ALBERT

Beschreibung: Evapotranspiration (ET) from tropical forests serves as a critical moisture source for regional and global climate cycles. However, the magnitude, seasonality, and interannual variability of ET in the Congo Basin remain poorly constrained due to a scarcity of direct observations, despite the Congo being the second-largest river basin in the world and containing a vast region of tropical forest. In this study, we applied a water balance model to an array of remotely sensed and in situ datasets to produce monthly, basin-wide ET estimates spanning April 2002 to November 2016. Data sources include water storage changes estimated from the Gravity Recovery and Climate Experiment (GRACE) satellites, in situ measurements of river discharge, and precipitation from several remotely sensed and gauge-based sources. An optimal precipitation dataset was determined as a weighted average of interpolated data by Nicholson et al. (2018), Climate Hazards InfraRed Precipitation with Station data version 2 (CHIRPS2) , and the Precipitation Estimation from Remotely Sensed Information using Artificial Neural Networks–Climate Data Record product (PERSIANN-CDR), with the relative weights based on the error magnitudes of each dataset as determined by triple collocation. The resulting water-balance-derived ET (ETwb) features a long-term average that is consistent with previous studies (117.2±3.5 cm yr−1) but displays greater seasonal and interannual variability than seven global ET products. The seasonal cycle of ETwb generally tracks that of precipitation over the basin, with the exception that ETwb is greater in March–April–May (MAM) than in the relatively wetter September–October–November (SON) periods. This pattern appears to be driven by seasonal variations in the diffuse photosynthetically active radiation (PAR) fraction, net radiation (Rn), and soil water availability. From 2002 to 2016, Rn, PAR, and vapor-pressure deficit (VPD) all increased significantly within the Congo Basin; however, no corresponding trend occurred in ETwb. We hypothesize that the stability of ETwb over the study period despite sunnier and less humid conditions may be due to increasing atmospheric CO2 concentrations that offset the impacts of rising VPD and irradiance on stomatal water use efficiency (WUE).

Beschreibung: Optimum management of irrigated crops in regions with shallow saline groundwater requires a careful balance between application of irrigation water and upward movement of salinity from the groundwater. Few field-validated surrogate models are available to aid in the management of irrigation water under shallow groundwater conditions. The objective of this research is to develop a model that can aid in the management using a minimum of input data that are field validated. In this paper a 2-year field experiment was carried out in the Hetao irrigation district in Inner Mongolia, China, and a physically based integrated surrogate model for arid irrigated areas with shallow groundwater was developed and validated with the collected field data. The integrated model that links crop growth with available water and salinity in the vadose zone is called Evaluation of the Performance of Irrigated Crops and Soils (EPICS). EPICS recognizes that field capacity is reached when the matric potential is equal to the height above the groundwater table and thus not by a limiting hydraulic conductivity. In the field experiment, soil moisture contents and soil salt conductivity at five depths in the top 100 cm, groundwater depth, crop height, and leaf area index were measured in 2017 and 2018. The field results were used for calibration and validation of EPICS. Simulated and observed data fitted generally well during both calibration and validation. The EPICS model that can predict crop growth, soil water, groundwater depth, and soil salinity can aid in optimizing water management in irrigation districts with shallow aquifers.

Beschreibung: The invasion of aquifer microbial communities by aboveground microorganisms, a phenomenon known as community coalescence, is likely to be exacerbated in groundwaters fed by stormwater infiltration systems (SISs). Here, the incidence of this increased connectivity with upslope soils and impermeabilized surfaces was assessed through a meta-analysis of 16S rRNA gene libraries. Specifically, DNA sequences encoding 16S rRNA V5-V6 regions from free-living and attached aquifer bacteria (i.e., water and biofilm samples) were analysed upstream and downstream of a SIS and compared with those from bacterial communities from watershed runoffs and surface sediments from the SIS detention and infiltration basins. Significant bacterial transfers were inferred by the SourceTracker Bayesian approach, with 23 % to 57 % of the aquifer bacterial biofilms being composed of taxa from aboveground sediments and urban runoffs. Sediments from the detention basin were found more significant contributors of taxa involved in the buildup of these biofilms than soils from the infiltration basin. Inferred taxa among the coalesced biofilm community were predicted to be high in hydrocarbon degraders such as Sphingobium and Nocardia. The 16S rRNA-based bacterial community structure of the downstream-SIS aquifer waters showed lower coalescence with aboveground taxa (8 % to 38 %) than those of biofilms and higher numbers of taxa predicted to be involved in the N and S cycles. A DNA marker named tpm enabled the tracking of bacterial species from 24 genera including Pseudomonas, Aeromonas and Xanthomonas, among these communities. Several tpm sequence types were found to be shared between the aboveground and aquifer samples. Reads related to Pseudomonas were allocated to 50 species, of which 16 were found in the aquifer samples. Several of these aquifer species were found to be involved in denitrification but also hydrocarbon degradation (P. aeruginosa, P. putida and P. fluorescens). Some tpm sequence types allocated to P. umsongensis and P. chengduensis were found to be enriched among the tpm-harbouring bacteria, respectively, of the aquifer biofilms and waters. Reads related to Aeromonas were allocated to 11 species, but only those from A. caviae were recovered aboveground and in the aquifer samples. Some tpm sequence types of the X. axonopodis phytopathogen  were recorded in higher proportions among the tpm-harbouring bacteria of the aquifer waters than in the aboveground samples. A significant coalescence of microbial communities from an urban watershed with those of an aquifer was thus observed, and recent aquifer biofilms were found to be significantly colonized by runoff-opportunistic taxa able to use urban C sources from aboveground compartments.

Beschreibung: Submarine groundwater discharge (SGD) is an important gateway for nutrients and pollutants from land to sea. While understanding SGD is crucial for managing nearshore ecosystems and coastal freshwater reserves, studying this discharge is complicated by its occurrence at the limit between land and sea, a dynamic environment. This practical difficulty is exacerbated by the significant spatial and temporal variability. Therefore, to capture the magnitude of SGD, a variety of techniques and measurements, applied over multiple periods, is needed. Here, we combine several geophysical methods to detect zones of fresh submarine groundwater discharge (FSGD) in the intertidal zone, upper beach, dunes, and shallow coastal area. Both terrestrial electrical-resistivity tomography (ERT; roll-along) and marine continuous resistivity profiling (CRP) are used from the shallow continental shelf up to the dunes and combined with frequency domain electromagnetic (FDEM) mapping in the intertidal zone. In particular, we apply an estimation of robust apparent electrical conductivity (rECa) from FDEM data to provide reliable lateral and vertical discrimination of FSGD zones. The study area is a very dynamic environment along the North Sea, characterized by semi-diurnal tides between 3 and 5 m. CRP is usually applied in calmer conditions, but we prove that such surveys are possible and provide additional information to primarily land-bound ERT surveying. The 2D inversion models created from ERT and CRP data clearly indicate the presence of FSGD on the lower beach or below the low-water line. This discharge originates from a potable freshwater lens below the dunes and flows underneath a thick saltwater lens, present from the dunes to the lower sandy beach, which is fully observed with ERT. Freshwater outflow intensity has increased since 1980, due to a decrease of groundwater pumping in the dunes. FDEM mapping at two different times reveals discharge at the same locations, clearly displays the lateral variation of the zone of discharge, and suggests that FSGD is stronger at the end of winter compared to the beginning of autumn. ERT, CRP, and FDEM are complementary tools in the investigation of SGD. They provide a high-resolution 3D image of the saltwater and freshwater distribution in the phreatic coastal aquifer over a relatively large area, both off- and onshore.

Beschreibung: Per capita arable land is decreasing due to the rapidly increasing population, and fresh water is becoming scarce and more expensive. Therefore, farmers should continue to use technology and innovative solutions to improve efficiency, save input costs, and optimise environmental resources (such as water). In the case study presented in this paper, the Global Navigation Satellite System interferometric reflectometry (GNSS-IR) technique was used to monitor soil moisture during 66 d, from 3 December 2018 to 6 February 2019, in the installations of the Cajamar Centre of Experiences, Paiporta, Valencia, Spain. Two main objectives were pursued. The first was the extension of the technique to a multi-constellation solution using GPS, GLONASS, and GALILEO satellites, and the second was to test whether mass-market sensors could be used for this technique. Both objectives were achieved. At the same time that the GNSS observations were made, soil samples taken at 5 cm depth were used for soil moisture determination to establish a reference data set. Based on a comparison with that reference data set, all GNSS solutions, including the three constellations and the two sensors (geodetic and mass market), were highly correlated, with a correlation coefficient between 0.7 and 0.85.

Beschreibung: Projecting the spatiotemporal changes in water resources under a no-analog future climate requires physically based integrated hydrologic models which simulate the transfer of water and energy across the earth's surface. These models show promise in the context of unprecedented climate extremes given their reliance on the underlying physics of the system as opposed to empirical relationships. However, these techniques are plagued by several sources of uncertainty, including the inaccuracy of input datasets such as meteorological forcing. These datasets, usually derived from climate models or satellite-based products, are typically only resolved on the order of tens to hundreds of kilometers, while hydrologic variables of interest (e.g., discharge and groundwater levels) require a resolution at much smaller scales. In this work, a high-resolution hydrologic model is forced with various resolutions of meteorological forcing (0.5 to 40.5 km) generated by a dynamical downscaling analysis from the regional climate model Weather Research and Forecasting (WRF). The Cosumnes watershed, which spans the Sierra Nevada and Central Valley interface of California (USA), exhibits semi-natural flow conditions due to its rare undammed river basin and is used here as a test bed to illustrate potential impacts of various resolutions of meteorological forcing on snow accumulation and snowmelt, surface runoff, infiltration, evapotranspiration, and groundwater levels. Results show that the errors in spatial distribution patterns impact land surface processes and can be delayed in time. Localized biases in groundwater levels can be as large as 5–10 m and 3 m in surface water. Most hydrologic variables reveal that biases are seasonally and spatially dependent, which can have serious implications for model calibration and ultimately water management decisions.

Beschreibung: In the title molecule, C20H24Br2N4, the imidazopyridine moiety is not planar as indicated by the dihedral angle of 2.0 (2)° between the constituent rings; the 4-dimethylaminophenyl ring is inclined to the mean plane of the imidazole ring by 27.4 (1)°. In the crystal, two sets of C—H...π(ring) interactions form stacks of molecules extending parallel to the a-axis direction. Hirshfeld surface analysis indicates that the most important contributions to the crystal packing are from H...H (42.2%), H...C/C...H (23.1%) and H...Br/Br...H (22.3%) interactions. The optimized structure calculated using density functional theory (DFT) at the B3LYP/ 6–311 G(d,p) level is compared with the experimentally determined structure in the solid state. The calculated HOMO–LUMO energy gap is 2.3591 eV.

Beschreibung: In the title unsymmetrical tertiary amine, C24H33NO2, which arose from the ring-opening reaction of a dihydrobenzoxazine, two 2,4-dimethylphenol moieties are linked by a 6,6′-(cyclohexylazanediyl)-bis(methylene) bridge: the dihedral angle between the dimethylphenol rings is 72.45 (7)°. The cyclohexyl ring adopts a chair conformation with the exocyclic C—N bond in an equatorial orientation. One of the phenol OH groups forms an intramolecular O—H...N hydrogen bond, generating an S(6) ring, and a short intramolecular C—H...O contact is also present. In the crystal, O—H...O hydrogen bonds link the molecules into C(10) chains propagating along the [100] direction. The Hirshfeld surface analysis of the title compound confirms the presence of these intra- and intermolecular interactions. The corresponding fingerprint plots indicate that the most significant contacts in the crystal packing are H...H (76.4%), H...C/C...H (16.3%), and H...O/O...H (7.2%).

Beschreibung: The complete molecule of the title hydrazine carbodithioate derivative, C32H30N4O2S4, is generated by a crystallographic twofold axis that bisects the disulfide bond. The molecule is twisted about this bond with the C—S—S—C torsion angle of 90.70 (8)° indicating an orthogonal relationship between the symmetry-related halves of the molecule. The conformation about the imine bond [1.282 (2) Å] is E and there is limited delocalization of π-electron density over the CN2C residue as there is a twist about the N—N bond [C—N—N—C torsion angle = −166.57 (15)°]. An intramolecular hydroxyl-O—H...N(imine) hydrogen bond closes an S(6) loop. In the crystal, methylene-C—H...π(tolyl) contacts assemble molecules into a supramolecular layer propagating in the ab plane: the layers stack without directional interactions between them. The analysis of the calculated Hirshfeld surfaces confirm the importance of H...H contacts, which contribute 46.7% of all contacts followed by H...C/C...H contacts [25.5%] reflecting, in part, the C—H...π(tolyl) contacts. The calculation of the interaction energies confirm the importance of the dispersion term and the influence of the stabilizing H...H contacts in the inter-layer region.

Beschreibung: In the title compound, C18H19Cl2N3, the planes of the benzene rings subtend a dihedral angle of 77.07 (10)°. In the crystal, molecules are associated into inversion dimers via short Cl...Cl contacts [3.3763 (9) Å]. A Hirshfeld surface analysis indicates that the most important contact percentages for the different types of interactions are H...H (43.9%), Cl...H/H...Cl (22.9%), C...H/H...C (20.8%) and N...H/H...N (8.0%).