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  • 551.48  (15)
  • 548  (13)
  • ddc:330  (12)
  • Englisch  (40)
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  • 2020-2022  (40)
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  • 1
    Publikationsdatum: 2021-04-14
    Beschreibung: Pyrroloquinoline quinone (PQQ) is an important cofactor of calcium‐ and lanthanide‐dependent alcohol dehydrogenases, and has been known for over 30 years. Crystal structures of Ca–MDH enzymes (MDH is methanol dehydrogenase) have been known for some time; however, crystal structures of PQQ with biorelevant metal ions have been lacking in the literature for decades. We report here the first crystal structure analysis of a Ca–PQQ complex outside the protein environment, namely, poly[[undecaaquabis(μ‐4,5‐dioxo‐4,5‐dihydro‐1H‐pyrrolo[2,3‐f]quinoline‐2,7,9‐tricarboxylato)tricalcium(II)] dihydrate], {[Ca3(C14H3N2O8)2(H2O)11]·2H2O}n. The complex crystallized as Ca3PQQ2·13H2O with Ca2+ in three different positions and PQQ3−, including an extensive hydrogen‐bond network. Similarities and differences to the recently reported structure with biorelevant europium (Eu2PQQ2) are discussed.
    Beschreibung: Pyrroloquinoline quinone (PQQ) is an important cofactor of calcium‐ and lanthanide‐dependent alcohol dehydrogenases. The crystal structure of a Ca–PQQ complex (Ca3PQQ2·13H2O) is reported for the first time outside a protein environment. image
    Beschreibung: research
    Schlagwort(e): 548 ; pyrroloquinoline quinone ; calcium ; PQQ ; methanol dehydrogenase ; crystal structure ; FID-GEO-DE-7
    Sprache: Englisch
    Materialart: article , publishedVersion
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  • 2
    Publikationsdatum: 2021-08-10
    Beschreibung: During evaporation of natural and synthetic K–Mg–Cl brines, the formation of almost square plate-like crystals of potassium carnallite (potassium chloride magnesium dichloride hexahydrate) was observed. A single-crystal structure analysis revealed a monoclinic cell [a = 9.251 (2), b = 9.516 (2), c = 13.217 (4) Å, β = 90.06 (2)° and space group C2/c]. The structure is isomorphous with other carnallite-type compounds, such as NH4Cl·MgCl2·6H2O. Until now, natural and synthetic carnallite, KCl·MgCl2·6H2O, was only known in its orthorhombic form [a = 16.0780 (3), b = 22.3850 (5), c = 9.5422 (2) Å and space group Pnna].
    Schlagwort(e): 548 ; crystallization ; metastable ; monoclinic ; potassium carnallite ; crystal structure ; potash ; fertilizer
    Sprache: Englisch
    Materialart: article
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  • 3
    Publikationsdatum: 2021-07-23
    Beschreibung: MgCO3·MgCl2·7H2O is the only known neutral magnesium carbonate containing chloride ions at ambient conditions. According to the literature, only small and twinned crystals of this double salt could be synthesised in a concentrated solution of MgCl2. For the crystal structure solution, single-crystal diffraction was carried out at a synchrotron radiation source. The monoclinic crystal structure (space group Cc) exhibits double chains of MgO octahedra linked by corners, connected by carbonate units and water molecules. The chloride ions are positioned between these double chains parallel to the (100) plane. Dry MgCO3·MgCl2·7H2O decomposes in the air to chlorartinite, Mg2(OH)Cl(CO3)·nH2O (n = 2 or 3). This work includes an extensive characterization of the title compound by powder X-ray diffraction, thermal analysis, SEM and vibrational spectroscopy.
    Schlagwort(e): 548 ; magnesium ; carbonate ; chloride ; hydrate ; synchrotron ; twinning ; crystal structure
    Sprache: Englisch
    Materialart: article
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  • 4
    Publikationsdatum: 2021-07-24
    Beschreibung: Relativistic electron diffraction depends on linear and quadratic terms in the electric potential, the latter being neglected in the frequently used relativistically corrected Schrödinger equation. The quadratic electric potential term modifies atomic scattering amplitudes in particular for large-angle scattering and backscattering. The respective correction increases with increasing scattering angle, increasing atomic number and increasing kinetic energy. Conventional tabulations for electron scattering and its large-angle extrapolations can be amended in closed form by a universal correction based on the screened Coulomb potential squared.
    Schlagwort(e): 548 ; electron diffraction ; atomic scattering factors ; relativity theory ; Schrödinger equation
    Sprache: Englisch
    Materialart: article
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  • 5
    Publikationsdatum: 2021-08-06
    Beschreibung: Energy poverty is high up on national and European Union policy agendas. A number of possible indicators to measure the issue have been identified in the literature, but comparable data with European coverage is scarce. The EU Commission thus proposes four independent indicators on the "EU Energy Poverty Observatory" based on self-reported items from the pan-European surveys on income and living conditions (SILC) and household budgets (HBS). It is of increasing public interest to analyse social impacts of energy policies, and quantify energy poverty indicators also from modelling. This paper first shortly outlines how the expenditure-based indicators using HBS micro data may be directly linked to existing macroeconomic models through their defining variables (energy expenditure and income). As endogenous modelling based on micro data is difficult, the link may be country-specific elasticities. The main contribution of the paper is a systematic in-depth sensitivity analysis of the two indicators to changes in income and energy expenditure following varying patterns in the underlying distributions of the micro data. The results may be used by future soft links to models. The results display sometimes counterintuitive effects. We find that whether these indicators increase/decrease after a change of income or energy expenditure largely depends on the specific country-wise income and energy expenditure distribution between households on a micro-level. Due to their definition, the examined indicators are especially sensitive, when income changes alter the indicator threshold values, which in these cases are the median values in underlying distributions. We discuss these findings and relate them to several indicator shortcomings and potential remedies through changes in indicator definition.
    Schlagwort(e): ddc:330
    Repository-Name: Wuppertal Institut für Klima, Umwelt, Energie
    Sprache: Englisch
    Materialart: article , doc-type:article
    Format: application/pdf
    Format: application/vnd.openxmlformats-officedocument.spreadsheetml.sheet
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  • 6
    Publikationsdatum: 2021-08-06
    Beschreibung: In order to calculate the financial return of energy efficiency measures, a cost-benefit analysis (CBA) is a proven tool for investors. Generally, however, most CBAs for investors have a narrow focus, which is - simply speaking - on investment costs compared with energy cost savings over the life span of the investment. This only provides part of the full picture. Ideally, a comprehensive or extended CBA would take additional benefits as well as additional costs into account. The objective of this paper is to reflect upon integrating into a CBA two important cost components: transaction costs and energy efficiency services - and how they interact. Even though this concept has not been carried out to the knowledge of the authors, we even go a step further to try to apply this idea. In so doing, we carried out a meta-analysis on relevant literature and existing data and interviewed a limited number of energy experts with comprehensive experience in carrying out energy services. Even though data is hardly available, we succeeded in constructing three real-world cases and applied an extended CBA making use of information gathered on transaction costs and energy services costs. We were able to show that, despite these additional cost components, the energy efficiency measures are economically viable. Quantitative data was not available on how energy services reduce transaction costs; more information on this aspect could render our results even more positive. Even though empirical and conceptual research must intensify efforts to design an even more comprehensive CBA, these first-of-its-kind findings can counterargue those that believe energy efficiency is not worth it (in monetary terms) due to transaction costs or energy services costs. In fact, this is good news for energy efficiency and for those that seek to make use of our findings to argue in favor of taking up energy efficiency investments in businesses.
    Schlagwort(e): ddc:330
    Repository-Name: Wuppertal Institut für Klima, Umwelt, Energie
    Sprache: Englisch
    Materialart: article , doc-type:article
    Format: application/pdf
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  • 7
    facet.materialart.
    Unbekannt
    Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publikationsdatum: 2021-05-18
    Beschreibung: The European Union (EU) has established that the goal of achieving climate neutrality by 2050 as a key driver of innovation and growth for industry and the economy in the EU. In addition to offering great opportunities, this also poses considerable challenges for the European economy and, for the most part, for basic industries, which are particularly emission-intensive and face strong international competition. An integrated climate and industry strategy is of central importance to protecting the climate, since the production of steel, cement, basic chemicals, glass, paper, and other materials in the EU and worldwide accounts for roughly one fifth of total greenhouse gas emissions. Even in a greenhouse gas-neutral future, we will not be able to fully eliminate our need for these materials. At the same time, it is particularly challenging to produce these materials without creating emissions given the state of technology and the necessary infrastructures. This applies above all to the question of how large amounts of green energy, including electricity and hydrogen, can be produced at competitive prices. Analyses show that despite the considerable costs involved in process changeover, the costs of transforming the raw materials industry are acceptable to society as a whole, given that the additional costs usually only increase the price of the end products by a few percentage points. However, in the case of crude steel or cement, the price would increase by between one third and 100 per cent. Since almost all raw materials manufacturers face strong global market competition, in most cases they are not able to bankroll the investments in climate-neutral production and the required energy infrastructure without outside support. This paper outlines an integrated climate industrial policy package that allows the EU to utilise its existing technological leadership in many of these industries to build a greenhouse gas-neutral raw materials industry.
    Schlagwort(e): ddc:330
    Repository-Name: Wuppertal Institut für Klima, Umwelt, Energie
    Sprache: Englisch
    Materialart: workingpaper , doc-type:workingPaper
    Format: application/pdf
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  • 8
    Publikationsdatum: 2021-05-06
    Beschreibung: In the light of Germany's chosen path towards the energy transition, the regulatory framework has changed considerably. New players have succeeded in entering the market, and renewable energies have become increasingly competitive. Greater electrification of the transport and heating sectors will be needed in the future to achieve national climate targets. Against this background, Germany's big energy companies need to be sure that their sales will increase. However, they were unable to anticipate this development, and made strategic mistakes in the past. The development of sustainable business models in line with the energy transition failed to materialize. Now it is becoming increasingly clear that companies must create new business models to survive in the long term. These business models have to keep with the tradition, whilst meeting the needs of low-carbon power supplies. In this paper, we will examine the past and future challenges of the four energy companies and develop a proposal for evaluating sustainable business models. For this purpose, we use the multi-level perspective to categorize developments in the electricity market over the last 50 years, and then apply a multi-criteria analysis to derive five suitable business models from the results.
    Schlagwort(e): ddc:330
    Repository-Name: Wuppertal Institut für Klima, Umwelt, Energie
    Sprache: Englisch
    Materialart: article , doc-type:article
    Format: application/pdf
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  • 9
    Publikationsdatum: 2021-05-04
    Schlagwort(e): ddc:330
    Repository-Name: Wuppertal Institut für Klima, Umwelt, Energie
    Sprache: Englisch
    Materialart: bookpart , doc-type:bookPart
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  • 10
    facet.materialart.
    Unbekannt
    Oxford : Oxford University Press
    Publikationsdatum: 2021-07-05
    Beschreibung: This chapter turns to the measurement of performance in delivering corporate and ecosystem purposes. The metrics are designed to capture the pain points in the ecosystem that need to be addressed and the success of the intervention in addressing them. This requires measures of non-financial as well as financial performance. The chapter provides an overview of measurements of non-financial forms of capital: natural, human, and social. In examining natural capital, it contrasts input measures that record the amount of natural resources that are used in the production process and output measures that examine the impact of the inputs on products, emissions, waste, etc. It notes that measuring inputs is in general more straightforward than outputs and it therefore argues that natural capital metrics should be constructed around inputs rather than outputs.
    Schlagwort(e): ddc:330
    Repository-Name: Wuppertal Institut für Klima, Umwelt, Energie
    Sprache: Englisch
    Materialart: bookpart , doc-type:bookPart
    Format: application/pdf
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  • 11
    Publikationsdatum: 2021-05-18
    Beschreibung: In this paper, we aim to present a comprehensive analysis on the emerging phenomenon of distributed innovation in commons-based peer production (CBPP) platforms. Starting with the exploration of the widely held belief on value-creation confined to industrial settings, we raise several questions regarding the feasibility of, and a need for, an inclusive innovation process that can tap grassroots capacity into both traditional (industrial research and development) and emerging (peer-to-peer) innovation models to yield sustainable solutions. In particular, we explore the emergence and structuration of digital innovations in the maker movement, as it presents an alternative construct of innovation wherein access to and sharing of knowledge is predominantly distributed. With innovation outcomes often freely revealed, its very structuration could pose a principal challenge to our conceptualizations of value creation and competitive advantage in the current economic model. Drawing from responses received from 200 collaborative innovation platforms, six semi‐structured interviews focusing on socio-technical innovation cases, as well as four in-depth narrative interviews with maker turned entrepreneurs, we present a detailed analysis on the topology of network, typology of actors, as well as the underlying innovation ecosystem in CBPP networks in Germany. In doing so, we contribute to the conceptualization of peer-to-peer distributed innovations in collaborative platforms.
    Schlagwort(e): ddc:330
    Repository-Name: Wuppertal Institut für Klima, Umwelt, Energie
    Sprache: Englisch
    Materialart: article , doc-type:article
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  • 12
    Publikationsdatum: 2021-07-05
    Beschreibung: The data centre industry (DCI) has grown from zero in the 1980s, to enabling 60% of the global population to be connected in 2021 via 7.2 million data centres. The DCI is based on a linear economy and there is an urgent need to transform to a Circular Economy to establish a secure supply chain and ensure an economically stable and uninterrupted service, which is particularly difficult in an industry that is comprised of ten insular subsectors. This paper describes the CEDaCI project which was established to address the challenge in this unique sector; this ground-breaking project employs a whole systems approach, Design Thinking and the Double Diamond methods, which rely on people/stakeholder engagement throughout. The paper reviews and assesses the impact of these methods and project to date, using quantitative and qualitative research, via an online sectoral survey and interviews with nine data centre and IT industry experts. The results show that the project is creating positive impact and initiating change across the sector and that the innovative output (designs, business models, and a digital tool) will ensure that sectoral transformation continues; the project methods and structure will also serve as an exemplar for other sectors.
    Schlagwort(e): ddc:330
    Repository-Name: Wuppertal Institut für Klima, Umwelt, Energie
    Sprache: Englisch
    Materialart: article , doc-type:article
    Format: application/pdf
    Format: application/pdf
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  • 13
    Publikationsdatum: 2021-11-03
    Beschreibung: The Gravity Recovery and Climate Experiment (GRACE) mission ended its operation in October 2017, and the GRACE Follow-On mission was launched only in May 2018, leading to approximately 1 year of data gap. Given that GRACE-type observations are exclusively providing direct estimates of total water storage change (TWSC), it would be very important to bridge the gap between these two missions. Furthermore, for many climate-related applications, it is also desirable to reconstruct TWSC prior to the GRACE period. In this study, we aim at comparing different data-driven methods and identifying the more robust alternatives for predicting GRACE-like gridded TWSC during the gap and reconstructing them to 1992 using climate inputs. To this end, we first develop a methodological framework to compare different methods such as the multiple linear regression (MLR), artificial neural network (ANN), and autoregressive exogenous (ARX) approaches. Second, metrics are developed to measure the robustness of the predictions. Finally, gridded TWSC within 26 regions are predicted and reconstructed using the identified methods. Test computations suggest that the correlation of predicted TWSC maps with observed ones is more than 0.3 higher than TWSC simulated by hydrological models, at the grid scale of 1° resolution. Furthermore, the reconstructed TWSC correctly reproduce the El Nino-Southern Oscillation (ENSO) signals. In general, while MLR does not perform best in the training process, it is more robust and could thus be a viable approach both for filling the GRACE gap and for reconstructing long-period TWSC fields globally when combined with statistical decomposition techniques.
    Schlagwort(e): 551.48 ; GRACE ; total water storage change ; predidicting method
    Sprache: Englisch
    Materialart: map
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  • 14
    Publikationsdatum: 2021-10-28
    Beschreibung: Due to seasonal or interannual variability, the relevance of hydrological processes and of the associated model parameters can vary significantly throughout the simulation period. To achieve accurately identified model parameters, temporal variations in parameter dominance should be taken into account. This is not achieved if performance criteria are applied to the entire model output time series. Even when using complementary performance criteria, it is often only possible to identify some of the model parameters precisely. We present an innovative approach to improve parameter identifiability that exploits the information available regarding temporal variations in parameter dominance. Using daily parameter sensitivity time series, we construct a set of sensitivity-weighted performance criteria, one for each parameter, whereby periods of higher dominance of a model parameter and its corresponding process are assigned higher weights in the calculation of the associated performance criterion. These criteria are used to impose constraints on parameter values. We demonstrate this approach by constraining 12 model parameters for three catchments and examine ensemble hydrological simulations generated using these constrained parameter sets. The sensitivity-weighted approach improves in particular the identifiability for parameters whose corresponding processes are dominant only for short periods of time or have strong seasonal patterns. This results overall in slight improvement of model performance for a set of 10 contrasting performance criteria. We conclude that the sensitivity-weighted approach improves the extraction of hydrologically relevant information from data, thereby resulting in improved parameter identifiability and better representation of model parameters.
    Schlagwort(e): 551.48 ; parameter identifiability ; parameter constraints ; temporal diagnostic analysis ; sensitivity analysis ; performance criteria
    Sprache: Englisch
    Materialart: map
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  • 15
    Publikationsdatum: 2021-09-27
    Beschreibung: The magnitudes of river floods in Europe have been observed to change, but their alignment with changes in the spatial coverage or extent of individual floods has not been clear. We analyze flood magnitudes and extents for 3,872 hydrometric stations across Europe over the past five decades and classify each flood based on antecedent weather conditions. We find positive correlations between flood magnitudes and extents for 95% of the stations. In central Europe and the British Isles, the association of increasing trends in magnitudes and extents is due to a magnitude-extent correlation of precipitation and soil moisture along with a shift in the flood generating processes. The alignment of trends in flood magnitudes and extents highlights the increasing importance of transnational flood risk management.
    Schlagwort(e): 551.48 ; flood ; synchrony ; magnitude ; climate change ; classification ; spatial statistics
    Sprache: Englisch
    Materialart: map
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  • 16
    Publikationsdatum: 2021-09-27
    Beschreibung: This investigation attempts to understand the eco-hydrology of, and accordingly suggest an option to manage floodwater for agriculture in, the understudied and data-sparse ephemeral Baraka River Basin within the hyper-arid region of Sudan. Reference is made to the major feature of the basin, that is, the Toker Delta spate irrigation scheme. A point-to-pixel comparison of gridded and ground-based data sets is performed to enhance the estimates of rainfall. Analysis of remotely sensed land use/cover data is performed. The results show a significant reduction of the grassland and barren areas explained by a significant expansion of the cropland and open shrubland (invasive mesquite trees) areas in the delta. The cotton sown area is highly dependent on the flooded area and the discharge volume in the delta. However, the area of this major crop has declined since the early 1990s in favour of cultivation of more profitable food crops. Expansion of mesquite in the delta is problematic, taking hold under increased floodwater, and can only be manged by clearance to provide crop cultivation area. There is a great potential for floodwater harvesting during the rainfall season (June to September). A total seasonal runoff volume of around 4.6 and 10.8 billion cubic metres is estimated at 90 and 50% probabilities of exceedance (reliabilities), respectively. Rather than leaving the runoff generated from rainfall events to pass to the Red Sea or be consumed by mesquite trees, a location for runoff harvesting structure in a highly suitable area is proposed. Such a structure will support any policy shifts towards planning and managing the basin water resources for use in irrigating the agricultural scheme.
    Schlagwort(e): 551.48 ; Baraka River Basin ; eco-hydrology ; floodwater harvesting ; land-cover classification ; Mesquite ; Toker Delta
    Sprache: Englisch
    Materialart: map
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  • 17
    Publikationsdatum: 2021-09-27
    Beschreibung: It is shown that it is possible to perform combined X-ray and neutron single-crystal studies in the same diamond anvil cell (DAC). A modified Merrill–Bassett DAC equipped with an inflatable membrane filled with He gas has been developed. It can be used on laboratory X-ray and synchrotron diffractometers as well as on neutron instruments. The data processing procedures and a joint structural refinement of the high-pressure synchrotron and neutron single-crystal data are presented and discussed for the first time.
    Schlagwort(e): 548 ; single-crystal X-ray diffraction ; single-crystal neutron diffraction ; high pressure ; diamond anvil cells
    Sprache: Englisch
    Materialart: map
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  • 18
    Publikationsdatum: 2021-09-27
    Beschreibung: White-beam X-ray topography has been performed to provide direct evidence of micro-voids in dislocation-free high-purity germanium single crystals. The voids are visible because of a dynamical diffraction contrast. It is shown that voids occur only in dislocation-free parts of the crystal and do not show up in regions with homogeneous and moderate dislocation density. It is further suggested that the voids originate from clustering of vacancies during the growth process. A general method is proposed to verify the presence of voids for any crystalline material of high structural perfection.
    Schlagwort(e): 548 ; X-ray topography ; dynamical theory ; high-purity germanium ; vacancies ; voids ; dislocation density ; diffraction contrast
    Sprache: Englisch
    Materialart: map
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  • 19
    Publikationsdatum: 2021-09-27
    Beschreibung: Droughts lead to falling river water levels and consequently expose river sediments. It is well known that from these exposed aquatic sediments, CO2 emits to the atmosphere, but upscaling of CO2 measurements from discrete point measurements to an entire river system remains challenging. Naturally occurring heterogeneous processes must be accounted for to obtain an overall CO2 flux and to assess its significance. We contribute to this challenge by incorporating a two stage scaling approach using in situ CO2 fluxes and remote sensing data. First, by combining optical airborne data with closed chamber measurements at a representative model site during a first scaling stage, we derive land cover type specific CO2 fluxes and identify distance to the water as the most suitable proxy for further upscaling. Second, we upscale derived spatial relations from the first scaling stage to the entire river system of the Elbe River using a satellite-based analysis. In this way, we derived area-weighted CO2 emissions from exposed river sediments of 56.6 ± 64.8 tC day−1 (corrected distance proxy) and 52.9 ± 44.6 tC day−1 (land cover proxy), respectively, for 1 day during the 2018 extreme drought. Given the intensification of droughts in terms of length and reoccurrence frequency, this result not only highlights the importance of drought-induced exposition of river sediment as a source of atmospheric CO2 but also underscores the ability to monitor CO2 emissions over an entire river system on a regular basis using remote sensing.
    Schlagwort(e): 551.48 ; carbon dioxide emission ; chamber measurements ; hydrological drought ; Sentinel-2 ; upscaling
    Sprache: Englisch
    Materialart: map
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  • 20
    Publikationsdatum: 2021-10-07
    Beschreibung: High-quality single-crystal X-ray diffraction measurements are a prerequisite for obtaining precise and reliable structure data and electron densities. The single crystal should therefore fulfill several conditions, of which a regular defined shape is of particularly high importance for compounds consisting of heavy elements with high X-ray absorption coefficients. The absorption of X-rays passing through a 50 µm-thick LiNbO3 crystal can reduce the transmission of Mo Kα radiation by several tens of percent, which makes an absorption correction of the reflection intensities necessary. In order to reduce ambiguities concerning the shape of a crystal, used for the necessary absorption correction, a method for preparation of regularly shaped single crystals out of large samples is presented and evaluated. This method utilizes a focused ion beam to cut crystals with defined size and shape reproducibly and carefully without splintering. For evaluation, a single-crystal X-ray diffraction study using a laboratory diffractometer is presented, comparing differently prepared LiNbO3 crystals originating from the same macroscopic crystal plate. Results of the data reduction, structure refinement and electron density reconstruction indicate qualitatively similar values for all prepared crystals. Thus, the different preparation techniques have a smaller impact than expected. However, the atomic coordinates, electron densities and atomic charges are supposed to be more reliable since the focused-ion-beam-prepared crystal exhibits the smallest extinction influences. This preparation technique is especially recommended for susceptible samples, for cases where a minimal invasive preparation procedure is needed, and for the preparation of crystals from specific areas, complex material architectures and materials that cannot be prepared with common methods (breaking or grinding).
    Schlagwort(e): 548 ; X-ray diffraction ; sample preparation ; focused ion beams
    Sprache: Englisch
    Materialart: map
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  • 21
    Publikationsdatum: 2021-10-15
    Beschreibung: As the Arctic coast erodes, it drains thermokarst lakes, transforming them into lagoons, and, eventually, integrates them into subsea permafrost. Lagoons represent the first stage of a thermokarst lake transition to a marine setting and possibly more saline and colder upper boundary conditions. In this research, borehole data, electrical resistivity surveying, and modeling of heat and salt diffusion were carried out at Polar Fox Lagoon on the Bykovsky Peninsula, Siberia. Polar Fox Lagoon is a seasonally isolated water body connected to Tiksi Bay through a channel, leading to hypersaline waters under the ice cover. The boreholes in the center of the lagoon revealed floating ice and a saline cryotic bed underlain by a saline cryotic talik, a thin ice-bearing permafrost layer, and unfrozen ground. The bathymetry showed that most of the lagoon had bedfast ice in spring. In bedfast ice areas, the electrical resistivity profiles suggested that an unfrozen saline layer was underlain by a thick layer of refrozen talik. The modeling showed that thermokarst lake taliks can refreeze when submerged in saltwater with mean annual bottom water temperatures below or slightly above 0°C. This occurs, because the top-down chemical degradation of newly formed ice-bearing permafrost is slower than the refreezing of the talik. Hence, lagoons may precondition taliks with a layer of ice-bearing permafrost before encroachment by the sea, and this frozen layer may act as a cap on gas migration out of the underlying talik.
    Schlagwort(e): 551.48 ; thermokarst lake ; talik ; lagoon ; subsea permafrost ; salt diffusion ; Siberia
    Sprache: Englisch
    Materialart: map
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  • 22
    Publikationsdatum: 2021-10-15
    Beschreibung: Nowadays, national and international requirements and laws emphasize the “natural” development of river-floodplain systems. One goal is to increase the connectivity between the river and its floodplains and thus reactivate floodplains as flooding areas, which potentially increases the mobility of fine sediments. The objective of this study is to analyze the long-term effects of reactivated floodplains on the mobility of floodplain deposits of small rivers based on two river restoration scenarios: elevating the riverbed or lowering the floodplains. Past channel fixation and degradation as well as the subsequent increase in the floodplain elevation led to the decoupling of the channel and floodplain morphodynamics associated with the reduction of the habitat connectivity. Here, the floodplain sedimentation rates were determined using a numerical model based on the Delft3D software. The novelty of these numerical investigations is the morphological long-term analysis over timescales of decades, which is not comparable to other short-term hydrodynamic and morphodynamic studies for small meandering lowland rivers. The results of 11 river restoration scenarios show that lowering the floodplain and raising the riverbed elevation both lead to an increase in the fine sediment deposition on the floodplain. However, lowering the floodplain elevation is generally more effective. Based on the numerical model results and the assumption of a fixed river channel, only anthropogenic activity might have increased the amount of fine sediments deposited on floodplains and has accelerated the decoupling of the floodplains from the riverbed in the past centuries.
    Schlagwort(e): 551.48 ; Reactivation of floodplain sediment deposits ; Numerical modelling ; River restorations
    Sprache: Englisch
    Materialart: map
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  • 23
    Publikationsdatum: 2021-10-15
    Beschreibung: Entangled embedded periodic nets and crystal frameworks are defined, along with their dimension type, homogeneity type, adjacency depth and periodic isotopy type. Periodic isotopy classifications are obtained for various families of embedded nets with small quotient graphs. The 25 periodic isotopy classes of depth-1 embedded nets with a single-vertex quotient graph are enumerated. Additionally, a classification is given of embeddings of n-fold copies of pcu with all connected components in a parallel orientation and n vertices in a repeat unit, as well as demonstrations of their maximal symmetry periodic isotopes. The methodology of linear graph knots on the flat 3-torus [0,1)3 is introduced. These graph knots, with linear edges, are spatial embeddings of the labelled quotient graphs of an embedded net which are associated with its periodicity bases.
    Schlagwort(e): 548 ; periodic nets ; embedded nets ; coordination polymers ; isotopy types ; crystallographic frameworks
    Sprache: Englisch
    Materialart: map
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  • 24
    Publikationsdatum: 2021-10-12
    Beschreibung: Crystallographic textures, as they develop for example during cold forming, can have a significant influence on the mechanical properties of metals, such as plastic anisotropy. Textures are typically characterized by a non-uniform distribution of crystallographic orientations that can be measured by diffraction experiments like electron backscatter diffraction (EBSD). Such experimental data usually contain a large number of data points, which must be significantly reduced to be used for numerical modeling. However, the challenge in such data reduction is to preserve the important characteristics of the experimental data, while reducing the volume and preserving the computational efficiency of the numerical model. For example, in micromechanical modeling, representative volume elements (RVEs) of the real microstructure are generated and the mechanical properties of these RVEs are studied by the crystal plasticity finite element method. In this work, a new method is developed for extracting a reduced set of orientations from EBSD data containing a large number of orientations. This approach is based on the established integer approximation method and it minimizes its shortcomings. Furthermore, the L1 norm is applied as an error function; this is commonly used in texture analysis for quantitative assessment of the degree of approximation and can be used to control the convergence behavior. The method is tested on four experimental data sets to demonstrate its capabilities. This new method for the purposeful reduction of a set of orientations into equally weighted orientations is not only suitable for numerical simulation but also shows improvement in results in comparison with other available methods.
    Schlagwort(e): 548 ; texture reconstruction ; integer approximation ; crystal plasticity ; micromechanical modeling
    Sprache: Englisch
    Materialart: map
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  • 25
    Publikationsdatum: 2021-10-13
    Beschreibung: The crystal structure of the mineral malayaite has been studied by single-crystal X-ray diffraction at a temperature of 20 K and by calculation of its phonon dispersion using density functional perturbation theory. The X-ray diffraction data show first-order satellite diffraction maxima at positions q = 0.2606 (8)b*, that are absent at room temperature. The computed phonon dispersion indicates unstable modes associated with dynamic displacements of the Ca atoms. The largest-frequency modulus of these phonon instabilities is located close to a wavevector of q = 0.3b*. These results indicate that the malayaite crystal structure is incommensurately modulated by static displacement of the Ca atoms at low temperatures, caused by the softening of an optic phonon with Bg symmetry.
    Schlagwort(e): 548 ; modulation ; optic phonon ; titanite ; satellite reflections ; DFPT
    Sprache: Englisch
    Materialart: map
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  • 26
    Publikationsdatum: 2021-10-13
    Beschreibung: Meltwater from glaciers is not only a stable source of water but also affects downstream streamflow dynamics. One of these dynamics is the interannual variability of streamflow. Glaciers can moderate streamflow variability because the runoff in the glacierized part, driven by temperature, correlates negatively with the runoff in the non-glacierized part of a catchment, driven by precipitation, thereby counterbalancing each other. This is also called the glacier compensation effect (GCE), and the effect is assumed to depend on relative glacier cover. Previous studies found a convex relationship between streamflow variability and glacier cover of different glacierized catchments, with lowest streamflow variability at a certain optimum glacier cover. In this study, we aim to revisit these previously found curves to find out if a universal relationship between interannual streamflow variability and glacier cover exists, which could potentially be used in a space-for-time substitution analysis. Moreover, we test the hypothesis that the dominant climate drivers (here precipitation and temperature) switch around the suggested optimum of the curve. First, a set of virtual nested catchments, with the same absolute glacier area but varying non-glacierized area, were modelled to isolate the effect of glacier cover on streamflow variability. The modelled relationship was then compared with a multicatchment data set of gauged glacierized catchments in the European Alps. In the third step, changes of the GCE curve over time were analysed. Model results showed a convex relationship and the optimum in the simulated curve aligned with a switch in the dominant climate driver. However, the multicatchment data and the time change analyses did not suggest the existence of a universal convex relationship. Overall, we conclude that GCE is complex due to entangled controls and changes over time in glacierized catchments. Therefore, care should be taken to use a GCE curve for estimating and/or predicting interannual streamflow variability in glacierized catchments.
    Schlagwort(e): 551.48 ; glacier compensation effect ; glacierized catchments ; interannual variability ; modelling experiment ; space-for-time substitution ; streamflow
    Sprache: Englisch
    Materialart: map
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  • 27
    Publikationsdatum: 2021-10-13
    Beschreibung: The generalized Darwin–Hamilton equations [Wuttke (2014). Acta Cryst. A70, 429–440] describe multiple Bragg reflection from a thick, ideally imperfect crystal. These equations are simplified by making full use of energy conservation, and it is demonstrated that the conventional two-ray Darwin–Hamilton equations are obtained as a first-order approximation. Then an efficient numeric solution method is presented, based on a transfer matrix for discretized directional distribution functions and on spectral collocation in the depth coordinate. Example solutions illustrate the orientational spread of multiply reflected rays and the distortion of rocking curves, especially if the detector only covers a finite solid angle.
    Schlagwort(e): 548 ; mosaic crystals ; multiple scattering ; Darwin–Hamilton equations ; spectral collocation
    Sprache: Englisch
    Materialart: map
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  • 28
    Publikationsdatum: 2021-10-14
    Beschreibung: This study proposes a new process-based framework to characterize and classify runoff events of various magnitudes occurring in a wide range of catchments. The framework uses dimensionless indicators that characterize space–time dynamics of precipitation events and their spatial interaction with antecedent catchment states, described as snow cover, distribution of frozen soils, and soil moisture content. A rigorous uncertainty analysis showed that the developed indicators are robust and regionally consistent. Relying on covariance- and ratio-based indicators leads to reduced classification uncertainty compared to commonly used (event-based) indicators based on absolute values of metrics such as duration, volume, and intensity of precipitation events. The event typology derived from the proposed framework is able to stratify events that exhibit distinct hydrograph dynamics even if streamflow is not directly used for classification. The derived typology is therefore able to capture first-order controls of event runoff response in a wide variety of catchments. Application of this typology to about 180,000 runoff events observed in 392 German catchments revealed six distinct regions with homogeneous event type frequency that match well regions with similar behavior in terms of runoff response identified in Germany. The detected seasonal pattern of event type occurrence is regionally consistent and agrees well with the seasonality of hydroclimatic conditions. The proposed framework can be a useful tool for comparative analyses of regional differences and similarities of runoff generation processes at catchment scale and their possible spatial and temporal evolution.
    Schlagwort(e): 551.48 ; event classification ; event type ; rainfall-runoff events ; event typology ; event characteristics ; runoff generation mechanisms
    Sprache: Englisch
    Materialart: map
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  • 29
    Publikationsdatum: 2021-10-14
    Beschreibung: Projections of potential impacts of climate change and groundwater abstraction on gaining and losing streams, particularly in ephemeral river basins exhibiting sporadic and intricate flux exchanges, have remained largely unexplored. To fill this gap, we propose a promising modeling scheme based on the new fully integrated hydrological model SWAT-MODFLOW-NWT, calibrated and validated for 1978–2012, to quantify the intertwined surface-groundwater interactions under a conjuncture of three climatic emission scenarios (RCP 2.6, 4.5 and 8.5) and two groundwater pumping variants: “pumping” (extending current groundwater utilization into the future) and “nonpumping” (assuming a complete cease of pumping in the future). By forcing the integrated model with future downscaled climate predictors of CanESM2 under the aforementioned RCPs for three time slices up to year 2100, projections of various water resources components for the Gharehsoo River Basin (GRB), in northwestern Iran were made. Results demonstrate that because of a general decrease of future precipitation, though with ups and downs across the total projection period, most of the surface and -subsurface budget quantities and fluxes are substantially affected. In particular, future groundwater discharge (baseflow) to the gaining streams will be more influenced by the “pumping” variant (increasing and decreasing for “nonpumping” and “pumping”, respectively) than the concentrated groundwater recharge from the losing streams (decreasing and increasing for “nonpumping” and “pumping”, respectively). Future water yield and groundwater storage will also diminish and, surprisingly, this cannot be alleviated by future “nonpumping”, indicating the groundwater overutilization is the compelling reason for the future water scarcity in the GRB, rather than climate change alone.
    Schlagwort(e): 551.48 ; losing streams ; gaining streams ; climate change scenarios ; baseflow ; concentrated groundwater recharge ; pumping variants
    Sprache: Englisch
    Materialart: map
    Standort Signatur Erwartet Verfügbarkeit
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  • 30
    Publikationsdatum: 2021-09-24
    Beschreibung: During investigations of the formation of hydrated magnesium carbonates, a sample of the previously unknown magnesium carbonate hexahydrate (MgCO3·6H2O) was synthesized in an aqueous solution at 273.15 K. The crystal structure consists of edge-linked isolated pairs of Mg(CO3)(H2O)4 octahedra and noncoordinating water molecules, and exhibits similarities to NiCO3·5.5H2O (hellyerite). The recorded X-ray diffraction pattern and the Raman spectra confirmed the formation of a new phase and its transformation to magnesium carbonate trihydrate (MgCO3·3H2O) at room temperature.
    Schlagwort(e): 548 ; magnesium ; carbonate ; low-temperature hydrate ; Raman spectroscopy ; crystal structure
    Sprache: Englisch
    Materialart: map
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  • 31
    Publikationsdatum: 2021-10-02
    Beschreibung: Human activities, such as human water use, have been shown to directly influence terrestrial water fluxes and states. Simulations of soil moisture, river discharge, evapotranspiration, and groundwater storage are significantly improved, if human interactions, such as irrigation and groundwater abstraction, are incorporated. Yet improvements through the incorporation of human water use on the simulation of local and remote precipitation are rarely studied but may contribute to the skill of land surface fluxes. In this study, we evaluate the impact of human water use on the skill of evapotranspiration and precipitation in a fully coupled bedrock-to-atmosphere modeling platform. The results show that human water use can potentially increase the skill of the simulations across scales. However, observational uncertainty at the watershed scale limits the identification of model deficiencies and added value related to human water use. Locally, daily precipitation statistics potentially benefit from the incorporation of human water use. Although the incorporation of human water use does not remove the wet bias, it can increase the model skill.
    Schlagwort(e): 551.48 ; added value ; human water use ; precipitation ; integrated modeling ; evapotranspiration ; observational uncertainty
    Sprache: Englisch
    Materialart: map
    Standort Signatur Erwartet Verfügbarkeit
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  • 32
    Publikationsdatum: 2021-10-01
    Beschreibung: The streamflow drought hazard can be characterized in a variety of ways, including using different indices. Traditionally, percentile-based indices, such as Q95 (the flow exceeded 95% of time), have been used by the hydrological community. Recently, the use of anomaly indices such as the Standardized Streamflow Index (SSI), a probability index-based approach adopted from the climatological community, has increased in popularity. The SSI can be calculated based on various (non)parametric methods. Up to now, there is no consensus which method to use. This study aims to raise awareness how the inherent sensitivity of the SSI to the used method influences derived drought characteristics. We compared SSI time series computed with seven different probability distributions and two fitting methods as well as with different nonparametric methods for 369 rivers across Europe. Results showed that SSI time series and associated drought characteristics are indeed sensitive to the method of choice. A resampling experiment demonstrated the sensitivity of the parametric SSI to properties of both the low and high end of the sample. Such sensitivities might hinder a fair comparison of drought in space and time and highlight the need for a clear recommendation which method to use. We could recommend overall suitable methods, for example, from the parametric approaches, the Tweedie distribution has several advantageous properties such as a low rejection rate (2%) and a lower bound at zero. However, the most suitable method depends on the used evaluation criteria. Rather, we stress that shown approach-specific sensitivities and uncertainties should be carefully considered.
    Schlagwort(e): 551.48 ; drought ; parametric ; drought identification ; Standardized Streamflow Index ; sensitivity analyses ; nonparametric
    Sprache: Englisch
    Materialart: map
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  • 33
    Publikationsdatum: 2021-12-03
    Beschreibung: In recent years, X-ray speckle-tracking techniques have emerged as viable tools for wavefront metrology and sample imaging applications. These methods are based on the measurement of near-field images. Thanks to their simple experimental setup, high angular sensitivity and compatibility with low-coherence sources, these methods have been actively developed for use with synchrotron and laboratory light sources. Not only do speckle-tracking techniques give the potential for high-resolution imaging, but they also provide rapid and robust characterization of aberrations of X-ray optical elements, focal spot profiles, and sample position and transmission properties. In order to realize these capabilities, software implementations are required that are equally rapid and robust. To address this need, a software suite has been developed for the ptychographic X-ray speckle-tracking technique, an X-ray speckle-based method suitable for highly divergent wavefields. The software suite is written in Python 3, with an OpenCL back end for GPU and multi-CPU core processing. It is accessible as a Python module, through the command line or through a graphical user interface, and is available as source code under Version 3 or later of the GNU General Public License.
    Schlagwort(e): 548 ; software ; wavefront metrology ; speckle tracking ; ptychography ; X-ray projection imaging
    Sprache: Englisch
    Materialart: map
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  • 34
    Publikationsdatum: 2021-12-03
    Beschreibung: Coupled groundwater flow and heat transport within hyporheic zones extensively affect water, energy, and solute exchange with surrounding sediments. The local and cumulative implications of this tightly coupled process strongly depend on characteristics of drivers (i.e., discharge and temperature of the water column) and modulators (i.e., hydraulic and thermal properties of the sediment). With this in mind, we perform a systematic numerical analysis of hyporheic responses to understand how the temporal variability of river discharge and temperature affect flow and heat transport within hyporheic zones. We identify typical time series of river discharge and temperature from gauging stations along the headwater region of Mississippi River Basin, which are characterized by different degrees of flow alteration, to drive a physics-based model of the hyporheic exchange process. Our modeling results indicate that coupled groundwater flow and heat transport significantly affects the dynamic response of hyporheic zones, resulting in substantial differences in exchange rates and characteristic time scales of hyporheic exchange processes. We also find that the hyporheic zone dampens river temperature fluctuations increasingly with higher frequency of temperature fluctuations. This dampening effect depends on the system transport time scale and characteristics of river discharge and temperature variability. Furthermore, our results reveal that the flow alteration reduces the potential of hyporheic zones to act as a temperature buffer and hinders denitrification within hyporheic zones. These results have significant implications for understanding the drivers of local variability in hyporheic exchange and the implications for the development of thermal refugia and ecosystem functioning in hyporheic zones.
    Schlagwort(e): 551.48 ; hyporheic exchange ; numerical analysis
    Sprache: Englisch
    Materialart: map
    Standort Signatur Erwartet Verfügbarkeit
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  • 35
    Publikationsdatum: 2021-12-06
    Beschreibung: We describe a low-cost three-dimensional underwater particle tracking velocimetry system to directly measure particle settling rate and flux in low-turbulence aquatic environments. The system consists of two waterproof cameras that acquire stereoscopic videos of sinking particles at 48 frames s−1 over a tunable sampling volume of about 45 × 25 × 24 cm. A dedicated software package has been developed to allow evaluation of particle velocities, concentration and flux, but also of morphometric parameters such as particle area, sinking angle, shape irregularity, and density. Our method offers several advantages over traditional approaches, like sediment trap or expensive in situ camera systems: (1) it does not require beforehand particle collection and handling; (2) it is not subjected to sediment trap biases from turbulence, horizontal advection, or presence of swimmers, that may alter particulate load and flux; (3) the camera system enables faster data processing and flux computation at higher spatial resolution; (4) apart from the particle settling rates, the particle size distribution, and morphology is determined. We tested the camera system in Lake Stechlin (Germany) in low turbulence and mean flow, and analyzed the morphological properties and settling rates of particles to determine their sinking behavior. The particle flux assessed from conventional sediment trap measurements agreed well with that determined by our system. By this, the low-cost approach demonstrated its reliability in low turbulence environments and a strong potential to provide new insights into particulate carbon transport in aquatic systems. Extension of the method to more turbulent and advective conditions is also discussed.
    Schlagwort(e): 551.48 ; aquatic environments ; particle velocity ; tracking system
    Sprache: Englisch
    Materialart: map
    Standort Signatur Erwartet Verfügbarkeit
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  • 36
    Publikationsdatum: 2021-12-03
    Beschreibung: The rising popularity and strong increase in the number of electric bicycles make it necessary to consider the built-in resources as well as possible treatments after the use phase. The time lag between the purchase and the occurrence of relevant defects suggests significant increases in defective components. Especially the great dynamics of the market due to regular innovations, product renewals, and the lack of spare parts availability for older models make the long-term use by customers much more difficult than for conventional bicycles. Therefore, it is necessary to analyze circular business models for the electric bicycle market. In this way, the required structures for a sustainable electric bicycle industry can be created so that valuable materials do not go into disposal but undergo a new use phase. Based on the results of "AddRE-Mo-Value Preservation Scenarios for Urban Electromobility of Persons and Loads through Additive Manufacturing and Remanufacturing," a research project funded by the German Federal Ministry of Education and Research, this paper addresses four circular business models, two sales models, and two service models. The guiding research interest of this paper is the combination of remanufacturing and additive manufacturing from a business model perspective, analyzing the extent to which additive remanufacturing can be considered a solution for electric bicycles' circularity. After describing the approach and methods used to develop these four circular business models the business models are described and analyzed using the Business Model Canvas. Based on this analysis, it is shown that the combination of remanufacturing and additive manufacturing can be applied to the electric bicycle market and be integrated into both sales and service models. The description of these business models will help managers design viable business models in the context of sustainable electric bicycles. It also shows that the individual partners within the value chain must collaborate more closely. In the electric bicycle industry, a single company will probably not be able to close the product cycle completely. Further research is needed to develop concepts of the business models and examine their practical feasibility in technical and organizational operations to achieve a circular economy.
    Schlagwort(e): ddc:330
    Repository-Name: Wuppertal Institut für Klima, Umwelt, Energie
    Sprache: Englisch
    Materialart: article , doc-type:article
    Format: application/pdf
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  • 37
    Publikationsdatum: 2021-11-11
    Beschreibung: Reuse is still seen as a "niche phenomenon" and consumers seem to waste economic opportunities linked to buying and selling second-hand products. For this reason, this paper focuses on incentives and barriers to sell and buy second-hand products, as indicated in the literature, and applies a theoretical framework of transaction costs to explain the existing consumption patterns. For this paper, a representative online survey was conducted in which 1023 consumers in Germany participated, age 16 and older. The data were analyzed for statistically significant deviations between different groups of economic actors selling or buying second-hand products. Results show that valuable unused products exist in households, but barriers such as uncertainties about the reliability of the buyer or the quality of the product hinder the transition into sustainable consumption. Different forms of transaction costs are important explanatory variables to explain why consumers nevertheless predominantly buy new products, although they are aware that second-hand would save money and make an individual contribution to climate protection.
    Schlagwort(e): ddc:330
    Repository-Name: Wuppertal Institut für Klima, Umwelt, Energie
    Sprache: Englisch
    Materialart: article , doc-type:article
    Format: application/pdf
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  • 38
    Publikationsdatum: 2021-11-11
    Beschreibung: This paper argues that, although Japan's and Germany's energy transition paths differ in detail, a trend towards decentralisation is clearly evident in both countries. Based on comprehensive screening, own stocktaking and the results of a stakeholder dialogue, this paper highlights the motivation for different local actors to enter the energy market in both countries. Although there are challenges to success in a market dominated by large energy companies, this paper argues that the benefits to local communities outweigh the efforts. Overall, it is shown that democratisation and the decentralisation of the energy system are suitable to facilitate a successful transformation process in both countries.
    Schlagwort(e): ddc:330
    Repository-Name: Wuppertal Institut für Klima, Umwelt, Energie
    Sprache: Englisch
    Materialart: article , doc-type:article
    Format: application/pdf
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  • 39
    Publikationsdatum: 2021-11-26
    Beschreibung: More and more companies are announcing their intention to become climate-neutral and numerous companies already offer climate-neutral products or services: From climate-neutral parcel delivery to air travel. But what exactly do the companies' net-zero targets mean? Is the target set ambitious? And what role does offsetting play, i.e., purchasing carbon credits that are accounted against the company's own climate target? The approaches behind the proclaimed targets are often difficult to understand. Against this background, this Zukunftsimpuls provides ten recommendations for the definition and implementation of neutrality targets. Among other things, the authors advocate the use of a robust database as the basis for net-zero targets, emphasize the importance of transparent communication, and highlight the role that offsetting should play. Purchased carbon credits should make as limited a contribution as possible for meeting climate targets and should only be used to offset emissions that cannot be reduced or avoided. More generally, net-zero targets should not be made the sole criterion for ambitious climate strategies. Rather, they are a building block of a much more comprehensive strategy of corporate climate action.
    Schlagwort(e): ddc:330
    Repository-Name: Wuppertal Institut für Klima, Umwelt, Energie
    Sprache: Englisch
    Materialart: workingpaper , doc-type:workingPaper
    Format: application/pdf
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  • 40
    Publikationsdatum: 2021-10-26
    Beschreibung: The rate of biogeochemical processing associated with natural degradation and transformation processes in the hyporheic zone (HZ) is one of the largest uncertainties in predicting nutrient fluxes. We present a lumped parameter model that can be used to quantify the mass loss for nitrate in the HZ operating at the scale of river reaches to the entire catchments. The model is based on using exposure times (ET) to account for the effective timescales of reactive transport in the HZ. Reach scale ET distributions are derived by removing the portion of hyporheic residence times (RT) associated with flow through the oxic zone. The model was used to quantify nitrate removal for two scenarios: (1) a 100 m generic river reach and (2) a small agricultural catchment in Brittany (France). For the field site, hyporheic RT were derived from measured in-stream 222Rn activities and mass balance modeling. Simulations were carried out using different types of RT distributions (exponential, power law, and gamma-type) for which ET were derived. Mass loss of nitrate in the HZ for the field site ranged from 0 to 0.45 kg day−1 depending on the RT distribution and the availability of oxygen in the streambed sediments. Simulations with power law ET distribution models only show very little removal of nitrate due to the heavy weighting toward shorter flow paths that are confined to the oxic sediments. Based on the simulation results, we suggest that using ET will likely lead to more realistic estimates for nutrient removal in river and stream networks.
    Schlagwort(e): 551.48 ; Lumped parameter modeling of hyporheic nitrate removal by applying exposure times ; Exposure time distributions are derived from analytical residence time distributions ; Using exposure times is likely to lead to more realistic estimates for nutrient removal
    Sprache: Englisch
    Materialart: map
    Standort Signatur Erwartet Verfügbarkeit
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