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  • 2020-2023  (647)
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  • 1
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    Leibniz Research Network Biodiversity
    Publication Date: 2022-12-16
    Description: The authors of the 10 Must Knows from Biodiversity Science (2022, DOI: 10.5281/zenodo.6257527, 10MustKnows) have developed their scientific findings further into 10 Must Dos from Biodiversity Science (10MustDos). The 10MustDos correspond with ten concrete recommendations for political actions that can be implemented in the short term. They are intended to serve as a guide for negotiations at the 15th UN Biodiversity Conference (CBD COP 15, 7-19 December 2022 in Montréal). In addition, they also aim at supporting practical policy-making in Germany, Europe and worldwide through well-founded scientific knowledge with the overarching goal to protect global biodiversity and to stop the man-made extinction of species. The proposed solutions open up possibilities for action which are in alignment with the goals of the UN Decade for the Restoration of Ecosystems (2021-2030) and contribute to the 17 Sustainable Development Goals (SDGs) which are to be implemented by all states by 2030 in order to tackle the biodiversity, climate, and equity crisis collectively. 
    Language: English
    Type: info:eu-repo/semantics/report
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  • 2
    Publication Date: 2022-12-16
    Description: We synthesize 10 topics within climate research where there have been significant advances or emerging scientific consensus since January 2021. The selection of these insights was based on input from an international open call with broad disciplinary scope. Findings concern: (1) new aspects of soft and hard limits to adaptation; (2) the emergence of regional vulnerability hotspots from climate impacts and human vulnerability; (3) new threats on the climate–health horizon – some involving plants and animals; (4) climate (im)mobility and the need for anticipatory action; (5) security and climate; (6) sustainable land management as a prerequisite to land-based solutions; (7) sustainable finance practices in the private sector and the need for political guidance; (8) the urgent planetary imperative for addressing losses and damages; (9) inclusive societal choices for climate-resilient development and (10) how to overcome barriers to accelerate mitigation and limit global warming to below 2°C.
    Language: English
    Type: info:eu-repo/semantics/article
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  • 3
    Publication Date: 2022-12-15
    Description: Variability of the North Atlantic Oscillation (NAO) drives wintertime temperature anomalies in the Northern Hemisphere. Dynamical seasonal prediction systems can skilfully predict the winter NAO. However, prediction of the NAO‐dependent air temperature anomalies remains elusive, partially due to the low variability of predicted NAO. Here, we demonstrate a hidden potential of a multi‐model ensemble of operational seasonal prediction systems for predicting wintertime temperature by increasing the variability of predicted NAO. We identify and subsample those ensemble members which are close to NAO index statistically estimated from initial autumn conditions. In our novel multi‐model approach, the correlation prediction skill for wintertime Central Europe temperature is improved from 0.25 to 0.66, accompanied by an increased winter NAO prediction skill of 0.9. Thereby, temperature anomalies can be skilfully predicted for the upcoming winter over a large part of the Northern Hemisphere through increased variability and skill of predicted NAO.
    Description: Plain Language Summary: Wintertime temperature in the Northern Hemisphere is regulated by the variations of atmospheric pressure, represented by the so‐called North Atlantic Oscillation (NAO). The NAO's phase—negative or positive—is associated with the pathways of cold and warm air masses leading to cold or warm winters in Europe. While the NAO phase can be predicted well, predictions of the NAO‐dependent air temperature remain elusive. Specifically, it is challenging to predict the strength of the NAO, the most important requirement for the accurate prediction of wintertime temperature. Here, we improve wintertime temperature prediction by increasing the strength of the predicted NAO. We use observation based autumn Northern Hemisphere ocean and air temperature, as well as ice and snow cover for statistical estimation of the first guess NAO for the upcoming winter. Then, we sub‐select only those simulations from the multi‐model ensemble, which are consistent with our first guess NAO. As a result, based on these selected members, the wintertime temperature prediction is substantially improved over a large part of the Northern Hemisphere.
    Description: Key Points: Amplitude and skill of predicted North Atlantic Oscillation (NAO) improve significantly by subsampling of ensemble of existing seasonal prediction systems. Amplified NAO variability leads to significant improvement in predicting the upcoming winter temperature anomalies in the Northern Hemisphere.
    Description: Deutsche Forschungsgemeinschaft
    Description: Climate, Climatic Change, and Society
    Description: Marine Institute grant
    Description: European Union's Horizon 2020 research and innovation programme
    Description: https://cds.climate.copernicus.eu/cdsapp#!/dataset/seasonal-original-single-levels?tab=overview
    Description: http://www.ecmwf.int/en/forecasts/datasets
    Keywords: ddc:551.6 ; seasonal prediction ; wintertime temperature anomalies
    Language: English
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  • 4
    Publication Date: 2022-12-15
    Description: High‐pressure (HP) X‐ray diffraction experiments at low temperature (LT) require dedicated instruments as well as non‐standard sample environments and measuring strategies. This is especially true when helium cryogenic temperatures below 80 K are targeted. Furthermore, only experiments on single‐crystalline samples provide the prerequisites to study subtle structural changes in the p–T phase diagram under extreme LT and HP conditions in greater detail. Due to special hardware requirements, such measurements are usually in the realm of synchrotron beamlines. This contribution describes the design of an LT/HP diffractometer (HTD2) to perform single‐crystal X‐ray diffraction experiments using a laboratory source in the temperature range 400 〉 T 〉 2 K while applying pressures of up to 20 GPa.
    Description: The design and operation of a newly commissioned single‐crystal X‐ray diffractometer (HTD2) are presented. The device enables experiments under simultaneous low‐temperature and high‐pressure conditions using a laboratory X‐ray source.
    Keywords: ddc:548 ; HTD2 ; low temperature ; high pressure ; single crystals ; instrumentation
    Language: English
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  • 5
    Publication Date: 2022-12-15
    Description: Most pyroclastic deposits of Popocatépetl volcano were emplaced at high temperatures and have similar mafic to more evolved compositions, suggesting a long‐lived, interconnected magma environment. We performed a magnetic and microscopic study on different eruptive sequences 〈14 ky in age and found that temperature and field dependence of magnetic susceptibility are suited to separate eruption phases. We observed homogeneous titanomagnetite with Curie temperatures (TC) of 50–200°C and 200–400°C, together with different amounts of oxy‐exsolved titanomagnetite with TC ∼ 570°C. Some block‐and‐ash flow deposits show remarkably irreversible TC in heating and cooling branches with a positive ΔTC (TC heating–TC cooling) of up to 130°C in the center. The central part of this sequence is characterized by decreasing magnetic susceptibility and low field dependence of magnetic susceptibility (〈10%), which is atypical for ulvöspinel‐rich titanomagnetite. The nonreversibility of heating and cooling runs measured with rates of around 10 K/min is probably related to vacancy‐enhanced nanoscale chemical clustering, which seems to occur preferentially during rapid quenching, possibly combined with subtle maghemitization. In contrast, pumice layers have the highest field dependence (∼20%) and contain Ti‐rich and intermediate titanomagnetite with TC 〈 100 and ∼300°C, which are in line with mafic and more evolved magma composition. In intermediate phases, irreversibility of TC is more common but with a relatively low ΔTC of ±20°C. We suggest that magneto‐mineralogy in pyroclastic density currents is complex but offers a complementary tool to the paleomagnetic directional analysis for emplacement temperature and contribute information on the volcanic material history and their emplacement conditions.
    Description: Plain Language Summary: Explosive eruptions of volcanoes are a dangerous threat to human settlements. In this study, we investigated pyroclastic material from the last 14 ky of Popocatépetl volcano using magnetic mineral assemblages, hysteresis properties, and temperature‐ and field‐dependent magnetic susceptibility. The data are suited to separate different eruption phases and provide information on the volcanic material history and emplacement conditions. Magnetic susceptibility analyses are suggested to be a complementary tool to the paleomagnetic directional analysis for the determination of emplacement temperatures.
    Description: Key Points: Several Curie temperatures were observed in pyroclastic deposits. Temperature and field dependence of magnetic susceptibility are suited to separate eruption phases. Irreversible Curie temperatures in heating and cooling curves observed in block‐and‐ash flows may suggest rapid quenching.
    Description: DGAPA‐UNAM
    Description: https://doi.org/10.17632/9g2tszftvr.2
    Description: https://earthref.org/MagIC/19591/206809c5-acfc-41e3-b4cb-411630a7025e
    Keywords: ddc:552.2 ; Popocatépetl volcano ; pyroclastic deposits ; magnetic rock studies ; magnetic mineralogy studies ; cooling temerature
    Language: English
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  • 6
    Publication Date: 2022-12-15
    Description: The subduction of serpentinized slabs is the dominant process to transport “water” into Earth's mantle, and plays a pivotal role for subduction dynamics. Antigorite, the most abundant serpentine mineral in subduction settings, may imprint a seismic signature on serpentinized slabs, making them seismically distinguishable from the dry, non‐serpentinized ones. However, the complete single‐crystal elasticity of antigorite has not been experimentally constrained at high pressures, hindering the use of seismological approaches to detect serpentinization in subducting slabs. Here, we report the full elastic stiffness tensor of antigorite by single‐crystal Brillouin spectroscopy and X‐ray diffraction up to 7.71(5) GPa. We use our results to model seismic properties of antigorite‐bearing rocks and show that their seismological detectability depends on the geometrical relation between seismic wave paths and foliation of serpentinized rocks. In particular, we demonstrate that seismic shear anisotropy shows low sensitivity to serpentinization for a range of relevant geometries.
    Description: Plain Language Summary: The subduction of serpentinized slabs plays a key role in the deep recycling of water into the Earth's interior. Antigorite is the main serpentine mineral in subducting slabs, and the most important carrier of water. Antigorite‐bearing rocks are predicted to have a distinct seismic signature, potentially allowing them to be detected with seismological approaches. However, our current knowledge on seismic properties of antigorite‐bearing rocks is limited, mostly hampered by a lack of experimental constraints on single‐crystal elasticity of antigorite at relevant pressures. In this study, state‐of‐the‐art techniques were employed to produce the first experimental description of the complete high‐pressure elasticity of antigorite single crystals. Our experimental data set was implemented in the modeling of seismic properties of antigorite‐bearing rocks at pressures relevant for subduction. Our results were used to discuss the relation between seismic wave path and shear wave anisotropy in serpentinized slabs, and challenge the use of shear wave splitting as a proxy for serpentinization in slabs.
    Description: Key Points: Single‐crystal elasticity of antigorite at high pressures is determined by Brillouin spectroscopy and X‐ray diffraction experiments. Seismic signature of serpentinized slabs is constrained in a relevant composition‐pressure space. Serpentinization in slabs may be undetectable through shear wave anisotropy.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: EC Horizon 2020 Framework Programme http://dx.doi.org/10.13039/100010661
    Description: https://doi.org/10.6084/m9.figshare.20348748
    Description: https://doi.org/10.6084/m9.figshare.20348781
    Keywords: ddc:550 ; serpentine ; elasticity ; Brillouin spectroscopy ; antigorite ; seismic anisotropy ; shear wave splitting
    Language: English
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  • 7
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    In:  The Climate Book
    Publication Date: 2022-12-15
    Language: English
    Type: info:eu-repo/semantics/bookPart
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  • 8
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    In:  The Climate Book
    Publication Date: 2022-12-15
    Language: English
    Type: info:eu-repo/semantics/bookPart
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  • 9
    Publication Date: 2022-12-14
    Description: The past as an analogue for the future is one of the main motivations to use climate models for paleoclimate applications. Assessing possible model limitations in simulating past climate changes can lead to an improved understanding and representation of the response of the climate system to changes in the forcing, setting the basis for more reliable information for the future. In this study, the regional climate model (RCM) COSMO-CLM is used for the investigation of the mid-Holocene (MH, 6000 years ago) European climate, aiming to contribute to the solution of the long-standing debate on the reconstruction of MH summer temperatures for the region, and gaining more insights into the development of appropriate methods for the production of future climate projections. Two physically perturbed ensembles (PPEs) are first built by perturbing model physics and parameter values, consistently over two periods characterized by different forcing (i.e., the MH and pre-industrial, PI). The goal is to uncover possible processes associated with the considered changes that could deliver a response in MH summer temperatures closer to evidence from continental-scale pollen-based reconstructions. None of the investigated changes in model configuration produces remarkable differences with respect to the mean model behavior. This indicates a limited sensitivity of the model to changes in the climate forcing, in terms of its structural uncertainty. Additional sensitivity tests are further conducted for the MH, by perturbing the model initial soil moisture conditions at the beginning of spring. A strong spatial dependency of summer near-surface temperatures on the soil moisture available in spring is evinced from these experiments, with particularly remarkable differences evident over the Balkans and the areas north of the Black Sea. This emphasizes the role of soil–atmosphere interactions as one of the possible drivers of the differences in proxy-based summer temperatures evident between northern and southern Europe. A well-known deficiency of the considered land scheme of COSMO-CLM in properly retaining spring soil moisture, confirmed by the performed tests, suggests that more attention should be paid to the performance of the soil component of climate models applied to this case study. The consideration of more complex soil schemes may be required to help bridging the gap between models and proxy reconstructions. Finally, the distribution of the PPEs with changes in model configuration is analyzed for different variables. In almost all of the considered cases the results show that what is optimal for one period, in terms of a model configuration, is not the best for another characterized by different radiative forcing. These results raise concerns about the usefulness of automatic and objective calibration methods for RCMs, suggesting that a preferable approach is the production of small PPEs that target a set of model configurations, properly representing climate phenomena characteristic of the target region and that will be likely to contain the best model answer under different forcing.
    Language: English
    Type: info:eu-repo/semantics/article
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  • 10
    Publication Date: 2022-12-10
    Description: In the course of the energy transition, storage technologies are required for the fluctuating and intermittently occurring electrical energy. The vanadium flow battery (VFB) is an especially promising electrochemical battery type for megawatt applications due to its unique characteristics. This work is intended as a benchmark for the evaluation of environmental impacts of a VFB, providing transparency and traceability. It considers the requirements for an industrial VFB from the technical and electrochemical point of view. The system design is based on a net capacity of 8 MWh and a net power of 1 MW. This ex ante study is a cradle‐to‐grave life cycle assessment (LCA) for a VFB to identify, analyze, and evaluate the environmental impacts for a lifetime of 20 years. Moreover, potential environmental impacts of several subsequent life cycles of the emission‐intensive and long‐lasting vanadium electrolyte are evaluated. With a focus on the electrolyte, the extraction process of vanadium pentoxide is studied in detail for the first time. Consequently, recommendations for the design of the life cycle of VFBs and for comparative LCAs with other energy storage technologies can be derived. Based on this work, more detailed work can follow, which helps to estimate the recycling potentials and emissions more precisely. This article met the requirements for a gold‐gold JIE data openness badge described at https://jie.click/badges
    Description: German Federal Ministry for Economic Affairs and Climate Action
    Keywords: ddc:621.31 ; climate change ; energy storage ; industrial ecology ; life cycle assessment ; vanadium flow battery ; vanadium pentoxide
    Language: English
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