ALBERT

All Library Books, journals and Electronic Records Telegrafenberg

X
feed icon rss

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
Filter
  • Articles  (201)
  • Hindawi  (201)
  • American Geophysical Union
  • American Meteorological Society
  • Blackwell Publishing Ltd
  • Copernicus
  • Institute of Electrical and Electronics Engineers
  • Molecular Diversity Preservation International
  • Springer Nature
  • Springer Science + Business Media
  • Wiley-Blackwell
  • 2020-2024
  • 2020-2022
  • 2010-2014  (201)
  • 1985-1989
  • 1970-1974
  • 1960-1964
  • Advances in Physical Chemistry  (111)
  • 124471
  • Physics  (201)
  • Mathematics
  • Architecture, Civil Engineering, Surveying
Collection
  • Articles  (201)
Source
Publisher
  • Hindawi  (201)
  • American Geophysical Union
  • American Meteorological Society
  • Blackwell Publishing Ltd
  • Copernicus
    • +
Years
Year
Journal
Topic
  • 1
    facet.materialart.
    Unknown
    Polyethylene Glycols as Efficient Catalysts for the Oxidation of Xanthine Alkaloids by Ceric Ammonium Nitrate in Acetonitrile: A Kinetic and Mechanistic Approach (2013)
    Hindawi
    Details
    Publication Date: 2013-06-11
    Description: Kinetics of oxidation of xanthine alkaloids, such as Xanthine (XAN), hypoxanthine (HXAN), caffeine (CAF), theophylline (TPL), and theobromine (TBR), have been studied with ceric ammonium nitrate (CAN) using poly ethylene glycols (PEG) as catalysts. Reaction obeyed first order kinetics in both [CAN] and [Xanthine alkaloid]. Highly sluggish CAN-xanthine alkaloid reactions (in acetonitrile media even at elevated temperatures) are enhanced in presence PEGs (PEG-200, -300, -400, -600). An increase in [PEG] increased the rate of oxidation linearly. This observation coupled with a change in absorption of CAN in presence of PEG, [H–(OCH2–CH2)n–O–NH4Ce(NO3)4(CH3CN)] (PEG bound CAN species), is considered to be more reactive than CAN. The mechanism of oxidation in PEG media has been explained by Menger-Portnoy’s enzymatic model.
    Print ISSN: 1687-7985
    Electronic ISSN: 1687-7993
    Topics: Chemistry and Pharmacology , Physics
    Published by Hindawi
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    PAPER CURRENT
  • 2
    facet.materialart.
    Unknown
    Theoretical Study on the Static (Hyper)Polarizabilities of α-t-Bu-ω-CN-Poly(methylphenyl)silane (2013)
    Hindawi
    Details
    Publication Date: 2013-04-01
    Description: The static linear and nonlinear optical properties of the σ-conjugated polymer α-t-Bu-ω-CN-poly(methylphenyl)silane (PMS) are studied at the Coupled-Perturbed Hartree-Fock (CPHF) level with 6-31+G(d) basis set. The calculated results reveal that the static first hyperpolarizabilities of this system increase with the main chain length and have a good agreement with experiments. The (hyper)polarizabilities per unit cell have been extrapolated to infinite chain limit and a comparison is made to those of polysilane and polyacetylene (PA). Besides, other structural properties depending on the σ-conjugated Si–Si skeleton length are investigated as well. Electron correlation effect is estimated and it turns out that the MP2 static first hyperpolarizability is about times larger than the corresponding CPHF value for the polymer with .
    Print ISSN: 1687-7985
    Electronic ISSN: 1687-7993
    Topics: Chemistry and Pharmacology , Physics
    Published by Hindawi
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    PAPER CURRENT
  • 3
    facet.materialart.
    Unknown
    Adsorption of Polyanion onto Large Alpha Alumina Beads with Variably Charged Surface (2014)
    Hindawi
    Details
    Publication Date: 2014-12-16
    Description: Adsorption of strong polyelectrolyte, poly(styrenesulfonate), PSS, of different molecular weights onto large α-Al2O3 beads was systematically investigated as functions of pH and NaCl concentrations. The ultraviolet (UV) absorption spectra of PSS at different pH and salt concentrations confirmed that the structure of PSS is independent of pH. With the change of molecular weight from 70 kg/mol (PSS 70) to 1000 kg/mol (PSS 1000), adsorption amount of PSS increases and proton coadsorption on the surface of α-Al2O3 decreases at given pH and salt concentration. It suggests that higher molecular weight of PSS was less flat conformation than lower one. The adsorption density of PSS 70 and PSS 1000 decreases with decreasing salt concentrations, indicating that both electrostatic and nonelectrostatic interactions are involved. Experimental results of both PSS 70 and PSS 1000 adsorption isotherms onto α-Al2O3 at different pH and salt concentrations can be represented well by two-step adsorption model. The effects of molecular weight and salt concentration are explained by structure of adsorbed PSS onto α-Al2O3. The influence of added SDS on the isotherms is evaluated from the sequential adsorption. The SDS uptake onto α-Al2O3 in the presence of hemimicelles can prevent the adsorption of PSS at low concentration so that adsorption of PSS reduces with preadsorbed SDS.
    Print ISSN: 1687-7985
    Electronic ISSN: 1687-7993
    Topics: Chemistry and Pharmacology , Physics
    Published by Hindawi
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    PAPER CURRENT
  • 4
    facet.materialart.
    Unknown
    Synergistic Effect of [Ru(III) + Ir(III)] in N-Bromosuccinimide Reaction with Certain Aliphatic Ketones: A Kinetic Study (2012)
    Hindawi
    Details
    Publication Date: 2012-12-26
    Description: Dramatic rate enhancements have been observed in the oxidation of acetone (MMK), ethyl methyl ketone (EMK), and isobutyl methyl ketone (IBMK) by N-bromosuccinimide (NBS) in the presence of a mixture of metal ions [Ru(III) + Ir(III)]. The rate of oxidation in the the [Ru(III) + Ir(III)] system is much faster than either in the Ru(III) or in Ir(III) catalyzed system. The order in [NBS] was found to be zero both in catalyzed as well as uncatalyzed reactions. However, the order in [ketone] changed from unity to a fractional one in metal ion catalyzed systems. On the basis of kinetic features, the most plausible mechanism involving the oxidation of [Ir(III)-ketone] by Ru(III) to give [Ir(V)-ketone] and Ru(I) in the rate limiting step is proposed. Ru(I) thus formed is oxidized by NBS to Ru(III) in a fast step is discussed and individual rate parameters were evaluated.
    Print ISSN: 1687-7985
    Electronic ISSN: 1687-7993
    Topics: Chemistry and Pharmacology , Physics
    Published by Hindawi
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    PAPER CURRENT
  • 5
    facet.materialart.
    Unknown
    Structural Studies on Nonequilibrium Microstructures of Dioctyl Sodium Dodecyl Sulfosuccinate (Aerosol-OT) in p-Toluenesulfonic Acid and Phosphatidylcholine (2012)
    Hindawi
    Details
    Publication Date: 2012-12-09
    Description: Several microstructures are evolved at the interface when sparingly soluble solid surfactants come in contact with water. One class of these microstructures is termed as “myelin figures”; these were observed when phosphatidylcholine came in contact with water. Although the myelins are initially simple rod-like, complex forms like helices, coils and so forth. appear in the later stage. Finally, the myelins fuse together to form a complex mosaic-like structure. When studied by taking a cross-section using cryoscanning electron microscopy, it revealed concentric circular pattern inside the myelin figures. The cross-sections of (dioctyl sodium dodecyl sulfosiccinate) AOT/water system myelin internal structures were lost. When p-toluenesulfonic acid (PTS) 2 wt% was present in the water phase, AOT myelins revealed the internal microstructures. It has annular concentric ring-like structure with a core axon at the centre. Further investigation revealed new microstructures for the first time having multiple axons in the single-myelin strand.
    Print ISSN: 1687-7985
    Electronic ISSN: 1687-7993
    Topics: Chemistry and Pharmacology , Physics
    Published by Hindawi
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    PAPER CURRENT
  • 6
    facet.materialart.
    Unknown
    Fluorescence Quenching by Reversible Charge Separation Followed by Ions Recombination and Their Separation Suppressed by Coulomb Attraction (2012)
    Hindawi
    Details
    Publication Date: 2012-12-09
    Description: The Stern-Volmer constant is specified for the luminescence quenched by reversible ionization of excited molecules. The exergonic branch of the Rehm-Weller free energy dependence of this constant is known to be a plateau determined by irreversible ionization being under diffusion control. In the endergonic region the ionization is reversible and competes with the irreversible in-cage recombination of ions and their escape from the cage. At strong Coulomb attraction the latter phenomenon is shown to be negligible compared to the former that determines the shape and location of the descending branch of the Rehm-Weller curve. At weaker Coulomb attraction (at higher solvent polarity), this curve turns down at larger endergonicity. The experimental data obtained in solvents of different polarities are put in order and in full accordance with present theory.
    Print ISSN: 1687-7985
    Electronic ISSN: 1687-7993
    Topics: Chemistry and Pharmacology , Physics
    Published by Hindawi
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    PAPER CURRENT
  • 7
    facet.materialart.
    Unknown
    New ab Initio Potential Energy Surfaces for the Renner-Teller Coupled (2013)
    Hindawi
    Details
    Publication Date: 2013-03-07
    Description: New ab initio potential energy surfaces (PESs) for the two lowest-lying singlet 11
    Print ISSN: 1687-7985
    Electronic ISSN: 1687-7993
    Topics: Chemistry and Pharmacology , Physics
    Published by Hindawi
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    PAPER CURRENT
  • 8
    facet.materialart.
    Unknown
    Potential Energy Surfaces for Reactions of X Metal Atoms (X = Cu, Zn, Cd, Ga, Al, Au, or Hg) with YH4 Molecules (Y = C, Si, or Ge) and Transition Probabilities at Avoided Crossings in Some Cases (2013)
    Hindawi
    Details
    Publication Date: 2013-03-07
    Description: We review ab initio studies based on quantum mechanics on the most important mechanisms of reaction leading to the C–H, Si–H, and Ge–H bond breaking of methane, silane, and germane, respectively, by a metal atom in the lowest states in Cs symmetry: X(2nd excited state, 1st excited state and ground state) + YH4→ H3XYH → H + XYH3 and XH + YH3. with X = Au, Zn, Cd, Hg, Al, and G, and Y = C, Si, and Ge. Important issues considered here are (a) the role that the occupation of the d-, s-, or p-shells of the metal atom plays in the interactions with a methane or silane or germane molecule, (b) the role of either singlet or doublet excited states of metals on the reaction barriers, and (c) the role of transition probabilities for different families of reacting metals with these gases, using the H–X–Y angle as a reaction coordinate. The breaking of the Y–H bond of YH4 is useful in the production of amorphous hydrogenated films, necessary in several fields of industry.
    Print ISSN: 1687-7985
    Electronic ISSN: 1687-7993
    Topics: Chemistry and Pharmacology , Physics
    Published by Hindawi
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    PAPER CURRENT
  • 9
    facet.materialart.
    Unknown
    Fundamental Mechanistic Understanding of Electrocatalysis of Oxygen Reduction on Pt and Non-Pt Surfaces: Acid versus Alkaline Media (2013)
    Hindawi
    Details
    Publication Date: 2013-03-07
    Description: Complex electrochemical reactions such as Oxygen Reduction Reaction (ORR) involving multi-electron transfer is an electrocatalytic inner-sphere electron transfer process that exhibit strong dependence on the nature of the electrode surface. This criterion (along with required stability in acidic electrolytes) has largely limited ORR catalysts to the platinum-based surfaces. New evidence in alkaline media, discussed here, throws light on the involvement of surface-independent outer-sphere electron transfer component in the overall electrocatalytic process. This surface non-specificity gives rise to the possibility of using a wide-range of non-noble metal surfaces as electrode materials for ORR in alkaline media. However, this outer-sphere process predominantly leads only to peroxide intermediate as the final product. The importance of promoting the electrocatalytic inner-sphere electron transfer by facilitation of direct adsorption of molecular oxygen on the active site is emphasized by using pyrolyzed metal porphyrins as electrocatalysts. A comparison of ORR reaction mechanisms between acidic and alkaline conditions is elucidated here. The primary advantage of performing ORR in alkaline media is found to be the enhanced activation of the peroxide intermediate on the active site that enables the complete four-electron transfer. ORR reaction schemes involving both outer- and inner-sphere electron transfer mechanisms are proposed.
    Print ISSN: 1687-7985
    Electronic ISSN: 1687-7993
    Topics: Chemistry and Pharmacology , Physics
    Published by Hindawi
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    PAPER CURRENT
  • 10
    facet.materialart.
    Unknown
    Conformational Analysis of Quaternary Ammonium-Type Ionic Liquid Cation, N,N-Diethyl-N-methyl-N-(2-methoxyethyl) Ammonium Cation (2012)
    Hindawi
    Details
    Publication Date: 2012-08-24
    Description: Conformational preference of N,N-diethyl-N-methyl-N-(2-methoxyethyl) ammonium cation ([DEME]+), which is one of the quaternary ammonium-based ionic liquid cation, in the gas phase has been investigated using a density functional theory (DFT) calculation. Eight candidates for the stable conformers of [DEME]+ exist in the gas phase, and can it energetically classify into two groups. One is a five conformers group, which has the N+⋯O− intramolecular attractive interaction form (the folded form). The other is a three conformers group, which is the noninteraction form (the extended form). The transformation from the folded form to the extended form induces large changes in the dipole moment and partial charges of N and O atoms. Here we show that the difference in the dipole moment and partial charges of N and O atoms associated with the conformational change of [DEME]+ are closely related to the molecular orientation of [DEME]-based ionic liquids in the liquid state.
    Print ISSN: 1687-7985
    Electronic ISSN: 1687-7993
    Topics: Chemistry and Pharmacology , Physics
    Published by Hindawi
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    PAPER CURRENT
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...