Publication Date:
2018-11-10
Description:
The reaction cavities of the nitro groups in the title compounds, trans-{2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato-κ4O,N,N′,O′}(nitro-κN)(pyridine-κN)cobalt(III), [Co(C16H14N2O2)(NO2)(C5H5N)], (I), and trans-{2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato-κ4O,N,N′,O′}(4-methylpyridine-κN)(nitro-κN)cobalt(III), [Co(C16H14N2O2)(NO2)(C6H7N)], (II), have been investigated to reveal that the intermolecular CMe—H...O(nitro) contacts in (II) are unfeasible for the nitro–nitrito photochemical linkage isomerization process. In (I), there are two independent complexes showing similar conformations, and the central five-membered chelate ring of the tetradentate salen ligand adopts the same absolute configuration. This is the result of pseudo-spontaneous resolution, since the configuration of the five-membered chelate ring may frequently be reversed in solution. In the crystals of (I) and (II), the molecules are linked into three-dimensional networks by C—H...O hydrogen bonds.
Keywords:
crystal structurenitro-nitrito photo-isomerizationreaction cavity
Electronic ISSN:
1600-5368
Topics:
Chemistry and Pharmacology
,
Geosciences
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