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  • American Chemical Society (ACS)  (66,957)
  • American Meteorological Society
  • 2015-2019  (77,968)
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  • 1
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    American Chemical Society (ACS)
    In:  EPIC3Environmental Science and Technology, American Chemical Society (ACS), 53(15), pp. 8747-8756, ISSN: 0013-936X
    Publication Date: 2024-04-12
    Description: Recent studies pointed to a high ice nucleating activity (INA) in the Arctic sea surface microlayer (SML). However, related chemical information is still sparse. In the present study, INA and free glucose concentrations were quantified in Arctic SML and bulk water samples from the marginal ice zone, the ice-free ocean, melt ponds, and open waters within the ice pack. T50 (defining INA) ranged from −17.4 to −26.8 °C. Glucose concentrations varied from 0.6 to 51 μg/L with highest values in the SML from the marginal ice zone and melt ponds (median 16.3 and 13.5 μg/L) and lower values in the SML from the ice pack and the ice-free ocean (median 3.9 and 4.0 μg/L). Enrichment factors between the SML and the bulk ranged from 0.4 to 17. A positive correlation was observed between free glucose concentration and INA in Arctic water samples (T50(°C) = (−25.6 ± 0.6) + (0.15 ± 0.04)·Glucose(μg/L), RP = 0.66, n = 74). Clustering water samples based on phytoplankton pigment composition resulted in robust but different correlations within the four clusters (RP between 0.67 and 0.96), indicating a strong link to phytoplankton-related processes. Since glucose did not show significant INA itself, free glucose may serve as a potential tracer for INA in Arctic water samples.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 2
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    American Chemical Society (ACS)
    In:  EPIC3Analytical Chemistry, American Chemical Society (ACS), 90(24), pp. 14188-14197, ISSN: 0003-2700
    Publication Date: 2024-04-09
    Description: Investigating the biogeochemistry of dissolved organic matter (DOM) requires the synthesis of data from several complementary analytical techniques. The traditional approach to data synthesis is to search for correlations between measurements made on the same sample using different instruments. In contrast, data fusion simultaneously decomposes data from multiple instruments into the underlying shared and unshared components. Here, Advanced Coupled Matrix and Tensor Factorization (ACMTF) was used to identify the molecular fingerprint of DOM fluorescence fractions in Arctic fjords. ACMTF explained 99.84% of the variability with six fully shared components. Individual molecular formulas were linked to multiple fluorescence components and vice versa. Molecular fingerprints differed in diversity and oceanographic patterns, suggesting a link to the biogeochemical sources and diagenetic state of DOM. The fingerprints obtained through ACMTF were more specific compared to traditional correlation analysis and yielded greater compositional insight. Multivariate data fusion aligns extremely complex, heterogeneous DOM data sets and thus facilitates a more holistic understanding of DOM biogeochemistry.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 3
    Publication Date: 2023-02-23
    Description: Author Posting. © American Meteorological Society, 2019. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Climate 32(5) (2019): 1551-1571. doi:10.1175/JCLI-D-18-0444.1.
    Description: Previous studies have documented a poleward shift in the subsiding branches of Earth’s Hadley circulation since 1979 but have disagreed on the causes of these observed changes and the ability of global climate models to capture them. This synthesis paper reexamines a number of contradictory claims in the past literature and finds that the tropical expansion indicated by modern reanalyses is within the bounds of models’ historical simulations for the period 1979–2005. Earlier conclusions that models were underestimating the observed trends relied on defining the Hadley circulation using the mass streamfunction from older reanalyses. The recent observed tropical expansion has similar magnitudes in the annual mean in the Northern Hemisphere (NH) and Southern Hemisphere (SH), but models suggest that the factors driving the expansion differ between the hemispheres. In the SH, increasing greenhouse gases (GHGs) and stratospheric ozone depletion contributed to tropical expansion over the late twentieth century, and if GHGs continue increasing, the SH tropical edge is projected to shift further poleward over the twenty-first century, even as stratospheric ozone concentrations recover. In the NH, the contribution of GHGs to tropical expansion is much smaller and will remain difficult to detect in a background of large natural variability, even by the end of the twenty-first century. To explain similar recent tropical expansion rates in the two hemispheres, natural variability must be taken into account. Recent coupled atmosphere–ocean variability, including the Pacific decadal oscillation, has contributed to tropical expansion. However, in models forced with observed sea surface temperatures, tropical expansion rates still vary widely because of internal atmospheric variability.
    Description: We thank Ori Adam, Nick Davis, Isaac Held, Tim Merlis, Lorenzo Polvani, and one anonymous reviewer for helpful comments and suggestions. We thank U.S. CLIVAR and the International Space Science Institute (ISSI) for funding working groups that stimulated this project. We thank all members of the working groups for helpful discussions, and the U.S. CLIVAR and ISSI offices and their sponsoring agencies (NASA,NOAA,NSF,DOE, ESA, Swiss Confederation, Swiss Academy of Sciences, and University of Bern) for supporting these groups and activities.We acknowledge WCRP’sWorking Group on CoupledModelling, which is responsible for CMIP, and we thank the climate modeling groups (Table 2) for producing and making available their model output. For CMIP, the U.S. DOE PCMDI provides coordinating support and led development of software infrastructure in partnership with the Global Organization for Earth System Science Portals.
    Description: 2019-08-06
    Keywords: Hadley circulation ; Climate models ; Reanalysis data ; Multidecadal variability ; Pacific decadal oscillation ; Trends
    Repository Name: Woods Hole Open Access Server
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  • 4
    Publication Date: 2022-10-27
    Description: Author Posting. © American Meteorological Society, 2018. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Marine Science and Engineering 6(4), (2018): 144. doi:10.3390/jmse6040144.
    Description: Geochronologies derived from sediment cores in coastal locations are often used to infer event bed characteristics such as deposit thicknesses and accumulation rates. Such studies commonly use naturally occurring, short-lived radioisotopes, such as Beryllium-7 (7Be) and Thorium-234 (234Th), to study depositional and post-depositional processes. These radioisotope activities, however, are not generally represented in sediment transport models that characterize coastal flood and storm deposition with grain size patterns and deposit thicknesses. We modified the Community Sediment Transport Modeling System (CSTMS) to account for reactive tracers and used this capability to represent the behavior of these short-lived radioisotopes on the sediment bed. This paper describes the model and presents results from a set of idealized, one-dimensional (vertical) test cases. The model configuration represented fluvial deposition followed by periods of episodic storm resuspension. Sensitivity tests explored the influence on seabed radioisotope profiles by the intensities of bioturbation and wave resuspension and the thickness of fluvial deposits. The intensity of biodiffusion affected the persistence of fluvial event beds as evidenced by 7Be. Both resuspension and biodiffusion increased the modeled seabed inventory of 234Th. A thick fluvial deposit increased the seabed inventory of 7Be and 234Th but mixing over time greatly reduced the difference in inventory of 234Th in fluvial deposits of different thicknesses.
    Description: The Bureau of Ocean Energy Management (BOEM) provided funding for Birchler, Harris, and Kniskern. During his M.S. program Birchler received additional funds from VIMS’ Office of Academic Studies. This work was partially supported by the U.S. Geological Survey, Coastal and Marine Geology Program.
    Keywords: Numerical model ; Sediment transport ; Marine ; Short-lived radioisotopes
    Repository Name: Woods Hole Open Access Server
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  • 5
    Publication Date: 2022-05-26
    Description: Author Posting. © American Meteorological Society, 2015. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Monthly Weather Review 143 (2015): 195–211, doi:10.1175/MWR-D-14-00051.1.
    Description: Lagrangian measurements from passive ocean instruments provide a useful source of data for estimating and forecasting the ocean’s state (velocity field, salinity field, etc.). However, trajectories from these instruments are often highly nonlinear, leading to difficulties with widely used data assimilation algorithms such as the ensemble Kalman filter (EnKF). Additionally, the velocity field is often modeled as a high-dimensional variable, which precludes the use of more accurate methods such as the particle filter (PF). Here, a hybrid particle–ensemble Kalman filter is developed that applies the EnKF update to the potentially high-dimensional velocity variables, and the PF update to the relatively low-dimensional, highly nonlinear drifter position variable. This algorithm is tested with twin experiments on the linear shallow water equations. In experiments with infrequent observations, the hybrid filter consistently outperformed the EnKF, both by better capturing the Bayesian posterior and by better tracking the truth.
    Description: The work of Apte benefited from the support of the AIRBUS Group Corporate Foundation Chair in Mathematics of Complex Systems established in ICTS-TIFR. Spiller would like to acknowledge support by NSF Grant DMS-1228265 and ONR Grant N00014-11-1-0087. Sandstede gratefully acknowledges support by the NSF through Grant DMS-0907904. Slivinski was supported by the NSF through Grants DMS-0907904 and DMS-1148284.
    Description: 2015-07-01
    Keywords: Bayesian methods ; Filtering techniques ; Kalman filters ; Statistical techniques ; Data assimilation
    Repository Name: Woods Hole Open Access Server
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  • 6
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    American Meteorological Society
    Publication Date: 2022-05-26
    Description: Author Posting. © American Meteorological Society, 2014. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Atmospheric and Oceanic Technology 31 (2014): 2871, doi:10.1175/JTECH-D-14-00187.1.
    Repository Name: Woods Hole Open Access Server
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  • 7
    Publication Date: 2022-05-26
    Description: Author Posting. © American Meteorological Society, 2015. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 46 (2016): 551-568, doi:10.1175/JPO-D-15-0047.1.
    Description: There exists a good deal of indirect evidence, from several locations around the world, that there is a substantial eddy field over continental shelves. These eddies appear to have typical swirl velocities of a few centimeters per second and have horizontal scales of perhaps 5–10 km. These eddies are weak compared to typical, wind-driven, alongshore flows but often seem to dominate middepth cross-shelf flows. The idea that motivates the present contribution is that the alongshore wind stress ultimately energizes these eddies by means of baroclinic instabilities, even in cases where obvious intense fronts do not exist. The proposed sequence is that alongshore winds over a stratified ocean cause upwelling or downwelling, and the resulting horizontal density gradients are strong enough to fuel baroclinic instabilities of the requisite energy levels. This idea is explored here by means of a sequence of idealized primitive equation numerical model studies, each driven by a modest, nearly steady, alongshore wind stress applied for about 5–10 days. Different runs vary wind forcing, stratification, bottom slope, bottom friction, and Coriolis parameter. All runs, both upwelling and downwelling, are found to be baroclinically unstable and to have scales compatible with the underlying hypothesis. The model results, combined with physically based scalings, show that eddy kinetic energy generally increases with bottom slope, stratification, wind impulse (time integral of the wind stress), and inverse Coriolis parameter. The dominant length scale of the eddies is found to increase with increasing eddy kinetic energy and to decrease with Coriolis parameter.
    Description: This work was supported by the Woods Hole Oceanographic Institution and by the National Science Foundation, Physical Oceanography section through Grant OCE-1433953.
    Description: 2016-06-09
    Keywords: Geographic location/entity ; Continental shelf/slope ; Variability ; Oceanic variability
    Repository Name: Woods Hole Open Access Server
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  • 8
    Publication Date: 2022-05-26
    Description: Author Posting. © American Meteorological Society, 2016. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 46 (2016): 1309-1321, doi:10.1175/JPO-D-15-0068.1.
    Description: Direct measurements of oceanic turbulent parameters were taken upstream of and across Drake Passage, in the region of the Subantarctic and Polar Fronts. Values of turbulent kinetic energy dissipation rate ε estimated by microstructure are up to two orders of magnitude lower than previously published estimates in the upper 1000 m. Turbulence levels in Drake Passage are systematically higher than values upstream, regardless of season. The dissipation of thermal variance χ is enhanced at middepth throughout the surveys, with the highest values found in northern Drake Passage, where water mass variability is the most pronounced. Using the density ratio, evidence for double-diffusive instability is presented. Subject to double-diffusive physics, the estimates of diffusivity using the Osborn–Cox method are larger than ensemble statistics based on ε and the buoyancy frequency.
    Description: This work was supported by grants from the U.S. National Science Foundation.
    Description: 2016-10-05
    Keywords: Geographic location/entity ; Southern Ocean ; Circulation/ Dynamics ; Diapycnal mixing ; Mixing ; Turbulence ; Atm/Ocean Structure/ Phenomena ; Fronts ; Observational techniques and algorithms ; Profilers, oceanic
    Repository Name: Woods Hole Open Access Server
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  • 9
    Publication Date: 2022-05-26
    Description: Author Posting. © American Meteorological Society, 2015. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 46 (2016): 439-459, doi:10.1175/JPO-D-15-0086.1.
    Description: The summertime California Current System (CCS) is characterized by energetic mesoscale eddies, whose sea surface temperature (SST) and surface current can significantly modify the wind stress and Ekman pumping. Relative importance of the eddy–wind interactions via SST and surface current in the CCS is examined using a high-resolution (7 km) regional coupled model with a novel coupling approach to isolate the small-scale air–sea coupling by SST and surface current. Results show that when the eddy-induced surface current is allowed to modify the wind stress, the spatially averaged surface eddy kinetic energy (EKE) is reduced by 42%, and this is primarily due to enhanced surface eddy drag and reduced wind energy transfer. In contrast, the eddy-induced SST–wind coupling has no significant impact on the EKE. Furthermore, eddy-induced SST and surface current modify the Ekman pumping via their crosswind SST gradient and surface vorticity gradient, respectively. The resultant magnitudes of the Ekman pumping velocity are comparable, but the implied feedback effects on the eddy statistics are different. The surface current-induced Ekman pumping mainly attenuates the amplitude of cyclonic and anticyclonic eddies, acting to reduce the eddy activity, while the SST-induced Ekman pumping primarily affects the propagation. Time mean–rectified change in SST is determined by the altered offshore temperature advection by the mean and eddy currents, but the magnitude of the mean SST change is greater with the eddy-induced current effect. The demonstrated remarkably strong dynamical response in the CCS system to the eddy-induced current–wind coupling indicates that eddy-induced current should play an important role in the regional coupled ocean–atmosphere system.
    Description: We thank NSF for support under GrantsOCE-0960770,OCE-1419235, andOCE-1419306. HS is grateful for the WHOI internal support from the Andrew W. Mellon Foundation Awards for Innovative Research and the additional support from the ONR We thank NSF for support under GrantsOCE-0960770,OCE-1419235, andOCE-1419306. HS is grateful for the WHOI internal support from the Andrew W. Mellon Foundation Awards for Innovative Research and the additional support from the ONR
    Description: 2016-05-30
    Keywords: Atm/Ocean Structure/ Phenomena ; Atmosphere-ocean interaction ; Ekman pumping ; Models and modeling ; Ocean models ; Regional models
    Repository Name: Woods Hole Open Access Server
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  • 10
    Publication Date: 2022-05-26
    Description: Author Posting. © American Meteorological Society, 2016. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 46 (2016): 1769-1783, doi:10.1175/JPO-D-15-0193.1.
    Description: High-resolution observations of velocity, salinity, and turbulence quantities were collected in a salt wedge estuary to quantify the efficiency of stratified mixing in a high-energy environment. During the ebb tide, a midwater column layer of strong shear and stratification developed, exhibiting near-critical gradient Richardson numbers and turbulent kinetic energy (TKE) dissipation rates greater than 10−4 m2 s−3, based on inertial subrange spectra. Collocated estimates of scalar variance dissipation from microconductivity sensors were used to estimate buoyancy flux and the flux Richardson number Rif. The majority of the samples were outside the boundary layer, based on the ratio of Ozmidov and boundary length scales, and had a mean Rif = 0.23 ± 0.01 (dissipation flux coefficient Γ = 0.30 ± 0.02) and a median gradient Richardson number Rig = 0.25. The boundary-influenced subset of the data had decreased efficiency, with Rif = 0.17 ± 0.02 (Γ = 0.20 ± 0.03) and median Rig = 0.16. The relationship between Rif and Rig was consistent with a turbulent Prandtl number of 1. Acoustic backscatter imagery revealed coherent braids in the mixing layer during the early ebb and a transition to more homogeneous turbulence in the midebb. A temporal trend in efficiency was also visible, with higher efficiency in the early ebb and lower efficiency in the late ebb when the bottom boundary layer had greater influence on the flow. These findings show that mixing efficiency of turbulence in a continuously forced, energetic, free shear layer can be significantly greater than the broadly cited upper bound from Osborn of 0.15–0.17.
    Description: Holleman was supported by the Devonshire Scholars program. The field study and the coauthors’ contributions were supported by NSF Grant OCE 0926427.
    Description: 2016-11-24
    Keywords: Circulation/ Dynamics ; Mixing ; Shear structure/flows ; Turbulence ; Observational techniques and algorithms ; Ship observations
    Repository Name: Woods Hole Open Access Server
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