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  • Life and Medical Sciences  (1.821)
  • Inorganic Chemistry  (732)
  • 1990-1994  (2.553)
  • 1992  (2.553)
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  • 1990-1994  (2.553)
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  • 1
    Digitale Medien
    Digitale Medien
    Oxidative Trimerisierung von Alkinylgruppen an Trimethylphosphan-Palladium-Komplexen (1992)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 125 (1992), S. 9-14 
    Details
    ISSN: 0009-2940
    Schlagwort(e): Alkynyl groups ; Palladium, trimethylphosphane complexes ; Trimerization, oxidative ; Chemistry ; Inorganic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Oxidative Trimerization of Alkynyl Groups at Trimethylphosphane Palladium ComplexesAlkynylpalladium halides trans-PdX (C ≡ CR)(PMe3)2 [1, 2, 4, X = Cl, R = SiMe3, (CH2)2CH3, (CH2)5CH3; 3, X = Br, R = (CH2)2CH3] were synthesized by routine methods, while further examples of the series trans-PdX (C ≡ CR)(PMe3)2 [5, 7, 8, 10, X = Br, R = SiMe3, CMe3, (CH2)2CH3, Ph; 7, 9, 11, X = I, R = SiMe3, SiPh3, OEt] and trans-PdX (C ≡ CR)(PPh3)2 (12-14, X=I, R=SiMe3, CMe3, CH2OH) were obtained by oxidative addition of 1-halogeno-1-alkynes to PdL4 (L=PMe3, PPh3). Just above the melting point or decomposition point 5-7 are transformed by oxidative trimerization of the alkynyl groups to give enediynyl complexes trans-PdX[C(C ≡ CR)=C(C ≡ CR)R](PMe3)2 (15, 16, R=SiMe3, X=Br, I; 17, X=Br, R=CMe3). According to an X-ray structure analysis 17 has E configuration.
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/cber.19921250103
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  • 2
    Digitale Medien
    Digitale Medien
    Substituted C3BN2 Heterocycles from Trialkylboranes and Nitriles (1992)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 125 (1992), S. 15-22 
    Details
    ISSN: 0009-2940
    Schlagwort(e): Boranes, trialkyl- ; Nitriles ; Condensation ; β-Diketimines ; Chemistry ; Inorganic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The reaction of trialkylboranes, e. g. triethylborane (Et3B), tripropylborane (Pr3B), or 9-alkyl-9-borabicyclo[3.3.1]nonane [alkyl-BBN; alkyl=Et, 1-methylpropyl, 1-methybutyl/1-ethylpropyl], with either aceto-, propio-, butyro-, pivalo-, and benzonitrile gives, depending on the reaction conditions used or the nitrile employed, either the substituted diazoniadibora-tetidines (1 a - c), products of partial hydroboration, or by condensation of two or three nitrile molecules, with or without a concomitant hydroboration, the C3BN2 heterocycles 2a - c, 8a/b, 9a - d, and 10a/b (X-ray structure analyses of 2a and 10b).
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/cber.19921250104
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  • 3
    Digitale Medien
    Digitale Medien
    Metalle in Biologie und Medizin, III. Bismutlactat: Darstellung und Strukturchemie eines Hydroxycarboxylat-Komplexes (1992)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 125 (1992), S. 43-46 
    Details
    ISSN: 0009-2940
    Schlagwort(e): Helicobacter Pylori ; Bismuth ; (S)-Lactate ; Chemistry ; Inorganic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Metals in Biology and Medicine, III.  -  Bismuth Lactate: Synthesis and Structure of a Hydroxycarboxylate ComplexAs a compound of medical relevance, bismuth (S)-lactate was synthesized and structurally characterized (single-crystal X-ray diffraction). Exploiting the versatile coordination chemistry of carboxylate groups (chelating and bridging ligands), the crystal structure is based upon a three-dimensional network, showing bismuth in a high coordination number environment.
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/cber.19921250108
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  • 4
    Digitale Medien
    Digitale Medien
    Darstellung neuartiger monomerer, oligomerer und polymerer Silyltriflate (1992)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 125 (1992), S. 47-53 
    Details
    ISSN: 0009-2940
    Schlagwort(e): Silyl triflates ; Oligosilanes ; Chemistry ; Inorganic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Preparation of New Monomeric, Oligomeric, and Polymeric Silyl TriflatesThe highly reactive silyl triflates R3SiOSO2CF3 are valuable reagents in organosilicon chemistry. New triflate derivatives of mono- and oligosilanes have been prepared by substitution of phenyl groups or hydrogen atoms for the trifluoromethanesulfonyl group. The presence of the electron-withdrawing triflate group leads to a strong deactivation of the other substituents at the silicon atom, and the displacement of a second phenyl group at the same silicon atom is much slower than the first step. For this reason in the case of phenylated oligosilanes stepwise monosubstitution of the silicon atoms has been found. Other new oligomeric silyl triflates are obtained by reaction of silanediyl(triyl) bis(tris)(trifluoromethanesulfonates) with lithium derivatives of organosilicon compounds. Finally, the cleavage of silicon-phenyl bonds of poly[methyl(phenyl)silanes] by CF3SO3H leads to triflate derivatives of polysilanes.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/cber.19921250109
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  • 5
    Digitale Medien
    Digitale Medien
    Die Kristallstrukturen von {Li3(12-Krone-4)2[HC(CN)2]3}, {Na(15-Krone-5)-[HC(CN)2]} und {Na[N(nBu)4][HC(CN)2]2 · THF} (1992)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 125 (1992), S. 87-92 
    Details
    ISSN: 0009-2940
    Schlagwort(e): Lithium dicyanomethanide ; Sodium dicyanomethanide ; Dicyanomethanides, lithium, sodium, tetrabutylammonium salts ; Chemistry ; Inorganic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The Crystal Structures of {Li3(12-crown-4)2[HC(CN)2]3}, {Na(15-crown-5)[HC(CN)2]}, and {NaN(nBu)4[HC(CN)2]2 · THF}The preparation and the crystal structures of the title compounds 1 - 3 are described. 1 forms a polymeric chain structure, in which one of the lithium ions is linked by Li…NCC(H)CN… bridges. The remaining lithium ions form (12-crown-4)Li[NCC(H)CN] units, which are coordinated by one of the nitrogen atoms of the dicyanomethanide ions with the lithium ions of the chain. 2 forms an ion pair, in which the sodium ion is coordinated by the five oxygen atoms of the crown ether molecule and by one nitrogen atom of the dicyanomethanide ion. 3 has a threedimensional network, in which the sodium ions are coordinated in a distorted tetrahedral manner by the nitrogen atoms of the dicyanomethanide ions. In the cavities of the network the tetrabutylammonium ions and the THF molecules are found.
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/cber.19921250114
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  • 6
    Digitale Medien
    Digitale Medien
    Synthese, Struktur und Reaktivität eines Stanna(II)-nickela(II)-cyclobuten-Komplexes (1992)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 125 (1992), S. 103-106 
    Details
    ISSN: 0009-2940
    Schlagwort(e): Alkynes ; Nickel complexes ; Stannenes ; Metallacycloalkenes ; Kinetic and thermodynamic reaction control ; Chemistry ; Inorganic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Synthesis, Structure, and Reactivity of a Stanna(II)-nickela(III)-cyclobutene KomplexesThe (ethyne)nickel(0) complex (iPr2PC2H4PiPr2)Ni(C2H2) (1) reacts with the stannene Sn[CH(SiMe3)2]2 below -30°C to yield the stanna(II)-nickela(II)-cyclobutene complex (iPr2PC2H4PiPr2)YYNiCH=YYCHSn[CH(SiMe3)2]2 (2; 83%) as the kinetically controlled product; 2 has been characterized by IR and NMR spectroscopy and an X-ray crystal-structure determination. The latter shows the central four-membered ring to be planar with a long Ni - Sn bond [2.626(1) Å]. According to the temperature-dependent NMR spectra, 2 dissociates reversibly in solution to the starting components. The synthesis reaction thus represents an equilibrium as long as the temperature is below 20°C. These observations indicate that the structural lability of the stanna(II)-nickela(II)-cyclobutene moiety is associated with the weakness of the Ni - Sn bond. The bonding situation in 2 is best described as an “inner complex” in which a stannyl anion is coordinated to a nickel(II) cation. An ethereal solution of 2 undergoes an oxidative addition of one ethyne C - H bond to the stannene at 20°C to give the Ni(0)/Sn(IV) complex iPr2PC2H4PiPr2)Ni({η2-HC≡CSn(H)[CH(SiMe3)2]2} (3) as the thermodynamically controlled product. Reaction of 3 with CO liberates the new alkyne ligand.
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/cber.19921250117
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  • 7
    Digitale Medien
    Digitale Medien
    Correction (1992)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 125 (1992), S. 123-123 
    Details
    ISSN: 0009-2940
    Schlagwort(e): Chemistry ; Inorganic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/cber.19921250121
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  • 8
    Digitale Medien
    Digitale Medien
    Synthese, Struktur und Isomerisierung von DiazaphosphiridinoxidenHerrn Professor Joseph Grobe zum 60. Geburtstag gewidmet. (1992)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 125 (1992), S. 93-96 
    Details
    ISSN: 0009-2940
    Schlagwort(e): Diazaphosphiridine oxides ; Chemistry ; Inorganic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Synthesis, Structure, and Isomerization of Diazaphosphiridine OxidesHerrn Professor Joseph Grobe zum 60. Geburtstag gewidmet.The 1,2-Bis(alkyl)iminophosphane, Et3C  -  P=N  -  tBu (1), reacts with nitroso compounds, RNO (R=tBu, Ph), to form the diazaphosphiridine oxides, Et3C  -  YYP(=O)  -  NtBu  -  NYYR, 4a, b. While 4a (R=tBu) is thermally stable, 4b (R=Ph) isomerizes with formation of the benzodiazaphosphole oxide Et3C  -  YYP(= O)  -  NH  -  C6H4  -  NYYtBu (5). The corresponding phospholimine Et3C  -  YYP(=NtBu)  -  NH  -  C6H4  -  NYYtBu (7) has been obtained from 1 and azobenzene. The three-membered phosphorus heterocycle 4a has been characterized by X-ray structure analysis, which reveales some remarkable features.
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/cber.19921250115
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  • 9
    Digitale Medien
    Digitale Medien
    Metal Complexes with Tetrapyrrole Ligands, LXI. Structure and Products of Electrochemical Oxidation of Zirconium(IV) and Hafnium(IV) Bisporphyrinate Double-Deckers (1992)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 125 (1992), S. 107-115 
    Details
    ISSN: 0009-2940
    Schlagwort(e): Zirconium porphyrins ; Hafnium porphyrins ; Porphyrin double-deckers ; Metal bisporphyrinates ; Chemistry ; Inorganic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The electrochemical oxidation of zirconium and hafnium double-deckers M(P)2 (M=Zr, Hf; P=OEP, TPP) (Scheme 1)2) leads to mono- and dications which show near infrared absorption bands which are of ≈ 2000 cm-1 higher energy than those of the corresponding cerium double-decker cations. [Zr(OEP)2]X, [Zr(OEP)2]X2, and [Zr(TPP)2]X (X=ClO4- and PF6-) are isolated after electrochemical oxidation and are characterized by IR and NMR spectroscopy. Magnetic susceptibility measurements (2 K 〈 T 〈 300 K) of the solids confirm the strong coupling of the electron spins in the diamagnetic dication salt [Zr(OEP)2][ClO4]2. The molecular structure of Zr(OEP)2 is elucidated by an X-ray structural analysis.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/cber.19921250118
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  • 10
    Digitale Medien
    Digitale Medien
    Mehrfachbindungen zwischen Hauptgruppenelementen und übergangsmetallen, CII. Flüchtige MN4-Metallkomplexe von Niob und Tantal mit Dimethylsilyl-Substituenten (1992)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 125 (1992), S. 117-118 
    Details
    ISSN: 0009-2940
    Schlagwort(e): Imido ligands ; Amido ligands ; Niobium complexes ; Tantalum complexes ; Chemistry ; Inorganic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Multiple Bonds between Main-Group Elements and Transition Metals, CII[1].  -  Volatile MN4 Metal Complexes of Niobium and Tantalum Containing Dimethylsilyl SubstituentsNiobium and tantalum complexes 4a and 4b of formula (Me2SiH)N=M[N(SiHMe2)2]3 (a: M=Nb; b: M=Ta) are formed from lithium bis(dimethylsilyl)amide and either MOCl3 (2a,b) or MCl5 (3a,b). No β-hydrogen decomposition of these compounds occurs under normal conditions.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/cber.19921250119
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