ALBERT

Description: This publication is a result of the 12th TRACE conference (Tree Rings in Archaeology, Climatology and Ecology) organized by the Department of Agriculture, Forests, Nature and Energy (DAFNE) of the Università della Tuscia (Viterbo, Italy) on May 08th – 11th 2013 in Viterbo, Italy. [...] A total of 20 manuscripts were submitted. After review 19 short papers are published in this volume, giving an overview of the wide spectrum of fields in tree-ring research.

Description: [...] In context of this work, a new damage mechanism is proposed: the mechanically induced fracture face skin. This new mechanism results from mechanical interactions between the proppants and the reservoir rock, due to the increasing stress on the rock-proppant system during production. Proppant embedment into the fracture face and proppant crushing leads to fines production and can impair the fracture performance. In order to achieve sustainable, longterm productivity from a reservoir, it is indispensable to understand the hydraulic and mechanical interactions in the rock-proppant system. In order to analyse the hydraulic and mechanical interactions, laboratory experiments using three different flow cells were conducted. These flow cells were used to localise and quantify the mechanical damage at the fracture face, as well as to investigate the long-term stability of a rock-proppant system under in-situ reservoir conditions. [...]

Description: This study represents the first investigating potential kinematic boundary conditions for subduction erosion in a systematic manner. For the subduction erosional process, the aperture at the box's rear, which allowed rearward material loss, was shown to have the largest influence on obtained results. If the amount of material leaving the system was larger than the amount of material subducted at the wedge's toe, the margin evolved as erosional. We found the surface slope to be the second important parameter, which strongly controls the amount of basally eroded material.

Description: This short report describes the first attempt at obtaining a preliminary cross-border risk model for Central Asia starting from datasets that were already available at the beginning of the EMCA Project.

Description: This volume contains 23 short papers which summarise the main subjects of talks and posters presented at the eighth TRACE (Tree Rings in Archaeology, Climatology and Ecology) conference organized by Jožica Gričar, Tom Levanič, Špela Jagodic, Robert Krajnc and Polona Hafner and held in Otočec, Slovenia on April 16th - 19th, 2009.

Description: This document serves as a record of the processing standards, models & parameters adopted for the generation of monthly and weekly (aligned to GPS weeks) Level-2 gravity field data products by the GRACE Science Data System component at the GFZ German Research Centre for Geosciences.

Description: SEG-Y data of small-scale high-resolution controlled-source seismic experiment to investigate the mesoscopic fault structure of the Wadi Arava fault, Dead Sea Transform.

Description: In order to analyze mineralogical-geochemical changes occurring in whole rock reservoir samples (Stuttgart Formation) from the Ketzin pilot CO2 storage site, Brandenburg/Germany as well as to investigate single fluid-mineral reactions laboratory experiments and geochemical modeling were performed. The whole rock core samples of the Stuttgart Formation were exposed to synthetic brine and pure CO2 at experimental P-T conditions and run durations of 5.5 MPa/40 °C/40 months for sandstone and 7.5 MPa/40 °C/6 months for siltstone, respectively. Mineralogical changes in both sets of experiments are generally minor making it difficult to differentiate the natural variability of the whole rock samples from CO2-induced alterations. Results of sandstone experiments suggest dissolution of analcime, anhydrite, the anorthite component of plagioclase, chlorite + biotite, hematite and K-feldspar. Dissolution of anhydrite, the anorthite component of plagioclase and K-feldspar is also observed in siltstone experiments. During equilibrium simulations best matching models were ranked based on a mathematical statistical dispersion relation. The best matching model comprises a mineral combination of the albite component of plagioclase, anhydrite, dolomite, hematite, and illite. The equilibrium modeling showed that it is difficult to match K+, Fe2+ and SO4 2- brine concentrations simultaneously. The best matching subsets of the equilibrium models were finally run including kinetic rate laws. These kinetic simulations reveal that experimentally determined brine data was well matched, but reactions involving K+ and Fe2+ were not completely covered. Generally larger mismatches for dissolved Al3+ and Si4+ in all the completed simulations are most likely related to the sampling strategy and respective inaccuracies in the measured concentrations of dissolved Al3+ and Si4+. The kinetic simulation suppressing mineral precipitation yields best matches with experimental observations. The modeling shows acceptably well matches with measured brine ion concentrations, and the modeling results identified primary minerals as well as key chemical processes. It was also shown that the modeling approach is not capable of completely covering complex natural systems. Experiments on mineral separates were conducted with 2 M NaCl brine and pure CO2 using siderite, illite and labradorite samples. Experimental P-T conditions were 20 (30) MPa and 80 °C; run durations were one (siderite), two (illite) and three weeks (labradorite), respectively. Based on the acquired set of mineralogical-geochemical data the distinct experiments show: (i) dissolution of ankerite and stable siderite, which is therefore interpreted to be a potential CO2 trapping phase, (ii) preferred dissolution of the Ca-smectite component out of the illite-smectite mixed-layer mineral and (iii) dissolution of labradorite, respectively. No mineral precipitates (e.g. carbonate phases) were detected in any of the conducted laboratory experiments, and only one single kinetic simulation predicts the formation of minute amounts of dolomite. Based on the data acquired during this dissertation the mineralogical-geochemical effects of CO2 are minor, and the (chemical) integrity of the Ketzin reservoir system is not significantly affected by injected CO2.