ALBERT

Description: An estimate of average river particulate matter (RPM) composition was bàsed on analyses of more than 40 elements in the Amazon, Congo, Ganges, Magdalena, Mekong, Parana and Orinoco rivers, to which were added literature data for 13 other major world rivers, covering the whole spectrum of morphoclimatic features. Geographic variations of major elements in RPM are mostly linked to weathering types and to the balance between weathering rate and river transport. As a result of chemical erosion, Al, Fe and Ti are enriched in RPM with respect to the average parent rock, while Na, Ca, Mg and Sr are strongly depleted. These figures are directly related to the relative importance of dissolved and particulate transport in rivers; this has been computed for each of 40 elements. In order to study weathering on a global scale, the total observed elemental fluxes (dissolved + particulate) have been computed and compared to theoretical ones. The latter were derived from the elemental content in the average parent rock and the total quantity of weathered material, computed from the Al ratio in RPM and in parent rock. Observed and theoretical fluxes are balanced for the less mobilized elements (rare earths, Co, Cr, Cs, Fe, Mn, Rb, Si, Th, Ti, U and V) for which no enrichment relative to Al is noted in RPM, and for B, Ba, Ca, K, Mg, Na, Sr which are relatively depleted in RPM due to their high dissolved transport. Additional fluxes have been found for Br, Sb, Pb, Cu, Mo, Zn and are possible also for Ni and P. This is reflected by marked enrichments in RPM relative to Al for the poorly or moderately dissolved transports (Pb, Cu, Zn). Several hypotheses involving either the natural origin (volcanic dust, marine aerosols, geochemical fractionation) or the artificial origin (worldwide pollution) are discussed to explain these discrepancies, assuming river transport and weathering either to be in a steady state on a global scale or not. However, none of them can fully account for these additional fluxes. It is most likely that these excesses have multiple origins, anthropogenic or natural or both. The comparison between RPM and deep-sea clay compositions emphasizes the prime influence of river input on oceanic sedimentation of Si, Al, Fe, Ti, lanthanides, Sc, Rb, V, etc. A few elements such as Zn, Sb, occur in excess in RPM as compared to deep-sea clays; in order to balance this excess, a remobilization of these elements out of the sediment can be considered. Finally, the enrichment of Co, Cu, Mn and Ni in deep-sea clays compared to RPM is discussed and attributed to several sources and processes.

Description: Calcium absorbtion was measured in fasting human beings after oral administration of Ca^45 in a solution containing 10 to 500mg stable calcium and an intravenous dose of Ca^47. Absorbtion was determined from the ratio of specific activities of the two isotopes (oral dose/intravenous dose) in calcium of urine collected more than 24 hours later. The accuracy of this calculation was confirmed by comparison with absorbtion calculated from recovery of the oral dose in stools (the completeness of collection being determined from recovery of simultaneously given Cr2O2or Cr^51 labeled protein and a correction for endogenous calcium being made from the fecal recovery of the intravenouse dose of Ca^47). In 20 tests, the average difference between the two calculations of per cent absorbtion was 2.2 and the coefficient of variation, 1.6. The Conditions under which the double isotope procedure gives an accurate result were evaluated and the results of its use with 3 different doses of calcium given to normal subjects are reported

Description: This chapter discusses the Maillard reaction. Results of the many investigations into the mechanism of the Maillard reaction support one of two main theories. The first assumes the formation of glycosylamines that undergo the Amadori (or, for ketoses, the Heyns) rearrangement. The 1-amino-l-deoxyketose derivative (or 2-amino-2-de- oxyaldose derivative) formed may be dehydrated and cyclized to form furan derivatives, or it may enolize. In either case, intermediates that are readily transformed into brown compounds are formed. A third possibility is for the deoxy sugar derivative to react with more amino acid to form colored products. The many workers who have supported this mechanism found also that optimum conditions for occurrence of the Maillard reaction are (1) fairly low water content, (2) a pH of 7 to 10, and (3) a high temperature. Nevertheless, some reaction occurs under conditions far removed from these, but in the absence of moisture there is no reaction. The formation of an acyclic Schiff base as an initial step is not very likely, since replacement of the aldose by salicylaldehyde caused only a very small loss of amino groups. The second theory of the mechanism of the browning reaction is of recent origin and maintains that the browning reaction and the Maillard reaction are separate and distinct. Browning, according to this school of thought, is due to the effect of pH on the sugar and can occur over a wide range of pH, whereas the Maillard reaction proceeds only in alkaline media.

Description: Several types of abyssal bedforms have been discovered during surveys with a deeply towed instrument package at water depths of 1.5–6 km in the Pacific and Atlantic Oceans. Cores and current-meter records obtained at the same sites provide data for interpreting their dynamics. Wave and current ripples are best portrayed in bottom photographs, but medium-scale bedforms, including sand waves, mud waves and erosional furrows, are described by interpreting high-resolution side-looking sonar records. The largest examples affect surface-ship echograms, though their shape and structure can seldom be resolved without near-bottom observations. Wave ripples are common on the slopes of seamounts and ridges, while current ripples and sand waves occur beneath some fast thermohaline currents whose beds are shallower than the foraminiferal compensation depth. Depositional and erosional bedforms in cohesive sediment have been found beneath the deepest thermohaline currents; they may be restricted to areas where the flow is unusually steady in direction.

Description: Fourteen instances of whales entangled in submarine cables are reported. Ten entanglements occured off the Pacific coast of Central and South America. Six cases occured in about 500 fathoms, with 620 fathoms the maximum depth reported. Five entanglements occured in the period, Februray-March-April. All whales positively identified were sperm whales. The submarine cable was generally wrapped around jaw and often around the flukes and fins. The cable was rarely broken but always badly mauled. The entanglements often occured near former repairs where there is a chance for extra slack cable on the bottom. Two photographs of a sperm whale entangled in a cable and one photograph of a whale-jaw entangled in a cable are presented. It is concluded that sperm whales often swim alog the sea floor in depths as grat as 620 fathoms. It is suggested that the whales become entangled while swimming along with their jaw plowing through the sediment in search of food. It is possible that the whales attack tangled masses of slack cable mistaking them for items of food.

Description: Sedimentary iron and heavy-metal deposits of undetermined size have been found in the middle of the Red Sea some 2000 meters below the surface of the sea (Fig. 1). This discovery has been made from the Research Vessel Atlantis II, which is still at sea engaged in a series of oceanographic investigations which ultimately will end in November 1965, after the ship has circumnavigated the globe. The discovery is significant because the environment and the processes controlling deposition of heavy metals are observable and appear to be still active.