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  • 1
    Publication Date: 2021-03-29
    Description: Photooxidants play an important role for the oxidation capacity of the troposphere. The presented work deals with seasonal changes of atmospheric photooxidants like hydrogen peroxide (H2O2), methylhydroperoxide (MHP) and formaldehyde (HCHO). The principal purpose was to follow and quantify the mixing-ratios of these photochemical species for the first time over a complete annual cycle in Antarctica. During two field campaigns at the German Antarctic station Neumayer (overwintering campaign from January 1997 until March 1998 and a shorter campaign from January to March 1999) continuous measurements of atmospheric mixing-ratios were performed. A continuous wet-chemical technique was used for peroxides and formaldehyde sampling and analysis. Species were quantified by fluorescence detection. In order to compare the results and measurements with well-known reaction mechanisms a photochemical box model was applied. The obtained time series show a pronounced seasonal variation with higher values during summer. For the first time atmospheric concentrations of H2O2, MHP and HCHO were documented during polar night in winter. The mixing-ratios were significantly higher than expected due to missing actinic radiation essential for photochemical production. Trajectory analyses and calculations with a three-dimensional model showed that during winter the mixing-ratios of photooxidants are mainly affected by long-range transport in the free troposphere. Investigations during the Antarctic ó́zone hole period ́́show no significant impact of the increased UV-B radiation on the photooxidants. The findings of this work contribute to a better understanding of the photochemistry of the investigated trace gases in the clean troposphere of Antarctica and provide a useful data record for further photochemical modeling.
    Description: thesis
    Keywords: 551.5 ; 551.9 ; 550 ; TYY 200 ; TVA 210 ; Antarktis {Meteorologie und Klimatologie} ; Chemische Zusammensetzung der Atmosphäre {Meteorologie}
    Language: German
    Type: monograph , publishedVersion
    Format: 176 S.
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  • 2
    Publication Date: 2021-03-29
    Description: Besides measurements of atmospheric trace gases and laboratory studies of chemical reactions, modelling has been recognised to be of increasing importance to improve our knowledge of the atmosphere and the capabilities of photochemical models. Main scope of this work was the development of a photochemical atmospheric model, which was especielly designed for the interpretation of Differential Optical Absorption measurments (DOAS). This model has been used to improve our knowledge of atmospheric chemistry. For example, for the first time it was possible to demonstrate that a significant amount of IO in a range of 0.65 to 0.8 pptv is present in the stratosphere in the polar region (Ny-Alesund,Spitzbergen). Moreover it has been shown that such amounts of stratospheric IO lead to an additional Ozone loss in the range of 10 % in cold arctic winters.
    Description: thesis
    Keywords: 551.5 ; 550 ; TUA 700 ; TVA 210 ; Verfahren zur Untersuchung der freien Atmosphäre {Meteorologie} ; Chemische Zusammensetzung der Atmosphäre {Meteorologie}
    Language: German
    Type: monograph , publishedVersion
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  • 3
    Publication Date: 2021-03-29
    Description: Ozone profile retrieval, ERS-2, GOME, FURM, ozone decline, Northern hemisphere. - Measurements of stratospheric ozone over the Northern hemisphere forthe winter/spring periods of 1997 to 2000 taken with the GOMEinstrument were used to derive the chemical ozone depletion inside thepolar vortex. GOME onboard the ERS-2 satellite measures radiationcoming from the Earth in the UV/vis spectral range.To discern the chemical depletion from dynamical influences, a modelwas developed to calculate vortex averaged diabatic descent ratesusing the radiative transfer model MIDRAD and the FURM ozoneprofiles. The permeability of the Arctic vortex was analysed by usingthe trajectory model TANGO in conjunction with a reverse domainfilling algorithm, developed within the framework of this thesis.The chemical ozone ...
    Description: thesis
    Keywords: 551.5 ; 550 ; TUA 850 ; TVA 210 ; TY 100 ; Satellitenmeteorologie ; Chemische Zusammensetzung der Atmosphäre {Meteorologie} ; Nördliche Hemisphäre {Meteorologie und Klimatologie}
    Language: German
    Type: monograph , publishedVersion
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  • 4
    Publication Date: 2021-03-29
    Description: Die Arbeit untersucht, inwieweit die rechnergestützte Analyse digitaler Luft- und Satellitenbilddaten bestehende Verfahren im Umweltmonitoring optimieren kann. Zunächst wird der Stand der Forschung im Bereich "Fernerkundung im Umweltmonitoring" dokumentiert, bevor die verschiedenen Vorprozessierungen (Mosaikierung, Atmosphärenkorrektur etc.) der Daten erläutert werden. Anschließend wird der Stand der Forschung für Klassifikationsverfahren und Methoden der Veränderungsanalysen erarbeitet, bevor die eigenen zum Teil neu entwickelten Verfahren/Methoden angewandt werden; die Nachvollziehbarkeit bildet hier einen Schwerpunkt. Die Ergebnisse münden in einen Praxisleitfaden. Die kritische Auseinandersetzung mit möglichen Fehlerquellen soll dem Leser helfen, die Leistungsfähigkeit der Verfahren abzuschätzen. Ein Ausblick auf zukünftige Einsatzmöglichkeiten von Fernerkundungsdaten im Umweltmonitoring bildet den Schluß; im Vordergrund stehen ethische Fragen sowie die Rolle des Internets.
    Description: thesis
    Keywords: 550.28 ; 550 ; VBH 000 ; Fernerkundung
    Language: German
    Type: monograph , publishedVersion
    Format: 338 S.
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  • 5
    Publication Date: 2021-03-29
    Description: Ozone chemistry, tracer measurements, radiometry, airborne,submillimeterwave, Arctic, stratosphere. - The Airborne Submillimeter Radiometer (ASUR) is a passive heterodyne instrument using a superconducting detector with an instrumental frequency range from 604.3 to 662.3 GHz.Operating onboard an aircraft to avoid absorption by tropospheric water vapor key species of the stratospheric ozone chemistry can be detected for a vertical altitude range from 15 to 55 km. In the winter 1999/2000 the ASUR instrument participated in the THESEO 2000/SOLVE project onboard the NASA research aircraft DC-8. Three deployments were carried ...
    Description: thesis
    Keywords: 551.5 ; 550 ; TUA 800 ; TVA 210 ; TYY 100 ; Radarmeteorologie ; Chemische Zusammensetzung der Atmosphäre {Meteorologie} ; Arktis {Meteorologie und Klimatologie}
    Language: German
    Type: monograph , publishedVersion
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  • 6
    Publication Date: 2021-03-29
    Description: Die Gesetzmäßigkeiten zwischen dem Stickstoffhaushalt und dem Feuchteregime von Pseudogleyen werden analysiert. Neben der standortbezogenen Quantifizierung und Bilanzierung des Stickstoff- und Bodenwasserhaushaltes ist der Stellenwert der Denitrifikation im Stauwasserbereich abgeschätzt worden. Die Untersuchungen haben gezeigt, daß die grundsätzlichen Vorstellungen über die Prozesse des Stickstoffumsatzes in ackerbaulich genutzten Böden auch auf landwirtschaftlich genutzten Pseudogleyen zutreffen. Es konnte jedoch darüber hinaus in kombinierten Freilanduntersuchungen und Bodensäulenexperimenten nachgewiesen werden, daß die Dynamik des Bodenwassers (Wechselfeuchtephasen) auf die Denitrifikationsraten einen größeren Einfluß hat als der absolute Wassergehalt. Abschließend wird der Praxisbezug zur Denitrifikation landwirtschaftlich genutzter Pseudogleye aufgezeigt.
    Description: thesis
    Keywords: 531.43 ; 550
    Language: German
    Type: monograph , publishedVersion
    Format: 252 S.
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  • 7
    Publication Date: 2021-03-29
    Description: thesis
    Keywords: 551.5 ; 550 ; TUA 850 ; TUA 500 ; TVA 210 ; Satellitenmeteorologie ; Meteorologische Modelle ; Chemische Zusammensetzung der Atmosphäre {Meteorologie}
    Language: German
    Type: monograph , publishedVersion
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  • 8
    Publication Date: 2021-03-29
    Description: Die Arbeit leistet einen wesentlichen Beitrag zum geodynamischen Verständnis der kretazischen Inselbogen-Kontinent-Kollision und von subsequenten Exhumierungprozessen in Zentralkuba bei. Grundlage hierfür sind die zeitliche Fixierung von Metamorphose- und Exhumierungsereignissen, insbesondere von HP-Metamorphiten des Escambray Massivs, die petrogenetische Diskussion und die Datierung von Inselbogenmagmatiten. Aufgrund dieser neuen Datenbasis vom N-Rand der Karibischen Platte können entscheidende Impulse für die plattentektonische Rekonstruktion des karibischen Raumes vom oberen Jura bis in das mittlere Tertiär gegeben werden. Außerdem versteht sich die Arbeit als Evaluation der Anwendbarkeit geochronologischer Methoden bei der Datierung von subduktionsgebundenen HP-Metamorphiten. Insgesamt stellt die Arbeit durch die Synthese von geochemisch-geochronologischen, petrologischen und strukturgeologischen Daten ein Novum in der Geologie Kubas dar.
    Description: thesis
    Keywords: 551.701 ; 552.4 ; 550 ; VBN 500 ; VKB 296 ; VEW 200 ; VDH 300 ; VAE 400 ; Geochronologie einzelner Regionen im allgemeinen ; Metamorphe Komplexe; Südamerika {Petrologie} ; Karibischer Raum {Geologie} ; Kreide ; Tektogenese {Geologie}
    Language: German
    Type: monograph , publishedVersion
    Format: 227 S.
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  • 9
    Publication Date: 2021-03-29
    Description: Thermohaline circulation, variability, energy and moisture balance model, paleoceanography. - Freshening of high latitude surface water can change the large scale oceanic transport of heat and salt. Consequently, atmospheric and sea ice perturbations over the deep water production sites excite a large scale response establishing an oceanic t̀̀eleconnection'' with time scales of years to centuries. To study these feed-backs, an atmospheric energy and moisture balance model (EMBM), predicting the heat and fresh water fluxes at the surface, and a thermodynamic sea ice model were constructed and coupled to the GFDL ocean model MOM2. The heat and moisture transports by transient eddies in the EMBM are parameterized by diffusion. The coupled model reproduces many aspects of today's oceanic circulation. The most interesting features of the coupled model are the sensitivity of the thermohaline circulation to changes in the configuration, the multidecadal variability in the ocean-sea ice system, and the behaviour of the thermohaline circulation during transitions between glacial and interglacial periods. A very strong thermohaline circulation develops in the coupled system that is not evident in the stand-alone ocean model. An interesting aspect of this behaviour is the existence of a maximum strength in the overturning. Beyond this maximum, evaporation in the subtropics cannot balance the northward salt-transport. As a result, the watermasses over the deep water production sites become fresher, leading to a collapse of the thermohaline circulation. The associated changes in the sea ice cover prevent the system to recover. ...
    Description: thesis
    Keywords: 551.6 ; 550 ; QDC 200 ; Synoptische Klimageographie ; Wärme- und Strahlungshaushalt der Atmosphäre {Meteorologie} ; Statistische Klimatologie und Klimatologische Modelle ; Klimaänderungen
    Language: German
    Type: monograph , publishedVersion
    Format: 132 S.
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  • 10
    Publication Date: 2021-03-29
    Description: Sea-ice, Finite Element Sea-Ice Model, Kalman Filter, Data Assimilation. - The Arctic region is sensitive to climate change. Since the Arctic sea-ice cover influences the surface heat budget of the Earth the observed sea-ice decline is seen as an indication of global warming. Furthermore, the dynamics of sea ice plays an important role for the sea-ice mass distribution in the Arctic, for the production of dense, cold, and salty water in the Arctic Ocean, which contributes to the thermohaline circulation, and also for the freshwater budget of the Nordic Seas. Thus, a realistic description of sea-ice motion is important to draw conclusions for the mass transport and sea-ice mass distribution. The Finite-Element Sea-Ice Model simulates the large-scale physical sea-ice processes like the sea-ice growth and circulation realistically. The model domain covers the entire Arctic Ocean and its marginal seas. Together with the Singular Evolutive Interpolated Kalman (SEIK) Filter and remotely sensed sea-ice drift observations this sea-ice model is applied for data assimilation to investigate details of the sea-ice dynamics. So far, drift assimilation has been carried out to analyze and modify only the drift field with subsequent computation of the advection or redistribution of ice mass which corresponds more to the physical model behavior than a statistical analysis that the SEIK Filter provides. The sea-ice drift data assimilation with the SEIK Filter achieves drift modification and furthermore changes in the two other sea-ice variables concentration and thickness. The modifications of these "unobserved variables" (within the meaning of data assimilation) are validated and it is found that they are in good agreement for at least 2 months for the sea-ice thickness and even 4 months for the sea-ice concentration which is the longest period examined. The drift improvement is achieved due to the sea-ice concentration and ...
    Description: thesis
    Keywords: 551 ; 550 ; VAQ 990 ; VAQ 500 ; TVH 100 ; TOY 000 ; Meereis {Glaziologie} ; Gletscherbewegung und Gletscherschwankungen ; Wärme- und Strahlungshaushalt der Atmosphäre {Meteorologie} ; Energiebilanzen in der Geodynamik {Geophysik}
    Language: German
    Type: monograph , publishedVersion
    Format: 141 S.
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