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  • 1
    Publication Date: 2015-08-11
    Description: In the present investigation, persistence of kresoxim-methyl (a broad spectrum strobilurin fungicide) was studied in water. Results revealed that kresoxim-methyl readily form acid metabolite. Therefore, residues of kresoxim-methyl were quantified on the basis of parent molecule alone and sum total of kresoxim-methyl and its acid metabolite. In water, influence of various abiotic factors like pH, temperature, light and atmospheric carbon dioxide level on dissipation of kresoxim-methyl was studied. The half life value for kresoxim-methyl and total residue varied from 1 to 26.1 and 6.1 to 94.0 days under different conditions. Statistical analysis revealed the significant effect of abiotic factors on the dissipation of kresoxim-methyl from water.
    Print ISSN: 0007-4861
    Electronic ISSN: 1432-0800
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Medicine
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  • 2
    Publication Date: 2015-08-11
    Description: In order to achieve process intensification for adsorption chillers and heat pumps, a new composite material was developed based on sintered aluminum fibers from a melt-extraction process and a dense layer of silico-aluminophosphate (SAPO-34) on the fiber surfaces. The SAPO-34 layer was obtained through a partial support transformation (PST) process. Preparation of a composite sample is described and its characteristic pore size distribution and heat conductivity are presented. Water adsorption data obtained under conditions of a large pressure jump are given. In the next step, preparation of the composite was scaled up to larger samples which were fixed on a small adsorption heat exchanger. Adsorption measurements on this heat exchanger element that confirm the achieved process intensification are presented. The specific cooling power for the adsorption step per volume of composite is found to exceed 500 kW/m3 under specified conditions.
    Electronic ISSN: 1996-1073
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Published by MDPI Publishing
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  • 3
    Publication Date: 2015-08-14
    Description: The ecotoxicological effects of a mixture of petroleum hydrocarbons were tested on densities of two algae, Platymonas helgolandica var. tsingtaoensis and Isochrysis galbana , and of a rotifer, Brachionus plicatilis , by single-species and customized community experiments. Test concentrations ranged from 0 to 100 mg L −1 , while five to seven treatments were assessed in triplicate within 1 month. A significant decrease in densities during single-species toxicity tests were found when concentrations of petroleum hydrocarbons were above 1.0 mg L −1 . However, equilibrium densities of algae in the customized community showed a different pattern, which increased with concentration and reached a peak at 20.0 mg L −1 . The community-based no observed effect concentration (NOEC; 1.0 mg L −1 ) was different from the NOEC derived by single-species toxic tests (0.25 mg L −1 ). This demonstrates that ecotoxicological effects on plankton as part of a community is significantly different from single-species toxicity tests owing to ecological interactions.
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    Topics: Energy, Environment Protection, Nuclear Power Engineering , Medicine
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  • 4
    Publication Date: 2015-08-14
    Description: This study presents the distribution of 17 major and trace elements in surface water, sediments and fish tissues from Lake Turkana, Kenya. Eight sediment and ten water samples from the west bank of the lake, as well as 34 specimens of the elongate tigerfish Hydrocynus forskahlii caught in that region were examined. It is the first report for Li, Rb, Sr, Mo from the lake and the first report on most of the trace elements for this fish species. The concentrations of elements in the water and sediments showed no sign of pollution. In fish muscle, Li, Zn and Cd showed relatively high abundances, with mean concentrations of 206, 427 and 0.56 mg/kg dw, respectively. The calculated target hazard quotient values for Li, Zn, Sr and Cd were 138.7, 1.9, 4.1 and 0.76, respectively; therefore the consumption of these fish poses a health risk to humans in the area.
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  • 5
    Publication Date: 2015-08-14
    Description: Transformation of silver oxide nanoparticles (nano-Ag 2 O) to silver nanoparticles (nano-Ag) and silver ions in environment is possible which might pose toxicity to plants and other species. The objective of this study was to study effects of nano-Ag 2 O and silver ions on growth of Mung bean ( Vigna radiata ) seedlings. V. radiata seeds were exposed to nano-Ag 2 O and silver ions (concentration range: 4.3 × 10 −7 , 4.3 × 10 −6 , 4.3 × 10 −5 , 4.3 × 10 −4 , and 4.3 × 10 −3  mol/L) for 6 days. Root length, shoot length and dry weight of seedlings were found to decrease due to exposure of nano-Ag 2 O and silver ions. These findings indicate silver ions to be more toxic to V. radiata seeds than nano-Ag 2 O. Silver content in seedlings was found to increase with increasing concentrations of nano-Ag 2 O and silver ions. Overall, findings of the present study add to the existing knowledge of phytotoxicity of silver-based nanoparticles of different chemical compositions to V. radiata seeds and need to be considered during use of nanoparticles-contaminated water for irrigation purposes.
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    Topics: Energy, Environment Protection, Nuclear Power Engineering , Medicine
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  • 6
    Publication Date: 2015-08-14
    Description: Concentration of organochlorine and organophosphorus pesticides and their metabolites were determined in whole body homogenate of L. acuminata, I. exustus, V. dissimilis, V. bengalensis , from Tighra Reservoir during summer and post monsoon season using GC–MS technique. The different types of pesticides viz., HCB, heptachlor, aldrin, endosulfan, dieldrin, p,p-DDT, choloropyrifos, methyl parathion, dicholorovos, ethion, malathion, parathion were found in resident molluscs studied. Concentration of these pesticides varied independently during the summer and the post monsoon season at monitored sites. The study concluded that presence of pesticides in Tighra Reservoir is a major concern on public and ecosystem health and use of biopesticides in the adjacent area of Reservoir is highly recommended.
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    Topics: Energy, Environment Protection, Nuclear Power Engineering , Medicine
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  • 7
    Publication Date: 2015-08-14
    Description: The ability of waxy corn, long bean and okra to remove two polycyclic aromatic hydrocarbons (PAHs) from soil containing 0.63 mg Pb kg −1 dry soil was assessed. The presence of Pb did not reduce the ability of these plants to remove the PAHs from soil. About 49 % of anthracene and 77 % of fluoranthene were removed from Pb-spiked or non-spiked soil, respectively, after 30 days. Among the plants, okra was the most efficient at removing anthracene and fluoranthene in the presence or absence of Pb in soil after 30 days. Pb did not affect fluoranthene removal, but stimulated the removal of anthracene, by long bean, waxy corn and okra. However, growth of long bean and waxy corn was poor in Pb-spiked soil and waxy corn plants died around 22 days after transplantation. The results show some promise in using plants to remove PAHs from soil which is also co-contaminated with Pb.
    Print ISSN: 0007-4861
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    Topics: Energy, Environment Protection, Nuclear Power Engineering , Medicine
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  • 8
    Publication Date: 2015-08-13
    Description: Accurate state of charge (SoC) estimation of batteries plays an important role in promoting the commercialization of electric vehicles. The main work to be done in accurately determining battery SoC can be summarized in three parts. (1) In view of the model-based SoC estimation flow diagram, the n-order resistance-capacitance (RC) battery model is proposed and expected to accurately simulate the battery’s major time-variable, nonlinear characteristics. Then, the mathematical equations for model parameter identification and SoC estimation of this model are constructed. (2) The Akaike information criterion is used to determine an optimal tradeoff between battery model complexity and prediction precision for the n-order RC battery model. Results from a comparative analysis show that the first-order RC battery model is thought to be the best based on the Akaike information criterion (AIC) values. (3) The real-time joint estimator for the model parameter and SoC is constructed, and the application based on two battery types indicates that the proposed SoC estimator is a closed-loop identification system where the model parameter identification and SoC estimation are corrected mutually, adaptively and simultaneously according to the observer values. The maximum SoC estimation error is less than 1% for both battery types, even against the inaccurate initial SoC.
    Electronic ISSN: 1996-1073
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Published by MDPI Publishing
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  • 9
    Publication Date: 2015-08-13
    Description: This is the second part of a study conducted to model the aerothermodynamic impact of suction parameters and gas properties on a multi-stage centrifugal compressor’s performance. A new iterative method has been developed in the first part to derive the equivalent performance at various operating conditions. This approach has been validated to predict the compressor map at different suction pressures and temperatures using the design characteristics as reference values. A further case is included in this paper in order to emphasize the validity of the developed approach to obtain the performance characteristics at various gas compositions. The provided example shows that the performance parameters at different gas mixtures can be predicted to within ±1.34%. Furthermore, the conducted optimization in this paper reveals that the proposed method can be applied for the compressor design evaluation corresponding to the expected variation in suction conditions. Moreover, the examined case study demonstrates the effect of gas properties’ variation on the operating point and aerodynamic stability of the entire compression system. In order to achieve that, a simple approach has been established to assess the contribution of gas properties’ variation to the inefficient and unstable compressor performance based on the available operational data.
    Electronic ISSN: 1996-1073
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 10
    Publication Date: 2015-08-13
    Description: The in-wheel electric vehicle is expected to be a popular next-generation vehicle because an in-wheel system can simplify the powertrain and improve driving performance. In addition, it also has an advantage in that it maximizes driving efficiency through independent torque control considering the motor efficiency. However, there is an instability problem if only the driving torque is controlled in consideration of only the motor efficiency. In this paper, integrated torque distribution strategies are proposed to overcome these problems. The control algorithm consists of various strategies for optimizing driving efficiency, satisfying driver demands, and considering tire slip and vehicle cornering. Fuzzy logic is used to determine the appropriate timing of intervention for each distribution strategy. A performance simulator for in-wheel electric vehicles was developed by using MATLAB/Simulink and CarSim to validate the control strategies. From simulation results under complex driving conditions, the proposed algorithm was verified to improve both the driving stability and fuel economy of the in-wheel vehicle.
    Electronic ISSN: 1996-1073
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 11
    Publication Date: 2015-08-13
    Description: The knowledge of unsteady forces is necessary when designing vertical axis wind turbines (VAWTs). Measurement data for turbines operating at an open site are still very limited. The data obtained from wind tunnels or towing tanks can be used, but have limited applicability when designing large-scale VAWTs. This study presents experimental data on the normal forces of a 12-kW straight-bladed VAWT operated at an open site north of Uppsala, Sweden. The normal forces are measured with four single-axis load cells. The data are obtained for a wide range of tip speed ratios: from 1.7 to 4.6. The behavior of the normal forces is analyzed. The presented data can be used in validations of aerodynamic models and the mechanical design for VAWTs.
    Electronic ISSN: 1996-1073
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 12
    Publication Date: 2015-08-13
    Description: This paper introduces a new iterative method to predict the equivalent centrifugal compressor performance at various operating conditions. The presented theoretical analysis and empirical correlations provide a novel approach to derive the entire compressor map corresponding to various suction conditions without a prior knowledge of the detailed geometry. The efficiency model was derived to reflect the impact of physical gas properties, Mach number, and flow and work coefficients. One of the main features of the developed technique is the fact that it considers the variation in the gas properties and stage efficiency which makes it appropriate with hydrocarbons. This method has been tested to predict the performance of two multistage centrifugal compressors and the estimated characteristics are compared with the measured data. The carried comparison revealed a good matching with the actual values, including the stable operation region limits. Furthermore, an optimization study was conducted to investigate the influences of suction conditions on the stage efficiency and surge margin. Moreover, a new sort of presentation has been generated to obtain the equivalent performance characteristics for a constant discharge pressure operation at variable suction pressure and temperature working conditions. A further validation is included in part two of this study in order to evaluate the prediction capability of the derived model at various gas compositions.
    Electronic ISSN: 1996-1073
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 13
    Publication Date: 2015-08-13
    Description: This paper presents an investigation of sewage sludge gasification in a fixed bed gasifier. Experiments were conducted on a laboratory scale fixed bed gasifier. In the experiments, two types of dried sewage sludge were tested and their properties were analysed. Parameters such as air ratio λ = 0.12 to 0.27, gasification agent temperature t = 50 to 250 °C and gasification agent composition ( = 0.21 and  > 0.21) were found to influence on temperature distribution, syngas Lower Heating Value (LHV) and syngas composition. The results indicate that the syngas LHV was found to decrease with increased air ratio for all analyzed cases: cold and preheated air and cold enriched air. The increase in the percentage of the main combustible components was accompanied by a decrease in the concentration of carbon dioxide. Increasing oxygen concentration increased the temperature, which tended to favor the formation of smaller molecules in the gas mixture. Thus, the enriched air medium produced a gas with a higher LHV. In contrast to conventional gasification, gasification process with gasification agent preheating causes that the flux of heat necessary to support endothermic gasification reactions is producing more effective. Air preheating causes increases hydrogen and carbon monoxide production.
    Electronic ISSN: 1996-1073
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 14
    Publication Date: 2015-08-15
    Description: Atmospheric concentrations of carbon dioxide (CO2), a major cause of global warming, have been rising due to industrial development. Carbon capture and storage (CCS), which is regarded as the most effective way to reduce such atmospheric CO2 concentrations, has several environmental and technical disadvantages. Carbon capture and utilization (CCU), which has been introduced to cover such disadvantages, makes it possible to capture CO2, recycling byproducts as resources. However, CCU also requires large amounts of energy in order to induce reactions. Among existing CCU technologies, the process for converting CO2 into CaCO3 requires high temperature and high pressure as reaction conditions. This study proposes a method to fixate CaCO3 stably by using relatively less energy than existing methods. After forming NaOH absorbent solution through electrolysis of NaCl in seawater, CaCO3 was precipitated at room temperature and pressure. Following the experiment, the resulting product CaCO3 was analyzed with Fourier transform infrared spectroscopy (FT-IR); field emission scanning electron microscopy (FE-SEM) image and X-ray diffraction (XRD) patterns were also analyzed. The results showed that the CaCO3 crystal product was high-purity calcite. The study shows a successful method for fixating CO2 by reducing carbon dioxide released into the atmosphere while forming high-purity CaCO3.
    Electronic ISSN: 1996-1073
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 15
    Publication Date: 2015-08-04
    Description: The effect of fuel composition on gasification process performance was investigated by performing mass and energy balances on a pre-pilot scale bubbling fluidized bed reactor fed with mixtures of plastic waste, wood, and coal. The fuels containing plastic waste produced less H2, CO, and CO2 and more light hydrocarbons than the fuels including biomass. The lower heating value (LHV) progressively increased from 5.1 to 7.9 MJ/Nm3 when the plastic waste fraction was moved from 0% to 100%. Higher carbonaceous fines production was associated with the fuel containing a large fraction of coal (60%), producing 87.5 g/kgFuel compared to only 1.0 g/kgFuel obtained during the gasification test with just plastic waste. Conversely, plastic waste gasification produced the highest tar yield, 161.9 g/kgFuel, while woody biomass generated only 13.4 g/kgFuel. Wood gasification showed a carbon conversion efficiency (CCE) of 0.93, while the tests with two fuels containing coal showed lowest CCE values (0.78 and 0.70, respectively). Plastic waste and wood gasification presented similar cold gas efficiency (CGE) values (0.75 and 0.76, respectively), while that obtained during the co-gasification tests varied from 0.53 to 0.73.
    Electronic ISSN: 1996-1073
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 16
    Publication Date: 2015-08-06
    Description: The current accelerated growth in demand for energy globally is confronted by water-resource limitations and hydrologic variability linked to climate change. The global spatial and temporal trends in water requirements for energy development and policy alternatives to address these constraints are poorly understood. This article analyzes national-level energy demand trends from U.S. Energy Information Administration data in relation to newly available assessments of water consumption and life-cycle impacts of thermoelectric generation and biofuel production, and freshwater availability and sectoral allocations from the U.N. Food and Agriculture Organization and the World Bank. Emerging, energy-related water scarcity flashpoints include the world’s largest, most diversified economies (Brazil, India, China, and USA among others), while physical water scarcity continues to pose limits to energy development in the Middle East and small-island states. Findings include the following: (a) technological obstacles to alleviate water scarcity driven by energy demand are surmountable; (b) resource conservation is inevitable, driven by financial limitations and efficiency gains; and (c) institutional arrangements play a pivotal role in the virtuous water-energy-climate cycle. We conclude by making reference to coupled energy-water policy alternatives including water-conserving energy portfolios, intersectoral water transfers, virtual water for energy, hydropower tradeoffs, and use of impaired waters for energy development.
    Electronic ISSN: 1996-1073
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 17
    Publication Date: 2015-08-06
    Description: In the last decades the increasing energy requirements along with the need to face the consequences of climate change have driven the search for renewable energy sources, in order to replace as much as possible the use of fossil fuels. In this context biomass has generated great interest as it can be converted into energy via several routes, including fermentation and anaerobic digestion. The former is the most common option to produce ethanol, which has been recognized as one of the leading candidates to substitute a large fraction of the liquid fuels produced from oil. As the economic competitiveness of bioethanol fermentation processes has to be enhanced in order to promote its wider implementation, the most recent trends are directed towards the use of fermentation by-products within anaerobic digestion. The integration of both fermentation and anaerobic digestion, in a biorefinery concept, would allow the production of ethanol along with that of biogas, which can be used to produce heat and electricity, thus improving the overall energy balance. This work aims at reviewing the main studies on the combination of both bioethanol and biogas production processes, in order to highlight the strength and weakness of the integrated treatment for industrial application.
    Electronic ISSN: 1996-1073
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 18
    Publication Date: 2015-08-07
    Description: Toxic cyanobacteria blooms are increasing in magnitude and frequency worldwide. However, this issue has not been adequately addressed in Malaysia. Therefore, this study aims to better understand eutrophication levels, cyanobacteria diversity, and microcystin concentrations in ten Malaysian freshwater lakes. The results revealed that most lakes were eutrophic, with total phosphorus and total chlorophyll- a concentrations ranging from 15 to 4270 µg L −1 and 1.1 to 903.1 µg L −1 , respectively. Cyanobacteria were detected in all lakes, and identified as Microcystis spp., Planktothrix spp., Phormidium spp., Oscillatoria spp., and Lyngbya spp. Microcystis spp. was the most commonly observed and most abundant cyanobacteria recorded. Semi-quantitative microcystin analysis indicated the presence of microcystin in all lakes. These findings illustrate the potential health risk of cyanobacteria in Malaysia freshwater lakes, thus magnifying the importance of cyanobacteria monitoring and management in Malaysian waterways.
    Print ISSN: 0007-4861
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    Topics: Energy, Environment Protection, Nuclear Power Engineering , Medicine
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  • 19
    Publication Date: 2015-08-08
    Description: There are no known biological requirements for lead (Pb), and elevated Pb levels in birds can cause a variety of sub-lethal effects and mortality. Historic and current levels of Pb in mottled ducks ( Anas fulvigula ) suggest that environmental sources of Pb remain available on the upper Texas coast. Because of potential risks of Pb exposure among coexisting marsh birds, black-necked stilt ( Himantopus mexicanus ) blood Pb concentrations were measured during the breeding season. Almost 80 % (n = 120) of 152 sampled stilts exceeded the background threshold (〉20 μg/dL) for Pb exposure. However, blood Pb concentrations did not vary by age or gender, and toxic or potentially lethal concentrations were rare (〈5 %). Consistent, low-level blood Pb concentrations of black-necked stilts in this study suggest the presence of readily bioavailable sources of Pb, although potential impacts on local stilt populations remain unclear.
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    Topics: Energy, Environment Protection, Nuclear Power Engineering , Medicine
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  • 20
    Publication Date: 2015-08-08
    Description: We propose an optimal electric energy management of a cooperative multi-microgrid community with sequentially coordinated operations. The sequentially coordinated operations are suggested to distribute computational burden and yet to make the optimal 24 energy management of multi-microgrids possible. The sequential operations are mathematically modeled to find the optimal operation conditions and illustrated with physical interpretation of how to achieve optimal energy management in the cooperative multi-microgrid community. This global electric energy optimization of the cooperative community is realized by the ancillary internal trading between the microgrids in the cooperative community which reduces the extra cost from unnecessary external trading by adjusting the electric energy production amounts of combined heat and power (CHP) generators and amounts of both internal and external electric energy trading of the cooperative community. A simulation study is also conducted to validate the proposed mathematical energy management models.
    Electronic ISSN: 1996-1073
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 21
    Publication Date: 2015-08-18
    Description: We investigated the synergetic effect between light-emitting diode (LED) lighting efficiency and building energy savings in heating and cooling using an alternative thermal operating system (ATOS) of indoor LED lighting integrated with the ventilation system of a building as an active cooling device. The heat generated from LED lighting and the indoor lighting illuminance were experimentally determined. The indoor heat gains in cooling and heating periods were determined using measurement data; the annual energy savings of an office building in heating and cooling were calculated through simulation. The LED lighting illuminance increased by approximately 40% and the lighting contribution for indoor heat gain was 7.8% in summer, while 69.8% in winter with the ATOS. Consequently, the annual total energy use of the office building could be reduced by 5.9%; the energy use in cooling and heating was reduced by 18.4% and 3.3%, respectively.
    Electronic ISSN: 1996-1073
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 22
    Publication Date: 2015-08-21
    Description: This paper reports on a study of the modelling, validation and analysis of an integrated 1 MW (electrical output) tri-generation system energized by solar energy. The impact of local climatic conditions in the Mediterranean region on the system performance was considered. The output of the system that comprised a parabolic trough collector (PTC), an organic Rankine cycle (ORC), single-effect desalination (SED), and single effect LiBr-H2O absorption chiller (ACH) was electrical power, distilled water, and refrigerant load. The electrical power was produced by the ORC which used cyclopentane as working fluid and Therminol VP-1 was specified as the heat transfer oil (HTO) in the collectors with thermal storage. The absorption chiller and the desalination unit were utilize the waste heat exiting from the steam turbine in the ORC to provide the necessary cooling energy and drinking water respectively. The modelling, which includes an exergetic analysis, focuses on the performance of the solar tri-generation system. The simulation results of the tri-generation system and its subsystems were produced using IPSEpro software and were validated against experimental data which showed good agreement. The tri-generation system was able to produce about 194 Ton of refrigeration, and 234 t/day distilled water.
    Electronic ISSN: 1996-1073
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 23
    Publication Date: 2015-08-20
    Description: Battery energy storage systems (BESSs) have been widely used for microgrid control. Generally, BESS control systems are based on proportional-integral (PI) control techniques with the outer and inner control loops based on PI regulators. Recently, model predictive control (MPC) has attracted attention for application to future energy processing and control systems because it can easily deal with multivariable cases, system constraints, and nonlinearities. This study considers the application of MPC-based BESSs to microgrid control. Two types of MPC are presented in this study: MPC based on predictive power control (PPC) and MPC based on PI control in the outer and predictive current control (PCC) in the inner control loops. In particular, the effective application of MPC for microgrids with multiple BESSs should be considered because of the differences in their control performance. In this study, microgrids with two BESSs based on two MPC techniques are considered as an example. The control performance of the MPC used for the control microgrid is compared to that of the PI control. The proposed control strategy is investigated through simulations using MATLAB/Simulink software. The simulation results show that the response time, power and voltage ripples, and frequency spectrum could be improved significantly by using MPC.
    Electronic ISSN: 1996-1073
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 24
    Publication Date: 2015-08-21
    Description: The determinations of heat collection rate and heat loss coefficient are crucial for the evaluation of in service water-in-glass evacuated tube solar water heaters. However, the direct determination requires complex detection devices and a series of standard experiments, which also wastes too much time and manpower. To address this problem, we propose machine learning models including artificial neural networks (ANNs) and support vector machines (SVM) to predict the heat collection rate and heat loss coefficient without a direct determination. Parameters that can be easily obtained by “portable test instruments” were set as independent variables, including tube length, number of tubes, tube center distance, heat water mass in tank, collector area, final temperature and angle between tubes and ground, while the heat collection rate and heat loss coefficient determined by the detection device were set as dependent variables respectively. Nine hundred fifteen samples from in-service water-in-glass evacuated tube solar water heaters were used for training and testing the models. Results show that the multilayer feed-forward neural network (MLFN) with 3 nodes is the best model for the prediction of heat collection rate and the general regression neural network (GRNN) is the best model for the prediction of heat loss coefficient due to their low root mean square (RMS) errors, short training times, and high prediction accuracies (under the tolerances of 30%, 20%, and 10%, respectively).
    Electronic ISSN: 1996-1073
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 25
    Publication Date: 2015-08-12
    Description: A state-of-health (SOH) estimation method for electric vehicles (EVs) is presented with three main advantages: (1) it provides joint estimation of cell’s aging states in terms of power and energy (i.e., SOHP and SOHE)—because the determination of SOHP and SOHE can be reduced to the estimation of the ohmic resistance increase and capacity loss, respectively, the ohmic resistance at nominal temperature will be taken as a health indicator, and the capacity loss is estimated based on a mechanistic model that is developed to describe the correlation between resistance increase and capacity loss; (2) it has wide applicability to various ambient temperatures—to eliminate the effects of temperature on the resistance, another mechanistic model about the resistance against temperature is presented, which can normalize the resistance at various temperatures to its standard value at the nominal temperature; and (3) it needs low computational efforts for on-board application—based on a linear equation of cell’s dynamic behaviors, the recursive least-squares (RLS) algorithm is used for the resistance estimation. Based on the designed performance and validation experiments, respectively, the coefficients of the models are determined and the accuracy of the proposed method is verified. The results at different aging states and temperatures show good accuracy and reliability.
    Electronic ISSN: 1996-1073
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 26
    Publication Date: 2015-08-12
    Description: Producing domestic hot water (DHW) with a ground source heat pump (GSHP) is challenging due to the high temperature (HT) of DHW. There are many studies proving the better performance of cascade heat pumps compared to single-stage heat pumps when the difference between the condensing and the evaporation temperature is large. In this system approach study, different GSHP arrangements are described and computationally compared. A two-stage heat pump arrangement is introduced in which water tanks of the heating system are utilized for warming up the DHW in two stages. It is shown that the electricity consumption with this two-stage system is approximately 31% less than with the single-stage heat pump and 12% less than with the cascade system. Further, both low temperature (LT) and HT heat pumps can run alone, which is not common in cascade or other two-stage heat pumps. This is advantageous because the high loads of the space heating and DHW production are not simultaneous. Proper insulation of the DHW and recirculation pipe network is essential, and drying towel rails or other heating coils should be avoided when aiming for a high efficiency. The refrigerants in the calculations are R407C for the LT heat pump and R134a for the HT heat pump. Investment costs are excluded from calculations.
    Electronic ISSN: 1996-1073
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 27
    Publication Date: 2015-08-15
    Description: Thermostatically controlled loads (TCLs), such as air conditioners (ACs), are important demand response resources—they have a certain heat storage capacity. A change in the operating status of an air conditioner in a small range will not noticeably affect the users’ comfort level. Load control of TCLs is considered to be equivalent to a power plant of the same capacity in effect, and it can significantly reduce the system pressure to peak load shift. The thermodynamic model of air conditioning can be used to study the aggregate power of a number of ACs that respond to the step signal of a temperature set point. This paper analyzes the influence of the parameters of each AC in the group to the indoor temperature and the total load, and derives a simplified control model based on the two order linear time invariant transfer function. Then, the stability of the model and designs its Proportional-Integral-Differential (PID) controller based on the particle swarm optimization (PSO) algorithm is also studied. The case study presented in this paper simulates both scenarios of constant ambient temperature and changing ambient temperature to verify the proposed transfer function model and control strategy can closely track the reference peak load shifting curves. The study also demonstrates minimal changes in the indoor temperature and the users’ comfort level.
    Electronic ISSN: 1996-1073
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 28
    Publication Date: 2015-08-18
    Description: With the microgrid revolution, each house will have the ability to meet its own energy needs locally from renewable energy sources such as solar or wind. However, real-time data gathering, energy management and control of renewable energy systems will depend mainly on the performance of the communications infrastructure. This paper describes the design of a communication network architecture using both wired and wireless technologies for monitoring and controlling distributed energy systems involving small-scale wind turbines and photovoltaic systems. The proposed communication architecture consists of three layers: device layer, network layer, and application layer. Two scenarios are considered: a smart-house and a smart-building. Various types of sensor nodes and measurement devices are defined to monitor the condition of the renewable energy systems based on the international electrotechnical commission standard. The OPNET Modeler is used for performance evaluation in terms of end-to-end (ETE) delay. The network performance is compared in view of ETE delay, reliability and implementation cost for three different technologies: Ethernet-based, WiFi-based, and ZigBee-based.
    Electronic ISSN: 1996-1073
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 29
    Publication Date: 2015-08-06
    Description: Artemia sp. is extensively used in ecotoxicity testing, despite criticisms inherent to both acute and long-term tests. Alternative endpoints and procedures should be considered to support the use of this biological model. The hatching process comprises several developmental steps and the cyst hatchability seems acceptable as endpoint criterion. In this study, we assessed the reliability of the hatching assay on A. franciscana by comparing with acute and long-term mortality tests, using two chemicals: Diethylene Glycol (DEG), Sodium Dodecyl Sulphate (SDS). Both DEG and SDS tests demonstrated a dose dependent hatching inhibition. The hatching test resulted more sensitive than acute mortality test and less sensitive than the long-term one. Results demonstrate the reliability and high sensitivity of this hatching assay on a short time lag and support its useful application in first-tier risk assessment procedures.
    Print ISSN: 0007-4861
    Electronic ISSN: 1432-0800
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Medicine
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  • 30
    Publication Date: 2015-08-06
    Description: In this paper, we present the results of an economic feasibility study and propose a system structure to test and maintain electrical stability. In addition, we present real operation results after constructing a remote microgrid on an island in South Korea. To perform the economic feasibility study, a commercial tool called HOMER was used. The developed remote microgrid consists of a 400 kW wind turbine (WT) generator, 314 kW photovoltaic (PV) generator, 500 kVA × 2 grid forming inverter, 3 MWh lithium ion battery, and an energy management system (EMS). The predicted renewable energy fraction was 91% and real operation result was 82%. The frequency maintaining rate of the diesel power plants was 57% but the remote microgrid was 100%. To improve the operating efficiency of the remote microgrid, we investigated the output range of a diesel generator.
    Electronic ISSN: 1996-1073
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 31
    Publication Date: 2015-08-06
    Description: Low energy X-ray fluorescence (XRF) and soft X-ray absorption (XAS) microspectroscopies at high space-resolution are employed for the investigation of the coelectrodeposition of composites consisting of a polypyrrole(PPy)-matrix and Mn-based ternary dispersoids, that have been proposed as promising electrocatalysts for oxygen-reduction electrodes. Specifically, we studied Mn–Co–Cu/PP, Mn–Co–Mg/PPy and Mn–Ni–Mg/PPy co-electrodeposits. The Mn–Co–Cu system features the best ORR electrocatalytic activity in terms of electron transfer number, onset potential, half-wave potential and current density. XRF maps and micro-XAS spectra yield compositional and chemical state distributions, contributing unique molecular-level information on the pulse-plating processes. Mn, Ni, Co and Mg exhibit a bimodal distribution consisting of mesoscopic aggregates of micrometric globuli, separated by polymer-rich ridges. Within this common qualitative scenario, the individual systems exhibit quantitatively different chemical distribution patterns, resulting from specific electrokinetic and electrosorption properties of the single components. The electrodeposits consist of Mn3+,4+-oxide particles, accompanied by combinations of Co0/Co2+, Ni0/Ni2+ and Cu0,+/Cu2+ resulting from the alternance of cathodic and anodic pulses. The formation of highly electroactive Mn3+,4+ in the as-fabricated material is a specific feature of the ternary systems, deriving from synergistic stabilisation brought about by two types of bivalent dopants as well as by galvanic contact to elemental metal; this result represents a considerable improvement in material quality with respect to previously studied Mn/PPy and Mn-based/PPy binaries.
    Electronic ISSN: 1996-1073
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 32
    Publication Date: 2015-08-06
    Description: The countries of the Gulf Cooperation Council (GCC) have both large fossil fuel resources and vast renewable energy potentials. Here, we investigate in a literature meta-analysis and a survey, whether there is a need for renewables in the GCC, what barriers and risks presently deter investments, and what possible policy-solutions could be. We find that there is a long-term need for renewables, to diversify the economy and prepare for a post-fossil fuel era. In the short term, two main obstacles deter investments: inefficient bureaucracy, and the combination of fossil fuel/electricity subsidies and the absence of renewable energy support. Removing fossil fuel and consumption subsidies or introducing a support scheme could make investments in renewables profitable. Eliminating energy subsidies appears particularly beneficial to the economic outlook but this seems particularly difficult to implement, due to the political economy of rentier states. Increased bureaucratic transparency and efficiency is needed, so that potentially attractive investments can rapidly and predictably obtain the necessary permissions. Hence, the administrative and economic environment for renewable energy investments in the GCC is not right today, and no breakthrough is on the horizon, but there is a range of policy solutions to enable investments in the future.
    Electronic ISSN: 1996-1073
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 33
    Publication Date: 2015-08-06
    Description: This study was conducted to develop an artificial neural network (ANN)-based prediction model that can calculate the amount of cooling energy during the setback period of accommodation buildings. By comparing the amount of energy needed for diverse setback temperatures, the most energy-efficient optimal setback temperature could be found and applied in the thermal control logic. Three major processes that used the numerical simulation method were conducted for the development and optimization of an ANN model and for the testing of its prediction performance, respectively. First, the structure and learning method of the initial ANN model was determined to predict the amount of cooling energy consumption during the setback period. Then, the initial structure and learning methods of the ANN model were optimized using parametrical analysis to compare its prediction accuracy levels. Finally, the performance tests of the optimized model proved its prediction accuracy with the lower coefficient of variation of the root mean square errors (CVRMSEs) of the simulated results and the predicted results under generally accepted levels. In conclusion, the proposed ANN model proved its potential to be applied to the thermal control logic for setting up the most energy-efficient setback temperature.
    Electronic ISSN: 1996-1073
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 34
    Publication Date: 2015-08-06
    Description: The non-uniform surface temperature distribution of a battery cell results from complex reactions inside the cell and makes efficient thermal management a challenging task. This experimental work attempts to determine the evolution of surface temperature distribution of three pouch type commercial cells: Nickel Manganese Cobalt oxide (NMC)-based 20 Ah cell, Lithium Iron Phosphate (LFP) 14 Ah, and Lithium Titanate Oxide (LTO) 5 Ah battery cell by using contact thermistor and infrared (IR) thermography. High current (up to 100 A) continuous charge/discharge and high current (80 A) micro pulse cycling profile were applied on the cells. It was found that thermistor based temperature profile varied cell to cell, especially the LTO cell. Among the investigated cells, the NMC cell shows highest temperature rise and the LTO cell the lowest rise. IR (Infrared) images revealed the spatial distribution of surface temperature, in particular the location of the hottest region varies depending not only on the geometrical and material properties of the cell, but also the type of loads applied on the cells. Finally, a modeling perspective of the cell temperature non-uniformity is also discussed.
    Electronic ISSN: 1996-1073
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 35
    Publication Date: 2015-08-07
    Description: A novel metal borohydride ammonia-borane complex Ca(BH4)2·NH3BH3 is characterized as the decomposition product of the recently reported perovskite-type metal borohydride NH4Ca(BH4)3, suggesting that ammonium-based metal borohydrides release hydrogen gas via ammonia-borane-complexes. For the first time the concept of proton-hydride interactions to promote hydrogen release is applied to a cation-anion pair in a complex metal hydride. NH4Ca(BH4)3 is prepared mechanochemically from Ca(BH4)2 and NH4Cl as well as NH4BH4 following two different protocols, where the synthesis procedures are modified in the latter to solvent-based ball-milling using diethyl ether to maximize the phase yield in chlorine-free samples. During decomposition of NH4Ca(BH4)3 pure H2 is released, prior to the decomposition of the complex to its constituents. As opposed to a previously reported adduct between Ca(BH4)2 and NH3BH3, the present complex is described as NH3BH3-stuffed α-Ca(BH4)2.
    Electronic ISSN: 1996-1073
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 36
    Publication Date: 2015-08-08
    Description: Lead is a commonly monitored heavy metal because of potential health effects on exposed organisms. We quantified lead in secondary feathers of two passerine bird species, clay-colored thrushes ( Turdus grayi ) and great-tailed grackles ( Quiscalus mexicanus ), from an urban and a rural site in the municipality of Merida, Yucatan. Urban lead concentration was significantly higher than its rural counterpart for both species ( p  〈 0.05). In the urban site, lead concentration was similar in both species ( p  = 0.14). However, data from the rural site showed that lead concentration was significantly higher in thrush feathers ( p  〈 0.05). Lead levels herein presented are among the lowest ever reported suggesting that either lead accumulation or absorption is limited. Finally, our data seem to support the hypothesis that species feeding ecology plays a major role in lead accumulation.
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  • 37
    Publication Date: 2015-08-08
    Description: In 2007, the EU established challenging goals for all Member States with the aim of obtaining 20% of their energy consumption from renewables, and offshore wind is expected to be among the renewable energy sources contributing highly towards achieving this target. Currently wind turbines are designed for a 25-year service life with the possibility of operational extension. Extending their efficient operation and increasing the overall electricity production will significantly increase the return on investment (ROI) and decrease the levelized cost of electricity (LCOE), considering that Capital Expenditure (CAPEX) will be distributed over a larger production output. The aim of this paper is to perform a detailed failure mode identification throughout the service life of offshore wind turbines and review the three most relevant end of life (EOL) scenarios: life extension, repowering and decommissioning. Life extension is considered the most desirable EOL scenario due to its profitability. It is believed that combining good inspection, operations and maintenance (O&M) strategies with the most up to date structural health monitoring and condition monitoring systems for detecting previously identified failure modes, will make life extension feasible. Nevertheless, for the cases where it is not feasible, other options such as repowering or decommissioning must be explored.
    Electronic ISSN: 1996-1073
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 38
    Publication Date: 2015-06-04
    Description: The distribution automation system (DAS) is vulnerable to cyber-attacks due to the widespread use of terminal devices and standard communication protocols. On account of the cost of defense, it is impossible to ensure the security of every device in the DAS. Given this background, a novel quantitative vulnerability assessment model of cyber security for DAS is developed in this paper. In the assessment model, the potential physical consequences of cyber-attacks are analyzed from two levels: terminal device level and control center server level. Then, the attack process is modeled based on game theory and the relationships among different vulnerabilities are analyzed by introducing a vulnerability adjacency matrix. Finally, the application process of the proposed methodology is illustrated through a case study based on bus 2 of the Roy Billinton Test System (RBTS). The results demonstrate the reasonability and effectiveness of the proposed methodology.
    Electronic ISSN: 1996-1073
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 39
    Publication Date: 2015-06-04
    Description: We analysed the environmental impacts of three biogas systems based on dairy manure, sorghum and maize. The geographical scope of the analysis is the Po valley, in Italy. The anaerobic digestion of manure guarantees high GHG (Green House Gases) savings thanks to the avoided emissions from the traditional storage and management of raw manure as organic fertiliser. GHG emissions for maize and sorghum-based systems, on the other hand, are similar to those of the Italian electricity mix. In crop-based systems, the plants with open-tank storage of digestate emit 50% more GHG than those with gas-tight tanks. In all the environmental impact categories analysed (acidification, particulate matter emissions, and eutrophication), energy crops based systems have much higher impacts than the Italian electricity mix. Maize-based systems cause higher impacts than sorghum, due to more intensive cultivation. Manure-based pathways have always lower impacts than the energy crops based pathways, however, all biogas systems cause much higher impacts than the current Italian electricity mix. We conclude that manure digestion is the most efficient way to reduce GHG emissions; although there are trade-offs with other local environmental impacts. Biogas production from crops; although not providing environmental benefits per se; may be regarded as an option to facilitate the deployment of manure digestion.
    Electronic ISSN: 1996-1073
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 40
    Publication Date: 2015-06-04
    Description: As the world moves toward greenhouse gas reduction, there is increasingly active work around Li-ion chemistry-based batteries as an energy source for electric vehicles (EVs), hybrid electric vehicles (HEVs) and smart grids. In these applications, the battery management system (BMS) requires an accurate online estimation of the state of charge (SOC) in a battery pack. This estimation is difficult, especially after substantial battery aging. In order to address this problem, this paper utilizes SOC estimation of Li-ion battery packs using a fuzzy-improved extended Kalman filter (fuzzy-IEKF) for Li-ion cells, regardless of their age. The proposed approach introduces a fuzzy method with a new class and associated membership function that determines an approximate initial value applied to SOC estimation. Subsequently, the EKF method is used by considering the single unit model for the battery pack to estimate the SOC for following periods of battery use. This approach uses an adaptive model algorithm to update the model for each single cell in the battery pack. To verify the accuracy of the estimation method, tests are done on a LiFePO4 aged battery pack consisting of 120 cells connected in series with a nominal voltage of 432 V.
    Electronic ISSN: 1996-1073
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 41
    Publication Date: 2015-06-04
    Description: The sustainability of a small-scale self-consumption wood-energy chain for heat generation in central Italy was analyzed from a technical, economic and energetic point of view. A micro-chain was developed within the CRA-ING farm at Monterotondo (Rome, Italy): The purpose of this system was to produce biomass for supplying a heating plant within the CRA-ING property as a substitute for diesel fuel. A poplar short rotation coppice, established with clones AF2, AF6 and Monviso, fed the micro-chain. The rotation was biennial. The average plantation production (Mgd.m.·ha−1·year−1) was 10.2, with a maximum of 13.53 for the twin-rows AF2 and a minimum of 8.00 for the single-row Monviso. The economic assessment was based on the Net Present Value (NPV) method and the equivalent annuity cost, and found an average saving of 15.60 €·GJ−1 of heat generated by the wood chips heating system in comparison with the diesel heating system over a 10 year lifetime of the thermal power plant. The energy assessment of the poplar plantation, carried out using the Gross Energy Requirements method, reported an energy output/input ratio of 12.3. The energy output/input ratio of the whole micro-chain was 4.5.
    Electronic ISSN: 1996-1073
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 42
    Publication Date: 2015-06-04
    Description: Natural gas is becoming increasingly important as a primary energy source. A suitable replacement for fossil natural gas is bio-SNG, produced by biomass gasification, followed by methanation. A major challenge is efficient gas cleaning processes for removal of sulfur compounds and other impurities. The present study focuses on development of a gas cleaning step for a product gas produced in a 50 MWfuel gasification system. The developed gas cleaning washing process is basically a modification of the Rectisol process. Several different process configurations were evaluated using Aspen plus, including PC-SAFT for the thermodynamic modeling. The developed configuration takes advantage of only one methanol wash column, compared to two columns in a conventional Rectisol process. Results from modeling show the ability of the proposed configuration to remove impurities to a sufficiently low concentrations - almost zero concentration for H2S, CS2, HCl, NH3 and HCN, and approximately 0.01 mg/Nm3 for COS. These levels are acceptable for further upgrading of the gas in a methanation process. Simultaneously, up to 92% of the original CO2 is preserved in the final cleaned syngas stream. No process integration or economic consideration was performed within the scope of the present study, but will be investigated in future projects to improve the overall process.
    Electronic ISSN: 1996-1073
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 43
    Publication Date: 2015-06-04
    Description: Cool roof coatings have a beneficial impact on reducing the heat load of a range of building types, resulting in reduced cooling energy loads. This study seeks to understand the extent to which cool roof coatings could be used as a residential demand side management (DSM) strategy for retrofitting existing housing in a constrained network area in tropical Australia where peak electrical demand is heavily influenced by residential cooling loads. In particular this study seeks to determine whether simulation software used for building regulation purposes can provide networks with the ‘impact certainty’ required by their DSM principles. The building simulation method is supported by a field experiment. Both numerical and experimental data confirm reductions in total consumption (kWh) and energy demand (kW). The nature of the regulated simulation software, combined with the diverse nature of residential buildings and their patterns of occupancy, however, mean that simulated results cannot be extrapolated to quantify benefits to a broader distribution network. The study suggests that building data gained from regulatory simulations could be a useful guide for potential impacts of widespread application of cool roof coatings in this region. The practical realization of these positive impacts, however, would require changes to the current business model for the evaluation of DSM strategies. The study provides seven key recommendations that encourage distribution networks to think beyond their infrastructure boundaries, recognising that the broader energy system also includes buildings, appliances and people.
    Electronic ISSN: 1996-1073
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 44
    Publication Date: 2015-06-04
    Description: The European Union and its Member States are seeking to decarbonize their energy systems, including the electricity sector and, at the same time, pursue market integration. However, renewable energy (RE) deployment and the liberalization of the energy-only market have raised concerns at the national level about the security of electricity supplies in the future. Some actors consider the lack of sufficient investments in generation capacities a threat to supply security. As a consequence, it was proposed that capacity markets solve these problems. The underlying assumption is that the market design is the only determining factor for investments in security of supply options. In this article, we question this narrow view and identify further determinants of the investment decisions of electricity market participants. Based on the insights of institutional sociology and economics, we understand the market to be a social institution that structures the behavioural expectations of market participants. Derived from the theoretical conceptualization and based on qualitative literature review and own work, we find four determinants for investment behaviour beyond the formal market design: Material opportunities, strategic actor behavior and identity, focusing events and discursive expectations about the future. With this perspective, we discuss the introduction of a European Energy Union as a possible tool that might have a great impact on the more informal determinants such as expectations about the future and the construction of a European energy narrative.
    Electronic ISSN: 1996-1073
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 45
    Publication Date: 2015-06-05
    Description: In this paper, an asymmetrical fuzzy-logic-control (FLC)-based maximum power point tracking (MPPT) algorithm for photovoltaic (PV) systems is presented. Two membership function (MF) design methodologies that can improve the effectiveness of the proposed asymmetrical FLC-based MPPT methods are then proposed. The first method can quickly determine the input MF setting values via the power–voltage (P–V) curve of solar cells under standard test conditions (STC). The second method uses the particle swarm optimization (PSO) technique to optimize the input MF setting values. Because the PSO approach must target and optimize a cost function, a cost function design methodology that meets the performance requirements of practical photovoltaic generation systems (PGSs) is also proposed. According to the simulated and experimental results, the proposed asymmetrical FLC-based MPPT method has the highest fitness value, therefore, it can successfully address the tracking speed/tracking accuracy dilemma compared with the traditional perturb and observe (P&O) and symmetrical FLC-based MPPT algorithms. Compared to the conventional FLC-based MPPT method, the obtained optimal asymmetrical FLC-based MPPT can improve the transient time and the MPPT tracking accuracy by 25.8% and 0.98% under STC, respectively.
    Electronic ISSN: 1996-1073
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 46
    Publication Date: 2015-06-05
    Description: Adhesion (cohesion) and agglomeration properties of gas hydrate particles have been a key to hydrate management in flow assurance in natural gas pipelines. Despite its importance, the relevant data in the area, such as the surface energy and the interfacial energy of gas hydrates with gas and/or water, are scarce; presumably due to the experimental difficulties involved in the measurements. Here we review what is known about the surface energy and the interfacial energy of gas hydrates to date. In particular, we ask a question as to whether pre-melting can occur on the surface of gas hydrates. Surface thermodynamic analyses show that pre-melting is favoured to occur on the surface of gas hydrates, however, not sufficient data are available to assess its thickness. The effects of the existence of pre-melting layers on the cohesion and friction forces between gas hydrate particles are also discussed.
    Electronic ISSN: 1996-1073
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 47
    Publication Date: 2015-06-06
    Description: Exposure to sub-lethal concentrations of a pollutant induces, in some organisms, an acclimation process which increases their resistance to other substances (cross-acclimation). Understanding this phenomenon is important as a basis for a better comprehension of the effects of pollutants in ecosystems. In this paper we investigated whether the exposure to Cd or Zn is able to modify the heart rate response of the crayfish Procambarus clarkii to acute Cu stress. A first set of experiments provided the basis to understand heart rate changes induced by varying Cd or Zn concentrations. In a second set of experiments crayfish were acclimated for 96 h to control water, Cd or Zn enriched water, and then exposed to a 10 mg L −1 Cu solution, known to induce bradycardia in this species. Bradycardia was suppressed in specimens previously exposed to Cd or Zn but not in those exposed to clean water, providing a clear evidence of a cross-acclimation in the heart rate response of P. clarkii.
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  • 48
    Publication Date: 2015-06-06
    Description: We analyzed residual PCBs in surface sediments at 19 sites in the Pearl River Delta in the wet and dry seasons. Seven indicative PCB congeners (PCB28, PCB52, PCB101, PCB118, PCB153, PCB138 and PCB180) were detected in the surface sediments, among which the detection rate and mass concentrations of PCB52 were the highest. Total concentrations of the seven PCBs ranged from 19.8 to 111 μg/kg, with an average of 48.2 μg/kg. For the spatial distribution, the sum of the seven PCB (∑PCB) concentrations for the stations that were located in the city region of the Pearl River Delta were significantly higher than the ∑PCB concentrations for the eight outlets of the Pearl River Delta ( p  〈 0.05). According to the US National Oceanic and Atmospheric Administration ERL and ERM guideline concentrations, the PCB concentrations may occasionally lead to adverse effects, especially in the dry season.
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  • 49
    Publication Date: 2015-06-06
    Description: Biodegradation of tributyltin (TBT) by four tin resistant Gram negative bacteria isolated from extremely contaminated river sediments in the Atacama Desert in Chile was studied. Moraxella osloensis showed the greatest resistance and degradation capability of TBT, producing less toxic by-products, such as dibutyltin (DBT) and inorganic tin. In 7 days, approximately 80 % of TBT degradation was achieved, generating close to 20 % of DBT as degradation product. The degradation rate constant (k) was 0.022 [day −1 ] and TBT half-life (t 1/2 ) in culture was 4.3 days. Debutylation is stated a probable mechanism of TBT degradation.
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  • 50
    Publication Date: 2015-06-06
    Description: Graphene oxide (GO) nanosheets have been extensively investigated to fabricate the graphene in recent years. The migration of GO nanosheets into the environment could lead to the instability of biological system. In this study, the GO nanosheets were synthesized and were characterized by SEM, high resolution TEM, XRD, Raman, FTIR and XPS techniques. Toxicology testing of GO nanosheets against Paecilomyces catenlannulatus ( P. catenlannulatus ) was performed by measuring the efflux of cytoplasmic materials of P. catenlannulatus . Approximate 35 % of the bacteria could survive on the surface of GO nanosheets compared to the control sample (~92 %) within 3 h, indicating that GO nanosheets presented significantly antibacterial activities. It was observed that the concentration of RNA in the solution was obviously higher than that of control sample, which could be due to direct contact of the bacterial cell. The results showed that the damage of cell membrane of P. catenlannulatus was attributed to the direct contact of the P. catenlannulatus with the extremely sharp edges of GO nanosheets, which resulted in the P. catenlannulatus inactivation. The less resistant to the damage of cell membrane was observed with increasing of GO concentration and contact time.
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  • 51
    Publication Date: 2015-06-06
    Description: To determine the actual concentrations of trace elements in surface sediments from the La Paz Lagoon, as well as their associations and possible origins, 91 sediment samples were analyzed for more than 50 elements using a combination of ICP-MS and ICP-AES. The results of a principal component analysis are used to distinguish four associative groups within the elements. Natural enrichment of As, Cd and U occurs due to the supply of weathered phosphorites from the El Cien formation located to the north-west of the lagoon. Sediment quality indices for potentially toxic trace elements do not show any probable impact on the biota of the lagoon. Only the concentrations of As in 30 % of the stations and Cu in 20 % of them exceed related effect range low levels. The highest concentration of Pb (36.8 mg kg −1 ) was measured in the sediments near the City of La Paz.
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  • 52
    Publication Date: 2015-06-06
    Description: Fish mediate many biological processes by olfaction, which can be impaired by contaminants (i.e. metals). While the olfactory recovery of fish from metal contaminated lakes if subsequently cultured in clean water has been shown at the neurophysiological level, the recovery potential of olfactory mediated behaviours remains unknown. To study behavioural recovery of fish from metal contaminated lakes, wild yellow perch ( Perca flavescens ) were collected from two metal-contaminated lakes (Ramsey and Hannah lakes) in the metal-mining district of Sudbury, ON, Canada and cultured in clean water from a reference lake (Geneva Lake) for another 24 h. Olfactory mediated behaviours of the test organisms were tested using avoidance responses to conspecific skin extract. While olfactory mediated behaviours of fish from Ramsey Lake (low contamination) recovered after 24 h in clean water, recovery could not be observed in fish from Hannah Lake (high contamination). These results demonstrate that the recovery of behavioural deficits of fish from metal contaminated lakes is depending on the habitats’ metal concentration.
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  • 53
    Publication Date: 2015-06-09
    Description: The dehydriding process and hydrogen–deuterium exchange (H–D exchange) of xLiBH4 + (1 − x)Mg2FeD6 (x = 0.25, 0.75) composites has been studied in detail. For the composition with x = 0.25, only one overlapping mass peak of all hydrogen and deuterium related species was observed in mass spectrometry. This implied the simultaneous dehydriding of LiBH4 and Mg2FeD6, despite an almost 190 °C difference in the dehydriding temperatures of the respective discrete complex hydrides. In situ infrared spectroscopy measurements indicated that H–D exchange between [BH4]− and [FeD6]4− had occurred during ball-milling and was promoted upon heating. The extent of H–D exchange was estimated from the areas of the relevant mass signals: immediately prior to the dehydriding, more than two H atoms in [BH4]− was replaced by D atoms. For x = 0.75, H–D exchange also occurred and about one to two H atoms in [BH4]− was replaced by D atoms immediately before the dehydriding. In contrast to the situation for x = 0.25, firstly LiBH4 and Mg2FeD6 dehydrided simultaneously with a special molar ratio = 1:1 at x = 0.75, and then the remaining LiBH4 reacted with the Mg and Fe derived from the dehydriding of Mg2FeD6.
    Electronic ISSN: 1996-1073
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 54
    Publication Date: 2015-08-04
    Description: Energy storage devices are expected to be more frequently implemented in wind farms in near future. In this paper, both pumped hydro and fly wheel storage systems are used to assist a wind farm to smooth the power fluctuations. Due to the significant difference in the response speeds of the two storages types, the wind farm coordination with two types of energy storage is a problem. This paper presents two methods for the coordination problem: a two-level hierarchical model predictive control (MPC) method and a single-level MPC method. In the single-level MPC method, only one MPC controller coordinates the wind farm and the two storage systems to follow the grid scheduling. Alternatively, in the two-level MPC method, two MPC controllers are used to coordinate the wind farm and the two storage systems. The structure of two level MPC consists of outer level and inner level MPC. They run alternatively to perform real-time scheduling and then stop, thus obtaining long-term scheduling results and sending some results to the inner level as input. The single-level MPC method performs both long- and short-term scheduling tasks in each interval. The simulation results show that the methods proposed can improve the utilization of wind power and reduce wind power spillage. In addition, the single-level MPC and the two-level MPC are not interchangeable. The single-level MPC has the advantage of following the grid schedule while the two-level MPC can reduce the optimization time by 60%.
    Electronic ISSN: 1996-1073
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 55
    Publication Date: 2015-08-04
    Description: Electric machines play an important role in modern energy conversion systems. This paper presents a novel brushless fault-tolerant flux-modulated memory (FTFM) machine, which incorporates the merits of a flux-modulated permanent magnet machine and multi-phase memory machine and is very suitable for applications that require wide speed ranges of constant-power operation. Due to the magnetic modulation effect, the FTFM machine can produce a large torque at relatively low speeds. Due to the usage of aluminum-nickel-cobalt (AlNiCo) magnets, this machine can readily achieve a flexible air-gap flux controllability with temporary DC current pulses. Consequently, the constant-power region is effectively expanded, and the machine\'s efficiency during constant-power operation is increased. Due to the multi-phase armature winding design, the FTFM machine enables lower torque ripple, increased fault tolerance ability and a higher possibility of splitting the machine power through a higher number of phases, thus the per-phase converter rating can be reduced. The design methodology and working principle of this kind of machine are discussed. The electromagnetic performances of the proposed machine are analyzed using the time-stepping finite element method (TS-FEM).
    Electronic ISSN: 1996-1073
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 56
    Publication Date: 2015-08-05
    Description: Pb and Cd contents in 13 plantation tree species (leaf and branch components), soil, water (groundwater and river water) at a young (3–5 year-old) seashore afforestation stand were investigated in Nansha district, Guangzhou city in southern China. The results showed that (1) soil, rather than water or trees, had the highest content of both Pb (averagely 48.79 mg/kg) and Cd (0.50 mg/kg), demonstrating that soil might function as a major reservoir for extraneously derived heavy metals; (2) Pb content was higher in branches than in leaves, but Cd content appeared similar in both components, implying possibly different accumulation mechanisms in trees; (3) Pb and Cd appeared to accumulate differently among some tree taxa, whereas almost no significant difference was detected between introduced and indigenous species. The study indicated that trees were potentially useful to remediate sites contaminated with Pb and Cd in the urbanized areas.
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  • 57
    Publication Date: 2015-08-05
    Description: The objectives of this study were to determine (1) the phosphorus (P) level required to induce cadmium (Cd) precipitation in a contaminated arable soil with low concentrations of Cd and (2) the primary mechanism of Cd immobilization at different P levels. Phosphorus was added at levels of 0 800, 1600, and 16,000 mg P kg −1 to a soil containing 5.57 mg Cd kg −1 . The concentration of 1 M NH 4 OAc extractable Cd decreased significantly with P levels up to 1600 mg kg −1 due to an increase in soil pH and negative charge of soil ( p  〈 0.001). A further decrease in 1 M NH 4 OAc extractable Cd concentration was noted when P was increased to 16,000 mg P kg −1 and may have been the result of Cd precipitation. This study suggest that adding P at high levels may help in the formation of geochemically stable Cd minerals in soil containing low levels of this heavy metal.
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  • 58
    Publication Date: 2015-08-05
    Description: The purpose of this paper is to investigate combustion characteristics for rotary engine via numerical studies. A 3D numerical model was developed to study the influence of several operative parameters on combustion characteristics. A novel rotary engine called, “Leaf Spring Rotary Engine”, was used to illustrate the structure and principle of the engine. The aims are to (1) improve the understanding of combustion process, and (2) quantify the influence of rotational speed, excess air ratio, initial pressure and temperature on combustion characteristics. The chamber space changed with crankshaft rotation. Due to the complexity of chamber volume, an equivalent modeling method was presented to simulate the chamber space variation. The numerical simulations were performed by solving the incompressible, multiphase Unsteady Reynolds-Averaged Navier–Stokes Equations via the commercial code FLUENT using a transport equation-based combustion model; a realizable  turbulence model and finite-rate/eddy-dissipation model were used to account for the effect of local factors on the combustion characteristics.
    Electronic ISSN: 1996-1073
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 59
    Publication Date: 2015-08-08
    Description: The efficiency of wireless power transfer is sensitive to the horizontal and vertical distances between the transmitter and receiver coils due to the magnetic coupling change. To address the output voltage variation and efficiency drop caused by misalignment, a uniform voltage gain frequency control is implemented to improve the power delivery and efficiency of wireless power transfer under misalignment. The frequency is tuned according to the amplitude and phase-frequency characteristics of coupling variations in order to maintain a uniform output voltage in the receiver coil. Experimental comparison of three control methods, including fixed frequency control, resonant frequency control, and the proposed uniform gain control was conducted and demonstrated that the uniform voltage gain control is the most robust method for managing misalignment in wireless charging applications.
    Electronic ISSN: 1996-1073
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 60
    Publication Date: 2015-08-14
    Description: We evaluated the bioconcentration and elimination of polycarbamate, a popular antifoulant classified as a dithiocarbamate fungicide, in a marine teleost fish, mummichog ( Fundulus heteroclitus ), and a polychaete ( Perinereis nuntia ). Following polycarbamate exposure and depuration, the calculated bioconcentration factor (BCF) and elimination rate constant (k 2 ) were 3.1 and 0.17 day −1 in fish and 1.5–7.8 and 0.13–0.18 day −1 in the polychaete, indicating that the fungicide has low bioconcentration potential in both organisms. Given the BCF of 3.1, the permissible environmental concentration level of polycarbamate in water was calculated to be 6.1 µg L −1 to satisfy the threshold pesticide residue levels in fish permitted by law, which is far below the permissible levels in Hiroshima Bay, Japan. Therefore, we consider that the current polycarbamate contamination level in terms of bioconcentration is not likely to be an alarming issue in coastal environments.
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  • 61
    Publication Date: 2015-08-14
    Description: The aim of this work was to define the bioaccumulation mechanism of metals onto the non-living biomaterial prepared from an extensively available plant bark biomass of neem ( Azadirachta indica ). Based on maximum ultimate fixation capacities (mmol/g) of the product, metals ions could be arranged as Hg 2+  〈 Cd 2+  〈 Pb 2+  ≅ Cu 2+ . Surface properties of the biomaterial were characterized by X-ray photoelectron spectroscopy and X-ray diffraction techniques for their sorption mechanism. Whewellite (C 2 CaO 4 ·H 2 O) was identified in the biomaterial, which indicated that calcium ions are electrovalently bonded with carboxylate ions facilitating the ion exchange mechanism with metal ions. Bioaccumulation of metal ions was also studied by Fourier transform infrared spectroscopy, which indicated the presence of functional groups implicated in adsorbing metal ions. Biomaterial did not adsorb anionic As(III), As(V) and Cr(VI), because of their electrostatic repulsion with carboxylic functional groups. Neem bark can be used as bioindicators, bioaccumulators and biomonitors while determining environmental pressures. Metal bioaccumulative properties and structural investigation of plant bark has potential in providing quantitative information on the metal contamination in the surrounding environment.
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  • 62
    Publication Date: 2015-08-14
    Description: Application of thiobencarb, pendimethalin and pretilachlor at rates of 7.5, 10.0 and 2.5 kg a.i. ha −1 , respectively, under laboratory conditions, significantly increased microbial biomass C, N and P, resulting in greater availability of C, N and P in soil amended with farm yard manure. Application of thiobencarb highly induced microbial biomass C (46.3 %) and N (40.6 %), while pretilachlor and thiobencarb augmented microbial biomass P to the extent of 14.9 % and 14.1 %, respectively. Application of pendimethalin retained the highest amount of total N (19.9 %), soluble NO 3 − (56 %) and available P (69.5 %) in soil. A similar trend was recorded with thiobencarb for oxidizable organic C (18.1 %) and with pretilachlor for exchangeable NH 4 + (65.8 %). At the end of the experiment, the highest stimulation of bacteria was recorded with thiobencarb (29.6 %), while pretilachlor harboured the maximum number of actinomycetes (37.2 %) and fungi (40 %) in soil compared to the untreated control.
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  • 63
    Publication Date: 2015-08-14
    Description: A field study in the Pearl River Delta of China was conducted in order to describe to the spatial and seasonal variation of occurrence and concentrations of total petroleum hydrocarbon (TPH) in surface water and sediments. Petroleum hydrocarbons and isoprenoid alkanes were quantified by UV spectroscopy and gas chromatography with a mass selective detector. The concentrations of TPH ranged from 4.3 to 68.7 µg L −1 in surface water, and from 66.6 to 1445 µg g −1 in surface sediments. The ratios of pristine to phytane suggested that the main sources of TPH in the sediment were petroleum importation. The highest concentrations of TPH were present in the spring season. When compared with results from previous studies, it can be concluded that the Pearl River Delta was moderately polluted by TPH. No statistically significant correlations were observed between the concentrations of TPH in surface water and sediments.
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  • 64
    Publication Date: 2015-08-14
    Description: Gold mining is known to generate important economic products but also to produce several types of contamination/pollution. We report here the first data about Hg concentrations in the soils of the Yacuambi River in the Ecuadorian Amazon. We analyzed soil samples to assess the extent of contamination caused by gold placer mining in this area. Hg concentrations in soils exceeded the local background concentrations. High concentrations of Mn, As, Pb, Cr, Cu, Fe and Zn in some soil samples were probably derived from the geology of the site, which is rich in polysulfides and metamorphic rocks. Placer mining may accelerate the natural release of these elements to the environment by the exposure of the bedrock to the atmosphere. Accumulation of Hg in the river soils may be a potential source of toxicity for aquatic life and a risk to human health in the future.
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  • 65
    Publication Date: 2015-08-14
    Description: Twenty eight surface water samples were collected from fourteen sites of the West Bokaro coalfield, India. The concentration of Mn, Cu, Zn, Ni, As, Se, Al, Cr, Ba, and Fe were analyzed using inductively coupled plasma mass spectrometry (ICP-MS) for determination of seasonal fluctuations and a heavy metal pollution index (HPI). The HPI values were below the critical pollution index value of 100. Metal concentrations were higher in the pre-monsoon season as compared to the post-monsoon season. The Zn, Ni, Mn, As, Se, Al, Ba, Cu, and Cr concentrations did not exceed the desirable limits for drinking water in either season. However, at many sites, concentrations of Fe were above the desirable limit of the WHO ( 2006 ) and Indian drinking water standard (BIS 2003 ) in both seasons. The water that contained higher concentrations of Fe would require treatment before domestic use.
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  • 66
    Publication Date: 2015-08-14
    Description: A new method was developed and validated for the determination of 2-(4-fluorophenyl)-5-methylsulfonyl-1,3,4-oxadiazole (jiahuangxianjunzuo, JHXJZ) by ultra-performance liquid chromatography equipped with photo-diode array detector. JHXJZ from tomato and soil was extracted with ethyl acetate without further cleanup. The limits of detection and quantification of JHXJZ were 0.0083 and 0.025 mg kg −1 in tomato, 0.0017 and 0.005 mg kg −1 in soil, respectively. The average recoveries of tomato and soil were studied at three spiked levels and ranged from 84.51 % to 101.30 % and 85.30 % to 101.53 %, respectively, with relative standard deviations of 2.61 %–4.13 % and 1.21 %–4.80 %, respectively. The results indicated that the reported method could meet the requirement for the analysis of JHXJZ in trace amount in tomato and soil.
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  • 67
    Publication Date: 2015-08-14
    Description: The competence of two fungal isolates for degrading petroleum hydrocarbons was evaluated. The filamentous fungi were isolated from a crude oil-contaminated soil in northeastern Ecuador, and were 99 %–100 % similar in 18S rDNA sequence to the genus Geomyces . Their efficiencies of degradation were tested in vitro for 30 days, using medium and soil microcosm. Residual hydrocarbons were tracked by gas liquid chromatography with a flame ionization detector. The maximum removal percentages of total petroleum hydrocarbons were 77.3 % and 79.9 % for experiments in the medium and soil microcosm, respectively. The percent germination of cow pea ( Vigna unguiculata ) seeds was increased from 20 % to 100 % upon bioremediation. Isolates sporulated optimally on minimal salts agar medium at pH 5, 25°C temperature, 1 %–1.5 % substrate (crude oil) and 4–6 g L −1 N–P–K. These findings suggest that these fungal isolates are potential degraders for bioremediation in crude oil-contaminated areas in Ecuador.
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  • 68
    Publication Date: 2015-08-14
    Description: Chironomids from the genus Chironomus are widely used in laboratory ecotoxicology, but are prone to inbreeding depression, which can compromise test results. The standard Chironomus test species ( C. riparius , C. dilutus and C. yoshimatsui ) are also not cosmopolitan, making it difficult to compare results between geographic regions. In contrast, the chironomid Paratanytarsus grimmii is cosmopolitan, and not susceptible to inbreeding depression because it reproduces asexually by apomictic parthenogenesis. However, there is no standardised culturing methodology for P. grimmii , and a lack of acute toxicity data for common pollutants (metals and pesticides). In this study, we developed a reliable culturing methodology for P. grimmii . We also determined 24-h first instar LC50s for the metals Cu, Pb, Zn, Cd and the insecticide imidacloprid. By developing this culturing methodology and generating the first acute metal and imidacloprid LC50s for P. grimmii , we provide a basis for using P. grimmii in routine ecotoxicological testing.
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  • 69
    Publication Date: 2015-08-14
    Description: The sorption behavior of chlorantraniliprole (CAP) by biochar and effect of soil extracts on sorptivity in soil–biochar systems were examined. The results showed that biochar amendment could enhance the sorption of CAP in soils. The values of K F increased significantly when the soils were amended with 0.5 % BC850, which were from 1.54 to 196.5. The indigenous sorptivity of biochar was suppressed after it was applied to the soils. The degree of biochar sorptivity attenuation in different soil–biochar systems varied with the properties of soil water soluble matters. Sorption of CAP by biochar from the five soil extracts was found to be lower than that from a CaCl 2 solution. The calculated K d values at C w of 0.01 mg kg −1 for biochar sorption of CAP from CaCl 2 solution were 21.4–26.6 times of that from soil extracts. Aging of biochar in soil extract reduced CAP sorption by up to 85 %.
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  • 70
    Publication Date: 2015-08-14
    Description: The prediction about metals behaviour in soil requires knowledge on their solid–liquid partitioning. Usually it is expressed with an empirical distribution coefficient or Kd, which gives the ratio of the metal concentration in the solid phase to that in the solution. Kd values have been determined for Zn, Pb and Cd from samples representing the two most exploited aquifers in Argentina, Pampeano and Puelche, at three different locations in the province of Buenos Aires. The Pampeano aquifer presented higher Kd values than the Puelche aquifer. Comparing Kd values, different relationships could be observed: (a) Pampeano aquifer: Pb 〉 Zn 〉 Cd, and (b) Puelche aquifer: Pb 〉 Cd 〉 Zn. Kd for Cd seems to be linked to cationic exchange capacity, but solid phases precipitation can be more determining for Pb and Zn.
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  • 71
    Publication Date: 2015-08-14
    Description: The cladocerans Ceriodaphnia dubia and Daphnia magna are widely used in environmental toxicity testing and the test methodologies for these species are well developed. However, copepods are a much more abundant contributor to zooplankton in many lakes, but they are not routinely used in toxicity tests. Therefore, we propose toxicity test methods for the freshwater copepod, Cyclops vernalis assessing effects on its survival and growth. A case study is presented in which the proposed test was performed with a range of concentrations of total dissolved solids (TDS) and used as part of a test battery to develop a site-specific water quality objective. C . vernalis was less sensitive to TDS compared to D . magna and C . dubia , but similarly sensitive to an alga, a diatom, a rotifer, a chironomid, and two fish species. No adverse effects were observed on survival or growth of C . vernalis at TDS concentrations up to 1500 mg/L.
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  • 72
    Publication Date: 2015-08-13
    Description: Electric vehicle (EV) energy consumption is variable and dependent on a number of external factors such as road topology, traffic, driving style, ambient temperature, etc. The goal of this paper is to detect and quantify correlations between the kinematic parameters of the vehicle and its energy consumption. Real-world data of EV energy consumption are used to construct the energy consumption calculation models. Based on the vehicle dynamics equation as underlying physical model, multiple linear regression is used to construct three models. Each model uses a different level of aggregation of the input parameters, allowing predictions using different types of available input parameters. One model uses aggregated values of the kinematic parameters of trips. This model allows prediction with basic, easily available input parameters such as travel distance, travel time, and temperature. The second model extends this by including detailed acceleration data. The third model uses the raw data of the kinematic parameters as input parameters to predict the energy consumption. Using detailed values of kinematic parameters for the prediction in theory increases the link between the statistical model and its underlying physical principles, but requires these parameters to be available as input in order to make predictions. The first two models show similar results. The third model shows a worse fit than the first two, but has a similar accuracy. This model has great potential for future improvement.
    Electronic ISSN: 1996-1073
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 73
    Publication Date: 2015-08-15
    Description: Energy saving, reduction of greenhouse gasses and increased use of renewables are key policies to achieve the European 2020 targets. In particular, distributed renewable energy sources, integrated with spatial planning, require novel methods to optimise supply and demand. In contrast with large scale wind turbines, small and medium wind turbines (SMWTs) have a less extensive impact on the use of space and the power system, nevertheless, a significant spatial footprint is still present and the need for good spatial planning is a necessity. To optimise the location of SMWTs, detailed knowledge of the spatial distribution of the average wind speed is essential, hence, in this article, wind measurements and roughness maps were used to create a reliable annual mean wind speed map of Flanders at 10 m above the Earth’s surface. Via roughness transformation, the surface wind speed measurements were converted into meso- and macroscale wind data. The data were further processed by using seven different spatial interpolation methods in order to develop regional wind resource maps. Based on statistical analysis, it was found that the transformation into mesoscale wind, in combination with Simple Kriging, was the most adequate method to create reliable maps for decision-making on optimal production sites for SMWTs in Flanders (Belgium).
    Electronic ISSN: 1996-1073
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 74
    Publication Date: 2015-08-11
    Description: Metal hydrides can be utilized for hydrogen storage and for thermal energy storage (TES) applications. By using TES with solar technologies, heat can be stored from sun energy to be used later, which enables continuous power generation. We are developing a TES technology based on a dual-bed metal hydride system, which has a high-temperature (HT) metal hydride operating reversibly at 600–800 °C to generate heat, as well as a low-temperature (LT) hydride near room temperature that is used for hydrogen storage during sun hours until there is the need to produce electricity, such as during night time, a cloudy day or during peak hours. We proceeded from selecting a high-energy density HT-hydride based on performance characterization on gram-sized samples scaled up to kilogram quantities with retained performance. COMSOL Multiphysics was used to make performance predictions for cylindrical hydride beds with varying diameters and thermal conductivities. Based on experimental and modeling results, a ~200-kWh/m3 bench-scale prototype was designed and fabricated, and we demonstrated the ability to meet or exceed all performance targets.
    Electronic ISSN: 1996-1073
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 75
    Publication Date: 2015-08-14
    Description: To reconstruct the history of environmental degradation in Sanliqi Lake (Daye City, central China), multiple proxies were analyzed in a sedimentary core which was dated using 137 Cs and spheroidal carbonaceous particles (SCPs). The results show that Sanliqi Lake has experienced serious degradation during the past 60 years, resulting from a large influx of metals and nutrients. Expansion of agricultural and industrial activities between 1945 and 1993 enhanced nutrient and metal enrichment, indicated by increases in metals, SCPs, magnetic susceptibility, total phosphorus, total nitrogen and total organic carbon. Further enrichment of Zn, Cd, Ni and Cr after 1993 was linked to a recent intensification of mining activities. Decreases in Cu and Pb after 2006 probably resulted from recent environmental remediation. This study verified the coupling between lake sediment pollution and human activities in Daye City during the past 60 years. The reconstructed history of lake pollution can provide reference information for continued restoration of Sanliqi Lake and other similar heavily polluted lakes in the developing regions.
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  • 76
    Publication Date: 2015-08-14
    Description: Assessing the performance or energy efficiency of a single construction element by itself is often a futile exercise. That is not the case, however, when an element is designed, among others, to improve building energy performance by harnessing renewable energy in a process that requires a source of external energy. Harnessing renewable energy is acquiring growing interest in Mediterranean climates as a strategy for reducing the energy consumed by buildings. When such reduction is oriented to lowering demand, the strategy consists in reducing the building’s energy needs with the use of construction elements able to passively absorb, dissipate, or accumulate energy. When reduction is pursued through M&E services, renewable energy enhances building performance. The efficiency of construction systems that use renewable energy but require a supplementary power supply to operate can be assessed by likening these systems to regenerative heat exchangers built into the building. The indicators needed for this purpose are particularly useful for designers, for they can be used to compare the efficiency or performance to deliver an optimal design for each building. This article proposes a series of indicators developed to that end and describes their application to façades bearing phase change materials (PCMs).
    Electronic ISSN: 1996-1073
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 77
    Publication Date: 2015-08-14
    Description: In the provinces of north China, combined heat and electric power generations (CHP) are widely utilized to provide both heating source and electricity. While, due to the constraint of thermal-electric coupling within CHP, a mass of wind turbines have to offline operate during heating season to maintain the power grid stability. This paper proposes a thermal-electric decoupling (TED) approach to release the energy waste. Within the thermal-electric decoupling system, heat storage and electric boiler/heat pump are introduced to provide an auxiliary thermal source during hard peak shaving period, thus relying on the participation of an outside heat source, the artificial electric power output change interval could be widened to adopt more wind power and reduce wind power curtailment. Both mathematic models and methods are proposed to calculate the evaluation indexes to weight the effect of TED, by using the Monte Carlo simulation technique. Numerical simulations have been conducted to demonstrate the effectiveness of the proposed methods, and the results show that the proposed approach could relieve up to approximately 90% of wind power curtailment and the ability of power system to accommodate wind power could be promoted about 32%; moreover, the heating source is extended, about 300 GJ heat could be supplied by TED during the whole heating season, which accounts for about 18% of the total heat need.
    Electronic ISSN: 1996-1073
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 78
    Publication Date: 2015-09-11
    Description: Avoidance tests with collembolans provide a quick assessment of soil quality. However, some parameters of the procedure can be modified in order to increase its performance. In this study we assessed the tendency of Folsomia candida to avoid soils contaminated with boric acid [350–700–1400–2800–5600 mg/kg soil dry weight (dw)], phenmedipham (35–70–140–280 mg/kg dw) or petroleum hydrocarbons (1312–1838–2625–3675–5250 mg/kg dw) by preferring an untreated soil. Two separate methodologies were applied, the one presented in the ISO standard 17512:2 and a modified version of the Petri dish method that allowed data acquisition after 2, 24 and 48 h of exposure. After combining data from three separate trials, effective median concentration values (EC 50 ) from the presented method were lower and showed similar or less variability than those from the ISO procedure, suggesting the modified protocol as a suitable alternative screening tool.
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    Topics: Energy, Environment Protection, Nuclear Power Engineering , Medicine
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  • 79
    Publication Date: 2015-09-17
    Description: In recent years, water (R718) as a kind of natural refrigerant—which is environmentally-friendly, safe and cheap—has been reconsidered by scholars. The systems of using water as the refrigerant, such as water vapor compression refrigeration and heat pump systems run at sub-atmospheric pressure. So, the research on water boiling heat transfer at sub-atmospheric pressure has been an important issue. There are many research papers on the evaporation of water, but there is a lack of data on the characteristics at sub-atmospheric pressures, especially lower than 3 kPa (the saturation temperature is 24 °C). In this paper, the experimental research on water boiling heat transfer on a horizontal copper rod surface at 1.8–3.3 kPa is presented. Regression equations of the boiling heat transfer coefficient are obtained based on the experimental data, which are convenient for practical application.
    Electronic ISSN: 1996-1073
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 80
    Publication Date: 2015-09-17
    Description: The dual-permanent-magnet-excited (DPME) machine employs permanent magnets (PMs) both on the stator and the rotor. It relies on the bi-directional field modulation effect (BFME) to achieve stable electromechanical energy conversion. Therefore, this new type of machine is capable of offering much higher torque capability than its traditional counterparts. This paper is devoted to investigating the optimum design method for improving the BFME of DPME machines, so as to further improve their produced electromagnetic torques. Response surface methodology is engaged to investigate the impacts of shape factors of the stator and rotor slots on the torque capability of the DPME machine, and the fitted models are built up by using both the finite element method (FEM) and the least-squares method. After that, the optimum shape factors are obtained from the fitted models. The results estimated by using both two-dimensional (2D)-FEM and three-dimensional (3D)-FEM demonstrate that the pull-out torque of the optimum case is 24.5% larger than that of the initial case, while the usage of PM material of the optimum case is 8.9% less than that of the initial case.
    Electronic ISSN: 1996-1073
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 81
    Publication Date: 2015-09-17
    Description: In this study, driving data for various types of drivers are collected using a VIDE (virtual integrated driving environment), and a driver model is developed. To represent the driver tendencies quantitatively, the DDA (degree of driver aggression) is proposed based on fuzzy logic. DDA has a 0-1 value; the closer the DDA is to one, the more aggressive the driver. Using the DDA, an engine on/off and battery charging power control algorithm are developed to improve the fuel economy of a power-split-type plug-in hybrid electric vehicle. The engine on/off control reduces the frequent engine on/off caused by aggressive driving, whereas the battery charging power control maintains the battery state of charge (SOC) by operating the engine according to the DDA. It is found that the proposed control algorithm improves fuel economy by 17.3% compared to the existing control for an aggressive driver.
    Electronic ISSN: 1996-1073
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 82
    Publication Date: 2015-09-17
    Description: This paper describes the Experimental Power Grid Centre (EPGC) microgrid test facility, which was developed to enable research, development and testing for a wide range of distributed generation and microgrid technologies. The EPGC microgrid facility comprises a integrated electrical and thermal grid with a flexible and configurable architecture, and includes various distributed energy resources and emulators, such as generators, renewable, energy storage technologies and programmable load banks. The integrated thermal grid provides an opportunity to harness waste heat produced by the generators for combined heat, power and cooling applications, and support research in optimization of combined electrical-thermal systems. Several case studies are presented to demonstrate the testing of different control and operation strategies for storage systems in grid-connected and islanded microgrids. One of the case studies also demonstrates an integrated thermal grid to convert waste heat to useful energy, which thus far resulted in a higher combined energy efficiency. Experiment results confirm that the facility enables testing and evaluation of grid technologies and practical problems that may not be apparent in a computer simulated environment.
    Electronic ISSN: 1996-1073
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 83
    Publication Date: 2015-09-17
    Description: Paraffin fuel has been found to have a regression rate that is higher than conventional HTPB (hydroxyl-terminated polybutadiene) fuel and, thus, presents itself as an ideal energy source for a hybrid rocket engine. The energy characteristics of paraffin-based fuel and HTPB fuel have been calculated by the method of minimum free energy. The thermal degradation characteristics were measured for paraffin, pretreated paraffin, HTPB and paraffin-based fuel in different working conditions by the using differential scanning calorimetry (DSC) and a thermogravimetric analyzer (TGA). The regression rates of paraffin-based fuel and HTPB fuel were tested by a rectangular solid-gas hybrid engine. The research findings showed that: the specific impulse of paraffin-based fuel is almost the same as that of HTPB fuel; the decomposition temperature of pretreated paraffin is higher than that of the unprocessed paraffin, but lower than that of HTPB; with the increase of paraffin, the initial reaction exothermic peak of paraffin-based fuel is reached in advance, and the initial reaction heat release also increases; the regression rate of paraffin-based fuel is higher than the common HTPB fuel under the same conditions; with the increase of oxidizer mass flow rate, the regression rate of solid fuel increases accordingly for the same fuel formulation.
    Electronic ISSN: 1996-1073
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 84
    Publication Date: 2015-09-17
    Description: This work reports results related to the “EU-FP7-HRC-Power” project aiming at developing micro-meso hybrid sources of power. One of the goals of the project is to achieve surface temperatures up to more than 1000 K, with a ∆T ≤ 100 K, in order to be compatible with a thermal/electrical conversion by thermo-photovoltaic cells. The authors investigate how to reach that goal adopting swirling chambers integrated in a thermally-conductive and emitting element. The converter consists of a small parallelepiped brick inside two separated swirling meso-combustion chambers, which heat up the parallelepiped, emitting material by the combustion of H2 and air at ambient pressure. The overall dimension is of the order of cm. Nine combustion simulations have been carried out assuming detailed chemistry, several length/diameter ratios (Z/D = 3, 5 and 11) and equivalence ratios (0.4, 0.7 and 1); all are at 400 W of injected chemical power. Among the most important results are the converter surfaces temperatures, the heat loads, provided to the environment, and the chemical efficiency. The high chemical efficiency, h > 99.9%, is due to the relatively long average gas residence time coupled with the fairly good mixing due to the swirl motion and the impinging air/fuel jets that provide heat and radicals to the flame.
    Electronic ISSN: 1996-1073
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 85
    Publication Date: 2015-09-17
    Description: The two core objectives of the Clean Development Mechanism (CDM) are cost-effective emission reduction and sustainable development. Despite the potential to contribute to both objectives, solar projects play a negligible role under the CDM. In this research, the greenhouse gas mitigation cost is used to evaluate the economic and environmental performances of small-scale rural photovoltaic solar projects. In particular, we compare the use of absolute and relative mitigation costs to evaluate the attractiveness of these projects under the CDM. We encourage the use of relative mitigation costs, implying consideration of baseline costs that render the projects profitable. Results of the mitigation cost analysis are dependent on the baseline chosen. To overcome this drawback, we complement the analysis with a multi-objective optimization approach, which allows quantifying the trade-off between economic and environmental performances of the optimal technologies without requiring a baseline.
    Electronic ISSN: 1996-1073
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 86
    Publication Date: 2015-09-17
    Description: With rising income and the emergence of modern shopping centers in urban China, shopping trips by private car becomes more and more common, leading to higher carbon emissions in the transport sector. Encouraging car owners to shift transport mode from private car to public transport could achieve significant emissions reductions. This study estimate carbon emissions savings by shifting from private cars to public transport for shopping trips in urban China, using Shenyang, one of the largest cities in China, as a case study. Our results show that the average carbon emissions per shopper is 426.9 g, and the carbon emissions on weekends is 13% higher than weekdays. Moreover, shoppers travelling by private car emitted five times more carbon emission than those by public transport. We also found that car ownership gradually increased as accessibility to public transport decreased, and that more car owners chose to travel by private cars than public transport in areas with limited access. This study, thus, highlights the potential for high-quality public transport to reduce the transport sector’s carbon emissions in urban China.
    Electronic ISSN: 1996-1073
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 87
    Publication Date: 2015-09-17
    Description: Fuel economy efficiency is one of the most important parameters for vehicle powertrains, which is of particular interest for heavy-duty powertrain calibration. Conventionally, this work relies heavily on road tests, which cost more and may lead to long duration product development cycles. The paper proposes a novel hardware-in-loop modeling and calibration method to work it out. A dSPACE hardware-based test bench was successfully established and validated, which is valuable for a more efficient and easier shift schedule in calibration. Meanwhile, a real-time dynamic powertrain model, including a diesel engine, torque converter, gear box and driver model was built. Typical driving cycles that both velocity and slope information were constructed for different road conditions. A basic economic shift schedule was initially calculated and then optimal calibrated by the test bench. The results show that there is an optimal relationship between an economic shift schedule and speed regulation. By matching the best economic shift schedule regulation to different road conditions; the fuel economy of vehicles can be improved. In a smooth driving cycle; when the powertrain applies a larger speed regulation such as 12% and the corresponding shift schedule; the fuel consumption is smaller and is reduced by 13%. In a complex driving cycle, when the powertrain applies a smaller speed regulation such as 5% along with the corresponding shift schedule; the fuel consumption is smaller and is reduced by 5%. The method thus can provide guidance for economic calibration experiments of off-road heavy-duty vehicles.
    Electronic ISSN: 1996-1073
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 88
    Publication Date: 2015-09-17
    Description: The objective of this paper is to implement a two-phase, interleaved, bidirectional DC/DC converter topology with an improved voltage conversion ratio for electric vehicle (EV) and DC-microgrid systems. In this study, a two-phase interleaved charge-pump topology is introduced to achieve a high voltage conversion ratio with very simple control circuits. In discharge mode, the circuit topology acts as a voltage-multiplier boost converter to achieve a high step-up conversion ratio (48 V to 240 V). In charge mode, the circuit topology acts as a voltage-divider buck converter to achieve a high voltage step-down conversion ratio (240 V to 48 V). The circuit configuration, operating principle, steady-state analysis and the closed-loop control of the proposed converter are presented. Experiments conducted on a laboratory prototype with 500 W power-rating are presented to verify the effectiveness. The maximum efficiency levels in discharge and charge modes are about 97.7% and 98.4% respectively.
    Electronic ISSN: 1996-1073
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 89
    Publication Date: 2015-09-17
    Description: Offshore wind farm (WF) projects have been promoted by support schemes as part of the expansion of renewable energy resources in Korea. This paper examines in detail how the Renewable Portfolio Standard (RPS), which was adopted post the Feed-in-Tariff scheme in 2012, has had a profound impact on the economic benefits of offshore WFs in Korea. A framework for analyzing the economic viability of RPS is presented and applied to the sixth basic plan for long-term electricity supply and demand in Korea. The electricity market price is forecast using a reformulated probabilistic production cost (PPC) model, and the renewable energy certificate (REC) price is calculated using its determination rule. The results show that the existing RPS will be ineffective in increasing the penetration of offshore WFs in Korea; however, they also indicate that the economic viability of offshore WFs could be improved by adjusting the existing RPS.
    Electronic ISSN: 1996-1073
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 90
    Publication Date: 2015-09-17
    Description: Conditions for load-independent output voltage or current in two-coil wireless power transfer (WPT) systems have been studied. However, analysis of load-independent output current in three-coil WPT system is still lacking in previous studies. This paper investigates the output current characteristics of a three-coil WPT system against load variations, and determines the operating frequency to achieve a constant output current. First, a three-coil WPT system is modeled by circuit theory, and the analytical expression of the root-mean-square of the output current is derived. By substituting the coupling coefficients, the quality factor, and the resonant frequency of each coil, we propose a method of calculating the frequency for load-independent output current in a three-coil WPT system, which indicates that there are two frequencies that can achieve load-independent output current. Experiments are conducted to validate these analytical results.
    Electronic ISSN: 1996-1073
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 91
    Publication Date: 2015-09-17
    Description: The formation of dense spacing fracture network is crucial to the hydraulic fracturing treatment of unconventional reservoir. However, one difficulty for fracturing treatment is the lack of clear understanding on the nature of fracture complexity created during the treatment. In this paper, fracture propagation is numerically investigated to find the conditions needed for the stable propagation of complex fracture network. Firstly, starting from a parallel fracture system, the stability of fracture propagation is analyzed and a dimensionless number M is obtained. Then, by developing a hydraulic fracturing simulation model based on displacement discontinuity method, the propagation of parallel fractures is simulated and a clear relation between M and the stability of parallel fractures is obtained. Finally, the investigation on parallel fractures is extended to complex fracture networks. The propagation of complex fracture networks is simulated and the results show that the effects of M on complex fracture networks is the same to that of parallel fractures. The clear relation between M and fracture propagation stability is important for the optimization of hydraulic fracturing operation.
    Electronic ISSN: 1996-1073
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 92
    Publication Date: 2015-09-17
    Description: To efficiently recover the waste heat from a diesel engine exhaust, a regenerative organic Rankine cycle (RORC) system was employed, and butane, R124, R416A, and R134a were used as the working fluids. The resulting diesel engine-RORC combined system was defined and the relevant evaluation indexes were proposed. First, the variation tendency of the exhaust energy rate under various diesel engine operating conditions was analyzed using experimental data. The thermodynamic model of the RORC system was established based on the first and second laws of thermodynamics, and the net power output and exergy destruction rate of the RORC system were selected as the objective functions. A particle swarm optimization (PSO) algorithm was used to optimize the operating parameters of the RORC system, including evaporating pressure, intermediate pressure, and degree of superheat. The operating performances of the RORC system and diesel engine-RORC combined system were studied for the four selected working fluids under various operating conditions of the diesel engine. The results show that the operating performances of the RORC system and the combined system using butane are optimal on the basis of optimizing the operating parameters; when the engine speed is 2200 r/min and engine torque is 1215 N·m, the net power output of the RORC system using butane is 36.57 kW, and the power output increasing ratio (POIR) of the combined system using butane is 11.56%.
    Electronic ISSN: 1996-1073
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 93
    Publication Date: 2015-09-17
    Description: For the development of the future smart grid, the detection of power quality events is a key issue for the power system monitoring. Voltage sags, swells, harmonics (variations) and interruptions, which produce large losses for commercial and industrial consumers, are the main events to be considered due to the sensitivity of equipment to these electrical anomalies. The steady-state events are even more frequently accompanied by transients, the discrimination and localization being far more exigent and requiring advanced signal separating tools to be incorporated in the measurement equipment. This paper shows the event detection performance of the spectral kurtosis as a signal separating tool in the frequency domain. The disturbances under test are hybrid signals resulting from the coupling between amplitude defects and non-desired higher frequencies. Being a fourth-order spectrum, the kurtosis is confirmed as a noise-resistant tool that enhances impulsiveness, therefore characterizing the electrical anomalies. In the beginning of the analysis, the voltage sag is established as a reference; then, the disturbances (oscillatory transients and harmonics) are coupled at the starting and ending instants of the sag, resulting in complex hybrid events. The results show that the spectral kurtosis enhances the detection Energies 2015, 8 9778 of both types of events (steady state and transients), which are outlined in a bump shape in the fourth-order frequency pattern and centered in the main carrier frequency. Indeed, while the oscillatory transients are associated with softer and lower-amplitude peaks, the harmonics correspond to crisper and higher ones. As these mixed electrical faults are very common in the actual power grid, the article postulates the higher-order spectra to be implemented in prospective online measurement instruments.
    Electronic ISSN: 1996-1073
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 94
    Publication Date: 2015-09-19
    Description: Heavy metal concentrations in surface water and soil samples around Gümüşköy Silver Mine, located in Köprüören Basin, were determined to evaluate the anthropogenic level of contamination due to mining activities. The mean concentrations of As, Pb, Sb and Cd in 12 soil samples came out to be 1193, 844, 66 and 19 ppm, respectively. Soil pollution assessment was carried out by using geoaccumulation index ( Igeo ), enrichment factor (EF) and pollution index (PI). Igeo , EF and PI suggest anthropogenic pollution of As, Pb, Sb and Zn in the areas where there is leakage of these heavy metals from the waste pools of the silver mine facility. Water samples collected from the surface waters also have elevated concentrations of these heavy metals. The contaminants are most probably transported by surface waters in the rainy season.
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  • 95
    Publication Date: 2015-09-19
    Description: A heavy metal risk assessment based on estimated daily intake (EDI) and target hazard quotient was made for children and adults. Five fish species captured from the eastern Aegean Sea were analyzed for Cr, Cu, Cd, Hg and Pb by inductively coupled plasma spectroscopy in muscle tissue of red mullet ( Mullus barbatus ), surmullet ( Mullus surmuletus ), sand steenbras ( Lithognathus mormyrus ), common two-banded seabream ( Diplodus vulgaris ) and common pandora ( Pagellus erythinus ). The ranges for mean metal concentration (mg/kg wet wt) in the five species were 0.27–0.39 Cr, 0.12–0.22 Cu, 0.09–0.10 Hg and 0.10–0.12 Pb. All means were identical for Cd at 0.03 mg/kg wet wt. The EDI values for each metal were ascertained not to exceed the tolerable daily intake amount. Fish did not contain sufficiently high levels of these metals to pose a carcinogenic risk.
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  • 96
    Publication Date: 2015-09-19
    Description: This study evaluated the expression level of antioxidant enzymes Cu, Zn-superoxide dismutase (Cu, Zn-SOD), catalase (CAT), glutathione peroxidase (GPx) and glutathione S-transferase (GST) in hemocytes of Macrobrachium rosenbergii exposed to copper by real-time PCR (qRT-PCR). Results showed that the mRNA expression of Cu, Zn-SOD increased to reach a peak at 6 h, then recovered to its normal level at 48 h. CAT expression level was significantly increased at 12 h and reached a peak at 24 h, but recovered to its normal level later. GPx expression level was significantly increased at 6 h and reached the peak at 12 h. GST expression level was significantly induced from 12 to 24 h and then dropped to its normal level at 48 h. These results indicated that antioxidant enzymes were inducible, possibly for removing excessive reactive oxygen species to protect prawn from oxidative stress.
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  • 97
    Publication Date: 2015-09-19
    Description: The distribution of butyltins (BTs) and polycyclic aromatic hydrocarbons (PAHs) were studied in surface sediments to assess how relevant is Mar del Plata port (Argentina) as a source of contamination to the surrounding environments. Within the port, TBT concentrations ranged from 24.2 to 150 ng Sn g −1 and PAHs (Σ16) from 180 to 17,094 ng g −1 . At the surrounding beaches, PAHs were detected at low concentrations and TBT concentrations reached 10.9 ng Sn g −1 . Although those low levels indicate that the Port might not be an important source of contamination to the surrounding beaches, the very low TOC content and the coarse grain size of the beaches sediments could explain the sedimentary levels. The results show a reduction in TBT levels in Mar del Plata port after national and international use restrictions of TBT-based antifouling paints.
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  • 98
    Publication Date: 2015-09-19
    Description: Sediment samples were analyzed to comprehensively characterize the concentrations, distribution, possible sources and potential biological risk of organochlorine pesticides in Qiandao Lake, China. Concentrations of sumHCH and sumDDT in sediments ranged from 0.03 to 5.75 ng/g dry weight and not detected to 14.39 ng/g dry weight. The predominant β -HCH and the α -HCH/ γ -HCH ratios indicated that the residues of HCHs were derived not only from historical technical HCH use but also from additional usage of lindane. Ratios of o,p’ -DDT/ p,p’ -DDT and DDD/DDE suggested that both dicofol-type DDT and technical DDT applications may be present in most study areas. Additionally, based on two sediment quality guidelines, γ-HCH, o,p ′-DDT and p,p ′-DDT could be the main organochlorine pesticides species of ecotoxicological concern in Qiandao Lake.
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  • 99
    Publication Date: 2015-09-19
    Description: Juvenile marine polychaetes, Neanthes arenaceodentata , were exposed for 28 days to copper (Cu)-spiked sediment at six concentrations ranging from 48.3 to 2380 mg Cu/kg dry sediment, plus control. Survival was reduced ( p  ≤ 0.05) at concentrations ≥1190 mg Cu/kg. Growth was inhibited at Cu concentrations ≥506 mg Cu/kg. Dose–response relationships yielded LC 10 and LC 50 estimates of 514 and 1230 mg Cu/kg, respectively. The growth effect EC 50 estimate was 409 mg Cu/kg. Ranges for the no observable effect concentration and lowest observable effect concentration were 506–1190 mg Cu/kg for survival, and 230–506 mg Cu/kg for growth. Pore water concentrations of Cu were 38.7–65.8 µg Cu/L in exposures where toxic effects were observed, compared to a range of 15.1–22.4 µg Cu/L in exposures where significant effects were not evident. The results of the study were compared with empirical and mechanistic sediment quality guidelines for the protection of benthic organisms.
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  • 100
    Publication Date: 2015-09-19
    Description: Metal concentration in marine sediments is influenced by sedimentation rate. In this study, the metal concentration in sediments of Bohai Bay, China, was adjusted by sedimentation rate, which was derived from the radionuclide dating method. The results showed that the sedimentation rate of Bohai Bay sediments increased from 0.3 to 0.55 g/a over time, especially in the last 30 years since the economic reform in China. The sequence of metal concentrations (mg/kg) is: Cr(97.41) 〉 Zn(73.14) 〉 Cu(20.59) 〉 Pb(16.42) 〉 Cd(0.49). Through the adjustment, the change of metal concentration in sediment cores increased obviously from bottom to surface sediments. It indicated that the increasing sedimentation rate of Bohai Bay in recent years diluted the metal concentration in the sediment.
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