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  • Elsevier  (90,657)
  • Public Library of Science
  • 2010-2014  (2)
  • 2005-2009  (91,813)
  • 1980-1984
  • 2005  (91,813)
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  • 1
    Publication Date: 2023-04-25
    Description: Arabidopsis genes encoding enzymes for each of the eight steps in l-arginine (Arg) synthesis were identified, based upon sequence homologies with orthologs from other organisms. Except for N-acetylglutamate synthase (NAGS; EC 2.3.1.1), which is encoded by two genes, all remaining enzymes are encoded by single genes. Targeting predictions for these enzymes, based upon their deduced sequences, and subcellular fractionation studies, suggest that most enzymes of Arg synthesis reside within the plastid. Synthesis of the l-ornthine (Orn) intermediate in this pathway from l-glutamate occurs as a series of acetylated intermediates, as in most other organisms. An N-acetylornithine:glutamate acetyltransferase (NAOGAcT; EC 2.3.1.35) facilitates recycling of the acetyl moiety during Orn formation (cyclic pathway). A putative N-acetylornithine deacetylase (NAOD; EC 3.5.1.16), which participates in the “linear” pathway for Orn synthesis in some organisms, was also identified. Previous biochemical studies have indicated that allosteric regulation of the first and, especially, the second steps in Orn synthesis (NAGS; N-acetylglutamate kinase (NAGK), EC 2.7.2.8) by the Arg end-product are the major sites of metabolic control of the pathway in organisms using the cyclic pathway. Gene expression profiling for pathway enzymes further suggests that NAGS, NAGK, NAOGAcT and NAOD are coordinately regulated in response to changes in Arg demand during plant growth and development. Synthesis of Arg from Orn is further coordinated with pyrimidine nucleotide synthesis, at the level of allocation of the common carbamoyl-P intermediate.
    Type: Article , PeerReviewed
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  • 2
    Publication Date: 2023-03-30
    Description: This paper presents seasonal variations of the wind characteristics and wind turbine characteristics in the regions around Elazig, namely Maden, Agin and Keban. Mean wind speed data in measured hourly time series format is statistically analyzed for the six year period 1998–2003. The probability density distributions are derived from the time series data and their distributional parameters are identified. Two probability density functions are fitted to the measured probability distributions on a seasonal basis. The wind energy characteristics of all the regions is studied based on the Weibull and Rayleigh distributions. Energy calculations and capacity factors for the wind turbine characteristics were determined for wind machines of different sizes between 300 and 2300 kW. It was found that Maden is the best region, among the regions analyzed, for wind characteristics and wind turbine characteristics.
    Type: Article , PeerReviewed
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  • 3
    Publication Date: 2023-01-19
    Description: Measuring and modeling the surface charge of clays, and more especially smectites, has become an important issue in the use of bentonites as a waste confinement material aimed at retarding migration of water and solutes. Therefore, many studies of the acid–base properties of montmorillonite have appeared recently in the literature, following older studies principally devoted to cation exchange. It is striking that beyond the consensus about the complex nature of the surface charge of clays, there are many discrepancies, especially concerning the dissociable charge, that prevents intercomparison among the published data. However, a general trend is observed regarding the absence of common intersection point on raw titration curves at different ionic strengths. Analysis of the literature shows that these discrepancies originate from the experimental procedures for the preparation of the clays and for the quantification of their surface charge. The present work is an attempt to understand how these procedures can impact the final results. Three critical operations can be identified as having significant effects on the surface properties of the studied clays. The first one is the preparation of purified clay from the raw material: the use of acid or chelation treatments, and the repeated washings in deionized water result in partial dissolution of the clays. Then storage of the purified clay in dry or wet conditions strongly influences the equilibria in the subsequent experiments respectively by precipitation or enhanced dissolution. The third critical operation is the quantification of the surface charge by potentiometric titration, which requires the use of strong acids and bases. As a consequence, besides dissociation of surface sites, many secondary titrant consuming reactions were described in the literature, such as cation exchange, dissolution, hydrolysis, or precipitation. The cumulated effects make it difficult to derive proper dissociation constants, and to build adequate models. The inadequation of the classical surface complexation models to describe the acid–base behavior of clays is illustrated by the electrokinetic behavior of smectites, which is independent from the pH and the ionic strength. Therefore, there is still a need on one hand for accurate data recorded in controlled conditions, and on the other hand for new models taking into account the complex nature of the charge of clays.
    Type: Article , PeerReviewed
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  • 4
    Publication Date: 2022-05-24
    Description: Many studies have assessed the strong influence of volcanic activity on the surrounding environment. This is particularly true for strong gas emitters such as Mt. Etna and Stromboli volcanoes. Among volcanic gases, fluorine compounds are potentially very harmful. Fluorine cycling through rainwater in the above volcanic areas was studied analysing more than 400 monthly bulk samples. Data indicate that only approximately 1% of fluorine emission through the plume is deposited on the two volcanic areas by meteoric precipitations. Although measured bulk rainwater fluorine fluxes are comparable to and sometimes higher than in heavily polluted areas, their influence on the surrounding vegetation is limited. Only annual crops, in fact, show some damage that could be an effect of fluorine deposition, indicating that long-living endemic plant species or varieties have developed some kind of resistance.
    Description: Published
    Description: 175–185
    Description: partially_open
    Keywords: Fluorine ; Rainwater chemistry ; Volcanic activity ; Mt. Etna ; Stromboli Island ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 03. Hydrosphere::03.03. Physical::03.03.01. Air/water/earth interactions ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.08. Risk::05.08.01. Environmental risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 5
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    Elsevier
    In:  On the influence of diabatic effects on the motion of 3D-mesoscale vortices within a baroclinic shear flow
    Publication Date: 2022-03-21
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  • 6
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    Elsevier
    In:  Dynamic food webs: multispecies assemblages, ecosystem development, and environmental change
    Publication Date: 2022-03-21
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  • 7
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    Elsevier
    In:  Dynamic food webs: multispecies assemblages, ecosystem development, and environmental change
    Publication Date: 2022-03-21
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  • 8
    Publication Date: 2022-02-21
    Description: The temporal evolution of fundamental flow conditions in the magma chamber plus conduit system–such as pressure, velocity, mass flow-rate, erupted mass, etc.–during sustained magmatic explosive eruptions was investigated. To this aim, simplified one-dimensional and isothermal models of magma chamber emptying and conduit flow were developed and coupled together. The chamber model assumed an homogeneous composition of magma and a vertical profile of water content. The chamber could have a cylindrical, elliptical or spherical rigid geometry. Inside the chamber, magma was assumed to be in hydrostatic equilibrium both before and during the eruption. Since the time-scale of pressure variations at the conduit inlet–of the order of hours–is much longer than the travel time of magma in the conduit–of the order of a few minutes–the flow in the conduit was assumed as at steady-state. The one dimensional mass and momentum balance equations were solved along a circular conduit with constant diameter assuming choked-flow conditions at the exit. Bubble nucleation was considered when the homogeneous flow pressure dropped below the nucleation pressure given the total water content and the solubility law. Above the nucleation level, bubbles and liquid magma were considered in mechanical equilibrium. The same equilibrium assumption was made above the fragmentation level between gas and pyroclasts. Due to the hydrostatic hypothesis, the integration of the density distribution in the chamber allowed to obtain the total mass in the chamber as a function of pressure at the chamber top and, through the conduit model, as a function of time. Simulation results pertaining to rhyolitic and basaltic magmas defined at the Volcanic Eruption Mechanism Modeling Workshops (Durham, NH, 2002; Nice, France, 2003) are presented. Important flow variables, such as pressure, density, velocity, shear stress in the chamber and conduit, are discussed as a function of time and magma chamber and conduit properties. Results indicate that vent variables react in different ways to the pressure variation of the chamber. Pressure, density and mass flow-rate show relative variations of the same order of magnitude as the conduit inlet pressure, whereas velocity is more constant in time. Sill-like chambers produce also significantly longer and more voluminous eruptions than dike-like chambers. Water content stratification in the chamber and the increase of chamber depth significantly reduce the eruption duration and volume. Maximum erupted mass fractions of about 0.2 are computed for small water-saturated and shallow chambers.
    Description: Published
    Description: 153-172
    Description: partially_open
    Keywords: Explosive eruptions ; Magma chamber discharge ; Conduit flow ; Temporal evolution ; Pressure evolution ; 05. General::05.01. Computational geophysics::05.01.05. Algorithms and implementation
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 9
    Publication Date: 2022-02-17
    Description: Dinoflagellates are an important component of the extant eukaryotic plankton. Their organic-walled, hypnozygotic cysts (dinocysts) provide a rich, albeit incomplete, history of the group in ancient sediments. Building on pioneering studies of the late 1970s and 1980s, recent drilling in the Southern Ocean has provided a wealth of new dinocyst data spanning the entire Paleogene. Such multidisciplinary studies have been instrumental in refining existing and furnishing new concepts of Paleogene paleoenvironmental and paleoclimatic reconstructions by means of dinocysts. Because dinocysts notably exhibit high abundances in neritic settings, dinocyst-based environmental and paleoclimatic information is important and complementary to the data derived from typically more offshore groups as planktonic foraminifera, coccolithophorids, diatoms and radiolaria. By presenting case-studies from around the globe, this contribution provides a concise review of our present understanding of the paleoenvironmental significance of dinocysts in the Paleogene (65–25 Ma). Representing Earth's greenhouse–icehouse transition, this episode holds the key to the understanding of extreme transient climatic change. We discuss the potential of dinocysts for the reconstruction of Paleogene sea-surface productivity, temperature, salinity, stratification and paleo-oxygenation along with their application in sequence stratigraphy, oceanic circulation and general watermass reconstructions.
    Type: Article , PeerReviewed
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  • 10
    Publication Date: 2022-02-17
    Description: Geochemical and petrographical studies of lavas and ignimbrites from the Quaternary Nisyros–Yali volcanic system in the easternmost part of the Hellenic arc (Greece) reveal insight into magma generating processes. A compositional gap between 61 and 68 wt.% SiO2 is recognized that coincides with the stratigraphic distinction between pre-caldera and post-caldera volcanic units. Trace element systematics support the subdivision of Nisyros and Yali volcanic units into two distinct suites of rocks. The variation of Nd and Hf present day isotope data and the fact that they are distinct from the isotope compositions of MORB rule out an origin by pure differentiation and require assimilation of a crustal component. Lead isotope ratios of Nisyros and Yali volcanic rocks support mixing of mantle material with a lower crust equivalent. However, 87Sr/86Sr ratios of 0.7036–0.7048 are incompatible with a simple binary mixing scenario and give low depleted mantle extraction ages (〈0.1 Ga), in contrast with Pb model ages of 0.3 Ga and Hf and Nd model ages of ca. 0.8 Ga. The budget of fluid-mobile elements Sr and Pb is likely to be dominated by abundant hydrous fluids characterised by mantle-like Sr isotope ratios. Late stage fluids probably were enriched in CO2, needed to explain the high Th concentrations. The occurrence of hydrated minerals (e.g., amphibole) in the first post-caldera unit with the lowermost 87Sr/86Sr ratio of 0.7036±2 can be interpreted as the result of the increased water activity in the source. The presence of two different plagioclase phenocryst generations in the first lava subsequent to the caldera-causing event is indicative for a longer storage time of this magma at a shallower level. A model capable of explaining these observations involves three evolutionary stages. First stage, assimilation of lower crustal material by a primitive magma of mantle origin (as modelled by Nd–Hf isotope systematics). This stage ended by an interruption in replenishment that led to an increase of crystallization and, hence, an increase in viscosity, suppressing eruption. During this time gap, differentiation by fractional crystallization led to enrichment of incompatible species, especially aqueous fluids, to silica depolymerisation and to a decrease in viscosity, finally enabling eruption again in the third stage.
    Type: Article , PeerReviewed
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