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  • Articles  (53)
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  • Springer  (53)
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  • Energy, Environment Protection, Nuclear Power Engineering  (23)
  • Electrical Engineering, Measurement and Control Technology  (21)
  • Physics  (6)
  • Sociology  (4)
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  • Articles  (53)
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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Risk analysis 19 (1999), S. 915-931 
    ISSN: 1539-6924
    Keywords: Yucca Mountain ; performance assessment ; logic tree ; high-level radioactive waste ; Monte Carlo ; expert judgment ; repository ; groundwater ; climate ; infiltration ; percolation ; hydrothermal ; corrosion
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The Electric Power Research Institute (EPRI) has sponsored the development of a model to assess the long-term, overall “performance” of the candidate spent fuel and high-level radioactive waste (HLW) disposal facility at Yucca Mountain, Nevada. The model simulates the processes that lead to HLW container corrosion, HLW mobilization from the spent fuel, and transport by groundwater, and contaminated groundwater usage by future hypothetical individuals leading to radiation doses to those individuals. The model must incorporate a multitude of complex, coupled processes across a variety of technical disciplines. Furthermore, because of the very long time frames involved in the modeling effort (≫104 years), the relative lack of directly applicable data, and many uncertainties and variabilities in those data, a probabilistic approach to model development was necessary. The developers of the model chose a logic tree approach to represent uncertainties in both conceptual models and model parameter values. The developers felt the logic tree approach was the most appropriate. This paper discusses the value and use of logic trees applied to assessing the uncertainties in HLW disposal, the components of the model, and a few of the results of that model. The paper concludes with a comparison of logic trees and Monte Carlo approaches.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of applied electrochemistry 27 (1997), S. 1265-1274 
    ISSN: 1572-8838
    Keywords: corrosion ; hydrogen embrittlement ; inhibitors ; HSLA steel ; nitrite compounds
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
    Notes: Abstract The inhibitive action of valeronitrile, benzonitrile and derivatives of benzonitrile on the corrosion and hydrogen embrittlement behaviour of HSLA steel in 0.5m H2SO4 was investigated. All these inhibitors reduced the corrosion rate of the steel with naphthonitrile showing the highest inhibitive efficiency and valeronitrile the lowest. All the inhibitors adsorbed on the steel as per the Temkin adsorption isotherm. The steel become less active on the addition of benzonitrile, 3-chlorobenzonitrile, 4-chlorobenzonitrile, 4-methylbenzonitrile and naphthonitrile to the acid while valeronitrile and 2-chlorobenzonitrile made the steel more active. Naphthonitrile reduced the rate of the hydrogen evolution reaction most efficiently. Derivatives of benzonitrile inhibited hydrogen absorption most effectively.
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Journal of applied electrochemistry 27 (1997), S. 1245-1253 
    ISSN: 1572-8838
    Keywords: fluorine production ; monel alloy ; corrosion ; passive films ; KF.2HF melts
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
    Notes: Abstract Commercial fluorine production is conducted from KF.2HF melts at 85∘C in Monel cells that are subject to corrosion. Here we report studies of passivation and depassivation of the Monel in relation to that of Ni, its principal (65 wt % ) constituent, by means of cyclic voltammetry and recording of open-circuit potential-relaxation transients. The latter exhibit arrests at characteristic Flade-type potentials and lead to information on the kinetics of passive film breakdown. The role of diffusion processes in such breakdown and film dissolution is evaluated using the rotating disc electrode technique which enables comparisons to be made with the passivation behaviour of the separate main components of Monel, viz. Ni and Cu.
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Journal of applied electrochemistry 28 (1998), S. 1351-1357 
    ISSN: 1572-8838
    Keywords: copper ; corrosion ; cyclic voltammetry ; iron ; Spirulina platensis
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
    Notes: Abstract Cyclic voltammograms of iron and copper electrodes were run in sodium hydroxide, carbonate–bicarbonate buffer and culture media for Spirulina platensis at 30°C. Potentiostatic steady state polarisation curves for both electrode surfaces in these electrolytes were performed in the presence and the absence of S. platensis at fixed temperature. Corrosion potential and corrosion current density values of iron and copper were obtained graphically from these curves. In all cases, the largest corrosion current density corresponded to the maximum biogenerated-oxygen concentrations, that is, illuminated culture media containing S. platensis. Corrosion potentials of iron electrodes shifted to positive values for increasing corrosion rates, whereas constant corrosion potentials were obtained for copper electrodes independently of the electrolyte.
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Journal of applied electrochemistry 28 (1997), S. 151-160 
    ISSN: 1572-8838
    Keywords: corrosion ; 1024 mild steel ; pitting ; film breakdown ; electro-oxidation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
    Notes: Abstract The passive film breakdown of 1024 mild steel induced by the presence of 0.05m chloride ions had been investigated in 0.075–0.75m bicarbonate solutions at pH8.9–9.7. A rotating disc electrode with a Kel-F holder was used in conjunction with a rotating ring-disc electrode. The resistance to localized attack is closely linked to the preanodization potential (Eox) applied in the absence of Cl- ions. For Eox below about 0.2–0.3V vs SCE, the resistance to localized attack provided by the passive film is independent of Eox; above the breakdown potential, the localized attack is manifested by the formation of pits at the mild steel surface. The breakdown potential increases linearly with NaHCO3 concentration and pH. Passive film breakdown for Eox below about 0.2–0.3V vs SCE most likely begins with a surface film dissolution prior to the penetration of the aggressive anions through the film. For Eox above about 0.3V vs SCE under the same conditions, no pitting is noticed and the potential associated with localized attack shifts considerably in the anodic direction due to interstitial (formation of crevices) corrosion at the mild steel/Kel-F interface.
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Journal of applied electrochemistry 28 (1998), S. 405-410 
    ISSN: 1572-8838
    Keywords: aluminium alloys ; corrosion ; voltage fluctuations ; impedance spectroscopy
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
    Notes: Abstract Electrochemical impedance spectroscopy (EIS) and spontaneous voltage fluctuation measurements were made on three orthogonal faces of 7039-T64 and 2519 aluminium alloy specimens during 10 day exposure periods into aerated 3% NaCl solutions. The spontaneous voltage fluctuations generated by the specimens were analysed with two techniques designed to reveal the stochastic character of these signals and their fractal dimension to establish practical correlation between noise measurements and the degree of pitting of the corroding aluminium specimens. Attempts were made to correlate the results of these analyses with parameters measurable by microscopic examination of the specimens or calculated from EIS measurements. During this study it was found that the slope of the voltage fluctuations and the depression angle of EIS results were both good indicators of the pit density observable on the corroded aluminium specimens.
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Journal of applied electrochemistry 29 (1999), S. 619-626 
    ISSN: 1572-8838
    Keywords: corrosion ; EIS ; H3PO4 ; organic onium compounds ; zinc
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
    Notes: Abstract The inhibiting properties of some organic phosphonium and ammonium compounds were studied with respect to the corrosion of zinc in 1 M H3PO4 solution. It was found that onium compounds which have π-electron system(s) are adsorbed following Frumkin's adsorption isotherm and provide better inhibition efficiency than those containing no π -electron system. The adsorption of the latter compounds was found to obey Langmuir's isotherm. Both potentiostatic and electrochemical impedance techniques proved that the studied onium compounds act as primary interface inhibitors without changing the mechanism of either hydrogen evolution reaction or zinc dissolution.
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  • 8
    Electronic Resource
    Electronic Resource
    Springer
    Journal of applied electrochemistry 29 (1999), S. 745-749 
    ISSN: 1572-8838
    Keywords: copper–nickel alloys ; corrosion ; electrochemistry ; rotating cylinder electrode
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
    Notes: Abstract A rotating cylinder electrode (RCE) for corrosion studies has been constructed and hydrodynamically characterized. Empirical hydrodynamic parameters were determined from limiting current density and weight loss measurements for four different electrochemical processes. Statistical data analysis established the confidence limits of these parameters.
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  • 9
    Electronic Resource
    Electronic Resource
    Springer
    Journal of applied electrochemistry 29 (1999), S. 647-654 
    ISSN: 1572-8838
    Keywords: conversion coatings ; corrosion ; impedance ; molybdate ; passivation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
    Notes: Abstract The behaviour of molybdate conversion coatings on zinc coated mild steel in corrosive chloride environments was investigated using electrochemical impedance spectroscopy (EIS), X-ray photoelectron spectroscopy (XPS) and neutral salt fog exposure. It was found that the presence of a simple molybdate coating initially increased the rate of corrosion of zinc. Molybdenum species were initially present in the conversion coating in either the +V or +VI oxidation states. Exposure to neutral salt fog reduced molybdenum to either Mo(IV) or Mo(III). This reduction of molybdenum, an additional cathodic process, may result in the activation of zinc observed in these studies. For molybdate-passivated surfaces in the early stages of exposure to neutral salt fog, corrosion products were found to be less voluminous than those observed on untreated surfaces. This may be due to the presence of inhibiting Mo(IV) or Mo(III) species in the corrosion product layers. However, after 24 h exposure to salt fog, no molybdenum could be detected. This implies that the lower oxidation state molybdenum species formed are soluble. However, surfaces passivated from molybdate solutions appear to forestall the onset of red rust, during immersion in chloride solutions and exposure to salt fog, by approximately 12 to 24 h. This behaviour may be attributable to corrosion inhibition by Mo(III) and Mo(IV) species while they are present at the surface.
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  • 10
    Electronic Resource
    Electronic Resource
    Springer
    Journal of applied electrochemistry 29 (1999), S. 1133-1137 
    ISSN: 1572-8838
    Keywords: cobalt ; corrosion ; multilayer deposition ; zinc
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
    Notes: Abstract The corrosion behaviour of Zn–Co compositionally modulated multilayers (CMM) was studied using corrosion potential measurement and the neutral salt spray (NSS) method. It was established that the corrosion potentials of the CMM, deposited from a single bath, are significantly more positive than those deposited from a dual bath. The best corrosion resistance was found for multilayers consisting of four sublayers, each 3.0 μm thick, deposited both from a dual bath and from a single bath (with an oversublayer of Zn–Co 1%).
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