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  • 1
    Publication Date: 2024-06-17
    Description: We present undercooling (∆T) experiments aimed at investigating the effect of growth kinetics on the textural and compositional evolution of clinopyroxene crystals growing from a high-K basalt erupted during the 2003 paroxysm of Stromboli volcano (Italy). The experiments were performed at P = 350 MPa, T = 1050–1210 °C, H2Omelt = 0–3 wt%, and fO2 = Ni-NiO + 1.5 buffer. An initial stage of supersaturation was imposed to the melt under nominally anhydrous (∆Tanh = 10–150 °C) and hydrous (∆Thyd = 25–125 °C) conditions. Afterwards, this supersaturation state was mitigated by melt relaxation phenomena over an annealing time of 24 h. Results show that plagioclase is the liquidus mineral phase of the high-K basalt at ∆Tanh = 10 °C and dominates the phase assemblage as the degree of undercooling increases. Conversely, clinopyroxene and spinel co-saturate the melt at ∆Thyd = 25 °C, followed by the subordinate formation of plagioclase. At ∆Tanh/hyd ≤ 50 °C, the textural maturation of clinopyroxene produces polyhedral crystals with {−111} (hourglass) and {hk0} (prism) sectors typical of a layer-by-layer growth mechanism governed by an interface-controlled crystallization regime. At ∆Tanh/hyd ≥ 75 °C, the attainment of dendritic and skeletal morphologies testifies to the establishment of diffusion-limited reactions at the crystal-melt interface. 3D reconstructions of synchrotron radiation X-ray microtomographic data reveal a composite growth history for clinopyroxene crystals obtained at ∆Tanh/hyd ≥ 95 °C. The early stage of melt supersaturation produces rosette-like structures composed of dendritic branches of clinopyroxene radiating from a common spinel grain, which acts as surface for heterogeneous nucleation. As diffusive relaxation phenomena progress over the annealing time, the elongate dendrites that constitute the inner crystal domain are partially infilled by the melt and develop skeletal overgrowths in the outer domain. With the increasing degree of undercooling, TAl and M1Ti cations are progressively incorporated in the lattice site of clinopyroxene at the expense of TSi and M1Mg cations. Because of the effect of H2Omelt on the liquidus depression and melt depolymerization, crystals obtained at ∆Thyd are also more enriched in TAl and M1Ti and depleted in TSi and M1Mg than those growing at ∆Tanh. The emerging picture is that the morphological and geochemical evolution of clinopyroxene is mutually controlled by the combined effects of melt supersaturation and relaxation phenomena. A new empirical relationship based on the cation exchange reactions in the lattice site of clinopyroxene is finally proposed to estimate the degree of undercooling governing the crystallization of augitic phenocrysts erupted during normal and violent explosions at Stromboli.
    Description: Published
    Description: 107327
    Description: OSV2: Complessità dei processi vulcanici: approcci multidisciplinari e multiparametrici
    Description: JCR Journal
    Keywords: Clinopyroxene ; Undercooling ; Hourglass ; Crystallization ; Microtomography ; Stromboli ; Experimental Petrology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2023-03-02
    Description: This study analyses the morphological changes induced by eruptive activity at Stromboli volcano (Italy) during and after events occurring during July–August 2019. This period was characterized by intense eruptive activity (two paroxysmal explosions, a two-month-long lava emission, and more intense and frequent “ordinary” explosive activity) that produced significant changes within the region known as Sciara del Fuoco, located on the most unstable, north-western flank of the volcano. Since September 2019, the eruptive activity waned but remained intense, and erosive phenomena continued to contribute to the re-shaping of the Sciara del Fuoco. The morphological changes described here were documented by integrating topographic (PLÉIADES satellite tri-stereo Digital Elevation Models) and multibeam bathymetric data, acquired before, during, and after the paroxysmal events. This allowed the study of the cumulative effect of the different processes and the characterization of the different phases of accumulation/emplacement, erosion, remobilization and re-sedimentation of the volcaniclastic materials. Data acquired at several periods between September 2018 and April 2020, allowed a comparison of the subaerial and submarine effects of the 2019 events. We find evidence of localized, significant erosion following the two pyroclastic density currents triggered by the paroxysmal explosion of the 3 July 2019. We interpret this erosion as being caused by submarine and subaerial landslides triggered by the propagation of pyroclastic density currents down the Sciara del Fuoco slope. Immediately after the explosion, a lava field accumulated on the sub-aerial slope, produced by effusive activity which lasted about two months. Subsequently, the newly emplaced lava, and in particular its breccia, was eroded, with the transfer of material onto the submarine slope. This work demonstrates how repeated topo-bathymetric surveys allowed identification of the slope processes that were triggered in response to the rapid geomorphological variations due to the eruptive activity. The surveys also allowed distinction of whether estimated volumetric losses were the result of single mass-flows or gradual erosive processes, with implications on the related geohazard. Furthermore, this work highlights how submarine slope failures can be triggered by the entry into the water of pyroclastic density currents, even of modest size. These results are important for the development and improvement of an early warning system for tsunami-induced by mass flows, both in Stromboli and for island-based and coastal volcanoes elsewhere, where landslides and pyroclastic density currents can trigger significant, potentially destructive, tsunami waves.
    Description: Published
    Description: 108093
    Description: 5V. Processi eruttivi e post-eruttivi
    Description: JCR Journal
    Keywords: Digital Elevation Models ; PLÉIADES ; Repeated bathymetric surveys ; Volcano geomorphology ; Submarine morphology ; Stromboli ; Active volcano ; Aeolian Archipelago ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
    Publication Date: 2023-03-02
    Description: An innovative method of estimating the relative risk of buildings exposed to seismic and tsunami hazards in volcanic islands is applied to Stromboli (Italy), a well-known stratovolcano affected by moderate earthquakes and mass-flow-induced tsunamis. The method uses a pre-existing quali-quantitative analysis to assess the relative risk indices of buildings, which provide comparative results useful for prioritisation purposes, in combination with a historical-geographical settlement analysis consistent with the ‘territorialist’ approach to the urban and regional planning and design. The quali-quantitative analysis is based on a new proposed survey-sheet model, useful to collect building information necessary for the relative risk estimation, whereas the historical-geographical investigation is based on the multi-temporal comparison of aerial and satellite images. The proposal to combine two consolidated methods represents an innovation in estimating relative risk. Considering that Stromboli Island had never been subjected to similar analyses, the results of the relative seismic risk assessment are novel and moreover identify buildings with a fairly-low and spatially-uniform relative risk. The results of the relative tsunami risk assessment are consistent with results of similar past studies, identifying buildings with a higher relative risk index on the northern coast of the island. The combined use of a building-by-building survey with a multi-temporal analysis of settlements allows obtaining a higher detail than previously available for the region. If adequately modified, the proposed combination of methods allows assessing relative risk also considering other geo-environmental hazards and their cascading effects, in a multi-hazard risk assessment perspective.
    Description: Published
    Description: 103002
    Description: 6V. Pericolosità vulcanica e contributi alla stima del rischio
    Description: JCR Journal
    Keywords: Relative risk assessment ; Seismic risk ; Tsunami risk ; Volcanic islands ; Stromboli ; Aeolian archipelago ; 05.08. Risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 4
    Publication Date: 2019-03-26
    Description: The examples of geochemical monitoring results provided in this review article show the close relationships among data analysis, interpretation, and modeling. We particularly focus on describing the fieldwork procedures, since any theoretical approach must always be verified and supported by field data, rather than just by experiments controlled in laboratory.
    Description: Fluids discharged from volcanic systems are the direct surface manifestation of magma degassing at depth and provide primary insights for evaluating the state of volcanic activity. We review the geochemical best practice in volcanic surveillance based to a huge amount of monitoring data collected at different active volcanoes using both continuous and discontinuous approaches. The targeted volcanoes belong to the Aeolian Arc located in the Tyrrhenian Sea (Italy), and they have exhibited different activity states during the monitoring activities reported here. La Fossa cone on Vulcano Island has been in an uninterrupted quiescent stage characterized by variable solfataric activity. In contrast, Stromboli Island has shown a persistent mild explosive activity, episodically interrupted by effusive eruptions (in 1985, 2002, 2007, and 2014). Panarea Island, which is the summit of a seamount rising from the seafloor of the southern Tyrrhenian Sea, showed only undersea fluid release. The only observable clues of active volcanism at Panarea Island have been impulsive changes in the undersea fluid release, with the last submarine gas burst event being observed in November 2002. The geochemical monitoring and observations at each of these volcanoes has directly involved the volcanic plume and/or the fumarole vents, thermal waters, and diffuse soil degassing, depending on the type of manifestations and the level of activity encountered. Through direct access to the magmatic samples (when possible) and the collection of as much observable data related to the fluid release as possible, the aim has been (i) to verify the thermodynamic equilibrium condition, (ii) to discern among the possible hydrothermal, magmatic, marine, and meteoric sources in the fluid mixtures, (iii) to develop models of the fluid circulation supported by data, (iv) to follow the evolution of these natural systems by long-term monitoring, and (v) to support surveillance actions related to defining the volcanic risk and the evaluation and possible mitigation of related hazards. The examples provided in this review article show the close relationships among data analysis, interpretation, and modeling. We particularly focus on describing the fieldwork procedures, since any theoretical approach must always be verified and supported by field data, rather than just by experiments controlled in laboratory. Indeed the natural systems involve many variables producing effects that cannot be neglected. The monitored volcanic systems have been regarded as natural laboratories, and all of the activities have focused on both volcanological research and surveillance purposes in order to ensure that these two goals have overlapped. An appendix is also included that explains the scientific approach to the systematic activities, regarding geochemical monitoring of volcanic activity.
    Description: Published
    Description: 241-276
    Description: 4V. Processi pre-eruttivi
    Description: JCR Journal
    Keywords: geochemical methodologies ; Vulcano ; Stromboli ; Panarea ; Geochemical Monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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