ALBERT

Description: Phytoplankton primary productivity (PP) varies significantly over environmental gradients, particularly in physically‐dynamic systems such as estuaries and coastal seas. During summer, runoff peaks in the Changjiang River driving large environmental gradients in both the Changjiang estuary and adjacent East China Sea (ECS), likely driving significant variability in PP. As satellite models of PP often underperform in coastal waters, we aimed to develop a novel approach for assessing net PP variability in such a dynamic environment. Parallel in situ measurements of Fast Repetition Rate (FRR) fluorometry and carbon (C) uptake rates were conducted for the first time in this region during two summer cruises in 2019 and 2021. A series of 13 C‐incubations ( n = 31) were performed, with measured PP ranging from ∼6 to 1,700 mgC m −3 d −1 . Net PP values were significantly correlated with salinity ( r = 0.45), phytoplankton chlorophyll a (Chl‐ a , r = 0.88), Photosystem II (PSII) functional absorption cross‐section ( σ PSII , r = −0.76) and maximum PSII quantum yield ( F v / F m , r = 0.59). Stepwise regression analysis showed that Chl‐ a and σ PSII were the strongest predictors of net PP. A generalized additive model (GAM) was also used to estimate net PP considering nonlinear effects of Chl‐ a and σ PSII . We demonstrate that GAM outperforms linear modeling approaches in estimating net PP in this study, as evidenced by a lower root mean square error (∼140 vs. 250 mgC m −3 d −1 ). Our novel approach provides a valuable tool to examine carbon cycling dynamics in this important region. Plain Language Summary The East China Sea has a complex current system that creates a highly dynamic physical environment for phytoplankton, particularly during the summer months. Net primary productivity (PP) is highly variable in this region, yet characterizing these spatial patterns in PP is difficult due to the lack of a high‐resolution data collecting method. Therefore, a strong need exists for a quick and easily implemented method for monitoring PP in this dynamic system. Based on parallel measurements of phytoplankton biomass and photophysiology, we present a novel approach that allows us to rapidly and easily assess regional PP at a high resolution. The high data volume potentially afforded by our net PP estimation method could not only contribute to a better understanding of PP variations in such a dynamic environment, but also help fill the large gaps in field data needed for validating satellite‐based PP models. Key Points Parallel in situ measurements of net primary productivity (PP) and Fast Repetition Rate fluorometry were conducted in the Changjiang estuary Productivity was highest at stations with high Chl and low σ PSII , typically located along the Chiangjiang river plume front A generalized additive model was developed to estimate net PP, providing an approach for assessing regional C‐cycling dynamics

Description: Submarine landslides pose a hazard to coastal communities and critical seafloor infrastructure, occurring on all of the world's continental margins, from coastal zones to hadal trenches. Offshore monitoring has been limited by the largely unpredictable occurrence of submarine landslides and the need to cover large regions. Recent subsea monitoring has provided new insights into the preconditioning and run-out of submarine landslides using active geophysical techniques. However, these tools measure a small spatial footprint and are power- and memory-intensive, thus limiting long-duration monitoring. Most landslide events remain unrecorded. In this chapter, we first show how passive acoustic and seismologic techniques can record acoustic emissions and ground motions created by terrestrial landslides. This terrestrial-focused research has catalyzed advances in characterizing submarine landslides using onshore and offshore networks of broadband seismometers, hydrophones, and geophones. We discuss new insights into submarine landslide preconditioning, timing, location, velocity, and down-slope evolution arising from these advances. Finally, we outline challenges, emphasizing the need to calibrate seismic and acoustic signals generated by submarine landslides. Passive seismic and acoustic sensing has a strong potential to enable more complete hazard catalogs to be built and open the door to emerging techniques (such as fiber-optic sensing) to fill key knowledge gaps.

Description: While basaltic volcanism is dominate during rifting and continental breakup, felsic magmatism may also comprise important components of some rift margins. During International Ocean Discovery Program (IODP) Expedition 396 on the continental margin of Norway, a graphite-garnet-cordierite bearing dacitic, pyroclastic unit was recovered within early Eocene sediments on Mimir High (Site U1570), a marginal high on the Vøring transform margin. Here, we present a comprehensive textural, mineralogical, and petrological study of the dacite in order to assess its melting origin and emplacement. The major mineral phases (garnet, cordierite, quartz, plagioclase, alkali feldspar) are hosted in a fresh rhyolitic, highly vesicular, glassy matrix, locally mingled with sediments. The xenocrystic major element chemistry of garnet and cordierite, the presence of zircon inclusions with inherited cores, and thermobarometric calculations all support a crustal metapelite origin. While most magma-rich margin models favor crustal anatexis in the lower crust, thermobarometric calculations performed here show that the dacite was produced at upper-crustal depths (〈 5 kbar) and high temperature (750–800 °C) with up to 3 wt% water content. In situ U-Pb analyses on zircon inclusions give a magmatic age of 54.6 ± 1.1 Ma, revealing the emplacement of the dacite post-dates the Paleocene-Eocene Thermal Maximum (PETM). Our results suggest that the opening of the North Atlantic was associated with a phase of low-pressure, high-temperature crustal melting at the onset of the main phase of magmatism.

Description: Aim Seamounts are conspicuous geological features with an important ecological role and can be considered vulnerable marine ecosystems (VMEs). Since many deep‐sea regions remain largely unexplored, investigating the occurrence of VME taxa on seamounts is challenging. Our study aimed to predict the distribution of four cold‐water coral (CWC) taxa, indicators for VMEs, in a region where occurrence data are scarce. Location Seamounts around the Cabo Verde archipelago (NW Africa). Methods We used species presence–absence data obtained from remotely operated vehicle (ROV) footage collected during two research expeditions. Terrain variables calculated using a multiscale approach from a 100‐m‐resolution bathymetry grid, as well as physical oceanographical data from the VIKING20X model, at a native resolution of 1/20°, were used as environmental predictors. Two modelling techniques (generalized additive model and random forest) were employed and single‐model predictions were combined into a final weighted‐average ensemble model. Model performance was validated using different metrics through cross‐validation. Results Terrain orientation, at broad scale, presented one of the highest relative variable contributions to the distribution models of all CWC taxa, suggesting that hydrodynamic–topographic interactions on the seamounts could benefit CWCs by maximizing food supply. However, changes at finer scales in terrain morphology and bottom salinity were important for driving differences in the distribution of specific CWCs. The ensemble model predicted the presence of VME taxa on all seamounts and consistently achieved the highest performance metrics, outperforming individual models. Nonetheless, model extrapolation and uncertainty, measured as the coefficient of variation, were high, particularly, in least surveyed areas across seamounts, highlighting the need to collect more data in future surveys. Main Conclusions Our study shows how data‐poor areas may be assessed for the likelihood of VMEs and provides important information to guide future research in Cabo Verde, which is fundamental to advise ongoing conservation planning.

Description: Volcanic flank collapses, especially those in island settings, have generated some of the most voluminous mass transport deposits on Earth and can trigger devastating tsunamis. Reliable tsunami hazard assessments for flank collapse-driven tsunamis require an understanding of the complex emplacement processes involved. The seafloor sequence southeast of Montserrat (Lesser Antilles) is a key site for the study of volcanic flank collapse emplacement processes that span subaerial to submarine environments. Here, we present new 2D and 3D seismic data as well as MeBo drill core data from one of the most extensive mass transport deposits offshore Montserrat, which exemplifies multi-phase landslide deposition from volcanic islands. The deposits reveal emplacement in multiple stages including two blocky volcanic debris avalanches, secondary seafloor failure and a late-stage erosive density current that carved channel-like incisions into the hummocky surface of the deposit about 15 km from the source region. The highly erosive density current potentially originated from downslope-acceleration of fine-grained material that was suspended in the water column earlier during the slide. Late-stage erosive turbidity currents may be a more common process following volcanic sector collapse than has been previously recognized, exerting a potentially important control on the observed deposit morphology as well as on the runout and the overall shape of the deposit. Key Points Landslide emplacement offshore Montserrat included volcanic flank collapses, sediment incorporation, and a late-stage erosive flow Highly erosive flows are likely to be common processes during volcanic flank collapse deposition Pre-existing topography plays a major role in shaping flank collapse-associated mass transport deposits Plain Language Summary Disintegration of volcanic islands can cause very large landslides and destructive tsunamis. To assess the tsunami hazard of such events, it is crucial to understand the processes that are involved in their formation. We present new insights from seismic data and drill cores from a landslide deposit offshore Montserrat, a volcanic island in the Lesser Antilles Arc in the Caribbean. Our analysis reveals the emplacement of landslide material in several stages, including multiple volcanic flank collapses, incorporation of seafloor sediments and an erosive flow that carved channels into the top of the deposit right after its emplacement. We suggest that highly erosive flows are a common process during volcanic flank collapse deposition and that they play a significant role in the shaping of the deposit's appearance.

Description: Marginal seas influenced by large rivers are characterized by complex hydrodynamic and organic matter cycling processes. However, the impacts of hydrodynamics on the composition and reactivity of particulate organic matter (POM) remain unclear. Here we conducted a comprehensive study on the bulk, molecular and biological properties of suspended POM in the Changjiang Estuary and adjacent area subjected to strong currents, eddies as well as typhoons during spring and autumn. D/L‐enantiomers of particulate amino acids (PAA) were analyzed to evaluate the bioreactivity of POM and quantify bacterial‐derived organic carbon. We found that POM bioavailability as indicated by carbon‐normalized yields of PAA (PAA‐C%) reflected the ecosystem productivity. Relatively high PAA‐C% values (20−35%) were observed in productive areas influenced by Changjiang River plume, cyclonic eddies and typhoons, likely related to the enhanced nutrient availability arising from hydrodynamic processes. In contrast, the oligotrophic Taiwan Warm Current‐influenced regions featured relatively low POM bioavailability (PAA‐C% 〈 10%) despite typhoons facilitating water mixing. The PAA‐C% values showed a significant positive correlation with extracellular enzyme activity, indicating that bioavailable POM can rapidly stimulate heterotrophic transformation. Hot spots of elevated bioavailable POM showed high contributions of bacterial organic carbon. A large portion (∼2/3) of bacterial organic carbon was present in the form of bacterial detritus, suggesting that patches of these biological hot spots represent important sites of carbon sequestration. Together, our findings indicate that fresh POM production is largely controlled by nutrient supply driven by hydrodynamic processes, with important implications for carbon sequestration in the dynamic ocean margins. Plain Language Summary Marginal seas are subject to complex hydrodynamic processes and play an important role in carbon sequestration. Disentangling the linkages between hydrodynamics and organic carbon reactivity and composition is crucial to understanding the regional carbon cycle. Here we collected suspended particulate organic matter (POM) in the Changjiang Estuary and adjacent coastal areas. Based on the biomarker D/L‐amino acids, we assessed the bioavailability of POM and quantified the organic carbon originating from bacteria. We found that high bioactivity of POM occurred in productive Changjiang River plume, cyclonic eddy, and typhoon influenced areas. These hydrodynamic processes appear to increase nutrient availability, therefore promoting phytoplankton growth. Bioavailable POM can rapidly stimulate heterotrophic activity and facilitate the transformation of algal‐derived organic carbon to bacterial detritus, thus contributing to carbon sequestration. Our findings suggest that the production of bioavailable POM is largely controlled by hydrodynamically driven nutrient supply. Key Points We use D/L‐amino acids to assess the bioreactivity and bacterial origins of particulate organic matter (POM) in the dynamic Changjiang Estuary and adjacent area High bioavailability of POM occurs in productive regions affected by Changjiang River plume, cyclonic eddies and typhoons Hot spots of bioavailable POM represent important sites for carbon sequestration

Description: The Arctic Ocean plays an important role in the regulation of the earth's climate system, for instance by storing large amounts of carbon dioxide within its interior. It also plays a critical role in the global thermohaline circulation, transporting water entering from the Atlantic Ocean to the interior and initializing the southward transport of deep waters. Currently, the Arctic Ocean is undergoing rapid changes due to climate warming. The resulting consequences on ventilation patterns, however, are scarce. In this study we present transient tracer (CFC-12 and SF6) measurements, in conjunction with dissolved oxygen concentrations, to asses ventilation and circulation changes in the Eurasian Arctic Ocean over three decades (1991–2021). We constrained transit time distributions of water masses in different areas and quantified temporal variability in ventilation. Specifically, mean ages of intermediate water layers in the Eurasian Arctic Ocean were evaluated, revealing a decrease in ventilation in each of the designated areas from 2005 to 2021. This intermediate layer (250–1,500 m) is dominated by Atlantic Water entering from the Nordic Seas. We also identify a variability in ventilation during the observation period in most regions, as the data from 1991 shows mean ages comparable to those from 2021. Only in the northern Amundsen Basin, where the Arctic Ocean Boundary Current is present at intermediate depths, the ventilation in 1991 is congruent to the one in 2005, increasing thereafter until 2021. This suggests a reduced ventilation and decrease in the strength of the Boundary Current during the last 16 years. Key Points Temporal variability of ventilation in the Eurasian Arctic Ocean during the past 30 years is estimated by observations of transient tracers We found a slow down of the ventilation between 2005 and 2021 in the intermediate waters Evidence of multidecadal variability of ventilation in the intermediate waters of the Eurasian Arctic Ocean is present Plain Language Summary The Eurasian Arctic Ocean, the region of the Arctic Ocean connected to the European and Asian continents, is an important pathway for recently ventilated water from the Nordic Seas. These waters are exported back to the North Atlantic following their travel through the Arctic Ocean. Ventilation describes the process of surface waters being transported into the interior ocean due to increasing density, which affects the underlying water masses. In this study we investigate how the ventilation patterns have evolved in the Eurasian Arctic Ocean over the past three decades, using transient tracer (CFC-12 and SF6) measurements. We observed a significant change in the intermediate layer (250–1,500 m) with older waters found in measurements in 1991 and 2021 compared to 2005 and 2015. Moreover, our data suggest a slowdown in ventilation throughout the three decades in the northern Amundsen Basin, implying a decrease in the circulation time-scale of the Arctic Ocean Boundary Current over the past 16 years. This has potentially important implications for the transport of, for example, heat, salt or oxygen from the Atlantic Ocean around the Arctic Ocean, and back.

Description: In the boreal summer of 2021, the equatorial Atlantic experienced the strongest warm event, that is, Atlantic Niño, since the beginning of satellite observations in the 1970s. Such events have far‐reaching impacts on large‐scale wind patterns and rainfall over the surrounding continents. Yet, developing a paradigm of how Atlantic Niño interacts with the upper‐ocean currents and intraseasonal waves remains elusive. Here we show that the equatorial Kelvin wave associated with the onset of the 2021 Atlantic Niño modulated both the background flow and the eddy flux of the equatorial upper‐ocean circulation, causing an extremely weak and delayed tropical instability wave (TIW) season. TIW‐induced variations of sea surface temperature (SST), sea surface salinity, sea surface height, and eddy temperature advection were exceptionally weak during May to July, the climatological peak of TIW activity, but rebounded in August when higher than normal variability was observed. Moored velocity data at 23°W show that during the peak of the 2021 Atlantic Niño from June to August, the Equatorial Undercurrent was deeper and stronger than usual. An anomalously weak eddy momentum flux strongly suppressed barotropic energy conversion north of the equator from May to July, likely contributing to low TIW activity. Reduced baroclinic energy conversion also might have played a role, as the meridional gradient of SST was sharply reduced during the Atlantic Niño. Despite extremely weak TIW velocities, modest intraseasonal variability of chlorophyll‐a (Chl‐ a ) was observed during the Atlantic Niño, due to pronounced meridional Chl‐ a gradients that partly compensated for the weak TIWs. Plain Language Summary Every few years the eastern equatorial Atlantic Ocean is significantly warmer than usual during boreal summer. Such warm events are referred to as Atlantic Niño events, and share similarities with El Niño events in the Pacific. In 2021, the strongest Atlantic Niño in at least four decades was observed in the equatorial Atlantic. This study is the first that investigates the complex interaction between Atlantic Niño, tropical Atlantic upper‐ocean currents, and equatorial waves based on various observational data sets. We show that the developing 2021 Atlantic Niño weakened both the background flow and the variability of near‐surface currents in May, which in turn largely reduced the strength of intraseasonal (20–50 days) waves that are usually generated by instability of the upper‐ocean zonal currents. As a consequence, the cooling effect that these waves usually have north of the equator and the warming effect along the equator vanished from May to July 2021. Interestingly, variability of chlorophyll concentration was enhanced, suggesting that enhanced meridional chlorophyll gradients compensated for reduced wave activity. Key Points The developing 2021 Atlantic Niño led to weaker equatorial surface currents and reduced vertical shear of upper‐ocean horizontal velocity Strong reduction of the surface flow, eddy flux, and meridional temperature gradient in May caused extremely weak and delayed tropical instability wave (TIW) season Reduced meridional TIW advection contributed to sharpen the north equatorial Chl‐ a front resulting in modest intraseasonal Chl‐ a variability

Description: Three volcanic arcs have been the source of New Zealand's volcanic activity since the Neogene: Northland arc, Coromandel Volcanic Zone (CVZ) and Taupō Volcanic Zone (TVZ). The eruption chronology for the Quaternary, sourced by the TVZ, is well studied and established, whereas the volcanic evolution of the precursor arc systems, like the CVZ (central activity c. 18 to 2 Ma), is poorly known due to limited accessibility to, or identification of, onshore volcanic deposits and their sources. Here, we investigate the marine tephra record of the Neogene, mostly sourced by the CVZ, of cores from IODP Exp. 375 (Sites U1520 and U1526), ODP Leg 181 (Sites 1123, 1124 and 1125), IODP Leg 329 (Site U1371) and DSDP Leg 90 (Site 594) offshore of New Zealand. In total, we identify 306 primary tephra layers in the marine sediments. Multi-approach age models (e.g. biostratigraphy, zircon ages) are used in combination with geochemical fingerprinting (major and trace element compositions) and the stratigraphic context of each marine tephra layer to establish 168 tie-lines between marine tephra layers from different holes and sites. Following this approach, we identify 208 explosive volcanic events in the Neogene between c. 17.5 and 2.6 Ma. This is the first comprehensive study of New Zealand's Neogene explosive volcanism established from tephrochronostratigraphic studies, which reveals continuous volcanic activity between c. 12 and 2.6 Ma with an abrupt compositional change at c. 4.5 Ma, potentially associated with the transition from CVZ to TVZ. Key Points New Zealand's Neogene explosive volcanism based on the marine tephra record Geochemical fingerprinting of marine tephra layers across the study area to establish volcanic events Insights into geochemical variations with time, repose times and spatiotemporal distribution