ALBERT

Description: Natural gas hydrates form at elevated pressure and low temperatures in the presence of sufficient quantities of gas and water and have therefore been discovered on all continental margins and in permafrost regions. In the marine hydrate-bearing sediments, gas hydrates, depending on their content, can transform a loose sediment into a consolidated rock with a strongly increased strength. In permafrost regions the hydrate stability zone can extent deep into the ice-bearing permafrost and, therefore, both, ice and hydrate can consolidate the sediment. However, the strength of methane hydrate is much higher than that of ice, which behaves much more ductile. Consequently, the resulting strength of a sediment, containing both components, strongly depends on the ice to hydrate ratio. Conversely, the decomposition of natural gas hydrates in marine or permafrost sediments leads to a reduction in the mechanical strength of the host sediment. In addition, the release of gas can create overpressure in the pore spaces, reducing the effective stress and leading to instabilities in the sediment structure. Since both continental margins and permafrost regions are used by humans for various activities that largely depend on the mechanical stability of the sediments, knowledge of the main factors and processes that determine the stability of weakly consolidated sediments is crucial. Both the thawing of ice and the decomposition of gas hydrates in permafrost soils lead to a change in the geo-mechanical properties of the host sediment. The residual and peak shear strengths of ice- and hydrate-bearing sediments were investigated using a ring shear cell developed at the GFZ. Based on literature data and our results, we discuss the dependence of the geo-mechanical properties of sediments on ice and hydrate saturation and the possible consequences if their proportion diminishes.

Description: Natural gas hydrates are crystalline compounds that are formed from hydrogen-bonded water molecules and gas molecules. They mainly contain climate-active CH4, but also other light hydrocarbons, CO2 or H2S They exhibit a high sensitivity to variations in temperature and pressure, mainly driven by environmental changes. The oceanic or atmospheric warming resulting from climate change may trigger the decompositions of hydrates, potentially releasing significant amounts of CH4. To assess the potential risks associated with CH4 release from destabilized hydrate deposits, a precise understanding of the dissociation behaviour of gas hydrates becomes crucial. In this study, a systematic investigation on the dissociation process of sI CH4 hydrates, sII CH4+C3H8 hydrates, and sII multi-component CH4+C2H6+C3H8+CO2 mixed hydrates was reported. We employed a combination of experimental and molecular dynamics (MD) simulations to provide a more nuanced understanding of the hydrate dissociation behaviours, which primarily shed light on the molecular aspects. The dissociation was induced through thermal stimulation to mimic climate warming. Both in situ and ex situ Raman spectroscopic measurements were performed continuously to characterize the hydrate phase. Throughout the dissociation process, hydrate composition, surface morphology, and the large-to-small cavity ratios were determined. MD simulations were carried out under similar conditions, providing advanced insights and perspectives that couldn't be readily extracted from experimental observations alone. Both experimental and simulation outcomes indicate that intrinsic kinetics likely govern the early stage of hydrate dissociation. A significant development in the dissociation process is the hindrance caused by the formation of a quasi-liquid or amorphous phase at the surface of the hydrate particles after the breakup of the outer layer of hydrate cavities. The unstable (partial) hydrate cavities that form within this quasi-liquid phase are oversaturated with gas molecules. Consequently, gas hydrates undergo a cycle of decomposition-reformation-continuing decomposition until the crystal eventually disappears. With decomposition dominating the process, both experimental and numerical simulation results demonstrate that the breakup of large cavities (51262) is faster than that of small ones (512) in sI hydrates. Conversely, a faster breakdown of small 512 cavities in sII hydrates is observed. Additionally, during the dissociation process of sII CH4-C3H8 hydrate, the cavities occupied by CH4 preferentially collapse compared to those filled with C3H8. Similarly, over the dissociation of multi-component hydrate, cavities filled with CH4 exhibit a preferential collapse compared to those filled with C3H8, C2H6, and CO2. These findings show the complexity and differences in the dissociation behavior of natural gas hydrates depending on their composition and structure and can therefore make an important contribution to an accurate assessment of CH4 release from destabilized hydrate deposits in response to climate change.

Description: This dataset is the result of an experimental series that was carried out in September/October 2022 at GFZ German Research Centre for Geosciences, Potsdam, Germany to observe biosorption of lead under extreme conditions. Synthetic solutions, simulating the geothermal fluids from the Heemskerk geothermal power plant were were prepared in 30 ml glass vials (Rotalibo screw neck ND24 EPA). To prepare the stock solutions, sodium chloride (NaCl, 99.8 %, Cellpure, Merck, DE) was added at 265 g/L and Pb(II), in form of lead nitrate (Pb(NO3 )2 , Merck, DE), at 1 g/L to ultrapure water. To assess the impact of acetic acid on lead biosorption, two treatments were done: one without acetic acid and one where acetic acid (100 %, Merck, DE) was added at 60 mg/L. Finally, dead biomass of the fungus Penicillium citrinum was added in the samples at a concentration of 4 g/L (Wahab et al., 2017). The samples were incubated in an autoclave at a pressure of 8 bars on a rotative shaker. The temperature was set at 25 °C, 60 °C or 98 °C with three contact times (1, 2 and 3 h). All treatments were performed in triplicates. For each treatment, two controls without biomass were done. Control samples without the addition of NaCl were done in duplicate, at 25 °C and for 2 h. After incubation, samples were filtered through a 0.22 µm nitrocellulose filter (Sartorius Stedim Biotech, FR) to separate the biomass from the liquid. The biomass on the filters was dried for 24 h at 45 °C before being scraped from the filter and kept in a Falcon tube at room temperature.

Description: Pit lakes in the ‘anthropogenic lake district’ in the Muskau Arch (western Poland; central Europe) are strongly affected by acid mine drainage (AMD). The studied acidic pit lake, ŁK-61 (pH 〈3), is also exposed to floods due to its location in the flood hazard area, which may significantly influence the geochemical behavior of elements. The elemental compositions of water and lake sediment samples were measured with ICP–OES and ICP–MS. The sediment profile was also examined for 137Cs and 210Po activity concentrations using gamma and alpha spectrometry, respectively. Grain size distribution, mineralogical composition, diatoms, and organic matter content in the collected core were also determined. The key factors responsible for the distribution of selected heavy metals (e.g., Cu, Ni, Pb, Zn) and radioisotopes (137Cs and 210Po) in the bottom sediments of Lake ŁK-61 are their coprecipitation/precipitation with Fe and Al secondary minerals and their sorption onto authigenic and allogenic phases. These processes are likely driven by the lake tributary, which is an important source of dissolved elements. The data also showed that the physiochemical parameters of Lake ŁK-61 water changed during an episodic depositional event, i.e., the flood of the Nysa Łużycka River in the summer of 2010. The flood caused an increase in the water pH, as interpreted from the subfossil diatom studies. The down-core profiles of the studied heavy metal and radionuclide (HMRs) contents were probably affected by this depositional event, which prevented a detailed age determination of the collected lake sediments with 137Cs and 210Pb dating methods. Geochemical modeling indicates that the flood-related shift in the physicochemical parameters of the lake water could have caused the scavenging of dissolved elements by the precipitation of fresh secondary minerals. Moreover, particles contaminated with HMRs have also possibly been delivered by the river, along with the nutrients (e.g., phosphorus and nitrogen).

Description: In the race against time, the European Union must move swiftly to navigate the green transition. This imperative isn't just about staying ahead in the global green technology competition; it is about securing the future of Europe's economy while combating climate change. Ahead of the EU elections looming, the urgency of this dual challenge cannot be overstated. With a new pro-EU Polish government in place, the Weimar Triangle - a trilateral forum that brings together Poland, France and Germany - could provide the ideal place to offer a new bold industrial policy leadership in Europe.

Description: Global coupled climate models are in continuous need for evaluation against independent observations to reveal systematic model deficits and uncertainties. Changes in terrestrial water storage (TWS) as measured by satellite gravimetry missions GRACE and GRACE-FO provide valuable information on wetting and drying trends over the continents. Challenges arising from a comparison of observed and modelled water storage trends are related to gravity observations including non-water related variations such as, for example, glacial isostatic adjustment (GIA). Therefore, correcting secular changes in the Earth's gravity field caused by ongoing GIA is important for the monitoring of long-term changes in terrestrial water from GRACE in particular in former ice-covered regions. By utilizing a new ensemble of 56 individual realizations of GIA signals based on perturbations of mantle viscosities and ice history, we find that many of those alternative GIA corrections change the direction of GRACE-derived water storage trends, for example, from gaining mass into drying conditions, in particular in Eastern Canada. The change in the sign of the TWS trends subsequently impacts the conclusions drawn from using GRACE as observational basis for the evaluation of climate models as it influences the dis-/agreement between observed and modelled wetting/drying trends. A modified GIA correction, a combined GRACE/GRACE-FO data record extending over two decades, and a new generation of climate model experiments leads to substantially larger continental areas where wetting/drying trends currently observed by satellite missions coincide with long-term predictions obtained from climate model experiments.

Description: Although many collisional orogens form after subduction of oceanic lithosphere between two continents, some orogens result from strain localization within a continent via inversion of structures inherited from continental rifting. Intracontinental rift-inversion orogens exhibit a range of structural styles, but the underlying causes of such variability have not been extensively explored. We use numerical models of intracontinental rift inversion to investigate the impact of parameters including rift structure, rift duration, post-rift cooling, and convergence velocity on orogen structure. Our models reproduce the natural variability of rift-inversion orogens and can be categorized using three endmember styles: asymmetric underthrusting (AU), distributed thickening (DT), and localized polarity flip (PF). Inversion of narrow rifts tends to produce orogens with more localized deformation (styles AU and PF) than those resulting from wide rifts. However, multiple combinations of the parameters we investigated can produce the same structural style. Thus, our models indicate no unique relationship between orogenic structure and the conditions prior to and during inversion. Because the style of rift-inversion orogenesis is highly contingent upon the rift history prior to inversion, knowing the geologic history that preceded rift inversion is essential for translating orogenic structure into the processes that produced that structure.

Description: The investigation of key minerals including zircon, apatite, titanite, rutile, monazite, xenotime, allanite, baddeleyite and garnet can retain critical information about petrogenetic and geodynamic processes and may be utilized to understand complex geological histories and the dynamic evolution of the continental crust. They act as small but often robust petrochronological capsules and provide information about crustal evolution, from local processes to plate tectonics and supercontinent cycles. They offer us insights into processes of magmatism, sedimentation, metamorphism and alteration, even when the original protolith is not preserved. In situ techniques have enabled a more in-depth understanding of trace element behaviour in these minerals within their textural context. This has led to more meaningful ages for many stages of geological events. New developments of analytical procedures have further allowed us to expand our petrochronological toolbox while improving precision and accuracy. Combining multiple proxies with multiple minerals has contributed to new interpretations of the crustal history of our planet.

Description: GPS satellite observations indicate that in the tectonically complex eastern Mediterranean and east African regions microplates rotate counterclockwise with respect to the neighboring African plate. Using 3D numerical models, Glerum relates these observations of crustal deformation to the dynamics of the lithosphere and the underlying mantle that may cause this deformation. Glerum first describes her additions to the ASPECT software necessary for numerically modeling the upper mantle and lithosphere dynamics of convergent and divergent plate boundaries. These additions include the tracking of multiple materials with different physical properties and nonlinear viscous as well as viscoplastic rheologies. The implementations of complex, multi-material rheologies are verified with well-known 2D benchmarks and multi-material viscoplasticity is applied in 3D time-dependent thermomechanical models of oceanic subduction. Subsequently, Glerum uses ASPECT to investigate the sensitivity of horizontal surface motions to individual geodynamic processes in the eastern Mediterranean. Identification of all mantle drivers that should participate in modeling attempts to explain observations of crustal flow is essential to fully exploit the information contained by surface motions about their driving processes. Glerum therefore employs 3D data-driven instantaneous dynamics models of compressible flow including a complete set of possible mantle drivers of surface deformation. The reference instantaneous flow model results indicate that mantle processes can explain a large part of the crustal motion of the Aegean-Anatolian microplate. Subsequent systematic perturbations of model properties with respect to this reference model help estimate the individual contributions of tectonic plate motions, slab pull and trench suction, and density-induced mantle flow interacting with the slab and overlying plates while moderated by the mantle’s bulk viscosity. In order of regional importance, the predicted crustal flow of the Aegean-Anatolian region is most sensitive to slab pull, followed by slab-mantle interaction and basal drag, mantle rheology, and the absolute plate motion reference frame. Lastly, Glerum demonstrates a possible mechanism for the counterclockwise rotation of the Victoria microplate in the East African Rift System, which is in striking contrast to the clockwise motion of the surrounding plates. 3D models of the divergent system show that Victoria’s rotation can be caused by the drag of the African and Somalian plates along the strong edges of the microplate, while the rift segments along inherited lithospheric weaknesses facilitate Victoria’s rotation. The amount of rotation is therefore primarily controlled by the distribution of preexisting stronger regions and the weaker Precambrian mobile belts that surround Victoria. The induced counterclockwise rotation of the microplate leads to a clockwise shift of the local extension direction from E-W to more WNW-ESE along the overlapping rift branches. Comparison of the resulting predicted stress field and tectonic regimes to observations helps to elucidate the interpretation of local stress and strain indicators and to reconcile different opening models used to interpret the East African Rift System.