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  • American Chemical Society  (33,082)
  • American Geophysical Union  (5,644)
  • 2005-2009  (38,726)
  • 1960-1964
  • 2006  (38,726)
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  • 1
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2006. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 111 (2006): C06028, doi:10.1029/2004JC002821.
    Description: This paper describes a simple “multibox” model of the Arctic atmosphere-ice-ocean system. The model consists of two major modules (an Arctic module and a Greenland Sea module) and several sub-modules. The Arctic module includes a shelf box model coupled with a thermodynamic sea ice model, and an Arctic Ocean model coupled with a sea ice model and an atmospheric box model. The Greenland Sea module includes an oceanic model coupled with a sea ice model and a statistical model of surface air temperature over the Greenland Sea. The full model is forced by daily solar radiation, wind stress, river runoff, and Pacific Water inflow through Bering Strait. For validation purposes, results from model experiments reproducing seasonal variability of the major system parameters are analyzed and compared with observations and other models. The model reproduces the seasonal variability of the Arctic system reasonably well and is used to investigate decadal Arctic climate variability in Part 2 of this publication.
    Description: This publication is the result of research sponsored by Alaska Sea Grant with funds from the National Oceanic and Atmospheric Administration Office of Sea Grant, Department of Commerce, under grant no. NA 86RG0050 (project no. GC/01-02), and from the University of Alaska with funds appropriated by the state. This research has also been supported by the National Science Foundation and by the International Arctic Research Center, University of Alaska Fairbanks, under auspices of the United States National Science Foundation.
    Keywords: Arctic decadal oscillations ; Idealized Arctic model ; Arctic–Greenland Sea interaction
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  • 2
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2005. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 6 (2005): Q03001, doi:10.1029/2004GC000849.
    Description: The Zagros mountains of southern Iran are marked by a zone of high seismicity and accommodate a significant portion of the convergence between Arabia and Eurasia. Due to the lack of dense local seismic or geodetic networks, the inferred kinematics of the collision in Iran is mainly based on catalogs of teleseismically determined earthquake locations. We surveyed all M w 〉 4.5 earthquakes in the Harvard Centroid Moment Tensor (HCMT) and International Seismological Centre (ISC) catalogs that occurred in the Zagros mountains during the period 1992–2002 and that were spanned by Interferometric Synthetic Aperture Radar (InSAR) images from the ERS 1 and 2 satellites. We invert the observed deformation for the best fitting point source, single fault plane, and distributed fault slip for four earthquakes and one unexplained deformation event. We find that we can precisely locate earthquakes that are too small to be well-located by either the HCMT or ISC catalogs, allowing us to tie specific earthquakes to active geologic structures.
    Description: ERS 1 and 2 data were acquired through an ESA category-1 proposal. R. Lohman is partially supported by a NASA New Investigator Program grant award to M. Simons.
    Keywords: DOAS ; SO2 emissions
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  • 3
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2004. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 5 (2004): Q10004, doi:10.1029/2004GC000772.
    Description: Long-chain, odd-carbon-numbered C25 to C35 n-alkanes are characteristic components of epicuticular waxes produced by terrestrial higher plants. They are delivered to aquatic systems via eolian and fluvial transport and are preserved in underlying sediments. The isotopic compositions of these products can serve as records of past vegetation. We have developed a rapid method for stable carbon isotopic analyses of total plant-wax n-alkanes using a novel, moving-wire system coupled to an isotope-ratio mass spectrometer (MW-irMS). The n-alkane fractions are prepared from sediment samples by (1) saponification and extraction with organic solvents, (2) chromatographic separation using silica gel, (3) isolation of straight-chain carbon skeletons using a zeolite molecular sieve, and (4) oxidation and removal of unsaturated hydrocarbons with RuO4. Short-chain n-alkanes of nonvascular plant origin (〈C25) are removed by evaporation on the moving wire. Test samples processed using this procedure yielded n-alkane fractions essentially free of interfering components. The δ13C values obtained by MW-irMS did not differ significantly from weighted averages of individual n-alkane δ13C values obtained by irmGC-MS. Isotopic variations in compound-class n-alkane fractions from a latitudinal transect of core-top sediments from the Southwest African margin (3°N–28°S) were congruent with those measured by compound-specific isotopic analyses of plant-wax n-alkanes. The amplitude of the variations was smaller, indicating contributions from non-plant-wax hydrocarbons, but the measurements revealed variations in carbon isotopic composition that are consistent with vegetation zones on the adjacent continent.
    Description: We thank the WHOI Summer Student Fellow program and NSF (BCS-0218511) for funding.
    Keywords: Moving wire ; Plant-wax n-alkanes ; Stable carbon isotopes
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  • 4
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2006. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 111 (2006): C05015, doi:10.1029/2005JC002989.
    Description: New in situ observations from 10°N, 125°W during 1997–1998 show strong intraseasonal variability in meridional velocity and sea surface temperature. The 50- to 100-day oscillations in sea surface height (SSH) have long been recognized as a prominent aspect of oceanic variability in the region of 9–13°N in the eastern Pacific Ocean. We use in situ and satellite data to more fully characterize this variability. The oscillations have zonal wavelengths of 550–1650 km and propagate westward in a manner consistent with the dispersion relation for first baroclinic mode, free Rossby waves in the presence of a mean westward flow. Analysis of 9 years of altimetry data shows that the amplitude of the 50- to 100-day SSH variability at 10°N is largest on 90–115°W, with peak amplitudes occurring around April. Some eddies traveling westward at 10–13°N emanate from near the gulfs of Tehuantepec and Papagayo, but eddies sometimes also appear to intensify well away from the coast while in the North Equatorial Current (NEC). The hypothesis that the intraseasonal variability and its annual cycle are associated with baroclinic instability of the NEC is supported by a spatiotemporal correlation between the amplitude of 50- to 100-day variability and the occurrence of westward zonal flows meeting an approximate necessary condition for baroclinic instability. The notion that baroclinic instability may be involved is further corroborated by the tendency of the NEC to weaken while the eddies intensify, even as the wind works to strengthen the current.
    Description: The authors gratefully acknowledge support for the fieldwork under the NOAA Office of Global Programs Pan American Climate Studies program (grants NA66GPO130 and NA96GPO428) and for analysis and publication (grants NA87RJ0445 and NA17RJ1223).
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  • 5
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2006. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 111 (2006): C07S06, doi:10.1029/2005JC003173.
    Description: Climate variability drives significant changes in the physical state of the North Pacific, and thus there may be important impacts of climate variability on the upper ocean carbon balance across the basin. We address this issue by considering the response of seven biogeochemical ocean models to climate variability in the North Pacific. The models’ upper ocean pCO2 and air-sea CO2 flux respond similarly to climate variability on seasonal to decadal timescales. Modeled seasonal cycles of pCO2 and its temperature and non-temperature driven components at three contrasting oceanographic sites capture the basic features found in observations [Takahashi et al., 2002, 2006; Keeling et al., 2004; Brix et al., 2004]. However, particularly in the Western Subarctic Gyre, the models have difficulty representing the temporal structure of the total pCO2 cycle because it results from the difference of these two large and opposing components. In all but one model, the airsea CO2 flux interannual variability (1σ) in the North Pacific is smaller (ranges across models from 0.03 to 0.11 PgC/yr) than in the Tropical Pacific (ranges across models from 0.08 to 0.19 PgC/yr), and the timeseries of the first or second EOF of the air-sea CO2 flux has a significant correlation with the Pacific Decadal Oscillation (PDO). Though air-sea CO2 flux anomalies are correlated with the PDO, their magnitudes are small (up to ±0.025 PgC/yr (1σ)). Flux anomalies are damped because anomalies in the key drivers of pCO2 (temperature, dissolved inorganic carbon (DIC) and alkalinity) are all of similar magnitude and have strongly opposing effects that damp total pCO2 anomalies.
    Description: F. Chai and L. Shi acknowledge grant support from NSF (OCE 0137272) and NASA (NAG5-9348; S. Doney and I. Lima from NSF/ONR NOPP (N000140210370) and NASA (NNG05GG30G); G. McKinley from NASA (NNG05GF94G); and T. Takahashi from NOAA (NA16GP2001).
    Keywords: Ocean carbon cycle ; Ocean models ; PDO
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  • 6
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    American Geophysical Union
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2006. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 33 (2006): L14614, doi:10.1029/2006GL026769.
    Description: Potential temperature differences are computed from hydrographic sections transiting the western basins of the South Atlantic Ocean from 60°S to the equator in 2005/2003 and 1989/1995. While warming is observed throughout much of the water column, the most statistically significant warming is about +0.04°C in the bottom 1500 dbar of the Brazil Basin, with similar (but less statistically significant) warming signals in the abyssal Argentine Basin and Scotia Sea. These abyssal waters of Antarctic origin spread northward in the South Atlantic. The observed abyssal Argentine Basin warming is of a similar magnitude to that previously reported between 1980 and 1989. The Brazil Basin abyssal warming is similar in size to and consistent in timing with previously reported changes in abyssal southern inflow and northern outflow. The temperature changes reported here, if they were to hold throughout the abyssal world ocean, would contribute substantially to global ocean heat budgets.
    Description: The 2005 and 2003 cruises on the NOAA Ship Ronald Brown are part of the NOAA/NSF funded U.S. CLIVAR/CO2 Repeat Hydrography Program. The NOAA Office of Oceanic and Atmospheric Research and the NOAA Climate Program Office further supported GCJ.
    Keywords: Antarctic bottom water ; Brazil Basin ; Atlantic Ocean
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  • 7
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2005. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 6 (2005): Q09008, doi:10.1029/2005GC000954.
    Description: We reconstruct the volcanic and tectonic evolution over the last 250,000 years of the median valley floor in the spreading segment of the Mid-Atlantic Ridge centered at 25°N. In the center of the segment, multibeam bathymetry and deep-towed side-scan images show a large area of smooth-textured lava flows more like those of the East Pacific Rise than those of the Mid-Atlantic Ridge. Hummocky flows more typical of the Mid-Atlantic Ridge are found toward the southern end of the segment. The presence of the abundant smooth-textured flows allows us to interpret the volcanic and tectonic relationships in the segment. We construct a geological map using (1) multibeam bathymetry to identify the key volcanic structures and fault scarps and (2) high-resolution TOBI side-scan sonar images to interpret age relationships between features on the basis of overall sediment cover as shown by backscatter brightness. Bottom photographs across key features on the median valley floor yield detailed information on stratigraphic relationships between volcanic features and faults and allow us to calibrate backscatter brightness in terms of sediment cover and hence of age. In this way we derive a history of volcanic activity and deformation in a detailed survey area at the segment center, with the most recent flows erupted about 5000 years ago, and the youngest smooth flows about 10,000 years ago, separated by an episode of faulting. Using bathymetry and side-scan surveys, we extrapolate this to the whole of the median valley floor. The volcanic activity giving rise to the smooth flows has been continuous for about a quarter of a million years at the segment center. Over the same period, hummocky flows have been continuously erupted at the southern end of the segment. Electron probe analyses of dredged basalt glasses show that there is a systematic variation in composition with position in the segment. Basalts from the segment center are all more evolved than those at the southern end of the segment. There is, however, no relation of chemistry with lava type. The basalts from the segment center have very nearly the same composition whether they come from hummocky flows or smooth flows. The boundary between the smooth flows and hummocky flows has fluctuated with time and migrated rapidly northward over the last few thousand years, so that shortly the eruption of smooth flows will probably have ceased. The survey shows that flows that are smooth on side-scan images are not necessarily sheet flows. In this study they uniformly show pillow morphology. We conclude that smooth flows were probably erupted at faster eruption rates than hummocky flows.
    Description: This project was funded by an NERC grant that enabled Charles Darwin cruise 65 and by NSF grant OCE-9811575.
    Keywords: Mid-Atlantic Ridge ; Volcanism ; Faulting ; Tectonic history ; Smooth-textured flows ; Hummocky flows
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  • 8
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2004. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 5 (2004): Q04G14, doi:10.1029/2002GC000439.
    Description: This paper presents new magmatic helium isotopic compositions in a suite of lavas from phase II of the Hawaiian Scientific Drilling Project (HSDP2) core, which sampled Mauna Kea volcano to a maximum depth of 3098 m below sea level. Most of the measurements were performed by in vacuo crushing of olivine phenocrysts, but include submarine pillow glasses from the 2200 to 2500 meter depth interval, and orthopyroxene phenocrysts from an intrusive at 1880 m. The magmatic 3He/4He ratios range from 6 to 24.7 times atmospheric (Ra), which significantly extends the range of values for Mauna Kea volcano. The 3He/4He ratios are lowest (i.e., close to MORB values of ∼8 Ra) near the top of the Mauna Kea section and rise slowly, to 10–12 Ra, at 1000 m below sea level, consistent with results from the HSDP1 core. At depths greater than 1000 m in the core, primarily in the submarine lavas, there are brief periods when the 3He/4He ratios are higher than 14.5 Ra, always returning to a baseline value. Twelve such excursions were identified in the core; all but one are in the submarine section, and most (7) are in the deepest section, at depths of 1950 to 3070 m. The baseline 3He/4He value rises from 10–12 Ra near 1000 m depth to 12–14 Ra at 3000 m. The helium spikes are found only in lavas that are older than 380 Ka in age, based on an age model derived from Ar-Ar data (W. D. Sharp et al., manuscript in preparation, 2003). Excluding the excursions defined by single lava flows (3) and intrusive units (3), the average spike duration is approximately 15 (±9) Ka (n = 6). The high 3He/4He spikes are interpreted as pulses of magma from the center of the actively upwelling Hawaiian hot spot. The short duration of the high 3He/4He excursions suggests that Mauna Kea was never directly over high the 3He/4He component of the plume (during the HSDP2 eruptive period), presumed to be the plume center. Assuming that the Mauna Kea helium spikes result from melting of heterogeneities within the plume, their short duration implies that the length scales of heterogeneities in the solid upwelling mantle are between 60 m and 12 km (for upwelling rates of 2 to 40 cm/yr). The high 3He/4He are associated with high 208Pb/204Pb, and relatively low 143Nd/144Nd, Zr/Nb, and SiO2. The correlations with major elements, trace elements and isotopes demonstrate that helium is coupled to the other geochemical variations, and that the Mauna Kea isotopic variability is caused by heterogeneities within the upwelling plume.
    Description: This work was supported by EAR/NSF through the Continental Dynamics and Instrumentation and Facilities programs.
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  • 9
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2004. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 5 (2004): Q06007, doi:10.1029/2004GC000702.
    Description: We deployed five ocean bottom hydrophones (OBHs) for a 1-year seismic monitoring study of Vailulu'u Seamount, the youngest and easternmost volcano in the Samoan Archipelago. Four instruments were placed on the summit crater rim at 600–700 m water depth, and one was placed inside the crater at 1000 m water depth. An analysis of the first 45 days of records shows a very large number of seismic events, 211 of them local. These events define a steady background activity of about four seismic events per day, increasing to about 10 events per day during a week of heightened seismic activity, which peaked at 40 events during 1 day. We identified 107 earthquakes, whose arrivals could be picked on all five stations and that are likely located within the seamount, based on their similar waveforms. Two linear trends are defined by 21 of these events. These are extremely well correlated and located, first downward then upward on a steeply inclined plane that is close to the axial plane of the southeast rift as it emerges from the main summit of Vailulu'u. These events resemble volcanotectonic earthquakes from subaerial volcanoes in displaying very coherent seismic waveforms and by showing systematic, narrowly defined progressions in hypocenter locations. We propose that these events reflect brittle rock failure due to magma redistribution in or near a central magma reservoir.
    Description: The bulk of this work was funded by NSF-OCE, in grants to HS and SRH and the OBSIP facility at Scripps.
    Keywords: Samoa ; Vailulu'u ; Volcano ; Seismic monitoring ; Volcanic activity ; Submarine
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  • 10
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2004. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 5 (2004): Q01007, doi:10.1029/2002GC000408.
    Description: Volcanic glasses contained in distal fallout tephras from the Izu arc volcanic front (Izu VF) provide unique perspectives on general problems of arc volcanism. Unlike cogenetic lavas, these glasses are liquid compositions where element concentrations as well as ratios have significance. Isotopic evidence and previous work show that there is no sediment melt contribution to the sources of the Izu VF tephras, and hence their trace element characteristics permit determination of the trace element contents of slab fluids. The slab fluid is a composite of metasediment (∼5% of total fluid) and metabasalt (∼95%) component fluids, and carries large ion lithophile elements (LILE) with high LILE/Th and LILE/U, and low Th and U relative to source. Except for Sr and K, the metabasalt fluid is much less enriched than the metasediment fluid, but its large relative proportions make it an important carrier of many trace elements. The metabasalt fluid has the characteristics of the arc trace element signature, obviating the need for ubiquitous involvement of sediment in arc magma genesis. The fluid component in the tephras is remarkably constant in composition over fifteen million years, and hence appears to be a robust composition that may be applicable to other convergent margins. Assuming that the metabasalt fluid is a common component, and that distribution coefficients between sediment and fluid are similar from one arc to another, composite fluid compositions can be estimated for other arcs. Differences from this composition then would likely result from a sediment melt component. Comparison to arcs with sediment melt components in their source (Marianas, eastern Aleutians) shows that partial sediment melts may be so enriched, that they can completely mask the signature of the comingling slab fluids. Hence sediment melts can easily dominate the trace element and isotopic signature of many convergent margins. Since sediment melts inherit the LILE/LILE ratios of the trench sediment, Earth's surface processes must eventually influence the compositional diversity of arcs.
    Description: This study was funded by the “Deutsche Forschungsgemeinschaft” (grants Str 441/3 and 441/4). The Northeast National Ion Microprobe Facility at WHOI was supported by grants EAR-9628749 and EAR-990440 from the National Science Foundation.
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