ISSN:
0009-2940
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Transition Metal Substituted VB Element System. Bis(VIA metal)methylstibines as Monofunction Ligands in Transition Metal ComplexesThe photochemical or thermal reaction of the metal corbonyls M(CO)6 (M=Cr, Mo, W), π-C5H5Mn(CO)3, and Fe2(CO)9 with the dimetalated stibines CH3Sb-[M′(CO)3π-C5H5]2 (M′=Cr, Mo, W) proceeds with elimination of CO or Fe(CO)5, yielding the neutral single antimony-bridged trinuclear complexes (CO)5M—Sb(CH3)[M′L4]2, π-C5H5(CO)2Mn—Sb(CH3)[M′L4]2, and (CO)4Fe-Sb(CH3)[M′L4]2. The new compounds are characterized by means of spectroscopy.
Notes:
Die photochemische bzw. thermische Umsetzung der Metallcarbonyle M(CO)6 (M=Cr, Mo, W), π-C5H5Mn(CO)3 und Fe2(CO)9 mit den dimetallierten Stibinen CH3Sb-[M′(CO)3π-C5H5]2 (M′=Cr, Mo, W) liefert unter Eliminierung von CO bzw. Fe(CO)5 die neutralen, einfach antimonverbrückten Dreikernkomplexe (CO)5M—Sb(CH3)[M′L4]2, π-C5H5(CO)2Mn—Sb(CH3)[M′L4])2 und (CO)4Fe—Sb(CH3)[M′L4]2, Die neuen Verbindungen werden spektroskopisch charakterisiert.
Additional Material:
3 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19751080237
Permalink
