ALBERT

Description: A methodology to assess future development in patterns of vulnerability is presented which can support the assessment of global policies with regard to their impacts on specific vulnerabilities on the regional or local scale. Patterns of vulnerability, formalized by vulnerability profiles (e.g. for the livelihoods of dryland smallholder farmers) were investigated under different consistent indicator scenarios reflecting different global policies. After unfolding several principal possibilities to do such an analysis of temporal change in vulnerability patterns we could conclude that the concept of “Clusters of Change” (CoCs) is the most straight forward and promising approach. The main arguments are that each interpretation has necessarily to consider both, the starting situation and it’s change over time (”poor and heavily improving”, ”rich and stagnating” etc.). This implies that we are looking for patterns which represent typical combinations of present states AND expected future changes. An application of the CoC-concept to the drylands vulnerability patterns considering the indicator set for the present situation and the same indicator set for 2050 under a baseline scenario was performed as a test. Comparison of the present vulnerability cluster partition with the spatial distribution of the CoCs revealed that most of these clusters are separated into an improving and a deteriorating part which shows where winners and losers of the baseline scenario are – an interesting result which illustrates the appropriateness of the CoC – method. To explore the potential of CoCs for the dryland vulnerability we applied the method to two different sets of scenarios until 2050: a baseline vs. Climate policy scenario (OECD, 2012) and a ”policy first” scenario vs. ”security first” scenario (UNEP, 2007). The first one serves as an example for a policy assessment while the second compares the vulnerability consequences of two scenarios based on different story-lines of further global development. The main conclusion to be drawn from these calculations is that the CoCs are rather insensitive with regard to the small differences between the scenarios. Regarding the first set of scenarios the relatively short time horizon of relevant influences of climate policies on climate change impacts and several indicators which are not influenced at all generate only a very small difference. The only significant change in the resulting vulnerability profiles was in the values of change in water scarcity: it was lower for all profiles in the climate policy case. The second set of scenarios is not directly related to policy decisions but to different global story-lines which deviate stronger. This resulted in an increasing cluster number from 4 (policy first) to 5 (security first) clusters, about 20% of the pixels changing cluster membership, 3 clusters showing the same spatial extent for both scenarios but the 4th cluster (“policy first”) “losing” India which generates a separate cluster in the “security first” scenario. This allows for the interpretation that a further development according to the “security first”-storyline compared to the “policy first”-storyline would make a difference particularly for India. Closer inspection of the respective profile shows a qualitatively different situation indicating increased vulnerability compared to the “policy first” scenario where India shares one cluster with e.g., Northern Africa.

Description: While deforestation represents an obvious ecosystem change, forest degradation is often more difficult to discern or quantify, but it impacts anumber of ecosystem functions which are vital for biodiversity and climate feedbacks. In the Brazilian Amazon, land-use changes increasefire occurrence, especially in fragmented forests close to managed land. We used remote sensing imagery to estimate the extent and impact of forest fires in degraded tropical rain-forest in the Brazilian Legal Amazon between 2007 and 2010and examinedland-use establishing in degraded areas. The trends in degraded area vs. burned area were different. Even though degradation increased one year after a high fire year, there wasnospatialoverlap, which pointsto other causes for degradation. Up to 11% of the degraded area was burned in the same year, playing escaping fires from managed and deforested lands a significant role in degradation by fire. Eighty-fourpercent of 2007s degraded area remained forest one year later, whereas the rest was identified as deforestation, secondary vegetation or pasture.Three years after degradation, 80% remained forest, the proportion of deforested area decreased and areas in regeneration after being deforested increased. Monitoring of forest degradation across tropical forests is critical for developing land management policies and for carbon stocks/emissions estimation.

Description: The dynamics of the 18O(3P) + 32O2 isotope exchange reaction were studied using crossed atomic and molecular beams at collision energies (Ecoll) of 5.7 and 7.3 kcal/mol, and experimental results were compared with quantum statistical (QS) and quasi-classical trajectory (QCT) calculations on the O3(X1A’) potential energy surface (PES) of Babikov et al. [D. Babikov, B. K. Kendrick, R. B. Walker, R. T. Pack, P. Fleurat-Lesard, and R. Schinke, J. Chem. Phys.118, 6298 (2003)]. In both QS and QCT calculations, agreement with experiment was markedly improved by performing calculations with the experimental distribution of collision energies instead of fixed at the average collision energy. At both collision energies, the scattering displayed a forward bias, with a smaller bias at the lower Ecoll. Comparisons with the QS calculations suggest that 34O2 is produced with a non-statistical rovibrational distribution that is hotter than predicted, and the discrepancy is larger at the lower Ecoll. If this underprediction of rovibrational excitation by the QS method is not due to PES errors and/or to non-adiabatic effects not included in the calculations, then this collision energy dependence is opposite to what might be expected based on collision complex lifetime arguments and opposite to that measured for the forward bias. While the QCT calculations captured the experimental product vibrational energy distribution better than the QS method, the QCT results underpredicted rotationally excited products, overpredicted forward-bias and predicted a trend in the strength of forward-bias with collision energy opposite to that measured, indicating that it does not completely capture the dynamic behavior measured in the experiment. Thus, these results further underscore the need for improvement in theoretical treatments of dynamics on the O3(X1A’) PES and perhaps of the PES itself in order to better understand and predict non-statistical effects in this reaction and in the formation of ozone (in which the intermediate O3 * complex is collisionally stabilized by a third body). The scattering data presented here at two different collision energies provide important benchmarks to guide these improvements.

Description: Abstract. It has been claimed for more than a century that atmospheric new particle formation is primarily influenced by the presence of sulfuric acid. However, the activation process of sulfuric acid related clusters into detectable particles is still an unresolved topic. In this study we focus on the PARADE campaign measurements conducted during August/September 2011 at Mt Kleiner Feldberg in central Germany. During this campaign a set of radicals, organic and inorganic compounds and oxidants and aerosol properties were measured or calculated. We compared a range of organic and inorganic nucleation theories, evaluating their ability to simulate measured particle formation rates at 3 nm in diameter (J3) for a variety of different conditions. Nucleation mechanisms involving only sulfuric acid tentatively captured the observed noon-time daily maximum in J3, but displayed an increasing difference to J3 measurements during the rest of the diurnal cycle. Including large organic radicals, i.e. organic peroxy radicals (RO2) deriving from monoterpenes and their oxidation products, in the nucleation mechanism improved the correlation between observed and simulated J3. This supports a recently proposed empirical relationship for new particle formation that has been used in global models. However, the best match between theory and measurements for the site of interest was found for an activation process based on large organic peroxy radicals and stabilised Criegee intermediates (sCI). This novel laboratory-derived algorithm simulated the daily pattern and intensity of J3 observed in the ambient data. In this algorithm organic derived radicals are involved in activation and growth and link the formation rate of smallest aerosol particles with OH during daytime and NO3 during night-time. Because the RO2 lifetime is controlled by HO2 and NO we conclude that peroxy radicals and NO seem to play an important role for ambient radical chemistry not only with respect to oxidation capacity but also for the activation process of new particle formation. This is supposed to have significant impact of atmospheric radical species on aerosol chemistry and should be taken into account when studying the impact of new particles in climate feedback cycles.

Description: The use of fossil hydrocarbons in the energy and transport sectors is a major source of greenhouse gas emissions. It also ties our society to ever dwindling reserves. Synthetic fuels could play a crucial role in establishing a carbon neutral energy supply.

Description: In the basement, in an alcove that's almost a small room, stands a small wood stove. If it weren't on a pedestal, it would barely be a metre high; but even so it's small, almost cute. The wood from which it's made appears to be untreated; its whiteness is rustic, quaint, innocent. It takes a minute to realise what's wrong. A 'wood stove' should be a stove for burning wood - not one made of wood. It should make combustion possible without itself being combustible.

Description: We examine the claim that in governance for solar climate engineering research, and especially field tests, there is no need for external governance beyond existing mechanisms such as peer review and environmental impact assessments that aim to assess technically defined risks to the physical environment. By drawing on the historical debate on recombinant DNA research, we show that defining risks is not a technical question but a complex process of narrative formation. Governance emerges from within, and as a response to, narratives of what is at stake in a debate. In applying this finding to the case of climate engineering, we find that the emerging narrative differs starkly from the narrative that gave meaning to rDNA technology during its formative period, with important implications for governance. While the narrative of rDNA technology was closed down to narrowly focus on technical risks, that of climate engineering continues to open up and includes social, political and ethical issues. This suggests that, in order to be legitimate, governance must take into account this broad perception of what constitutes the relevant issues and risks of climate engineering, requiring governance that goes beyond existing mechanisms that focus on technical risks. Even small-scale field tests with negligible impacts on the physical environment warrant additional governance as they raise broader concerns that go beyond the immediate impacts of individual experiments.