ISSN:
0935-6304
Keywords:
Gas chromatography
;
Capillary, glass
;
Surface roughening by diatomaceous support (5 micron particles deposition)
;
Organic glue (polar polymethacrylate acetate) used as intermediate material
;
Reproducibility and durability of capillaries discussed
;
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
A technique for adhesion of fine particles (ca. 5 μ) of the 405 white diatomaceous support on the inner wall of glass tube with organic glue [poly (diethylaminoethyl methacrylate) acetate] is described. The coated tube was drawn to capillary column by using a machine designed according to Desty's. The capillary column was then coated with stationary phase (such as squaiane, QF-1, Dexsil 300, PEG 20 M, OV-1, SE 30 and etc.) by the conventional dynamic or static method. This preparation method has proved easy to duplicate and is simple. The coating efficiency (UTE %) is within 60-90. The theoretical plate number per meter of an SE 30 column is about 4000, and per meter of a PEG 20 M column is about 2500. The columns thus prepared have been successfully used to analyze petroleum hydrocarbons, essential oils, petrochemicals, pheromone, steroid metabolites and others.
Additional Material:
6 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/jhrc.1240020711
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