ALBERT

Description: Real-world labs are witnessing continued growth and institutionalization in the field of transformation-oriented sustainability research, as well as in adjacent disciplines. With their experimental research agendas, these labs aim at sustainability transformations, however, there is still a need to improve the understanding of their impacts. Drawing from this Special Issue's contributions, we offer a broad overview of the impacts achieved by various real-world labs, highlight the diverse areas and forms of impact, and elucidate strategies as well as mechanisms for achieving impact. We present methodological advances, and address common challenges along with potential solutions for understanding and realizing impact.

Description: Natural alteration of zircon takes place in melts or fluids either via dissolution coupled with overgrowth or via a coupled dissolution-reprecipitation process. The latter results in the zircon being partially or totally replaced by new, compositionally re-equilibrated zircon or a new mineral phase or both. In this study, fragments (50–300 μm) from a large, inclusion-free, clear, 520–530 Ma euhedral zircon with light radiation damage from a nepheline syenite pegmatite, Seiland Igneous Province, northern Norway, were experimentally reacted in 20 mg batches with 5 mg of ThO2 + ThSiO2 + SiO2 and a series of alkali-bearing fluids in sealed Pt capsules at 900 °C and 1000 MPa for 6–11 days in the piston cylinder press using a CaF2 setup with a cylindrical graphite oven. ThO2 + ThSiO2 + SiO2 was present at the end of the experiment. In experiments involving H2O, H2O + NaCl, H2O + KCl, and 2 N KOH, no reaction textures formed other than a slight dissolution of the zircon grain fragments. Experiments involving 2 N NaOH, Na2Si2O5 + H2O, and NaF + H2O resulted in zircon reaction textures with varying degrees of intensity, which took the form of partial replacement by compositionally modified zircon via a coupled dissolution-reprecipitation process. In the NaF + H2O experiment some overgrowth also occurred. Altered zircon is separated by sharp compositional boundaries from unaltered zircon. Secondary ion mass spectrometry (SIMS) and laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) analysis indicates that, relative to the unaltered zircon, the altered zircon is strongly enriched in Th, and heavily to moderately depleted in U and (Y + REE). In all the experiments, 206Pb (3–5 ppm in unaltered zircon) is depleted in the altered zircon to below the SIMS detection limit and to at or below the LA-ICP-MS detection limit. Hafnium and Ti concentrations in the altered zircon retained the same approximate value (within error) as the original zircon. The results from these experiments demonstrate that zircon can be compositionally modified by alkali-bearing and alkali-F-bearing fluids via a coupled dissolution-reprecipitation process. Near to total loss of radiogenic Pb via such processes under high-grade conditions resets the internal zircon geochronometer. Although the end result is the same as with zircon overgrowth, i.e. the production of new generation zircon at the time of a metamorphic/metasomatic event, such replacement processes can explain incomplete isotopic ‘resetting’; inclusion production through unmixing of solid solutions in metastable zircon compositions; and ‘ghost’ textures that preserve initial growth features but with isotopic disturbance. Diagnostic replacement features produced in experiments, such as interface geometries between altered and unaltered zircon, provide markers of the mechanism and aid in zircon interpretation. A major implication from this study is that if zircon with low radiation damage can be metasomatically altered under high-grade conditions, this would have important consequences with respect to zircons presumed role as an impregnable container for mineral inclusions. Namely the mineral inclusions contained within zircon could also be altered, reset as a geochronometer, or even replaced by another mineral.

Description: Earlier experiments have shown that cyclic hydraulic fracturing (CHF) systematically reduces the monotonic breakdown pressure (MBP). However, cyclic injection also causes a significantly longer injection time to failure as compared to the monotonic injection tests and complex fracture propagation that is hard to predict. In this study, a different injection scheme employing rock fatigue behavior, named creep injection, was tested on granite cylinders. The creep injection creates continuous pressurization under a constant borehole pressure (CBP) with a pre-defined maximum value below the MBP. Three different pressure ratios (CBP/MBP) of 0.85, 0.9 and 0.95 were tested. We found that both the CHF and hydraulic fracturing with creep injection can reduce the breakdown pressure by ca. 15 ~ 20% without confining pressure. Two mechanisms could explain the reduction: the influence of fluid infiltration within the theory of linear poroelasticity and stress corrosion within the subcritical crack growth theory. The lifetime of the granite cores subjected to creep injection is comparable with previous CHF experiments employing the same pressure ratio. In addition, the lifetime increases logarithmically when the ratio of CBP/MBP is decreased. This relationship has a high regression coefficient of R2 = 0.97, and the lifetime can be well predicted using a stress corrosion index of 70. On the contrary, CHF shows a significantly larger variance in the lifetime with a regression coefficient of R2 = 0.19 and, therefore, is hard to predict. Our results also point out that the injection scheme can modify hydraulic fracture patterns, in terms of fracture aperture, branching, and fracture propagation.

Description: Qongjiagang pegmatite-type Li deposit in Tibet is the first discovered pegmatite-type deposit with economic value in the Himalayan region, which confirms that the Himalayan region has the potential to become a strategic base of rare metal in China, and provide indications to find pegmatite-type Li deposit in the Himalayan region. In this study, we use SEM to identify the type, frequency and occurrence (relationship with cracks) of mineral inclusions in the three main accessory minerals, monazite, apatite and zircon from granite and pegmatite of Qongjiagang Li deposit, combining with the EPMA analysis of feldspar inclusions in apatite to comprehensively trace the property and evolution of the melts and fluids. Our study indicates that: (1) the main mineral inclusions in monazite, apatite and zircon from Qongjiagang Li deposit include silicate, oxide, phosphates and a small amount of sulfide, not only the REE-rich monazite and apatite filling or intersecting cracks are formed by hydrothermal alteration, but also the uraninite and thorianite isolated from cracks occur in the self-irradiation region of zircon are related to fluids; (2) the appearances of columbite and pyrochlore inclusions in the apatite from tourmaline-muscovite granite demonstrate that the initial melt is enriched in Nb and Ta, the amount and type of rare metal mineral inclusions can be used as an indicator for rare metal mineralization in highly evolved granite and pegmatite; (3) the plagioclase inclusions with high and a large range of An values in apatite from spodumene pegmatite represent the capture of less-differentiated melt and continuously fractional crystallization. Our results indicate that the types and compositions of mineral inclusions in accessory minerals can be good tracers for the characteristics and evolution of melts and fluids in the highly evolved granite-pegmatite system

Description: This publication provides the codes produced for the article "Temporally dynamic carbon dioxide and methane emission factors for rewetted peatlands. Nature Communications Earth and Environment" by Aram Kalhori, Christian Wille, Pia Gottschalk, Zhan Li, Josh Hashemi, Karl Kemper, and Torsten Sachs (https://doi.org/10.1038/s43247-024-01226-9). In the article, the authors estimate the cumulative GHG emissions of a rewetted peatland in Germany using the long-term ecosystem flux measurements. They observe a source-to-sink transition of annual carbon dioxide (CO2) fluxes and decreasing trend of methane (CH4) emissions. This software is written in R and MATLAB. Running the codes ([R files and .m files](Code)) and loading the data files ([CSV files and .mat files](Data)) requires the pre-installation of [R and RStudio] (https://posit.co/downloads/) and ([MATLAB]. The RStudio 2022.07.2 Build 576 version has been used for the R scripts. The land cover classification work was performed in QGIS, v.3.16.11-Hannover. Data were analyzed in both MATLAB and R and plots created with R (R Core Development Team 2020) in RStudio®.

Description: The data provided here is an exemplary dataset for the flux site Zarnekow from one year (2018). The complete dataset that is needed to run the codes for all the years can be obtained from the European Fluxes Database Cluster under site ID DE-Zrk (Sachs et al., 2016) or provided upon request. This repository is intended to provide the necessary MATLAB and R code to reproduce the results by Kalhori et al. (2024). The data are provided as zip folder containing (1) a csv file with associated definition of variables and units (file: 2023-004_Kalhori-et-al_README_2018_units.txt), (2) a shapefile (file: 2023-004_Kalhori-et-al_2018_LAiV_DOP.shp) and (3) a Geotiff (file: 2023-004_Kalhori-et-al_2018_LAiV_DOP.tiff).

Description: The West Siberian Seaway connected the Tethys to the Arctic Ocean in the Paleogene and played an important role for Eurasian-Arctic biogeography, ocean circulation, and climate. However, the paleogeography and geological mechanisms enabling the seaway are not well constrained, which complicates linking the seaway evolution to paleoenvironmental changes. Here, we investigate the paleogeography of the Peri-Tethys realms for the Cenozoic time (66–0 Ma), including the West Siberian Seaway, and quantify the influence of mantle convection and corresponding dynamic topography. We start by generating continuous digital elevation models for Eurasia, Arabia, and Northern Africa, by digitizing regional paleogeographic maps and additional geological information and incorporate them in a global paleogeography model with nominal million-year resolution. Then we compute time-dependent dynamic topography for the same time interval and find a clear correlation between changes in dynamic topography and the paleogeographic evolution of Central Eurasia and the West Siberian Seaway. Our results suggest that mantle convection played a greater role in Eurasian paleogeography than previously recognized. Mantle flow may have influenced oceanic connections between the Arctic and global ocean providing a link between deep mantle convection, surface evolution, and environmental changes. Our reconstructions also indicate that the Arctic Ocean may have been isolated from the global ocean in the Eocene, even if the West Siberian Seaway was open, as the Peri-Tethys – Tethys connection was limited, and the Greenland-Scotland Ridge was a landbridge.

Description: Lower crustal flow in regions of post-orogenic extension has been inferred to explain the exhumation of metamorphic core complexes and associated low-angle normal (detachment) fault systems. However, the origin of detachment faults, whether initially formed as high-angle or low-angle shear zones, and the extension is symmetric or asymmetric remains enigmatic. Here, we use numerical modeling constrained by geophysical and geological data to show that symmetric extension in the central Menderes Massif of western Anatolia is accommodated by the crustal flow. Our geodynamic model explains how opposite dipping Gediz and Büyük Menderes detachment faults are formed by ∼40° footwall rotation. Model predictions agree with seismic tomography data that suggests updoming of lower crust beneath the exhumed massifs, represented as “twin domes” and a flat Moho. Our work helps to account for the genetic relation between the exhumation of metamorphic core complexes and low-angle normal faulting in both Cordillera and Aegean orogenic regions and has important implications on crustal dynamics in extensional provinces.

Description: The geoid is an equipotential surface that broadly mimics the mean sea level. The difference between the geoid and the reference spheroid at any location is referred to as a geoid anomaly. The geoid ‘highs’ (positive) or ‘lows’ (negative) are primarily associated with mass anomalies, thereby could offer important information about compositional and thermal properties in the Earth's interior. The maximum geoidal surplus (+85 m) is observed to the east of New Guinea whereas the largest deficit (−106 m) is observed in the Indian Ocean south of Sri Lanka – commonly known as the Indian Ocean geoid low (IOGL). On a global geoid map, the IOGL anomaly covers an extensive circular area spanning 〉2000 km in diameter (Fig. 1). Several different hypotheses have been put forth to explain this enigmatic anomaly. These include effects of isostatically uncompensated crust (Ihnen and Whitcomb, 1983), depression in the core-mantle boundary (Negi et al., 1987), slab graveyards in the mantle (Spasojevic et al., 2010), anomalous variations in the mantle transition zone (Reiss et al., 2017; Rao et al., 2020) and presence of a very low-velocity material arising from the African large low shear velocity province (LLSVP) or simply known as the African superplume (Ghosh et al., 2017). Most of these hypotheses rely upon either very sparse seismological observations, numerical modelling or remote sensing data. Global seismic tomographic models provide first-order information about the Earth's interior (Simmons et al., 2010, Simmons et al., 2012, Simmons et al., 2015). However, the uneven distribution of seismological networks has stymied production of high-resolution sub-surface images. In search of concrete causative mechanisms behind the IOGL anomaly, deep seismological observations from the Indian Ocean have been awaited for a long time. Between 2015 and 2020, the Ministry of Earth Sciences (MoES) India deployed a focused linear broadband passive seismological array comprising 17 ocean bottom seismometers (OBS) for two successive seasons comprising 14 months each (Fig. 1). These OBS stations thus continuously recorded local and teleseismic events for 〉28 months (Pandey, 2017). Besides, some recent studies also carried out active OBS deployments in this region to evaluate crustal and upper mantle structures (Pandey et al., 2022; Ningthoujam et al., 2022; Altenbernd-Lang et al., 2022). This special issue was conceived to present a compilation of new field observations as well as numerical modelling studies to infer potential mass anomalies within the crust and mantle beneath the IOGL region. A collection of nine papers presented in this volume explore the role of causative sources at varying depths to explain the IOGL anomaly. In summary, scientific contributions in this special issue suggest minimal crustal contributions towards the spectacular IOGL anomaly. On the other hand, new seismological studies suggest that the IOGL anomaly can be reasonably explained by a combination of positive mass anomalies in the lower mantle and/or negative mass anomalies in the upper mantle. Varied outcomes further stress upon the need to carry out more long-term seismological observations in order to image precise mantle structure beneath the IOGL region.

Description: The detection of geothermal anomalies using Thermal Infrared (TIR) remote sensing data is challenging because of how sensor specifications (such as the infrared wavelength used for the measurement, spectral dependence of the emissivity, angle at which the measurement is made, state of the surface and height of the sensor above the surface) and physical parameters (such as solar radiation, topography, albedo, soil compaction and coherence of rocks) affect Land Surface Temperature (LST) retrieval and analysis. This work tests whether TIR remote sensing measurements with thorough spatial and temporal sampling can improve LST retrievals. Multi-temporal TIR data from 2000 through 2019 from Landsat 7 and 8 TIR instruments and the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) were used to detect geothermal areas in the geologically active region of the southern Main Ethiopian Rift. In addition, field-based temperature data from 19 sites were evaluated for comparison to the remotely detected geothermal anomaly areas. We have used the single-channel algorithm and Normalized Difference Vegetation Index (NDVI) method of emissivity retrieval to derive LST for each year. The result shows that the mean LST is highest in 2003 (320.1 K) and lowest in 2019 (303.1 K). The change in mean LST was between −9 K to 13 K. These LST results from ASTER images were validated with MODIS LST products and showed a correlation coefficient 〉0.6. LST of the year 2003 has been much closer to the actual temperature value from field data. Fifteen sites (79%) fit with the identified geothermal anomaly areas. LST values in known geothermal activity sites show no correlation (〈 0.5) with time attesting. That is, even though LST varies with time (e.g., day and night and seasonal changes), the LST of areas with geothermal potential remain more or less constant on yearly basis.