. Then, we carry out a simulation study to analyze the obtained objective functions and resolution times. Our simulation study shows that an exact solution can be obtained very quickly without requiring heuristic algorithms, provided that the planning period does not exceed five hours.

Description: Minerals, Vol. 8, Pages 341: Activation Mechanism of Lead Ions in Perovskite Flotation with Octyl Hydroxamic Acid Collector Minerals doi: 10.3390/min8080341 Authors: Yu Zheng Yating Cui Weiqing Wang The activation mechanism of lead ions (Pb2+) in perovskite flotation with an octyl hydroxamic acid collector was systematically investigated using microflotation experiments, zeta-potential measurements, adsorption tests, Fourier transform infrared (FT-IR) analysis, and X-ray photoelectron spectroscopy (XPS) analysis. The results of microflotation experiments and adsorption tests indicate that the presence of Pb2+ can promote the adsorption of octyl hydroxamic acid (OHA) on the perovskite surface and enhance the flotability of perovskite under weakly acidic conditions. The maximum recovery of 79.62% was obtained at pH 6.5 in the presence of Pb2+, and the maximum recovery of 57.93% was obtained at pH 5.7 without Pb2+. At pHs below 7, lead species are mainly present as Pb2+ and PbOH+ in the solution; besides this, the relative content of titanium increases on the perovskite surface. The adsorption of Pb2+ and PbOH+ on the perovskite surface makes the zeta-potential of perovskite shift positively, and increases the number of activated sites on the perovskite surface. FT-IR and XPS analyses confirm that OHA chemisorbs on the surface of Pb2+-activated perovskite and forms hydrophobic Pb-OHA complexes, which improve the flotability of perovskite.

Description: Minerals, Vol. 8, Pages 340: Dynamic Disorder of Fe3+ Ions in the Crystal Structure of Natural Barioferrite Minerals doi: 10.3390/min8080340 Authors: Arkadiusz Krzątała Taras L. Panikorovskii Irina O. Galuskina Evgeny V. Galuskin A natural barioferrite, BaFe3+12O19, from a larnite–schorlomite–gehlenite vein of paralava within gehlenite hornfels of the Hatrurim Complex at Har Parsa, Negev Desert, Israel, was investigated by Raman spectroscopy, electron probe microanalysis, and single-crystal X-ray analyses acquired over the temperature range of 100–400 K. The crystals are up to 0.3 mm × 0.1 mm in size and form intergrowths with hematite, magnesioferrite, khesinite, and harmunite. The empirical formula of the barioferrite investigated is as follows: (Ba0.85Ca0.12Sr0.03)∑1(Fe3+10.72Al0.46Ti4+0.41Mg0.15Cu2+0.09Ca0.08Zn0.04Mn2+0.03Si0.01)∑11.99O19. The strongest bands in the Raman spectrum are as follows: 712, 682, 617, 515, 406, and 328 cm−1. The structure of natural barioferrite (P63/mmc, a = 5.8901(2) Å, c = 23.1235(6) Å, V = 694.75(4) Å3, Z = 2) is identical with the structure of synthetic barium ferrite and can be described as an interstratification of two fundamental blocks: spinel-like S-modules with a cubic stacking sequence and R-modules that have hexagonal stacking. The displacement ellipsoids of the trigonal bipyramidal site show elongation along the [001] direction during heating. As a function of temperature, the mean apical Fe–O bond lengths increase, whereas the equatorial bond lengths decrease, which indicates dynamic disorder at the Fe2 site.

Description: Minerals, Vol. 8, Pages 339: Thalhammerite, Pd9Ag2Bi2S4, a New Mineral from the Talnakh and Oktyabrsk Deposits, Noril’sk Region, Russia Minerals doi: 10.3390/min8080339 Authors: Anna Vymazalová František Laufek Sergey F. Sluzhenikin Vladimir V. Kozlov Chris J. Stanley Jakub Plášil Federica Zaccarini Giorgio Garuti Ronald Bakker Thalhammerite, Pd9Ag2Bi2S4, is a new sulphide discovered in galena-pyrite-chalcopyrite and millerite-bornite-chalcopyrite vein-disseminated ores from the Komsomolsky mine of the Talnakh and Oktyabrsk deposits, Noril’sk region, Russia. It forms tiny inclusions (from a few μm up to about 40–50 μm) intergrown in galena, chalcopyrite, and also in bornite. Thalhammerite is brittle and has a metallic lustre. In plane-polarized light, thalhammerite is light yellow with weak bireflectance, weak pleochroism, in shades of slightly yellowish brown and weak anisotropy; it exhibits no internal reflections. Reflectance values of thalhammerite in air (R1, R2 in %) are: 41.9/43.0 at 470 nm, 43.9/45.1 at 546 nm, 44.9/46.1 at 589 nm, and 46.3/47.5 at 650 nm. Three spot analyses of thalhammerite give an average composition: Pd 52.61, Bi 22.21, Pb 3.92, Ag 14.37, S 7.69, and Se 0.10, total 100.90 wt %, corresponding to the empirical formula Pd8.46Ag2.28(Bi1.82Pb0.32)Σ2.14(S4.10Se0.02)Σ4.12 based on 17 atoms; the average of five analyses on synthetic thalhammerite is: Pd 55.10, Bi 24.99, Ag 12.75, and S 7.46, total 100.30 wt %, corresponding to Pd8.91Ag2.03Bi2.06S4.00. The density, calculated on the basis of the empirical formula, is 9.72 g/cm3. The mineral is tetragonal, space group I4/mmm, with a 8.0266(2), c 9.1531(2) Å, V 589.70(2) Å3 and Z = 2. The crystal structure was solved and refined from the single-crystal X-ray-diffraction data of synthetic Pd9Ag2Bi2S4. Thalhammerite has no exact structural analogues known in the mineral system; chemically, it is close to coldwellite (Pd3Ag2S) and kravtsovite (PdAg2S). The strongest lines in the X-ray powder diffraction pattern of synthetic thalhammerite [d in Å (I) (hkl)] are: 3.3428(24)(211), 2.8393(46)(220), 2.5685(21)(301), 2.4122(100)(222), 2.3245(61)(123), 2.2873(48)(004), 2.2201(29)(132), 2.0072(40)(400), 1.7481(23)(332), and 1.5085(30)(404). The mineral honours Associate Professor Oskar Thalhammer of the University of Leoben, Austria.

Description: Diversity, Vol. 10, Pages 86: Validation of the Names of Four Weevil Species Described by Caldara & Košťál, Description of Four New Species of the Afrotropical Weevil Genus Afroryzophilus (Coleoptera, Curculionidae); Diversity 2018, 10, 37 Diversity doi: 10.3390/d10030086 Authors: Roberto Caldara Michael Košťál Four new species of the erirhinine genus Afroryzophilus Lyal, 1990 from Africa are described, A. centrafricanus sp. n., A. congoanus sp. n., A. kuscheli sp. n. and A. somalicus sp. n., with bibliographic reference to fuller descriptions and illustrations in the recent paper by Caldara & Košťál (2018) published in the journal Diversity 10 (2), 37, in which the names were not made available under the rules of the International Code of Zoological Nomenclature dealing with electronic publication.

Description: Forests, Vol. 9, Pages 484: Fungal Frequency and Mite Load Trends Interact with a Declining Mountain Pine Beetle Population Forests doi: 10.3390/f9080484 Authors: Javier E. Mercado Beatriz Ortiz-Santana Shannon L. Kay The mite and fungal biota associated with the mountain pine beetle (MPB) (Dendroctonus ponderosae Hopk.) may not be stable throughout an irruptive event. In congeneric beetles, variations in the frequency of their associated organisms affect population trends and similar effects may occur in MPB. We studied fungi and mite trends in a declining irruptive MPB population as it attacked three different pine hosts in the Colorado Front Range. During the study, we found two new associates including one biologically relevant mite and one beneficial blue-stain fungus. Fungi hyperphoretic on mites were also documented. This included beneficial and potentially detrimental species to the MPB. The frequency of several organisms varied between some years or pine hosts but not within male or female beetles. A large increase of Trichouropoda sp. and T. ips mites trended inversely with the declining beetle population, while a decrease in the beneficial blue-stain fungi trended similarly to the declining beetle population. We discuss the interactions and potential effects of phoretic biota in relation to (1) the MPB associates’ population trends, (2) the MPB incursions into cooler areas, and (3) the redundancy of blue-stain fungi carried by the MPB holobiont. These findings increase our knowledge of the mechanisms that influence MPB populations.

Description: Forests, Vol. 9, Pages 485: Developing and Field Testing a Tool Designed to Operationalize a Multitreatment Approach in Hardwood-Dominated Stands in Eastern Canada Forests doi: 10.3390/f9080485 Authors: Eric R. Labelle Gaetan Pelletier Michel Soucy Variations in species composition, diameter and height distributions, and quality make the management of hardwood-dominated stands difficult, particularly when considering mechanized forest operations. This study aimed to develop and field test a tool designed to improve the feasibility of forest operations in heterogeneous forest stands in Eastern Canada. To address inherent stand variability, a multitreatment approach was selected using conventional forest inventory (one inventory plot per hectare) and a silvicultural treatment decision key as main inputs. The Excel-based spreadsheet in combination with an ArcGIS model, referred to as the Multitreatment Planning Tool (MTPT), allowed to build operational maps identifying the type and spatial extent of silvicultural treatments to be performed. Once uploaded to positioning systems in harvesting machines, the operators were provided guidance on the silvicultural treatment to be performed and the location of the suggested machine trails. Field results obtained from nine harvest blocks (over 300 ha treated in total) showed the potential of using the MTPT until more mature and higher resolution-enhanced inventories become mainstream. Machine operators and operational managers both appreciated the straightforward and flexible method. Additional testing and refinement of the method is necessary, particularly when considering re-entry scheduling.

Description: Forests, Vol. 9, Pages 483: Impacts of a High Nitrogen Load on Foliar Nutrient Status, N Metabolism, and Photosynthetic Capacity in a Cupressus lusitanica Mill. Plantation Forests doi: 10.3390/f9080483 Authors: Ruirui Li Yi Lu Fuxu Wan Yiming Wang Xiaocheng Pan At present, anthropogenic nitrogen deposition has dramatically increased worldwide and has shown negative impacts on temperate/boreal forest ecosystems. However, it remains unclear how an elevated N load affects plant growth in the relatively N-rich subtropical forests of Southern China. To address this question, a study was conducted in a six-year-old Cupressus lusitanica Mill. plantation at the Scientific Research and Teaching Base of Nanjing Forestry University, with N addition levels of N0 (0 kg ha−1 year−1), N1 (24 kg ha−1 year−1), N2 (48 kg ha−1 year−1), N3 (72 kg ha−1 year−1), N4 (96 kg ha−1 year−1), and N5 (120 kg ha−1 year−1). Leaf physiological traits associated with foliar nutrient status, photosynthetic capacity, pigment, and N metabolites were measured. The results showed that (1) N addition led to significant effects on foliar N, but had no marked effects on K concentration. Furthermore, remarkable increases of leaf physiological traits including foliar P, Ca, Mg, and Mn concentration; photosynthetic capacity; pigment; and N metabolites were always observed under low and middle-N supply. (2) High N supply notably decreased foliar P, Ca, and Mg concentration, but increased foliar Mn content. Regarding the chlorophyll, photosynthetic capacity, and N metabolites, marked declines were also observed under high N inputs. (3) Redundancy analysis showed that the net photosynthesis rate was positively correlated with foliar N, P, Ca, Mg, and Mn concentration; the Mn/Mg ratio; and concentrations of chlorophyll and N metabolites, while the net photosynthesis rate was negatively correlated with foliar K concentration and N/P ratios. These findings suggest that excess N inputs can promote nutrient imbalances and inhibit the photosynthetic capacity of Cupressus lusitanica Mill., indicating that high N deposition could threaten plant growth in tropical forests in the future. Meanwhile, further study is merited to track the effects of high N deposition on the relationship between foliar Mn accumulation and photosynthesis in Cupressus lusitanica Mill.

Description: Minerals, Vol. 8, Pages 342: Numerical Modeling of REE Fractionation Patterns in Fluorapatite from the Olympic Dam Deposit (South Australia) Minerals doi: 10.3390/min8080342 Authors: Sasha Krneta Cristiana L. Ciobanu Nigel J. Cook Kathy J. Ehrig Trace element signatures in apatite are used to study hydrothermal processes due to the ability of this mineral to chemically record and preserve the impact of individual hydrothermal events. Interpretation of rare earth element (REE)-signatures in hydrothermal apatite can be complex due to not only evolving fO2, fS2 and fluid composition, but also to variety of different REE-complexes (Cl-, F-, P-, SO4, CO3, oxide, OH− etc.) in hydrothermal fluid, and the significant differences in solubility and stability that these complexes exhibit. This contribution applies numerical modeling to evolving REE-signatures in apatite within the Olympic Dam iron-oxide-copper-gold deposit, South Australia with the aim of constraining fluid evolution. The REE-signatures of three unique types of apatite from hydrothermal assemblages that crystallized under partially constrained conditions have been numerically modeled, and the partitioning coefficients between apatite and fluid calculated in each case. Results of these calculations replicate the measured data well and show a transition from early light rare earth element (LREE)- to later middle rare earth element (MREE)-enriched apatite, which can be achieved by an evolution in the proportions of different REE-complexes. Modeling also efficiently explains the switch from REE-signatures with negative to positive Eu-anomalies. REE transport in hydrothermal fluids at Olympic Dam is attributed to REE–chloride complexes, thus explaining both the LREE-enriched character of the deposit and the relatively LREE-depleted nature of later generations of apatite. REE deposition may, however, have been induced by a weakening of REE–Cl activity and subsequent REE complexation with fluoride species. The conspicuous positive Eu-anomalies displayed by later apatite with are attributed to crystallization from high pH fluids characterized by the presence of Eu3+ species.

Description: Minerals, Vol. 8, Pages 345: Eogenetic Karst Control of Carbonate Reservoirs during a Transient Exposure: A Case Study of the Ordovician Yingshan Formation in the Northern Slope of the Tazhong Uplift, Tarim Basin, China Minerals doi: 10.3390/min8080345 Authors: Yong Dan Liangbiao Lin Bin Liang Qingyu Zhang Yu Yu Jianwen Cao Jingrui Li The Tazhong area of the Tarim Basin contains abundant oil and gas resources in Ordovician carbonate rocks, especially in the karst pores and caves of the Yingshan Formation. Research has indicated that the Yingshan Formation underwent a 7–11 Ma exposure during the middle Caledonian Period, resulting in large-scale karst pores and caves. However, the continental freshwater karst model cannot adequately explain the origin and distribution of karst pores and caves. In order to develop a more accurate karst model to guide petroleum exploration in the region, we analyzed the karst morphology, cave development statistics, and paleokarst environments. Karst reservoir characteristics were analyzed on the basis of the following analysis: (1) Karst morphological analyses based on core description and formation micro-imager (FMI) log analyses. The results showed that alveolar-like and Swiss cheese-like solution pores, spongy dissolution zones, pit cenotes, and small continuous karst caves developed in the Yingshan Formation. (2) The statistical analysis of pore and cave characteristics indicated that most of the karst pores and caves developed within 50 m below the unconformity where the average height of these features ranged from 0.1 to 3.0 m and their widths ranged up to 100 m. These pores and caves were commonly filled with gravel, clay, and calcite. Horizontal well and seismic attribute analysis indicated that these pores and caves were distributed over a large area. In plain view, the karst pore-cave system is comprised of cross-linked anastomosing networks of horizontal cave passages. And (3) Cathode luminescence and electron microprobe analyses suggested that clay filling within karst caves was freshwater related, while calcite filling was of seawater origin. Cements within solution pores showed three phases of luminescence, suggesting an alternating freshwater and seawater environment. Based on these characteristics, the karsts of the Yingshan Formation in the Tazhong area are interpreted to be similar to the eogenetic karsts in the Yucatan Peninsula of modern Mexico. Accordingly, this study indicates that the pore-caves of the Yingshan Formation can be subdivided into three sections. Further, the development and filling of these pore-cave sections are interpreted to have formed by eogenetic mixed-water karstification during three phases of relatively stable sea level in a coastal margin environment.

Description: Diversity, Vol. 10, Pages 85: High Duty Cycle Echolocation May Constrain the Evolution of Diversity within Horseshoe Bats (Family: Rhinolophidae) Diversity doi: 10.3390/d10030085 Authors: David S. Jacobs Anna Bastian The phenotype of organisms is the net result of various evolutionary forces acting upon their lineages over time. When an innovative trait arises that confers a substantial advantage in terms of survival and reproduction, the evolution of adaptive complexes between such an innovation and other traits may constrain diversification of that lineage. The specialized echolocation system of the Rhinolophidae may represent such an innovation which affects other parts of the phenotype. We investigated a potential constraint on the diversity of phenotypes of several species of horseshoe bats within a phylogenetic framework. If phenotypic convergence stems from stasis as a result of the specialized echolocation system, phenotypes should converge not only among members of the same species and between sexes but also among species. We analyzed the phenotypic diversity of >800 individuals of 13–16 species. The phenotypes in the horseshoe bats did indeed converge. There was no sexual size dimorphism in mass, forearm length and wingspan within species and there was marked interspecific similarity in both wing and echolocation variables but marked variability in body mass. Furthermore, correlations of wing and echolocation variables with mass suggest that variability within horseshoe bats was largely the result of selection on body size with allometric responses in wing and echolocation parameters, a potential consequence of constraints imposed by their specialized echolocation.

Description: Forests, Vol. 9, Pages 488: Influence of Natural and Artificial Weathering on the Colour Change of Different Wood and Wood-Based Materials Forests doi: 10.3390/f9080488 Authors: Davor Kržišnik Boštjan Lesar Nejc Thaler Miha Humar The importance of the aesthetic performance of wood is increasing and the colour is one of the most important parameters of aesthetics, hence the colour stability of twelve different wood-based materials was evaluated by several in-service and laboratory tests. The wood used for wooden façades and decking belongs to a group of severely exposed surfaces. Discolouration of wood in such applications is a long-known phenomenon, which is a result of different biotic and abiotic causes. The ongoing in-service trial started in October 2013, whilst a laboratory test mimicking seasonal exposure was performed in parallel. Samples were exposed to blue stain fungi (Aureobasidium pullulans and Dothichiza pithyophila) in a laboratory test according to the EN 152 procedure. Afterwards, the same samples were artificially weathered and re-exposed to the same blue stain fungi for the second time. The purpose of this experiment was to investigate the synergistic effect of weathering and staining. The broader aim of the study was to determine the correlation factors between artificial and natural weathering and to compare laboratory and field test data of fungal disfigurement of various bio-based materials. During the four years of exposure, the most prominent colour changes were determined on decking. Respective changes on the façade elements were significantly less prominent, being the lest evident on the south and east façade. The results showed that there are positive correlations between natural weathering and the combination of artificial weathering and blue staining. Hence, the artificial weathering of wood-based materials in the laboratory should consist of two steps, blue staining and artificial weathering, in order to simulate colour changes.

Description: Forests, Vol. 9, Pages 489: Sustainability of Forest Cover under Climate Change on the Temperate-Continental Xeric Limits Forests doi: 10.3390/f9080489 Authors: Csaba Mátyás Imre Berki András Bidló György Csóka Kornél Czimber Ernő Führer Borbála Gálos Zoltán Gribovszki Gábor Illés Anikó Hirka Zoltán Somogyi Climate change particularly threatens the xeric limits of temperate-continental forests. In Hungary, annual temperatures have increased by 1.2 °C–1.8 °C in the last 30 years and the frequency of extreme droughts has grown. With the aim to gain stand-level prospects of sustainability, we have used local forest site variables to identify and project effects of recent and expected changes of climate. We have used a climatic descriptor (FAI index) to compare trends estimated from forest datasets with climatological projections; this is likely for the first time such a comparison has been made. Four independent approaches confirmed the near-linear decline of growth and vitality with increasing hot droughts in summer, using sessile oak as model species. The correlation between droughts and the expansion of pest and disease damages was also found to be significant. Projections of expected changes of main site factors predict a dramatic rise of future drought frequency and, consequently, a substantial shift of forest climate classes, especially at low elevation. Excess water-dependent lowland forests may lose supply from groundwater, which may change vegetation cover and soil development processes. The overall change of site conditions not only causes economic losses, but also challenges long-term sustainability of forest cover at the xeric limits.

Description: Forests, Vol. 9, Pages 486: Effects of Narrow Linear Disturbances on Light and Wind Patterns in Fragmented Boreal Forests in Northeastern Alberta Forests doi: 10.3390/f9080486 Authors: Eleanor R. Stern Federico Riva Scott E. Nielsen Forest fragmentation threatens forest biodiversity and ecosystem function. One of the concerns relates to increases in edge effects, which among other things affects the forest microclimate that influences the distribution and behavior of species. In Alberta, Canada, boreal anthropogenic disturbances from in situ oil exploration are increasing forest fragmentation, especially in the form of exploratory well pads and seismic lines (i.e., linear forest clearings created during the exploration phase of oil extraction). Dissection of these forests by seismic lines has the potential to change local patterns in wind and light, and thus may alter forest communities. Although alterations of these abiotic conditions are likely, the magnitude of these changes is unknown, particularly the effects of changes in the width and orientation of linear disturbances. Here we investigated changes in light and wind on seismic lines compared to that of adjacent undisturbed forests and nearby cleared openings. Specifically, we examined how seismic line characteristics (i.e., line direction, line width, and adjacent canopy height) altered local responses in these abiotic conditions. Generalized Linear Mixed Effect models predicted a 2-fold increase in average light intensity and maximum wind speeds, and a 4-fold increase in average wind speeds on seismic lines compared to adjacent forests. These changes did not approach the conditions in large openings, which compared to forests had a 3-fold increase in average light intensity, a 16-fold increase in average wind speeds, and a 4-fold increase in maximum wind speeds. Line width and orientation interacted with adjacent forest height altering the abiotic environment with wider lines having a 3-fold increase on maximum wind speed. We conclude that even localized, narrow (<10-m wide) forest disturbances associated with oil sands exploration alter forest microclimatic conditions. Recent changes in practices that reduce line width as well as promoting tree regeneration, will minimize the environmental effects of these anthropogenic disturbances.

Description: Minerals, Vol. 8, Pages 349: Role of DTAB and SDS in Bubble-Particle Attachment: AFM Force Measurement, Attachment Behaviour Visualization, and Contact Angle Study Minerals doi: 10.3390/min8080349 Authors: Yaowen Xing Mengdi Xu Ming Li Wei Jin Yijun Cao Xiahui Gui Atomic force microscopy (AFM) and contact angle measurements were used to study the role of dodecyltrimethylammonium bromide (DTAB) and sodium dodecyl sulphate (SDS) in bubble-particle attachment. The results show that the forces between bubbles and the hydrophilic glass particle were always repulsive in the absence of DTAB and SDS. An attractive hydrophobic force was induced when the particles became hydrophobic, and the force was proportional to the water contact-angle. In the presence of DTAB and SDS, the cationic head group of DTAB adsorbed onto the negative hydrophilic glass surface as a monolayer and thus induced a hydrophobic force. However, at a high DTAB concentration, the DTAB molecules began to adsorb as a bilayer, reverting back to a hydrophilic surface. The hydrophobic force disappeared and the water film between the bubble and particle was stabilised under the repulsive double-layer force. The anionic SDS molecules could not adsorb onto the hydrophilic glass surface. The repulsive force always dominated the bubble-particle interaction. In the case of hydrophobic glass, the hydrophobic force decreased, and even disappeared, with the addition of DTAB and SDS. All the findings from the AFM force curves were consistent with the attachment behaviour and contact angle results.

Description: Forests, Vol. 9, Pages 490: Determinants of Above-Ground Biomass and Its Spatial Variability in a Temperate Forest Managed for Timber Production Forests doi: 10.3390/f9080490 Authors: María de los Ángeles Soriano-Luna Gregorio Ángeles-Pérez Mario Guevara Richard Birdsey Yude Pan Humberto Vaquera-Huerta José René Valdez-Lazalde Kristofer D. Johnson Rodrigo Vargas The proper estimation of above-ground biomass (AGB) stocks of managed forests is a prerequisite to quantifying their role in climate change mitigation. The aim of this study was to analyze the spatial variability of AGB and its uncertainty between actively managed pine and unmanaged pine-oak reference forests in central Mexico. To investigate the determinants of AGB, we analyzed variables related to forest management, stand structure, topography, and climate. We developed linear (LM), generalized additive (GAM), and Random Forest (RF) empirical models to derive spatially explicit estimates and their uncertainty, and compared them. AGB was strongly influenced by forest management, as LiDAR-derived stand structure and stand age explained 80.9% to 89.8% of its spatial variability. The spatial heterogeneity of AGB varied positively with stand structural complexity and age in the managed forests. The type of predictive model had an impact on estimates of total AGB in our study site, which varied by as much as 19%. AGB densities varied from 0 to 492 ± 17 Mg ha−1 and the highest values were predicted by GAM. Uncertainty was not spatially homogeneously distributed and was higher with higher AGB values. Spatially explicit AGB estimates and their association with management and other variables in the study site can assist forest managers in planning thinning and harvesting schedules that would maximize carbon stocks on the landscape while continuing to provide timber and other ecosystem services. Our study represents an advancement toward the development of efficient strategies to spatially estimate AGB stocks and their uncertainty, as the GAM approach was used for the first time with improved results for such a purpose.

Description: Minerals, Vol. 8, Pages 353: Multiscale Computational Simulation of Amorphous Silicates’ Structural, Dielectric, and Vibrational Spectroscopic Properties Minerals doi: 10.3390/min8080353 Authors: José Ángel Martínez-González Javier Navarro-Ruiz Albert Rimola Silicates are among the most abundant and important inorganic materials, not only in the Earth’s crust, but also in the interstellar medium in the form of micro/nanoparticles or embedded in the matrices of comets, meteorites, and other asteroidal bodies. Although the crystalline phases of silicates are indeed present in nature, amorphous forms are also highly abundant. Here, we report a theoretical investigation of the structural, dielectric, and vibrational properties of the amorphous bulk for forsterite (Mg2SiO4) as a silicate test case by a combined approach of classical molecular dynamics (MD) simulations for structure evolution and periodic quantum mechanical Density Functional Theory (DFT) calculations for electronic structure analysis. Using classical MD based on an empirical partial charge rigid ionic model within a melt-quenching scheme at different temperatures performed with the GULP 4.0 code, amorphous bulk structures for Mg2SiO4 were generated using the crystalline phase as the initial guess. This has been done for bulk structures with three different unit cell sizes, adopting a super-cell approach; that is, 1 × 1 × 2, 2 × 1 × 2, and 2 × 2 × 2. The radial distribution functions indicated a good degree of amorphization of the structures. Periodic B3LYP-geometry optimizations performed with the CRYSTAL14 code on the generated amorphous systems were used to analyze their structure; to calculate their high-frequency dielectric constants (ε∞); and to simulate their IR, Raman, and reflectance spectra, which were compared with the experimental and theoretical crystalline Mg2SiO4. The most significant changes of the physicochemical properties of the amorphous systems compared to the crystalline ones are presented and discussed (e.g., larger deviations in the bond distances and angles, broadening of the IR bands, etc.), which are consistent with their disordered nature. It is also shown that by increasing the unit cell size, the bulk structures present a larger degree of amorphization.

Description: Forests, Vol. 9, Pages 500: Taylor’s Power Law for Leaf Bilateral Symmetry Forests doi: 10.3390/f9080500 Authors: Ping Wang David A. Ratkowsky Xiao Xiao Xiaojing Yu Jialu Su Lifang Zhang Peijian Shi Leaf shape and symmetry is of interest because of the importance of leaves in photosynthesis. Recently, a novel method was proposed to measure the extent of bilateral symmetry in leaves in which a leaf was divided into left and right sides by a straight line through the leaf apex and base, and a number of equidistant strips were drawn perpendicular to the straight line to generate an equivalent number of differences in area between the left and right parts. These areal differences are the basis for a measure of leaf bilateral symmetry, which was then examined to see how well it follows Taylor’s power law (TPL) using three classes of plants, namely, 10 geographical populations of Parrotia subaequalis (H.T. Chang) R.M. Hao et H.T. Wei, 10 species of Bambusoideae, and 10 species of Rosaceae. The measure of bilateral symmetry followed TPL for a single species or for a class of closely related species. The estimate of the exponent of TPL for bamboo plants was significantly larger than for the dicotyledonous trees, but its goodness of fit was the best among the three classes of plants. The heterogeneity of light falling on branches and leaves due to above-ground architectural patterns is an important contributor to leaf asymmetry.

Description: Forests, Vol. 9, Pages 499: Ecological Factors Affecting White Pine, Red Oak, Bitternut Hickory and Black Walnut Underplanting Success in a Northern Temperate Post-Agricultural Forest Forests doi: 10.3390/f9080499 Authors: Benoit Truax Daniel Gagnon Julien Fortier France Lambert Marc-Antoine Pétrin This study took place in southern Québec (Canada) where young stands of white ash and grey birch have been underplanted with white pine, red oak, bitternut hickory and black walnut. The establishment success of white pine and red oak was measured with and without tree shelters (to protect from deer). Ecological factors affecting the height growth of the four species were also measured for protected trees. After 6 years, the survival and total height of unprotected oak was 29% and 44.3 cm vs. 80.5% and 138.5 cm for protected oak. White pine was less affected by browsing (survival of 79.5 and 93.5%; height of 138.5 and 217.9 cm for unprotected vs. protected pine). Height of white pine was higher in the grey birch stands, while height of all hardwoods was higher in the white ash stands, which had better soil drainage, higher fertility, and an understory dominated by Rubus species. Total height of all hardwoods was significantly (p < 0.05) correlated with Rubus cover and with soil fertility. Pine and walnut height were strongly correlated (p < 0.001) to shelterwood structure (canopy openness or total basal area). Pine was less sensitive to variations in shelterwood characteristics, while black walnut showed high sensitivity. This study provides evidence that underplanting is suitable for black walnut assisted migration northward and for bitternut hickory restoration, despite soil conditions that were less favorable than in bottomland habitats mainly supporting these species in eastern Canada. Tree shelters offering protection from deer browsing and species-specific site selection are recommended for underplanting in the southern Québec region.

Description: Minerals, Vol. 8, Pages 359: Influence of the Structure and Experimental Surfaces Modifications of 2:1 Clay Minerals on the Adsorption Properties of Methylene Blue Minerals doi: 10.3390/min8080359 Authors: Pardo Cecilia López-Moreno Hernández Pozo Bentabol Franco In this work the adsorption capacities of methylene blue on Mg-smectite and sepiolite and its derived material obtained after acid treatment and/or the addition of Fe at its surfaces are studied. Natural smectite with high Mg-content in its octahedral sheet (Mg-smectite) displays higher adsorption capacity than the sepiolite due to the ability of Mg-smectite to expand the basal spacing to accommodate methylene blue cations between adjacent layers and the inability of sepiolite to adsorb these cations within the structural channels. The acid-activation of Mg-smectite causes a clear decrease in the adsorption capacity attributed to the partial loss of the interlayer positions by the loss of the octahedral sheet and subsequent formation of amorphous silica. Moreover, the adsorption of the Mg-smectite decreases even more when iron oxohydroxides species are incorporated in its interlayer spacing making inaccessible the interlayer active sites for the adsorption of methylene blue cations. On the contrary, the microwave-assisted acid treatment of sepiolite causes a slight increase in the adsorption capacity related with the dispersion of fibers. Nevertheless, contrary to that observed with Mg-smectite, higher increasing of adsorption capacities are obtained after the formation of new adsorption centers due to the incorporation of iron oxohydroxides species at the external surfaces of sepiolite.

Description: Diversity, Vol. 10, Pages 94: Water Availability Coincides with Population Declines for an Endangered Butterfly Diversity doi: 10.3390/d10030094 Authors: Heather L. Cayton Nick M. Haddad As global climate change causes population declines across numerous taxa, it becomes critical to understand the specific pathway by which climatic and anthropogenic factors influence population size. Water availability is a key environmental condition that links climate and humans to species response, especially for rare or threatened butterflies that are highly sensitive to changes in climate and the surrounding landscape. We use the wetland-dependent endangered St. Francis’ satyr butterfly (Neonympha mitchellii francisci) to test how changes in water availability affect population size via changes in host plant growth. We show that long-term declines in water availability are directly linked to a decline in host plant growth and contributed to a population decrease of 95% for St. Francis’ satyrs in the past decade, threatening the persistence of the species. Recent restoration work, which includes efforts to increase water availability via hardwood removal, has been successful in increasing population numbers. Many butterflies are broadly dependent on water availability and flow, and only by understanding the specific pathway that directly links water availability to species response can we make effective conservation plans to prepare for the altered water conditions of the future.

Description: Minerals, Vol. 8, Pages 360: Adsorption Structure and Mechanism of Styryl Phosphoric Acid at the Rutile–Water Interface Minerals doi: 10.3390/min8080360 Authors: Wei Xiao Fen Jiao Hongbo Zhao Wenqing Qin Guanzhou Qiu Jun Wang The microstructure and mechanism of styryl phosphoric acid (SPA) adsorbed at the rutile–water interface were investigated through zeta potential measurement, ultraviolet-visible spectrophotometry (UV-Vis), Fourier transform infrared spectroscopy (FT-IR) and X-ray photoelectron spectroscopy (XPS). The results of the zeta potential measurement illustrate that SPA is mainly electrostatically adsorbed on the rutile surface, and the adsorption process and result can be well fitted by the Stern-Grahame equation. The adsorption is severely affected by pH due to different species of SPA occurring in different pH solutions. The compound of P–O–Ti, with a structure of bidentate binuclear or bidentate mononuclear complexes, is formed after SPA is adsorbed on the rutile surface. SPA can be adsorbed on the rutile surface through the coordination of self-polymerization and bidentate mononuclear, which greatly increases the hydrophobicity of the rutile surface. Based on the above analysis and discussion, we proposed the adsorption model of SPA at the rutile–water interface, which was conducive to the modification and synthesis of a highly efficient flotation collector of the primary rutile ore.

Description: Minerals, Vol. 8, Pages 365: The Prismatic Layer of Pinna: A Showcase of Methodological Problems and Preconceived Hypotheses Minerals doi: 10.3390/min8090365 Authors: Yannicke Dauphin Alain Brunelle Kadda Medjoubi Andrea Somogyi Jean-Pierre Cuif The prismatic layer of Pinna (Mollusca) is one of the most studied models for the understanding of the biomineralization mechanisms, but our knowledge of the organic components of this layer is limited to the proteins of the soluble organic matrices. The interplay of the mineral and organic matrices is studied using scanning electron and atomic force microscopy, infra-red spectrometry, thermogravimetric analyses, aminoacids analyses, thin layer chromatography (TLC), X-ray fluorescence, X-ray Absorption near Edge Structure (XANES) and time-of-flight secondary ion mass spectrometry (TOF-SIMS). Proteins, polysaccharides and lipids are detected within the prisms and their envelopes. The role of the technical choices to study calcareous biominerals is evidenced, showing that a single analysis is not enough to decipher complex biominerals.

Description: Minerals, Vol. 8, Pages 362: Authigenic Clay Minerals from Interface Reactions of Concrete-Clay Engineered Barriers: A New Perspective on Mg-Clays Formation in Alkaline Environments Minerals doi: 10.3390/min8090362 Authors: Jaime Cuevas Ana Isabel Ruiz Raúl Fernández Daniel González-Santamaría María Angulo Almudena Ortega Elena Torres María Jesús Turrero Artificial and singular geochemical environments are created around the engineered barrier systems (EBS) designed to isolate high level nuclear wastes in deep geological repositories. A concrete-bentonite interface takes place within the EBS and it builds a significant chemical gradient (pH), approximately from pH 8 (bentonite) to pH 12 (low alkali concrete), in a few millimetre thickness. This disequilibrium triggers dissolution and precipitation reactions and form a thin altered region. In this area, poorly ordered authigenic clay minerals, mainly hydrated magnesium silicates, are formed adjacent to hydrated calcium silicates and calcite precipitates adhered to the interface with concrete. This paper presents the development of this authigenic mineral layer comparing 6–18 months to 13 years interfaces. Scanning Electron Microscopy with Energy Dispersive X-ray spectroscopy (SEM-EDX) morphological and chemical characterization with the aid of ternary plots, X-ray diffraction (XRD) and infrared (IR) data show the young to old interface evolution from single brucite layers to stevensite-saponite silicates composition. Geochemical calculations indicate that this layer acts as a pH~11 buffer useful to minimize bentonite alteration and to favour the retention of amphoteric metal ions.

Description: Minerals, Vol. 8, Pages 363: Hydrothermal Metasomatism and Gold Mineralization of Porphyritic Granite in the Dongping Deposit, North Hebei, China: Evidence from Zircon Dating Minerals doi: 10.3390/min8090363 Authors: Hao Wei Jiuhua Xu Guorui Zhang Xihui Cheng Haixia Chu Chunjing Bian Zeyang Zhang A porphyritic granite intrusion was recently discovered in the Zhuanzhilian section of the Dongping gold deposit. There is as many as one tonnage of Au in the fractured shear zone within the porphyritic granite intrusion, but no relevant reports concerning the origin and age of the intrusion has been published as yet. In this paper, zircon U-Pb dating is used to study the geochronology of porphyritic granite, in order to find out the evidence of age and the relationship with gold mineralization. There are two groups of zircon 207Pb/235U-206Pb/238U concordant ages of porphyritic granites: The concordant age of 373.0 ± 3.5 Ma, with the weighted mean age of 373.0 ± 6.4 Ma; and the concordant age of 142.02 ± 1.2 Ma with the weighted mean age of 142.06 ± 0.84 Ma. We believe that the first group might represent the age of residual zircon of alkaline complex, while the second group might be related with main gold mineralization. The obtained results of the petrography and electron probe analysis indicate that the porphyritic quartz and porphyritic granite, as well as gold mineralization, might be products of a late replacement of tectonic-hydrothermal fluid, which was rich in Si, Na and K originally and later yielded gold-forming fluids.

Description: Forests, Vol. 9, Pages 510: Exogenous Oxalic Acid and Citric Acid Improve Lead (Pb) Tolerance of Larix olgensis A. Henry Seedlings Forests doi: 10.3390/f9090510 Authors: JinFeng Song Daniel Markewitz Shaoping Wu Ying Sang Chengwei Duan XiaoYang Cui We investigated the beneficial role of different concentrations of exogenous oxalic acid (OA) or citric acid (CA) for improving Pb tolerance and mitigating Pb-induced physiological toxicity in Changbai larch (Larix olgensis A. Henry) seedlings in northeast China. The seedlings were exposed to 100 mg·kg−1 Pb in soil alone or in combination with OA or CA irrigation for 10, 20, or 30 days. Pb-induced damage in L. olgensis was evident from elevated lipid peroxidation that significantly inhibited plant growth. Malondialdehyde (MDA) contents also increased in the presence of elevated Pb; however, superoxide dismutase (SOD) and peroxidase (POD) activities, as well as proline and pigment contents, all decreased. The damage increased in controls over the application periods. Pb contents in fine roots and leaves generally decreased with low-concentration organic acids (<1.0 mmol·L−1), but often increased at 5.0 and 10.0 mmol·L−1. Alternatively, when Pb-stressed plants were exposed to an organic acid (especially 5.0 or 10.0 mmol·L−1 for 10 days), the damage, as indicated by the physiological parameters, was reversed, and plant growth was promoted; CA was more effective in inducing these changes than OA. Therefore, exogenous organic acids have the potential to alleviate Pb-induced oxidative injuries, and can improve the tolerance of L. olgensis seedlings to Pb stress. Under lower OA and CA concentrations, the detoxification mechanism appears to be an external resistance mechanism; however, under higher concentrations (5.0–10.0 mmol·L−1) internal resistance mechanisms appear dominant. It is also possible that the two mechanisms work in tandem.

Description: Forests, Vol. 9, Pages 515: 25 Years of Criteria and Indicators for Sustainable Forest Management: Why Some Intergovernmental C&I Processes Flourished While Others Faded Forests doi: 10.3390/f9090515 Authors: Stefanie Linser Bernhard Wolfslehner Fady Asmar Simon R. J. Bridge David Gritten Vicente Guadalupe Mostafa Jafari Steven Johnson Pablo Laclau Guy Robertson The use of criteria and indicators (C&I) for data collection, monitoring, assessing and reporting on sustainable forest management (SFM) has been growing since the Earth Summit in 1992, supported by eleven intergovernmental, regional and international forest-related C&I processes. The initial effort led to varying levels of implementation across countries. Several processes never went much beyond the adoption of a first set of C&I while others have made substantial progress. In recent years, interest in C&I for SFM has again increased. In light of the Sustainable Development Goals and emerging global challenges the contribution of C&I to monitor, assess and report on forest conditions and trends is increasingly important. We compare and analyse the structure, activities and progress of the intergovernmental C&I processes. The work is based on document analysis and questionnaires sent to the secretariats of the processes and C&I experts. We found many similarities but also major differences in the structure and content of the C&I sets. The results provide a context for discussing and understanding why some of the C&I processes are successful in their work while others have stalled. Finally, we propose the required ingredients for success for the future activities of the forest-related intergovernmental C&I processes.

Description: Minerals, Vol. 8, Pages 370: Revisiting the Organic Template Model through the Microstructural Study of Shell Development in Pinctadamargaritifera, the Polynesian Pearl Oyster Minerals doi: 10.3390/min8090370 Authors: Cuif Dauphin Luquet Medjoubi Somogyi Perez-Huerta A top-down approach to the mineralized structures and developmental steps that can be separated in the shells of Pinctada margaritifera was carried out. Detailed characterizations show that each of the two major layers usually taken into account (the outer prismatic layer and the inner nacreous layer) is actually the result of a complex process during which the microstructural patterns were progressively established. From its early growing stages in the deeper part of the periostracal grove up to the formation of the most inner nacreous layers, this species provides a demonstrative case study illustrating the leading role of specifically secreted organic structures as determinants of the crystallographic properties of the shell-building units. Gathering data established at various observational scales ranging from morphology to the nanometer level, this study allows for a reexamination of the recent and current biomineralization models.

Description: Minerals, Vol. 8, Pages 369: Effects of Xanthate on Flotation Kinetics of Chalcopyrite and Talc Minerals doi: 10.3390/min8090369 Authors: Limei Bai Jie Liu Yuexin Han Kai Jiang Wenqing Zhao This paper investigated the effects of using or not using potassium butyl xanthate (PBX) as a collector on the flotation kinetics of talc and chalcopyrite. By means of atomic force microscopy (AFM), Fourier-transform infrared spectroscopy (FTIR), a contact angle measuring instrument and particle size analyzer, the underlying causes behind the flotation rate changes of talc and chalcopyrite are analyzed. Experimental results showed that in collectorless flotation, the law of change in the flotation rate constant (k) of the two minerals over time is independent of pH, and k values of chalcopyrite are much smaller than those of talc. In the presence of PBX, the flotation speed of chalcopyrite greatly increases, and the k values of chalcopyrite are far larger than those of talc. This is mainly because the amount of xanthate adsorbed on the surface of chalcopyrite is large and the adsorption is in the form of chemisorption, while the adsorption of xanthate on the talcum surface is in very small amounts and in the form of physical adsorption. Simulation results indicated that the collectorless flotation of chalcopyrite conform to the classical first-order kinetics model and the Kelsall model, whereas that of talc only conform to the latter, which is due to the layered structure of talc. In the presence of the collector, talc flotation conforms to the two model, because talc has a higher floatability and particle morphology has less influence on the flotation rate.

Description: Forests, Vol. 9, Pages 516: Variation of Traits on Seeds and Germination Derived from the Hybridization between the Sections Tacamahaca and Aigeiros of the Genus Populus Forests doi: 10.3390/f9090516 Authors: Jialei Zhu Ju Tian Jun Wang Shuijing Nie Poplar is an important research organism, and species in sections Tacamahaca and Aigeiros, have advantages in terms of stress resistance, ease of propagation, and fast growth. Poplar species are widely distributed and well-adapted in the world, presenting a large potential for genetic improvement. Hybridization between different species allows us to generate offspring with a unique combinations of traits. This approach has a huge potential for breeding new poplar varieties that could aid in controlling desertification in the arid and semi-arid zones of the “Three-North” in China. In this study, we carried out a cross test scheme with nine female and thirteen male poplar trees. A total of 105,401 seeds were collected from 117 crosses. Flowering phenology and seed maturation differences of the hybrid progeny were monitored in greenhouses. For male trees, Populus deltoides had the longest flowering time. For female trees, Populus pseudo-simonii showed the longest seed maturity time. The number of carpals and ovules were not the same in different females. Meanwhile, three carpals were found in P. pseudo-simonii. A highly significant positive correlation was found between the seed size and the Thousand Kernel Weight, as well as the seedling cotyledon length. During seed germination, non-radicle and non-hypocotyl seedlings were observed. We also observed a number of cotyledon variants, including single and fused cotyledons, two cotyledons with one cotyledon cracking into two parts, three cotyledons, as well as four cotyledons. These results lay a favorable foundation for combining the research between the sections Tacamahaca and Aigeiros in future work.

Description: Forests, Vol. 9, Pages 517: Fine Root Dynamics in Three Forest Types with Different Origins in a Subalpine Region of the Eastern Qinghai-Tibetan Plateau Forests doi: 10.3390/f9090517 Authors: Shun Liu Da Luo Hongguo Yang Zuomin Shi Qianli Liu Li Zhang Ying Kang Fine roots play a crucial role in plant survival potential and biogeochemical cycles of forest ecosystems. Subalpine areas of the Eastern Qinghai-Tibetan Plateau have experienced different forest re-establishment methods after clear-cutting primary forest. However, little is known about fine root dynamics of these forests originating from artificial, natural and their combined processes. Here, we determined fine root traits (biomass, production and turnover rate) of three subalpine forest types, i.e., Picea asperata Mast. plantation forest (artificial planting, PF), natural secondary forest (natural without assisted regeneration, NF) and P. asperata broadleaved mixed forest (natural regeneration after artificial planting, MF) composed of planted P. asperata and naturally regenerated native broadleaved species. At the soil depth of 0–30 cm, fine root biomass was the highest in PF and fine root production was the highest in NF, and both were the lowest in MF. Fine root dynamics of the three forest types tended to decrease with soil depth, with larger variations in PF. Fine root biomass and production were the highest in PF in 0–10 cm soil layer but were not significantly different among forest types in the lower soil layers. There were positive correlations between these parameters and aboveground biomass across forest types in soil layer of 0–10 cm, but not in the lower soil layers. Fine root turnover rate was generally higher in mixed forests than in monocultures at all soil depths. In conclusion, the natural regeneration procedure after clear-cutting in the subalpine region of western Sichuan seems to be superior from the perspective of fine root dynamics.

Description: Forests, Vol. 9, Pages 518: Estimation and Uncertainty of the Mixing Effects on Scots Pine—European Beech Productivity from National Forest Inventories Data Forests doi: 10.3390/f9090518 Authors: Sonia Condés Hubert Sterba Ana Aguirre Kamil Bielak Andrés Bravo-Oviedo Lluís Coll Maciej Pach Hans Pretzsch Patrick Vallet Miren del Río An increasing amount of research is focusing on comparing productivity in monospecific versus mixed stands, although it is difficult to reach a general consensus as mixing effects differ both in sign (over-yielding or under-yielding) and magnitude depending on species composition as well as on site and stand conditions. While long-term experimental plots provide the best option for disentangling the mixing effects, these datasets are not available for all the existing mixtures nor do they cover large gradients of site factors. The objective of this study was to evaluate the effects and uncertainties of tree species mixing on the productivity of Scots pine–European beech stands along the gradient of site conditions in Europe, using models developed from National and Regional Forest Inventory data. We found a positive effect of pine on beech basal area growth, which was slightly greater for the more humid sites. In contrast, beech negatively affected pine basal area growth, although the effects switched to positive in the more humid sites. However, the uncertainty analysis revealed that the effect on pine at mid- and more humid sites was not-significant. Our results agree with studies developed from a European transect of temporal triplets in the same pine–beech mixtures, confirming the suitability of these datasets and methodology for evaluating mixing effects at large scale.

Description: Forests, Vol. 9, Pages 526: Mobility Range of a Cable Skidder for Timber Extraction on Sloped Terrain Forests doi: 10.3390/f9090526 Authors: Andreja Đuka Tomislav Poršinsky Tibor Pentek Zdravko Pandur Dinko Vusić Ivica Papa The use of forestry vehicles in mechanised harvesting systems is still the most effective way of timber procurement, and forestry vehicles need to have high mobility to face various terrain conditions. This research gives boundaries of planning timber extraction on sloped terrain with a cable skidder, considering terrain parameters (slope, direction of skidding, cone index), vehicle technical characteristics and load size (5 different loads) relying on sustainability and eco-efficiency. Skidder mobility model was based on connecting two systems: vehicle-terrain (load distribution) and wheel-soil (skidder traction performance) with two mobility parameters: (1) maximal slope during uphill timber extraction by a cable skidder based on its traction performance (gradeability), and (2) maximal slope during downhill timber extraction by a cable skidder when thrust force is equal to zero. Results showed mobility ranges of an empty skidder for slopes between −50% and +80%, skidder with 1 tonne load between −26% and +63%, skidder with 2 tonne load between −30% and +51%, skidder with 3 tonne load between −34% and +39%, skidder with 4 tonne load between −35% and +30% and skidder with 5 tonne load between −41% and +11%.These results serve to improve our understanding of safer, more efficient timber extraction methods on sloped terrain.

Description: Forests, Vol. 9, Pages 527: Quantifying the Effects of Wood Moisture and Temperature Variation on Time-of-Flight Acoustic Velocity Measures within Standing Red Pine and Jack Pine Trees Forests doi: 10.3390/f9090527 Authors: Peter F. Newton The relationship between the dynamic modulus of elasticity (me) of xylem tissue and acoustic velocity (vd) has been established for a number of commercially-important coniferous species, including red pine (Pinus resinosa Ait.) and jack pine (Pinus banksiana Lamb.). However, vd has been shown to vary systematically with xylem temperature (tx) and moisture (mx) for some species, and hence when the calibrated me–vd relationships are used outside of the range of conditions under which they were parameterized, erroneous predictions may arise. Consequently, the objectives of this study were (1) to investigate the significance of tx and mx effects on vd measurements within standing red pine and jack pine trees, and (2), given (1), to develop correction equations for standardizing vd measurements to referenced tx and mx conditions if warranted. Analytically, based on a temporal replicated sampling design, 26 mature red pine and 36 semi-mature jack pine trees growing in managed plantations located within central Ontario, Canada (Kirkwood Forest, Great Lakes—St. Lawrence Forest Region), were continuously measured for vd, tx, and mx during the spring-to-autumn seasonal periods in 2016 (red pine) and 2017 (jack pine). A total of 6 measurement events per species occurred at approximately 4–8 week intervals in which a total of 624 red pine and 864 jack pine cardinal-specific (north, east, south, and west) breast-height acoustic velocity, xylem temperature, and xylem moisture measurements were obtained: Yielding a total of 156 red pine and 216 jack pine mean tree-based values available for analysis. Over the sampling periods, (1) mean tree xylem temperatures ranged from a minimum of 3 °C to a maximum of 31 °C (mean = 19.2 °C) in red pine and from a minimum of 0 °C to a maximum of 27 °C (mean = 16.5 °C) in jack pine, and (2) mean tree xylem moistures ranged from a minimum 31% to a maximum of 45% (mean = 38.6%) in red pine and from a minimum 25% to a maximum of 50% (mean = 38.8%) in jack pine. Graphical examination of the moisture effect on the vd and tx relationship by tree and species revealed inversely proportional, linear-like trends at lower moisture levels and directly-proportional, linear-like trends at higher moisture levels where the effect was more evident for red pine than for jack pine. In order to describe this multivariate relationship, species-specific, two-level hierarchical, mixed-effects linear models inclusive of random and fixed effects were specified and subsequently parameterized. The first-level model described the tree-specific vd–tx relationship deploying a simple linear regression specification, whereas the second-level model expressed the first-level parameter estimates as a linear function of seasonal mean tree moisture. The resultant statistically-validated, parameterized regression models, for which 64% (red pine) and 90% (jack pine) of the vd variation was explained, indicated that the vd–tx relationship varied systematically with seasonal mean moisture level in red pine but not so in jack pine. More precisely, in red pine, vd declined with increasing tx at lower moisture levels (<38%), but increased with increasing tx at higher moisture levels (>38%). Conversely, although vd declined with increasing tx in jack pine, the relationship was unaffected by changes in seasonal mean tree moisture levels. Consequently, based on the final hierarchical model specifications, correction equations for adjusting observed vd values to standardized temperature (20 °C) and moisture conditions (40% for red pine) were developed for each species. Across the range of temperatures (≈5 °C–30 °C) and mean moisture levels (≈30–45%) examined, these equations generated a mean absolute vd adjustment of approximately 0.12 km/s for red pine and 0.04 km/s for jack pine. However, based on the corresponding relative magnitude of these adjustments which account for the narrow species-specific vd sample ranges observed (0.80 and 0.85 km/s for red pine and jack pine, respectively), the standardization of vd estimates could be of operational significance when acoustic sampling during periods in which xylem temperature and moisture levels approach the extremities of their spring-to-autumn seasonal ranges. Overall, the results of this empirical-based assessment, which confirmed the presence of temperature and moisture induced variation in acoustic velocity measures within standing red pine and jack pine trees, were largely in accordance with expectation. The subsequent provision of species-specific correction functions for adjusting observed vd sample values to corresponding equivalents referenced to standardized temperature and moisture conditions could assist in mitigating the consequences of environmental variability when acoustic sampling.

Description: Diversity, Vol. 10, Pages 97: Changes in Species Composition of Birds and Declining Number of Breeding Territories over 40 Years in a Nature Conservation Area in Southwest Germany Diversity doi: 10.3390/d10030097 Authors: Fabian Etienne Schrauth Michael Wink Global loss of biodiversity is occurring at an alarming rate and is a major issue in current times. Long-term studies offer the possibility to analyse changes in biodiversity and allow assessments of anthropogenic interventions in ecosystems. At present, various studies in most countries show partially strong declines of insect populations. Due to their role as a food source for many organisms it is assumed that declines of insect abundance might have effects on higher trophic levels like insectivorous birds. For reliable statements on relationships between food availability and population trends, systematic and extensive records of breeding birds are necessary. In this study, we analysed the changes in the range of species, biodiversity, and abundance of a breeding bird community over 43 years in a large nature conservation area in southwest Germany (“Lampertheimer Altrhein” near Mannheim). Since 1974, considerable changes in the spectrum of breeding birds have been found, but the overall biodiversity index did not change. Furthermore, 70% of the investigated species showed decreasing numbers of breeding bird territories, and the overall number of territories across species declined by more than 65%. A classification based on the main diet during the breeding period and habitat use revealed strong declines for insectivorous birds in the study area, especially in wetland and open cultivated landscapes.

Description: Forests, Vol. 9, Pages 524: Drought Sensitiveness on Forest Growth in Peninsular Spain and the Balearic Islands Forests doi: 10.3390/f9090524 Authors: Marina Peña-Gallardo Sergio M. Vicente-Serrano J. Julio Camarero Antonio Gazol Raúl Sánchez-Salguero Fernando Domínguez-Castro Ahmed El Kenawy Santiago Beguería-Portugés Emilia Gutiérrez Martin de Luis Gabriel Sangüesa-Barreda Klemen Novak Vicente Rozas Pedro A. Tíscar Juan C. Linares Edurne Martínez del Castillo Montserrat Ribas Matamoros Ignacio García-González Fernando Silla Álvaro Camisón Mar Génova José M. Olano Luis A. Longares Andrea Hevia J. Diego Galván Drought is one of the key natural hazards impacting net primary production and tree growth in forest ecosystems. Nonetheless, tree species show different responses to drought events, which make it difficult to adopt fixed tools for monitoring drought impacts under contrasting environmental and climatic conditions. In this study, we assess the response of forest growth and a satellite proxy of the net primary production (NPP) to drought in peninsular Spain and the Balearic Islands, a region characterized by complex climatological, topographical, and environmental characteristics. Herein, we employed three different indicators based on in situ measurements and satellite image-derived vegetation information (i.e., tree-ring width, maximum annual greenness, and an indicator of NPP). We used seven different climate drought indices to assess drought impacts on the tree variables analyzed. The selected drought indices include four versions of the Palmer Drought Severity Index (PDSI, Palmer Hydrological Drought Index (PHDI), Z-index, and Palmer Modified Drought Index (PMDI)) and three multi-scalar indices (Standardized Precipitation Evapotranspiration Index (SPEI), Standardized Precipitation Index (SPI), and Standardized Precipitation Drought Index (SPDI)). Our results suggest that—irrespective of drought index and tree species—tree-ring width shows a stronger response to interannual variability of drought, compared to the greenness and the NPP. In comparison to other drought indices (e.g., PDSI), and our results demonstrate that multi-scalar drought indices (e.g., SPI, SPEI) are more advantageous in monitoring drought impacts on tree-ring growth, maximum greenness, and NPP. This finding suggests that multi-scalar indices are more appropriate for monitoring and modelling forest drought in peninsular Spain and the Balearic Islands.

Description: Forests, Vol. 9, Pages 525: Effects of Stand Structure, Browsing, and Biophysical Conditions on Regeneration Following Mountain Pine Beetle in Mixed Lodgepole Pine and Aspen Forests of the Southern Rockies Forests doi: 10.3390/f9090525 Authors: Kristen A. Pelz Frederick W. Smith Aspen (Populus tremuloides) and lodgepole pine (Pinus contorta var. latifolia) co-occur in the southern Rocky Mountains (USA), where mountain pine beetle (MPB, Dendroctonus ponderosae) has caused extensive lodgepole pine mortality since the late 1990s. Both species excel in post-disturbance high-light environments, but lodgepole pine has generally been thought to establish poorly on undisturbed seedbeds, and aspen suckering may be inhibited by intact aspen overstory. We ask whether lodgepole pine and aspen will regenerate in sufficient quantities to revegetate these forests. We visited a random sample of aspen and lodgepole pine stands across the affected landscape in northern Colorado and southern Wyoming to measure regeneration and overstory mortality. Lodgepole pine regeneration is occurring in 85% of stands, and most stands have >550 stems ha−1. The median aspen sucker density was 6175 stems ha−1. Surprisingly, neither lodgepole pine nor aspen regeneration density was related to overstory mortality level. Animal damage is currently affecting aspen in these forests. Over 50% of stands had damage to 60% or more of their suckers, but 30% of stands had <20% of their stems damaged. Browsed stems were significantly shorter for their ages and were shorter than the 2.5-m height threshold for possible elk browsing. However, the results suggest that sufficient quantities of down lodgepole pine may protect aspen from damage and allow aspen to successfully recruit to the overstory. Multiple regression analysis showed that down lodgepole pine basal area, followed by browsing pressure, were the most important predictors of sucker height and the proportion of suckers browsed. Although 15% of stands had no lodgepole pine regeneration, aspen and lodgepole pine forests are generally regenerating despite animal browsing on aspen. This study is the first to present a regional perspective on regeneration in MPB-affected lodgepole pine and aspen forests, and overall, intervention does not seem necessary to ensure a mix of both species in the future.

Description: Forests, Vol. 9, Pages 528: Drought Influence on Forest Plantations in Zululand, South Africa, Using MODIS Time Series and Climate Data Forests doi: 10.3390/f9090528 Authors: Sifiso Xulu Kabir Peerbhay Michael Gebreslasie Riyad Ismail South Africa has a long history of recurrent droughts that have adversely affected its economic performance. The recent 2015 drought has been declared the most serious in 26 years and impaired key agricultural sectors including the forestry sector. Research on the forests’ responses to drought is therefore essential for management planning and monitoring. The effects of the latest drought on the forests in South Africa have not been studied and are uncertain. The study reported here addresses this gap by using Moderate Resolution Imaging Spectroradiometer (MODIS)-derived normalized difference vegetation index (NDVI) and precipitation data retrieved and processed using the JavaScript code editor in the Google Earth Engine (GEE) and the corresponding normalized difference infrared index (NDII), Palmer drought severity index (PDSI), and El Niño time series data for KwaMbonambi, northern Zululand, between 2002 and 2016. The NDVI and NDII time series were decomposed using the Breaks for Additive Seasonal and Trend (BFAST) method to establish the trend and seasonal variation. Multiple linear regression and Mann–Kendall tests were applied to determine the association of the NDVI and NDII with the climate variables. Plantation trees displayed high NDVI values (0.74–0.78) from 2002 to 2013; then, they decreased sharply to 0.64 in 2015. The Mann–Kendall trend test confirmed a negative significant (p = 0.000353) trend between 2014 and 2015. This pattern was associated with a precipitation deficit and low NDII values during a strong El Niño phase. The PDSI (−2.6) values indicated severe drought conditions. The greening decreased in 2015, with some forest remnants showing resistance, implying that the tree species had varying sensitivity to drought. We found that the plantation trees suffered drought stress during 2015, although it seems that the trees began to recover, as the NDVI signals rose in 2016. Overall, these results demonstrated the effective use of the NDVI- and NDII-derived MODIS data coupled with climatic variables to provide insights into the influence of drought on plantation trees in the study area.

Description: Minerals, Vol. 8, Pages 376: Microwave-Assisted Acid Activation of Clays Composed of 2:1 Clay Minerals: A Comparative Study Minerals doi: 10.3390/min8090376 Authors: Juan Antonio Cecilia Laura Pardo Manuel Pozo Eva Bellido Francisco Franco The effect of the microwave-assisted acid treatment (MAT) on the structure and texture of dioctahedral (montmorillonite) and trioctahedral (saponite) smectites, kerolitic clays and sepiolites were studied by scanning electron microscopy, nitrogen adsorption, X-ray fluorescence, X-ray diffraction and Fourier transform infrared spectroscopy. This study shows that in the smectite group of minerals the effectiveness of MAT is notably influenced by the chemical composition of the octahedral sheet, whereas in kerolitic clays it is influenced by the proportion of the expandable phase in the mixed layer sequence. On the other hand, the reactivity of sepiolites depends on the width of the natural fibres. With these treatments, extremely high specific surface area (SSA) increments are achieved in just 16 min. The SSA increments reach values up to 231 m2/g (%ΔSBET = 80) in sepiolites, 198 m2/g (%ΔSBET = 155) in Mg-smectites, and 161 m2/g (%ΔSBET = 61) in kerolitic clays.

Description: Forests, Vol. 9, Pages 533: Rethinking Fuelwood: People, Policy and the Anatomy of a Charcoal Supply Chain in a Decentralizing Peru Forests doi: 10.3390/f9090533 Authors: Aoife Bennett Peter Cronkleton Mary Menton Yadvinder Malhi In Peru, as in many developing countries, charcoal is an important source of fuel. We examine the commercial charcoal commodity chain from its production in Ucayali, in the Peruvian Amazon, to its sale in the national market. Using a mixed-methods approach, we look at the actors involved in the commodity chain and their relationships, including the distribution of benefits along the chain. We outline the obstacles and opportunities for a more equitable charcoal supply chain within a multi-level governance context. The results show that charcoal provides an important livelihood for most of the actors along the supply chain, including rural poor and women. We find that the decentralisation process in Peru has implications for the formalisation of charcoal supply chains, a traditionally informal, particularly related to multi-level institutional obstacles to equitable commerce. This results in inequity in the supply chain, which persecutes the poorest participants and supports the most powerful actors.

Description: Forests, Vol. 9, Pages 531: Intersectoral and Intermunicipal Cooperation as a Tool for Supporting Local Economic Development: Prospects for the Forest and Wood-Based Sector in Poland Forests doi: 10.3390/f9090531 Authors: Leszek Wanat Tomasz Potkański Jan Chudobiecki Elżbieta Mikołajczak Katarzyna Mydlarz Intersectoral and intermunicipal cooperation are still underdeveloped spheres of public and economic development policies. This also applies to the natural economy to a large extent. Scientific discussions are invariably focused on pro-competitive activities, the economic efficiency of which is not always sufficient. In this paper the authors attempt to identify factors leading to cooperation between local government authorities and economic entities focusing on the forestry and wood-based sector in Poland. These processes were analyzed within the framework of the Spatial Economics and New Institutional Economy, both in the theoretical and practical context. The aim of the research was to identify the ability to create intersectoral and intermunicipal partnerships in already existing and newly established functional areas, as this may determine the development of the forestry and wood-based industry.

Description: Minerals, Vol. 8, Pages 374: Kriging Interpolation for Evaluating the Mineral Resources of Cobalt-Rich Crusts on Magellan Seamounts Minerals doi: 10.3390/min8090374 Authors: Dewen Du Shijuan Yan Fengli Yang Zhiwei Zhu Qinglei Song Gang Yang The evaluation of mineral resources on seamounts by geostatistics faces two key challenges. First, the conventional distance/orientation- and the simple distance-based variogram functions used are ineffective at expressing the spatial self-correlation and continuity of cobalt-rich crust thicknesses on seamounts. Second, the sampling stations used for a single seamount are generally very sparsely distributed because of the high survey costs, which results in an insufficient number of information points for variogram fitting. Here, we present an alternative geostatistical method that uses distance/gradient- and distance/relative-depth-based variograms to process data collected from several neighboring seamounts, allowing the variogram fitting. The application example reported for the Magellan seamounts demonstrates the suitability of the method for evaluating the mineral resources of cobalt-rich crusts. The method could be effective also for the analysis of surface data obtained from mountain slopes on land (e.g., soil).

Description: Minerals, Vol. 8, Pages 373: Sulfide Formation as a Result of Sulfate Subduction into Silicate Mantle (Experimental Modeling under High P,T-Parameters) Minerals doi: 10.3390/min8090373 Authors: Yuliya Bataleva Yuri Palyanov Yuri Borzdov Ca,Mg-sulfates are subduction-related sources of oxidized S-rich fluid under lithospheric mantle P,T-parameters. Experimental study, aimed at the modeling of scenarios of S-rich fluid generation as a result of desulfation and subsequent sulfide formation, was performed using a multi-anvil high-pressure apparatus. Experiments were carried out in the Fe,Ni-olivine–anhydrite–C and Fe,Ni-olivine–Mg-sulfate–C systems (P = 6.3 GPa, T of 1050 and 1450 °C, t = 23–60 h). At 1050 °C, the interaction in the olivine–anhydrite–C system leads to the formation of olivine + diopside + pyrrhotite assemblage and at 1450 °C leads to the generation of immiscible silicate-oxide and sulfide melts. Desulfation of this system results in the formation of S-rich reduced fluid via the reaction olivine + anhydrite + C → diopside + S0 + CO2. This fluid is found to be a medium for the recrystallization of olivine, extraction of Fe and Ni, and subsequent crystallization of Fe,Ni-sulfides (i.e., olivine sulfidation). At 1450 °C in the Ca-free system, the generation of carbonate-silicate and Fe,Ni-sulfide melts occurs. Formation of the carbonate component of the melt occurs via the reaction Mg-sulfate + C → magnesite + S0. It is experimentally shown that the olivine-sulfate interaction can result in mantle sulfide formation and generation of potential mantle metasomatic agents—S- and CO2-dominated fluids, silicate-oxide melt, or carbonate-silicate melt.

Description: Minerals, Vol. 8, Pages 379: Origin of Platinum Group Minerals (PGM) Inclusions in Chromite Deposits of the Urals Minerals doi: 10.3390/min8090379 Authors: Federica Zaccarini Giorgio Garuti Evgeny Pushkarev Oskar Thalhammer This paper reviews a database of about 1500 published and 1000 unpublished microprobe analyses of platinum-group minerals (PGM) from chromite deposits associated with ophiolites and Alaskan-type complexes of the Urals. Composition, texture, and paragenesis of unaltered PGM enclosed in fresh chromitite of the ophiolites indicate that the PGM formed by a sequence of crystallization events before, during, and probably after primary chromite precipitation. The most important controlling factors are sulfur fugacity and temperature. Laurite and Os–Ir–Ru alloys are pristine liquidus phases crystallized at high temperature and low sulfur fugacity: they were trapped in the chromite as solid particles. Oxygen thermobarometry supports that several chromitites underwent compositional equilibration down to 700 °C involving increase of the Fe3/Fe2 ratio. These chromitites contain a great number of PGM including—besides laurite and alloys—erlichmanite, Ir–Ni–sulfides, and Ir–Ru sulfarsenides formed by increasing sulfur fugacity. Correlation with chromite composition suggests that the latest stage of PGM crystallization might have occurred in the subsolidus. If platinum-group elements (PGE) were still present in solid chromite as dispersed atomic clusters, they could easily convert into discrete PGM inclusions splitting off the chromite during its re-crystallization under slow cooling-rate. The presence of primary PGM inclusions in fresh chromitite of the Alaskan-type complexes is restricted to ore bodies crystallized in equilibrium with the host dunite. The predominance of Pt–Fe alloys over sulfides is a strong indication for low sulfur fugacity, thereby early crystallization of laurite is observed only in one deposit. In most cases, Pt–Fe alloys crystallized and were trapped in chromite between 1300 and 1050 °C. On-cooling equilibration to ~900 °C may produce lamellar unmixing of different Pt–Fe phases and osmium. Precipitation of the Pt–Fe alloys locally is followed by an increase of sulfur fugacity leading to crystallize erlichmanite and Ir–Rh–Ni–Cu sulfides, occurring as epitaxic overgrowth on the alloy. There is evidence that the system moved quickly into the stabilization field of Pt–Fe alloys by an increase of the oxygen fugacity marked by an increase of the magnetite component in the chromite. In summary, the data support that most of the primary PGM inclusions in the chromitites of the Urals formed in situ, as part of the chromite precipitation event. However, in certain ophiolitic chromitites undergoing annealing conditions, there is evidence for subsolidus crystallization of discrete PGM from PGE atomic-clusters occurring in the chromite. This mechanism of formation does not require a true solid solution of PGE in the chromite structure.

Description: Minerals, Vol. 8, Pages 380: Major and Trace Element Geochemistry of Pyrite and Pyrrhotite from Stratiform and Lamellar Orebodies: Implications for the Ore Genesis of the Dongguashan Copper (Gold) Deposit, Eastern China Minerals doi: 10.3390/min8090380 Authors: Zhongfa Liu Yongjun Shao Haodi Zhou Nan Liu Kuanxin Huang Qingquan Liu Jiandong Zhang Cheng Wang The Dongguashan copper (gold) deposit in Anhui Province is one of the largest copper (gold) deposits in the Tongling ore district, which is the most important region in the Middle–Lower Yangtze River Metallogenic Belt, Eastern China. Stratiform and lamellar orebodies are the major deposit types. Pyrite and pyrrhotite from the stratiform deposit type (Py I, Po I) and lamellar deposit type (Py II, Po II) are investigated using Electron-probe Microanalyses (EPMA) and Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LA-ICP-MS). Py I, Py II, Po I and Po II have high contents of Cu, Co, Au and Se, low contents of As, Pb and Zn, with Co/Ni ratios of 0.50−48.00, 4.00−45.00, 1.55−14.45 and 1.02−1.36, respectively, most of which are greater than 1 and vary widely; these characteristics are consistent with those of pyrite with a magmatic–hydrothermal origin. The higher Au/Ag and Fe/(S + As) ratios of pyrite and crystallization temperatures (286–387 °C) of hexagonal pyrrhotite indicate that the mineralization occurrs in environments with medium- to high-temperatures, high sulfur fugacity and medium-shallow depths. Therefore, we suggest that the Dongguashan copper (gold) deposit is a stratabound skarn-type ore deposit associated with magma intrusion activity during the Yanshanian Period.

Description: Forests, Vol. 9, Pages 540: Influence of Natural and Anthropogenic Linear Canopy Openings on Forest Structural Patterns Investigated Using LiDAR Forests doi: 10.3390/f9090540 Authors: Udayalakshmi Vepakomma Daniel D. Kneeshaw Louis De Grandpré In much of the commercial boreal forest, dense road networks and energy corridors have been developed to access natural resources with unintended and poorly understood effects on surrounding forest structure. In this study, we compare the effects of anthropogenic and natural linear openings on surrounding forest conditions in black spruce stands (gap fraction, tree and sapling height, and density). Forest structure within a 100 m band around the edges of anthropogenic (roads and power lines), natural linear openings (streams), and a reference black spruce forest was measured by identifying individual stems and canopy gaps on recent high density airborne LiDAR canopy height models. CUSUM curves were used to assess the distance of edge influence. Forests surrounding anthropogenic openings were found to be gappier, less dense, and have smaller trees than those around natural openings. Forests were denser around natural and anthropogenic linear openings than in the reference forest with edge effects observed up to 24–75 m and 18–54 m, respectively, into the forest. A high density of saplings in the gappier forests surrounding anthropogenic openings may eventually lead to a higher forest biomass in the zone area surrounding roads as is currently observed around natural openings.

Description: Minerals, Vol. 8, Pages 386: Water Adsorption on the β-Dicalcium Silicate Surface from DFT Simulations Minerals doi: 10.3390/min8090386 Authors: Qianqian Wang Hegoi Manzano Iñigo López-Arbeloa Xiaodong Shen β-dicalcium silicate (β-Ca2SiO4 or β-C2S in cement chemistry notation) is one of the most important minerals in cement. An improvement of its hydration rate would be the key point for developing environmentally-friendly cements with lower energy consumption and CO2 emissions. However, there is a lack of fundamental understanding on the water/β-C2S surface interactions. In this work, we aim to evaluate the water adsorption on three β-C2S surfaces at the atomic scale using density functional theory (DFT) calculations. Our results indicate that thermodynamically favorable water adsorption takes place in several surface sites with a broad range of adsorption energies (−0.78 to −1.48 eV) depending on the particular mineral surface and adsorption site. To clarify the key factor governing the adsorption of the electronic properties of water at the surface were analyzed. The partial density of states (DOS), charge analysis, and electron density difference analyses suggest a dual interaction of water with a β-C2S (100) surface including a nucleophilic interaction of the water oxygen lone pair with surface calcium atoms and an electrophilic interaction (hydrogen bond) of one water hydrogen with surface oxygen atoms. Despite the elucidation of the adsorption mechanism, no correlation was found between the electronic structure and the adsorption energies.

Description: Minerals, Vol. 8, Pages 384: Rock Classification Using Multivariate Analysis of Measurement While Drilling Data: Towards a Better Sampling Strategy Minerals doi: 10.3390/min8090384 Authors: Veena S. Vezhapparambu Jo Eidsvik Steinar L. Ellefmo Measurement while drilling (MWD) data are gathered during drilling operations and can provide information about the strength of the rock penetrated by the boreholes. In this paper MWD data from a marble open-pit operation in northern Norway are studied. The rock types are represented by discrete classes, and the data is then modeled by a hidden Markov model (HMM). Results of using different MWD data variables are studied and presented. These results are compared and co-interpreted with optical televiewer (OTV) images, magnetic susceptibility and spectral gamma values collected in the borehole using down-the-hole sensors. A model with penetration rate, rotation pressure and dampening pressure data show a good visual correlation with OTV image for the studied boreholes. The marble class is characterized by medium penetration rate and medium rotation pressure, whereas the intrusions are characterized by low penetration rate and medium to high rotation pressure. The fractured marble is characterized by high penetration rate, high rotation and low dampening pressure. Future research will use the presented results to develop a heterogeneity index, develop an MWD-based 3D-geology model and an improved sampling strategy and investigate how to implement this in the mine planning process and reconciliation.