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  • 1
    Publication Date: 2024-05-27
    Description: To enhance the EU's economic autonomy, feasible options for local sourcing of critical raw materials that would allow for shorter supply routes along with ethical and responsible value chains are under contemplation. Social acceptance of mining in Europe is, however, low, and the establishment of new mining sites faces strong public opposition. Therefore, innovative solutions for the production of primary raw materials need to be developed. A new idea for raw material extraction is the extraction of essential elements from geothermal fluids. Deep geothermal fluids, increasingly used for energy production, often contain high concen-trations of dissolved ions and gases in commercially interesting concentrations. The EU-funded project CRM-geothermal aims to develop new technologies to extract these highly relevant elements, including helium, during geothermal production cycles. In this way, an environmentally friendly and socially acceptable exploration and exploitation method could be deployed. One aim of the CRM-geothermal project is to gain an overview of the actual quantities of critical raw materials in various geothermal fluids in Europe by taking and analyzing fluid samples. In Turkey for instance, classical high enthalpy (volcanic) systems exist, which are representative for many geothermal areas worldwide. The sites are located at the edges of tectonic plates and close to areas undergoing volcanic activity. The brines are mixed with seawater and circulate in the deeper crust. The data publication contains analyses results of three gas samples from Tuzla, two samples from Seferihisar geothermal power plant and one sample from the Dikili geothermal field in Turkey, taken in 2023 as part of the CRM-geothermal project.
    Language: English
    Type: info:eu-repo/semantics/workingPaper
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  • 2
    Publication Date: 2024-05-22
    Description: The EU funded project CRM-geothermal aims to establish an overview of the potential for critical raw materials (CRM) in geothermal fluids across the EU and third countries (Ref). Within this framework, the geothermal sites of Tuzla, Seferihisar and Dikili in eastern Turkey have been visited in March 2023. To estimate the potential of CRM at these sites, a comprehensive sampling program was performed. Rock samples (drill gravel) of the production borehole and scaling from gas-water separators were obtained. Furthermore, sampling of geothermal fluids (gas and brine) and precipitates (salt) along the production line was performed. Here, the results of the geochemical analyses of solid sample materials (drill gravel, scales and salt) are presented. All analyses were performed in the ElMiE-Lab (Elements and Minerals of the Earth Laboratory) at German Research Centre for Geosciences Potsdam, Germany (https://labinfrastructure.geo-x.net/laboratories/8). For their major and minor element compositions, bulk samples of drill gravel and scales were analyzed with XRF and ICP-MS, respectively. Salt precipitates were analyzed for dry loss and mineral composition using XRD
    Language: English
    Type: info:eu-repo/semantics/workingPaper
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  • 3
    Publication Date: 2024-05-22
    Description: In autumn 2022, an expedition to Tanzania was undertaken within the framework of the research project “CRM-geothermal” and Scintific Priority Program (SPP) 2238 “Dynamics of Ore Metal Enrichment”. Within „CRM-geothermal“ we are looking for an environmentally friendly co-production of critical raw materials together with the provision of geothermal energy. In the EARS, high levels of rare earth elements (REE), Sr, Ba and Mg are expected in waters and solids in areas with alkaline volcanic rocks, while other critical elements, including helium, have been sought in other localities. In particular, the eastern branch is the most juvenile sector and has increased geothermal potential related to hot fluids migrating along permeable faults. Tanzania was crossed from north to south, along the eastern arm of the EARS, to collect gas, water, rock and sediment samples associated with natural hot springs, lakes and vents. On site, physical and chemical parameters were measured in-situ and documented together with the geology, infrastructure and the domestic use of the hot site. In the south, existing drill sites and geothermal development areas were visited and gas and water samples were taken from boreholes and rocks sampled from drill cores. The survey covered 13 sites, from Lake Natron in the north to Lake Malawi in the south (see map).
    Language: English
    Type: info:eu-repo/semantics/workingPaper
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  • 4
    Publication Date: 2024-05-17
    Description: This dataset is the result of an experimental series that was carried out in September/October 2022 at GFZ German Research Centre for Geosciences, Potsdam, Germany to observe biosorption of lead under extreme conditions. Synthetic solutions, simulating the geothermal fluids from the Heemskerk geothermal power plant were were prepared in 30 ml glass vials (Rotalibo screw neck ND24 EPA). To prepare the stock solutions, sodium chloride (NaCl, 99.8 %, Cellpure, Merck, DE) was added at 265 g/L and Pb(II), in form of lead nitrate (Pb(NO3 )2 , Merck, DE), at 1 g/L to ultrapure water. To assess the impact of acetic acid on lead biosorption, two treatments were done: one without acetic acid and one where acetic acid (100 %, Merck, DE) was added at 60 mg/L. Finally, dead biomass of the fungus Penicillium citrinum was added in the samples at a concentration of 4 g/L (Wahab et al., 2017). The samples were incubated in an autoclave at a pressure of 8 bars on a rotative shaker. The temperature was set at 25 °C, 60 °C or 98 °C with three contact times (1, 2 and 3 h). All treatments were performed in triplicates. For each treatment, two controls without biomass were done. Control samples without the addition of NaCl were done in duplicate, at 25 °C and for 2 h. After incubation, samples were filtered through a 0.22 µm nitrocellulose filter (Sartorius Stedim Biotech, FR) to separate the biomass from the liquid. The biomass on the filters was dried for 24 h at 45 °C before being scraped from the filter and kept in a Falcon tube at room temperature.
    Language: English
    Type: info:eu-repo/semantics/workingPaper
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  • 5
    Publication Date: 2024-05-03
    Description: This data set includes the results of high-resolution digital elevation models (DEM) and digital image correlation (DIC) analysis applied to analogue modelling experiments. Twenty generic analogue models are extended on top of a rubber sheet. Two benchmark experiments are also reported. Detailed descriptions of the experiments can be found in Liu et al. (submitted) to which this data set is supplement. The data presented here are visualized as topography and the horizontal cumulative surface strain (principal strain and slip rake).
    Language: English
    Type: info:eu-repo/semantics/workingPaper
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  • 6
    Publication Date: 2024-04-22
    Description: This publication provides the codes produced for the article "Temporally dynamic carbon dioxide and methane emission factors for rewetted peatlands. Nature Communications Earth and Environment" by Aram Kalhori, Christian Wille, Pia Gottschalk, Zhan Li, Josh Hashemi, Karl Kemper, and Torsten Sachs (https://doi.org/10.1038/s43247-024-01226-9). In the article, the authors estimate the cumulative GHG emissions of a rewetted peatland in Germany using the long-term ecosystem flux measurements. They observe a source-to-sink transition of annual carbon dioxide (CO2) fluxes and decreasing trend of methane (CH4) emissions. This software is written in R and MATLAB. Running the codes ([R files and .m files](Code)) and loading the data files ([CSV files and .mat files](Data)) requires the pre-installation of [R and RStudio] (https://posit.co/downloads/) and ([MATLAB]. The RStudio 2022.07.2 Build 576 version has been used for the R scripts. The land cover classification work was performed in QGIS, v.3.16.11-Hannover. Data were analyzed in both MATLAB and R and plots created with R (R Core Development Team 2020) in RStudio®.
    Language: English
    Type: info:eu-repo/semantics/other
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  • 7
    Publication Date: 2024-04-22
    Description: The data provided here is an exemplary dataset for the flux site Zarnekow from one year (2018). The complete dataset that is needed to run the codes for all the years can be obtained from the European Fluxes Database Cluster under site ID DE-Zrk (Sachs et al., 2016) or provided upon request. This repository is intended to provide the necessary MATLAB and R code to reproduce the results by Kalhori et al. (2024). The data are provided as zip folder containing (1) a csv file with associated definition of variables and units (file: 2023-004_Kalhori-et-al_README_2018_units.txt), (2) a shapefile (file: 2023-004_Kalhori-et-al_2018_LAiV_DOP.shp) and (3) a Geotiff (file: 2023-004_Kalhori-et-al_2018_LAiV_DOP.tiff).
    Language: English
    Type: info:eu-repo/semantics/workingPaper
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  • 8
    Publication Date: 2024-04-10
    Description: In near-Earth space, a large population of high-energy electrons are trapped by Earth’s magnetic field. These energetic electrons are trapped in the regions called Earth’s ring current and radiation belts. They are very dynamic and show a very strong dependence on solar wind and geomagnetic conditions. These energetic electrons can be dangerous to satellites in the near-Earth space. Therefore, it is very important to understand the mechanisms which drive the dynamics of these energetic electrons. Wave-particle interaction is one of the most important mechanisms. Among the waves that can be encountered by the energetic electrons when they move around our Earth, whistler mode chorus waves can cause both acceleration and the loss of energetic electrons in the Earth's radiation belts and ring current. Using more than 5 years of wave measurements from NASA’s Van Allen Probe mission, Wang et al (2019) developed chorus wave models which depend on magnetic local time (MLT), Magnetic Latitude (MLat), L-shell, and geomagnetic condition index Kp. To quantify the effect of chorus waves on energetic electrons, we calculated the bounce-averaged quasi-linear diffusion coefficients using the chorus wave model developed by Wang et al (2019) and extended to higher latitudes according to Wang and Shprits (2019). Using these diffusion coefficients, we calculated the lifetime of the electrons with an energy range from 1 keV to 2 MeV. In each MLT, we calculate the lifetime for each energy and L-shell using two different methods according to Shprits et al (2007) and Albert and Shprits (2009). We make the calculated electron lifetime database available here. Please notice that the chorus wave model by Wang et al (2019) is valid when Kp 〈= 6. If the user wants to use this lifetime database for Kp 〉6, please be careful and contact the authors.
    Language: English
    Type: info:eu-repo/semantics/workingPaper
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  • 9
    Publication Date: 2024-03-05
    Description: The META-WT project was designed to perform a 4-weeks seismic experiment in Germany with a dense seismic array of ~400 three-component geophones that covered (1) a 2.5km x 2.5km wind farm area in Brandenburg, Germany, with almost 200 wind turbines (WTs) and a well-studied subsurface structure and (2) a 20-km long radial line from the center of the wind farm with one geophone every half-kilometer. The objective was to capture the spatio-temporal seismic wave-field signature of the wind farm from continuous recordings of ambient noise. Due to the dense interstation distance and proposed geometry the experiment allowed for analyzing both small-scale wave field characteristics at an unprecedented spatial resolution and the longer distance radiation pattern of the wind farm. Waveform data is available from the GEOFON data centre, under network code XF, and is embargoed until Jan 2025.
    Language: English
    Type: info:eu-repo/semantics/workingPaper
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  • 10
    Publication Date: 2024-02-28
    Description: This data set contains the results from a 2023 GFZ Innovative Research Expedition project to explore for natural hydrogen gas (H2) occurrences in the NW Pyrenean foreland, near the town of Biarritz in France. The data represent in-situ measurements of soil and spring water gas, as well as in-situ spring water property measurements, complemented with laboratory analysis results of gas contents and noble gas isotopic compositions of gas and spring water samples collected during the expedition. This GFZ Innovative Research Expedition was inspired by previous exploration efforts in the region by Lefeuvre et al. (2021, 2022). These authors detected elevated concentrations of natural H2 gas in the soil and interpreted this natural H2 to be derived from serpentinizing mantle rocks below the Pyrenees. The main aims of this expedition were the following: (1) in-situ measuring soil gas contents and taking soil gas samples for laboratory analysis at a site near the town of Peyrehorade in the NW of the general study area of Lefeuvre et al. (2021), thus improving the soil gas data coverage along the NW end of the North Pyrenean Frontal Thrust (NPFT); (2) taking gas samples from degassing springs (or water samples from non-degassing springs to be degassed in the lab) in the general Lefeuvre et al. (2021) study area for additional laboratory analysis of gas contents and noble gas isotopic compositions, which may be indicative of (deep) gas origins; and (3) performing a detailed soil gas analysis by means of a portable mass spectrometer at Sauveterre-de-Béarn, a site along the NPFT where Lefeuvre et al. (2022) measured elevated concentrations of natural H2 in the soil. Furthermore, we also measured the properties of the visited springs (temperature, pH, conductivity) while on site, and performed additional in-situ soil gas measurements from manual drillholes. Details on the measurement and sampling methods, on the laboratory analyses, as well as the results of these measurements and analyses are provided in the data description file The expedition involved six field days in July 2023, during which a total of 26 sites were visited. These sites were selected for their vicinity near a major geological contact or fault zone that could have facilitated upward circulation of gas or (thermal) water from the (deep) subsurface (i.e., potentially from the mantle).
    Language: English
    Type: info:eu-repo/semantics/workingPaper
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