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  • 1
    Publication Date: 2024-06-17
    Description: We present undercooling (∆T) experiments aimed at investigating the effect of growth kinetics on the textural and compositional evolution of clinopyroxene crystals growing from a high-K basalt erupted during the 2003 paroxysm of Stromboli volcano (Italy). The experiments were performed at P = 350 MPa, T = 1050–1210 °C, H2Omelt = 0–3 wt%, and fO2 = Ni-NiO + 1.5 buffer. An initial stage of supersaturation was imposed to the melt under nominally anhydrous (∆Tanh = 10–150 °C) and hydrous (∆Thyd = 25–125 °C) conditions. Afterwards, this supersaturation state was mitigated by melt relaxation phenomena over an annealing time of 24 h. Results show that plagioclase is the liquidus mineral phase of the high-K basalt at ∆Tanh = 10 °C and dominates the phase assemblage as the degree of undercooling increases. Conversely, clinopyroxene and spinel co-saturate the melt at ∆Thyd = 25 °C, followed by the subordinate formation of plagioclase. At ∆Tanh/hyd ≤ 50 °C, the textural maturation of clinopyroxene produces polyhedral crystals with {−111} (hourglass) and {hk0} (prism) sectors typical of a layer-by-layer growth mechanism governed by an interface-controlled crystallization regime. At ∆Tanh/hyd ≥ 75 °C, the attainment of dendritic and skeletal morphologies testifies to the establishment of diffusion-limited reactions at the crystal-melt interface. 3D reconstructions of synchrotron radiation X-ray microtomographic data reveal a composite growth history for clinopyroxene crystals obtained at ∆Tanh/hyd ≥ 95 °C. The early stage of melt supersaturation produces rosette-like structures composed of dendritic branches of clinopyroxene radiating from a common spinel grain, which acts as surface for heterogeneous nucleation. As diffusive relaxation phenomena progress over the annealing time, the elongate dendrites that constitute the inner crystal domain are partially infilled by the melt and develop skeletal overgrowths in the outer domain. With the increasing degree of undercooling, TAl and M1Ti cations are progressively incorporated in the lattice site of clinopyroxene at the expense of TSi and M1Mg cations. Because of the effect of H2Omelt on the liquidus depression and melt depolymerization, crystals obtained at ∆Thyd are also more enriched in TAl and M1Ti and depleted in TSi and M1Mg than those growing at ∆Tanh. The emerging picture is that the morphological and geochemical evolution of clinopyroxene is mutually controlled by the combined effects of melt supersaturation and relaxation phenomena. A new empirical relationship based on the cation exchange reactions in the lattice site of clinopyroxene is finally proposed to estimate the degree of undercooling governing the crystallization of augitic phenocrysts erupted during normal and violent explosions at Stromboli.
    Description: Published
    Description: 107327
    Description: OSV2: Complessità dei processi vulcanici: approcci multidisciplinari e multiparametrici
    Description: JCR Journal
    Keywords: Clinopyroxene ; Undercooling ; Hourglass ; Crystallization ; Microtomography ; Stromboli ; Experimental Petrology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
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    Elsevier
    In:  Comment to “Shallow portion of an active geothermal system revealed by multidisciplinary studies: The case of Le Biancane (Larderello, Italy)” by Granieri D., Mazzarini F., Cerminara M., Calusi B., Scozzari A., Menichini M., and Lelli M. (2023) Luca Bolognesi Geothermics 113 (2023) 102753 https://doi.org/10.1016/j.geothermics.2023.102753
    Publication Date: 2024-04-09
    Description: Reply to the comment by Luca Bolognesi
    Description: Reply to the comment by Luca Bolognesi
    Description: Published
    Description: 102754
    Description: OSA5: Energia e georisorse
    Description: JCR Journal
    Keywords: 04. Solid Earth
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
    Publication Date: 2024-04-09
    Description: The natural park of Le Biancane is located in the southern sector of the Larderello-Travale geothermal field (LTGF). It extends over an approximately 100,000 m2 area where the impermeable caprock is locally absent and deep fluids may directly reach the surface. Through a multidisciplinary approach including measurements of soil CO2 flux (total output of 11.5 t day􀀀 1), soil temperature (average 34.4 ◦C), stable isotope and chemical data on fluids from fumaroles (dominated by a mixture of geothermal gases and air or gases from air-saturated meteoric water), and structural analysis of the formation outcropping, we found that anomalous CO2 emissions are positively correlated with shallow temperature anomalies. These are in restricted locations adjacent to vents and fumaroles, where a network of well-connected fractures (preferentially NW-SE and NE-SW orientated and with steep dips) drains efficiently allowing upward migration of the deep fluids and the energy toward the surface.
    Description: INGV Project RL 2021 - AGEREMUS
    Description: Published
    Description: 102616
    Description: OSA5: Energia e georisorse
    Description: JCR Journal
    Keywords: Larderello geothermal field ; Fracture network connectivity ; Diffuse CO2 soil degassing ; Thermal infrared images ; Hydrothermal gas ; 04. Solid Earth
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 4
    Publication Date: 2023-11-21
    Description: Highlights -He isotopic R/Ra of emitted gas decreases moving away from Albani Hills volcano -Total soil flux of endogenous CO2 at Lavinio-Tor Caldara is estimated to 20 ton/day -Tor Caldara gas has the highest H2S content (up to 6.3 vol.%) of central Italy -Repetition of soil CO2 flux survey shows that flux increases during earthquakes -Gas air concentration monitoring shows that H2S is the killer gas of small animals
    Description: Gas hazard was evaluated at Lavinio-Tor Caldara, the southernmost gas-discharging zone of the quiescent Albani Hills volcano in central Italy. Also this zone, like the other gas discharges of this volcanic complex, is located above a structural high of the buried Mesozoic carbonate basement, which represents the main reservoir for gas rising from depth. All extensional faults affecting the carbonates are leaking pathways along which gas may rise to the surface creating hazardous conditions. Gas is dominated by CO2 (〉90 vol.%) and the second component at Lavinio-Tor Caldara is H2S that displays the highest content (4.0-6.3 vol.%) of all gas manifestations of the Rome region. This H2S enrichment corresponds to a marked decrease in 3He/4He (R/Ra) isotopic ratio suggesting that gas was contaminated in an upper crustal environment. The main gas discharge occurs at the natural reserve of Tor Caldara, in zones where past sulphur mining excavations removed the surficial impervious cover, or along a ditch. Comparison of the results of four soil CO2 flux surveys carried out in 2005-2018 at Miniera Grande within Tor Caldara, indicates that the highest soil CO2 release occurs shortly after local earthquakes. Continuous monitoring of CO2 and H2S air concentration and of wind speed has been carried out for four months in twelve anomalous gas realising sites of Tor Caldara. Results indicate that only H2S reaches lethal concentration (〉250 ppm) near the soil in no wind nights, explaining the presence of small dead animals. At Lavinio, the main soil gas release occurs near old water wells that likely produced a gas blowout during drilling. A total release of over 20 tons/day from 2.93 km2 of gas of endogenous origin, has been estimated for the Lavinio-Tor Caldara area by a detailed soil CO2 flux survey (2,572 measurement points over an area of 3.65 km2). The main structural lineaments of the area have N-S and W-E directions, but also NE-SW and NW-SE directions are well represented. Some sectors of the investigated area are exposed to a severe gas hazard for people and animals and precautionary measures should be adopted.
    Description: Published
    Description: 106985
    Description: 6V. Pericolosità vulcanica e contributi alla stima del rischio
    Description: JCR Journal
    Keywords: •Lavinio-Tor Caldara, southern periphery of Albani Hills volcano ; •He isotopic R/Ra values ; •Soil CO2 flux surveys ; •CO2 and H2S air concentration monitoring ; •Gas chemistry ; •Gas hazard assessment ; 04. Solid Earth
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 5
    Publication Date: 2023-11-21
    Description: This study presents a detailed analysis of minor seismic sequences recorded in the Amatrice-Norcia area (central Italy) before 2016 when the most important seismic sequence of the last 40 years struck the region with the Mw 6.0 Amatrice and the Mw 6.5 Norcia earthquakes. We observe that, in the four decades before the 2016–2018 Amatrice-Visso-Norcia sequence, the instrumental seismicity rate is low, with maximum magnitudes lower than Mw 4.0, and is characterized by different types of behaviours as single shock events, swarms and minor se- quences. For the first time, we relocate the minor seismicity recorded before 2016 by the Italian National Seismic Network of the Istituto Nazionale di Geofisica e Vulcanologia by applying the nonlinear inversion code Non- LinLoc in a local velocity model. Revised earthquake locations of the past seismic sequences are compared to the recent 2016–2018 seismicity in order to investigate some possible correlations with the seismogenic structures reactivated in 2016. With this goal, we also integrated our new hypocentral locations with fault plane solutions and geological data to interpret our results with respect to the 2016–2018 seismicity. Our results show how some of the structures identified by the minor seismicity before 2016 were reactivated during the recent sequence, while others seismic structures remained silent. We therefore highlight how the study of minor seismic sequences provides important information about the seismogenic attitude of less active or less known seismogenic struc- tures with consequent impact on the evaluation of the seismic hazard.
    Description: Published
    Description: 228858
    Description: 4T. Sismicità dell'Italia
    Description: JCR Journal
    Keywords: 04.07. Tectonophysics ; 04. Solid Earth
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 6
    Publication Date: 2023-03-15
    Description: The exploitation of a geothermal field can be accompanied by both natural and induced seismicity. Hence the installation of a seismic network suitable for locating also low magnitude earthquakes is of great interest for geothermal development, especially for monitoring the activity related to the injection or production. Here we propose an improvement of the D-OPTIMAL algorithm (Tramelli et al., 2013) that tries and find optimal station positions minimizing the volume of the error ellipsoid of the event location using the D-criterion. In this version, we introduced the possibility to account for several prior information that is generally available when instrumenting a monitoring site permanently or temporarily. The a priori parameters introduced are: i) three-dimensional seismic velocity models, ii) seismic noise levels, iii) topographic gradient, and iv) H/V ratio values. The last three parameters are introduced in the station position 24 selection using aweighting system. We applied the methodology to the Acoculco geothermal field (Mexico) where an injection test was planned and executed in 2021. The comparison between the network defined usingthe standard approach and this updated version shows the importance of introducing a prioriinformation during the selection of the network. Installation sites resulted better distributed on the region, resulting in an overall increase of the sensitivity, and in a decreasing of the error location estimation in the target region. The methodology presented here is easy to apply to other study cases such as active volcanoes, anthropogenic activities, or whatever other study at local scale.
    Description: Published
    Description: 103995
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: JCR Journal
    Keywords: Network optimization ; Geothermal areas ; 04. Solid Earth
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 7
    Publication Date: 2023-03-02
    Description: This study analyses the morphological changes induced by eruptive activity at Stromboli volcano (Italy) during and after events occurring during July–August 2019. This period was characterized by intense eruptive activity (two paroxysmal explosions, a two-month-long lava emission, and more intense and frequent “ordinary” explosive activity) that produced significant changes within the region known as Sciara del Fuoco, located on the most unstable, north-western flank of the volcano. Since September 2019, the eruptive activity waned but remained intense, and erosive phenomena continued to contribute to the re-shaping of the Sciara del Fuoco. The morphological changes described here were documented by integrating topographic (PLÉIADES satellite tri-stereo Digital Elevation Models) and multibeam bathymetric data, acquired before, during, and after the paroxysmal events. This allowed the study of the cumulative effect of the different processes and the characterization of the different phases of accumulation/emplacement, erosion, remobilization and re-sedimentation of the volcaniclastic materials. Data acquired at several periods between September 2018 and April 2020, allowed a comparison of the subaerial and submarine effects of the 2019 events. We find evidence of localized, significant erosion following the two pyroclastic density currents triggered by the paroxysmal explosion of the 3 July 2019. We interpret this erosion as being caused by submarine and subaerial landslides triggered by the propagation of pyroclastic density currents down the Sciara del Fuoco slope. Immediately after the explosion, a lava field accumulated on the sub-aerial slope, produced by effusive activity which lasted about two months. Subsequently, the newly emplaced lava, and in particular its breccia, was eroded, with the transfer of material onto the submarine slope. This work demonstrates how repeated topo-bathymetric surveys allowed identification of the slope processes that were triggered in response to the rapid geomorphological variations due to the eruptive activity. The surveys also allowed distinction of whether estimated volumetric losses were the result of single mass-flows or gradual erosive processes, with implications on the related geohazard. Furthermore, this work highlights how submarine slope failures can be triggered by the entry into the water of pyroclastic density currents, even of modest size. These results are important for the development and improvement of an early warning system for tsunami-induced by mass flows, both in Stromboli and for island-based and coastal volcanoes elsewhere, where landslides and pyroclastic density currents can trigger significant, potentially destructive, tsunami waves.
    Description: Published
    Description: 108093
    Description: 5V. Processi eruttivi e post-eruttivi
    Description: JCR Journal
    Keywords: Digital Elevation Models ; PLÉIADES ; Repeated bathymetric surveys ; Volcano geomorphology ; Submarine morphology ; Stromboli ; Active volcano ; Aeolian Archipelago ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 8
    Publication Date: 2023-03-02
    Description: An innovative method of estimating the relative risk of buildings exposed to seismic and tsunami hazards in volcanic islands is applied to Stromboli (Italy), a well-known stratovolcano affected by moderate earthquakes and mass-flow-induced tsunamis. The method uses a pre-existing quali-quantitative analysis to assess the relative risk indices of buildings, which provide comparative results useful for prioritisation purposes, in combination with a historical-geographical settlement analysis consistent with the ‘territorialist’ approach to the urban and regional planning and design. The quali-quantitative analysis is based on a new proposed survey-sheet model, useful to collect building information necessary for the relative risk estimation, whereas the historical-geographical investigation is based on the multi-temporal comparison of aerial and satellite images. The proposal to combine two consolidated methods represents an innovation in estimating relative risk. Considering that Stromboli Island had never been subjected to similar analyses, the results of the relative seismic risk assessment are novel and moreover identify buildings with a fairly-low and spatially-uniform relative risk. The results of the relative tsunami risk assessment are consistent with results of similar past studies, identifying buildings with a higher relative risk index on the northern coast of the island. The combined use of a building-by-building survey with a multi-temporal analysis of settlements allows obtaining a higher detail than previously available for the region. If adequately modified, the proposed combination of methods allows assessing relative risk also considering other geo-environmental hazards and their cascading effects, in a multi-hazard risk assessment perspective.
    Description: Published
    Description: 103002
    Description: 6V. Pericolosità vulcanica e contributi alla stima del rischio
    Description: JCR Journal
    Keywords: Relative risk assessment ; Seismic risk ; Tsunami risk ; Volcanic islands ; Stromboli ; Aeolian archipelago ; 05.08. Risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 9
    Publication Date: 2023-02-07
    Description: Fault zone architecture and its internal structural variability play a pivotal role in earthquake mechanics, by controlling, for instance, the nucleation, propagation and arrest of individual seismic ruptures and the evolution in space and time of foreshock and aftershock seismic sequences. Nevertheless, the along-strike architectural variability of crustal-scale seismogenic sources over regional distances is still poorly investigated. Here, we describe the architectural variability of the 〉40-km-long exhumed, seismogenic Bolfin Fault Zone (BFZ) of the intra-arc Atacama Fault System (Northern Chile). The BFZ cuts through plutonic rocks of the Mesozoic Coastal Cordillera and was seismically active at 5–7 km depth and ≤ 300 °C in a fluid-rich environment. The BFZ includes multiple altered fault core strands, consisting of chlorite-rich cataclasites-ultracataclasites and pseudotachylytes, surrounded by chlorite-rich protobreccias to protocataclasites over a zone up to 60-m-thick. These fault rocks are embedded within a low-strain damage zone, up to 150-m-thick, which includes strongly altered volumes of dilatational hydrothermal breccias and clusters of epidote-rich fault-vein networks at the linkage of the BFZ with subsidiary faults. The strong hydrothermal alteration of rocks along both the fault core and the damage zone attests to an extensive percolation of fluids across all the elements of the structural network during the activity of the entire fault zone. In particular, we interpret the epidote-rich fault-vein networks and associated breccias as an exhumed example of upper-crustal fluid-driven earthquake swarms, similar to the presently active intra-arc Liquiñe-Ofqui Fault System (Southern Andean Volcanic Zone, Chile).
    Description: European Research Council Consolidator Grant Project (NOFEAR) No 614705
    Description: Published
    Description: 104745
    Description: 3T. Fisica dei terremoti e Sorgente Sismica
    Description: JCR Journal
    Keywords: Atacama fault system ; Earthquakes ; Fault structure ; Fault zone rocks ; Fluid-driven seismicity ; Seismogenic faults ; 04. Solid Earth
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 10
    Publication Date: 2023-01-27
    Description: Seismic coupling helps define how large the earthquake potential of a region is, as well as the presence of asperities along plate zones. This work seeks to provide an improved picture of the seismic coupling for the Aegean-Anatolian region by taking advantage of extensive seismic and geodetic datasets. To estimate coupling, we compiled a series of by-products that are specific ingredients also for seismic hazard studies. With these by-products, we found that the seismogenic thickness is thinner (10–15 km) or thicker (20 to 30 km) to the east and to the west, respectively and even deeper along the Hellenic subduction zone. The b-value ranges between 0.9 and 1.1 for the entire area with high values concentrated at locations of Late Miocene to -recent volcanism whereas low b-values (〈0.8) concentrate along most of the Northern Anatolian fault zone that may suggests stress accumulation. Seismic coupling is low (〈35%) or intermediate (35% - 70%) in most of the area, while the Karliova triple junction, on a N-S-oriented belt along the boundary between western and central Anatolia, and the southeastern Peloponnese are fully coupled, suggesting a full seismic release of the entire deformation budget. An intermediate value of seismic coupling is observed for the eastern and central segments of the Northern and Eastern Anatolian Fault zones, for part of the Hellenic volcanic arc, the Kefalonia Transform Fault and the Corinth gulf active faults. Considering historical earthquake data, these intermediate coupling values indicate either aseismic deformation or catalog incompleteness. Furthermore, the time period since large magnitude earthquakes clearly raises the possibility of impending earthquakes on the Northern and Eastern Anatolian Fault zones. A broad seismic gap is evidenced along the Hellenic subduction zone, because of the reduced coupling and the absence of ~M8 earthquakes in the last 700 years, at least. We conclude that in most of the central Aegean Sea aseismic deformation prevails as suggested by the small value of coupling and the modest seismic release over the last millennium.
    Description: Published
    Description: 103993
    Description: 2T. Deformazione crostale attiva
    Description: JCR Journal
    Keywords: GNSS ; crustal deformation ; seismic coupling ; b-value ; 04. Solid Earth
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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