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  • Articles  (3,733)
  • Physical Chemistry  (3,728)
  • 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
  • Wiley-Blackwell  (3,731)
  • Blackwell
  • Elsevier Ltd
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  • Articles  (3,733)
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  • 1
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    Gas hazard assessment at the Monticchio crater lakes of Mt. Vulture, a volcano in Southern Italy (2008)
    Blackwell
    Details
    Publication Date: 2020-11-16
    Description: Geochemical investigations have shown that there is a considerable inflow of gas into both crater lakes of Monticchio, Southern Italy. These lakes are located in two maars that formed 140,000 years ago during Mt. Vulture volcano’s last eruptive activity. Isotopic analyses suggest that CO2 and helium are of magmatic origin; the latter displays 3He/4He isotope ratios similar to those measured in olivines of the maar ejecta. In spite of the fact that the amount of dissolved gases in the water is less than that found in Lake Nyos (Cameroon), both the results obtained and the historical reports studied indicate that these crater lakes could be highly hazardous sites, even if they are located in a region currently considered inactive. This could be of special significance in very popular tourist areas such as the Monticchio lakes, which are visited by about 30,000 people throughout the summer, for the most part on Sundays.
    Description: In press
    Description: 83-87
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: JCR Journal
    Description: open
    Keywords: volcanic gases ; gas hazard ; crater lakes ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
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    Structural features of Panarea volcano in the frame of the Aeolian Arc (Italy): Implications for the 2002–2003 unrest (2009)
    Elsevier Ltd
    Details
    Publication Date: 2017-04-04
    Description: Panarea, characterized by gas unrest in 2002–2003, is the volcanic island with the least constrained structure in the eastern-central Aeolian Arc (Italy). Based on structural measurements, we define here its deformation pattern relative to the Arc. The main deformations are subvertical extension fractures (63% of data), normal faults (25%) and dikes (12%). The mean orientation of the extension fractures and faults is ∼N38◦E, with a mean opening direction of N135◦ ±8◦, implying extension with a moderate component of dextral shear. These data, matched with those available for Stromboli volcano (pure opening) and Vulcano, Lipari and Salina volcanoes (predominant dextralmotions) along the eastern-central Arc, suggest a progressivewestward rotation of the extension direction and an increase in the dextral shear. The dextral shear turns into compression in the western arc. The recent unrest at Panarea, coeval to that of nearby Stromboli, may also be explained by the structural context, as both volcanoes lie along the portion of the Arc subject to extension.
    Description: Protezione Civile, project INGV-DPC-V2
    Description: Published
    Description: 288-292
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 3.2. Tettonica attiva
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: 3.6. Fisica del vulcanismo
    Description: JCR Journal
    Description: reserved
    Keywords: Panarea ; Aeolian Arc ; fault ; dike ; 2002-2003 unrest ; 04. Solid Earth::04.01. Earth Interior::04.01.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.07. Tectonophysics::04.07.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.04. Plate boundaries, motion, and tectonics ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress ; 04. Solid Earth::04.07. Tectonophysics::04.07.06. Subduction related processes ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.07. Tectonophysics::04.07.08. Volcanic arcs ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
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    Gas hazard assessment at the Monticchio Mt. Vulture, a volcano in Southern Italy (2009)
    Wiley-Blackwell
    Details
    Publication Date: 2017-04-04
    Description: Geochemical investigations have shown that there is a considerable inflow of gas into both crater lakes of Monticchio, Southern Italy. These lakes are located in two maars that formed 140 000 years ago during Mt. Vulture volcano s last eruptive activity. Isotopic analyses suggest that CO2 and helium are of magmatic origin; the latter displays 3He ⁄ 4He isotope ratios similar to those measured in olivines of the maar ejecta. In spite of the fact that the amount of dissolved gases in the water is less than that found in Lake Nyos (Cameroon), both the results obtained and the historical reports studied indicate that these crater lakes could be highly hazardous sites, even though they are located in a region currently considered inactive. This could be of special significance in very popular tourist areas such as the Monticchio lakes, which are visited by about 30 000 people throughout the summer, for the most part on Sundays.
    Description: Published
    Description: 83-87
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: JCR Journal
    Description: reserved
    Keywords: volcanic gases ; gas hazard ; crater lakes ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 4
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    Decarbonation and thermal microcracking under magmatic P-T-fCO2 conditions: the role of skarn substrata in promoting volcanic instability (2014)
    Wiley-Blackwell
    Details
    Publication Date: 2017-04-04
    Description: We present a systematic study on the influence of pressure (0.1–600 MPa), temperature (750– 1200 ◦C), carbon dioxide fugacity (logfCO2 = −4.41 to 3.60) and time (2–12 hr) on the chemical and physical properties of carbonate rock. Our experiments aim to reproduce the conditions at the periphery of magma chamber where carbonate host rock is influenced by, but not readily assimilated by, magma. This permits the investigation of the natural conditions at which circulating fluids/gases promote infiltration reactions typical of metasomatic skarns that can involve large volumes of subvolcanic carbonate basements. Results show that, providing that carbon dioxide is retained in the pore space, decarbonation does not proceed at any magmatic pressure and temperature. However, when the carbon dioxide is free to escape, decarbonation can occur rapidly and is not hindered by a low initial porosity or permeability. Together with carbon dioxide and lime, portlandite, a mineral commonly found in voluminous metasomatic skarns, readily forms during carbonate decomposition. Post-experimental analyses highlight that thermal microcracking, a result of the highly anisotropic thermal expansion of calcite, exerts a greater influence on rock physical properties (porosity, ultrasonic wave velocities and elastic moduli) than decarbonation. Our data suggest that this will be especially true at the margins of dykes or magma bodies, where temperatures can reach up to 1200 ◦C. However, rock compressive strength is significantly reduced by both thermal cracking and decarbonation, explained by the relative weakness of lime + portlandite compared to calcite, and an increase in grain size with increasing temperature. Metasomatic skarns, whose petrogenetic reactions may involve a few tens of cubic kilometres, could therefore represent an important source of volcanic instability.
    Description: Published
    Description: 369-380
    Description: 2R. Laboratori sperimentali e analitici
    Description: JCR Journal
    Description: restricted
    Keywords: Volcanic hazards and risks ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 5
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    Palaeomagnetic analysis on pottery as indicator of the pyroclastic flow deposits temperature: new data and statistical interpretation from the Minoan eruption of Santorini, Greece (2015)
    Wiley-Blackwell
    Details
    Publication Date: 2017-04-04
    Description: We present the results of palaeomagnetic analysis on Late Bronge Age pottery from Santorini carried out in order to estimate the thermal effect of the Minoan eruption on the pre-Minoan habitation level. A total of 170 specimens from 108 ceramic fragments have been studied. The ceramics were collected from the surface of the pre-Minoan palaeosol at six different sites, including also samples from the Akrotiri archaeological site. The deposition temperatures of the first pyroclastic products have been estimated by the maximum overlap of the re-heating temperature intervals given by the individual fragments at site level. A new statistical elaboration of the temperature data has also been proposed, calculating at 95 per cent of probability the re-heating temperatures at each site. The obtained results show that the precursor tephra layer and the first pumice fall of the eruption were hot enough to re-heat the underlying ceramics at temperatures 160–230 ◦C in the non-inhabited sites while the temperatures recorded inside the Akrotiri village are slightly lower, varying from 130 to 200 ◦C. The decrease of the temperatures registered in the human settlements suggests that there was some interaction between the buildings and the pumice fallout deposits while probably the buildings debris layer caused by the preceding and syn-eruption earthquakes has also contributed to the decrease of the recorded re-heating temperatures.
    Description: Published
    Description: 33-47
    Description: 1A. Geomagnetismo e Paleomagnetismo
    Description: JCR Journal
    Description: restricted
    Keywords: Archaeomagnetism ; Rock and mineral magnetism ; Volcaniclastic deposits ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism ; 04. Solid Earth::04.05. Geomagnetism::04.05.07. Rock magnetism ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 6
    Electronic Resource
    Electronic Resource
    Masthead (1988)
    Chichester : Wiley-Blackwell
    Journal of Physical Organic Chemistry 1 (1988) 
    Details
    ISSN: 0894-3230
    Keywords: Organic Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/poc.610010301
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  • 7
    Electronic Resource
    Electronic Resource
    Photocyclization of N-Alkyl-N-(3-aryl-3-butenyl) ureas. Hydrogen transfer via charge transfer exciplexes in alkene photochemistry (1988)
    Chichester : Wiley-Blackwell
    Journal of Physical Organic Chemistry 1 (1988), S. 123-131 
    Details
    ISSN: 0894-3230
    Keywords: Organic Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Photolysis of N-alkyl-N-(3-aryl-3-butenyl) ureas (1) in acetonitrile gave cyclization products, 3-aryl-3-methyl-pyrrolidines, in good yields, whereas irradiation of 1 in methanol afforded methanol adducts as well as the cyclization products. Both the reactions are singlet reactions, and the cyclization is presumed to proceed via 1,6-hydrogen transfer from exciplexes with charge transfer character.
    Additional Material: 2 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/poc.610010302
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  • 8
    Electronic Resource
    Electronic Resource
    The Effect of hydrophobic-lipophilic interactions on chemical reactivity. 12. Mechanistic investigations of NaCMA-catalyzed hydrolysis of esters (1988)
    Chichester : Wiley-Blackwell
    Journal of Physical Organic Chemistry 1 (1988), S. 143-151 
    Details
    ISSN: 0894-3230
    Keywords: Organic Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The dependence of the catalytic efficiencies of sodium carboxymethylamylose (NaCMA) for the hydrolysis of N-lauryl-3-acetoxypyridinium iodide (1) and p-nitrophenyl dodecanoate (3) on its degree of substitution (D. S. = 0·00, 0·12, 0·18, 0·24, 0·29 and 0·35) and on the pH values of the solutions (pH = 7·32, 7·80, 8·10 and 9·30) have been studied. At fixed D. S. values, the observed hydrolysis rates of 1 and 3 increase with increasing concentrations of NaCMA and follow saturation kinetics. At fixed concentration of NaCMA, the rates increase with decreasing D. S. values until they reach maxima at D. S. = 0·00. Furthermore, at any D. S. value the catalytic efficiency increases with increasing pH values of the solutions. All these results indicate that the hydroxyl groups are actually the principal catalyzing groups.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/poc.610010304
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  • 9
    Electronic Resource
    Electronic Resource
    Masthead (1988)
    Chichester : Wiley-Blackwell
    Journal of Physical Organic Chemistry 1 (1988) 
    Details
    ISSN: 0894-3230
    Keywords: Organic Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/poc.610010401
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  • 10
    Electronic Resource
    Electronic Resource
    ESR studies of photochemical reaction of 2-methyl-3-acetylquinoxaline N,N′-dioxide(MAQO) (1988)
    Chichester : Wiley-Blackwell
    Journal of Physical Organic Chemistry 1 (1988), S. 191-195 
    Details
    ISSN: 0894-3230
    Keywords: Organic Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The photochemical reaction of MAQO with various aromatic amines were studied by ESR. The results show that nitroxide radicals are stable productrs of the photooxidation of both diphenylamines and phenylamines. The photolyzed phenothiazine does not yield nitroxide as the final product, instead it gives the neutral radical as the stable final product.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/poc.610010403
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