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  • CO2
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  • 1
    Publication Date: 2021-03-29
    Description: According to a model by Cerling (1991, 1999), the carbon isotope composition of calcretes should depend on the soil type and the CO2-concentration in the atmosphere. We have tested Cerling’s model by investigating 14 Palaeozoic sections with soil profiles. A large number of carbonate types of different genetic origin exist in the localities examined. Comparing the Palaeozoic samples with recent and subrecent calcretes, it can be demonstrated that anhedral, cryptocrystalline (〈10 μm) and subhedral microcrystalline (10 - 40 μm) carbonates are clearly of pedogenic origin. Crystals of larger size with a poikilotopic texture are of groundwater or burial diagenetic origin. Macro- and micromorphological features, typical of recent calcretes, occur in several soil profiles, but thin section microscopy reveals a strong diagenetic overprint of most pedogenic carbonates. Time equivalent sections with comparable soil types (protosols, calcisols and vertisols) show large variations in carbon isotope composition. On the other hand, different carbonate generations at one site do not differ much. Therefore Palaeozoic calcretes appear to be unsuitable for a deduction of the Palaeozoic CO2-concentration.
    Description: German Research Foundation (DFG)
    Description: research
    Keywords: 551.9 ; 552.5 ; VKB 350 ; VJJ 110 ; VCA 300 ; VKB 332 ; VKA 300 ; VKB 371 ; VEA 000 ; VKB 372 ; Lithogenese {Sedimentologie} ; Geochemie der Stabilen Isotopen ; Paläozoische Geologie ; Sedimentationsbedingungen ; Petrogenese ; Klastische Sedimentgesteine ; Europa insgesamt {Geologie} ; Karbonatische Sedimentgesteine ; Kohlenstoffkreislauf ; C-isotope ; Jungpaläozoikum ; Paläopedologie ; Kalkkruste ; CO2 ; calcrete ; carbon cycle ; upper Paleozoic ; paleosol ; C-13/C-12 ; Europa ; paläoklima ; Europe ; 38.41 ; 38.61 ; 38.32
    Language: English
    Type: article
    Format: application/pdf
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  • 2
    Publication Date: 2023-09-13
    Description: Atmospheric carbon dioxide concentrations (pCO〈sub〉2〈/sub〉) beyond ice core records have been reconstructed from δ〈sup〉11〈/sup〉B derived from planktic foraminifera found in equatorial sediment cores. Here, I applied a carbon cycle model over the Plio‐Pleistocene to evaluate the assumptions leading to these numbers. During glacials times, simulated atmospheric pCO〈sub〉2〈/sub〉 was unequilibrated with pCO〈sub〉2〈/sub〉 in the equatorial surface ocean by up to 35 ppm while the δ〈sup〉11〈/sup〉B‐based approaches assume unchanged (quasi)equilibrium between both. In the Pliocene, δ〈sup〉11〈/sup〉B‐based estimates of surface ocean pH are lower in the Pacific than in the Atlantic resulting in higher calculated pCO〈sub〉2〈/sub〉. This offset in pH between ocean basins is not supported by models. To calculate pCO〈sub〉2〈/sub〉 in surface waters out of the δ〈sup〉11〈/sup〉B‐based pH some assumptions on either total alkalinity or dissolved inorganic carbon are necessary. However, the assumed values of these under‐constrained variables were according to my results partly inconsistent with chemically possible combinations within the marine carbonate system. The model results show glacial/interglacial variability in total alkalinity of the order of 100 μmol/kg, which is rarely applied to proxy reconstructions. Simulated atmospheric pCO〈sub〉2〈/sub〉 is tightly (r〈sup〉2〈/sup〉 〉 0.9) related to equatorial surface‐ocean pH, which can be used for consistency checks. Long‐term trends in volcanic CO〈sub〉2〈/sub〉 outgassing and the strength of the continental weathering fluxes are still unconstrained, allowing for a wide range of possible atmospheric pCO〈sub〉2〈/sub〉 across the Plio‐Pleistocene. Nevertheless, this carbon cycle analysis suggests that reported atmospheric pCO〈sub〉2〈/sub〉 above 500 ppm in the Pliocene might, for various reasons, need to be revised to smaller numbers.
    Description: Key Points: Simulated equatorial surface ocean 𝑝CO〈sub〉2〈/sub〉 is near‐equilibrium with atmosphere during interglacials but enriched (≤35 ppm) during glacials. Models suggest similar equatorial surface 𝑝H in Pacific and in Atlantic in high CO〈sub〉2〈/sub〉 worlds while Pliocene reconstructions show offsets. Carbon cycle model analysis suggests that reported CO〈sub〉2〈/sub〉 values above 500 ppm in the Pliocene might need revisions to smaller numbers.
    Keywords: ddc:551 ; carbon cycle ; modeling ; CO2 ; boron isotopes ; pH ; Plio‐Pleistocene
    Language: English
    Type: doc-type:article
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  • 3
    Publication Date: 2024-04-25
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉The seasonal deposition and sublimation of CO〈sub〉2〈/sub〉 constitute a major element in the Martian volatile cycle. Here, we propose to use the shadow variations of the ice blocks at the foot of the steep scarps of the North Polar Layered Deposits (NPLD) to infer the vertical evolution of the seasonal deposits. We conduct an experiment at a steep scarp centered at (85.0°N, 151.5°E). We assume that no snowfall remains on top of the selected ice blocks, the frost ice layer is homogeneous around the ice blocks and their surroundings, and no significant moating is present. We show that the average thickness of the seasonal deposits due to snowfalls in Mars Year 31 is 0.97 ± 0.13 m at Ls = 350.7° in late winter. The large depth measured makes us wonder if snowfalls are more frequent and violent than previously thought. Meanwhile, we show that the average frost thickness in Mars Year 31 reaches 0.64 ± 0.18 m at Ls = 350.7° in late winter. Combined, the total thickness of the seasonal cover in Mars Year 31 reaches 1.63 ± 0.22 m at Ls = 350.7° in late winter, continuously decreases to 0.45 ± 0.06 m at Ls = 42.8° in middle spring and 0.06 ± 0.05 m at Ls = 69.6° in late spring. These estimates are up to 0.8 m lower than the existing Mars Orbiter Laser Altimeter results during the spring. Meanwhile, we observe that snow in the very early spring of Mars Year 36 can be 0.36 ± 0.13 m thicker than that in Mars Year 31. This study demonstrates the dynamics of the Martian climate and emphasizes the importance of its long‐term monitoring.〈/p〉
    Description: Plain Language Summary: Like Earth, Mars also has seasons. Up to one third of the atmospheric CO〈sub〉2〈/sub〉 annually exchanges with the polar surface through seasonal deposition/sublimation processes. Deposition can be either atmospheric precipitation as snowfall or direct surface condensation as frost. At the steep scarps of the North Polar Layered Deposits (NPLD), fractured ice fragments can detach and fall to form ice blocks. We propose to use variations in the shadows of these ice blocks, observed in the High Resolution Imaging Science Experiment images, to infer the thickness evolution of the seasonal deposits. We make reasonable assumptions about the distribution of snowfall and frost around the ice blocks and their surroundings, which allow us to separately measure the thickness of snowfall and frost. Meanwhile, we introduce a novel approach that allows us to estimate the thickness of the seasonal deposits during late winter and early spring when image quality is insufficient. This approach also enables us to peer into the interannual thickness variations of snowfall. We carry out a successful experiment at a scarp centered at (85.0°N, 151.5°E). The obtained thickness measurements demonstrate the dynamics of the Martian volatile cycling and can be used to constrain the Martian climate models.〈/p〉
    Description: Key Points: 〈list list-type="bullet"〉 〈list-item〉 〈p xml:lang="en"〉We propose to examine the shadow variations of the ice blocks at the Martian polar region to infer the thickness of the seasonal deposits〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉Maximum thickness of the seasonal deposits at the study scarp in MY31 is 1.63 ± 0.22 m to which snowfalls contribute 0.97 ± 0.13 m〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉Seasonal deposits at the study scarp are up to 0.8 m shallower than previous measurements during spring〈/p〉〈/list-item〉 〈/list〉 〈/p〉
    Description: HX, LML, and PJG
    Description: https://doi.org/10.17189/1520303
    Description: https://doi.org/10.17632/5yy475dbry.1
    Description: https://doi.org/10.17632/x953mzxxvv.1
    Description: https://doi.org/10.17189/1520101
    Description: http://www.msss.com/moc_gallery/2001
    Keywords: ddc:523 ; Mars ; seasonal polar caps ; thickness ; ice blocks ; HiRISE ; CO2
    Language: English
    Type: doc-type:article
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