ALBERT

Description: Gravitational sinking of photosynthetically fixed particulate organic carbon (POC) constitutes a key component of the biological carbon pump. The fraction of POC leaving the surface ocean depends on POC sinking velocity (SV) and remineralization rate (Cremin), both of which depend on plankton community structure. However, the key drivers in plankton communities controlling SV and Cremin are poorly constrained. In fall 2014, we conducted a 6 weeks mesocosm experiment in the subtropical NE Atlantic Ocean to study the influence of plankton community structure on SV and Cremin. Oligotrophic conditions prevailed for the first 3 weeks, until nutrient‐rich deep water injected into all mesocosms stimulated diatom blooms. SV declined steadily over the course of the experiment due to decreasing CaCO3 ballast and – according to an optical proxy proposed herein – due to increasing aggregate porosity mostly during an aggregation event after the diatom bloom. Furthermore, SV was positively correlated with the contribution of picophytoplankton to the total phytoplankton biomass. Cremin was highest during a Synechococcus bloom under oligotrophic conditions and in some mesocosms during the diatom bloom after the deep‐water addition while it was particularly low during harmful algal blooms. The temporal changes were considerably larger in Cremin (max. 15‐fold) than in SV (max. 3‐fold). Accordingly, estimated POC transfer efficiency to 1000 m was mainly dependent on how the plankton community structure affected Cremin. Our approach revealed key players and interactions in the plankton food web influencing POC export efficiency thereby improving our mechanistic understanding of the biological carbon pump.

Description: Most permafrost is located in the Arctic, where frozen organic carbon makes it an important component of the global climate system. Despite the fact that the Arctic climate changes more rapidly than the rest of the globe, observational data density in the region is low. Permafrost thaw and carbon release to the atmosphere are a positive feedback mechanism that can exacerbate climate warming. This positive feedback functions via changing land-atmosphere energy and mass exchanges. There is thus a great need to understand links between the energy balance, which can vary rapidly over hourly to annual time scales, and permafrost, which changes slowly over long time periods. This understanding thus mandates long-term observational data sets. Such a data set is available from the Bayelva Site at Ny-Ålesund, Svalbard, where meteorology, energy balance components and subsurface observations have been made for the last 20 years. Additional data include a high resolution digital elevation model and a panchromatic image. This paper presents the data set produced so far, explains instrumentation, calibration, processing and data quality control, as well as the sources for various resulting data sets. The resulting data set is unique in the Arctic and serves a baseline for future studies. Since the data provide observations of temporally variable parameters that mitigate energy fluxes between permafrost and atmosphere, such as snow depth and soil moisture content, they are suitable for use in integrating, calibrating and testing permafrost as a component in Earth System Models. The data set also includes a high resolution digital elevation model that can be used together with the snow physical information for snow pack modeling.

Description: The Surface Ocean CO2 Atlas (SOCAT) is a synthesis activity by the international marine carbon research community (〉100 contributors). SOCATv2019 has 25.7 million quality-controlled, surface ocean fCO2 (fugacity of carbon dioxide) observations from 1957 to 2019 for the global oceans and coastal seas. Calibrated sensor data are also available. Automation allows annual, public releases. SOCAT data is discoverable, accessible and citable. SOCAT enables quantification of the ocean carbon sink and ocean acidification and evaluation of ocean biogeochemical models. SOCAT represents a milestone in biogeochemical and climate research and in informing policy. This publication contains the individual cruise files that are new or updated from SOCATv6, with cruise QC flags A-E and all fCO2 WOCE flags. The synthesis file hosted in NOAA NCEI (see other version) contains A-D cruises and WOCE flag 2 (good) data. To download the SOCATv2019 data product in other formats or subsets, please go to www.socat.info.

Description: As a natural sediment trap, marine sediments of the sheltered central part of the Maldives Inner Sea represent an exceptional archive for paleoenvironmental and climate changes of the equatorial Indian Ocean. To evaluate the complex interplay between high-latitude and monsoonal climate variability, related dust fluxes, and regional oceanographic responses, we focused on Fe/Al, Ti/Al and Si/Ca ratios as proxies for terrigenous sediment delivery, and total organic carbon (TOC) and Br XRF counts as proxies for marine productivity. Benthic foraminiferal fauna distributions, grain size, and stable d18O and d13C data were used for evaluating changes in the benthic ecosystem, as well as changes in the intermediate water circulation, bottom water current velocity and oxygenation. Our multi-proxy data record reveals an enhanced dust supply during the glacial intervals, causing elevated Fe/Al and Si/Ca ratios, an overall coarsening of the sediment and an increasing amount of agglutinated benthic foraminifera. The enhanced dust fluxes can be attributed to higher dust availability in the Asian desert and loess areas and its transport by intensified winter monsoon winds during glacial conditions. These combined effects of wind-induced mixing of surface waters and dust fertilisation during the cold phases resulted in an increased surface-water productivity and related organic carbon fluxes. Thus, the development of highly diverse benthic foraminiferal faunas with certain detritus and suspension feeders were fostered. The difference in the d13C signal between epifaunal and deep infaunal benthic foraminifera reveals intermediate water oxygen concentrations between approximately 40 and 100 µmol kg-1 during this time. The precessional fluctuation pattern of oxygen changes resembles that from the deep Arabian Sea, suggesting an expansion of the Oxygen Minimum Zone (OMZ) from the Arabian Sea into the tropical Indian Ocean with a probable regional signal of strengthened winter-monsoon-induced organic matter fluxes and oxygen consumption, and further controlled by the varying inflow intensity of the Antarctic Intermediate Water (AAIW). In addition, the bottom water oxygenation pattern of the Maldives Inner Sea reveals a long phase of reduced ventilation during the last glacial period. This process is likely linked to the combined effects of generally enhanced oxygen consumption rates during high-productivity phases, reduced AAIW production, and the restriction of upper bathyal environments of the Inner Sea during sea-level lowstands. Thus, our multi-proxy record reflects a close linkage between the Indian monsoon oscillation, intermediate water circulation, productivity and sea-level changes on orbital time-scale.

Description: The Labrador Sea is important for the modern global thermohaline circulation system through the formation of intermediate Labrador Sea Water (LSW) that has been hypothesized to stabilize the modern mode of North Atlantic deep-water circulation. The rate of LSW formation is controlled by the amount of winter heat loss to the atmosphere, the expanse of freshwater in the convection region and the inflow of saline waters from the Atlantic. The Labrador Sea, today, receives freshwater through the East and West Greenland Currents (EGC, WGC) and the Labrador Current (LC). Several studies have suggested the WGC to be the main supplier of freshwater to the Labrador Sea, but the role of the southward flowing LC in Labrador Sea convection is still debated. At the same time, many paleoceanographic reconstructions from the Labrador Shelf focussed on late Deglacial to early Holocene meltwater run-off from the Laurentide Ice Sheet (LIS), whereas little information exists about LC variability since the final melting of the LIS about 7,000 years ago. In order to enable better assessment of the role of the LC in deep-water formation and its importance for Holocene climate variability in Atlantic Canada, this study presents high-resolution middle to late Holocene records of sea surface and bottom water temperatures, freshening and sea ice cover on the Labrador Shelf during the last 6,000 years. Our records reveal that the LC underwent three major oceanographic phases from the Mid- to Late Holocene. From 6.2 to 5.6 ka BP, the LC experienced a cold episode that was followed by warmer conditions between 5.6 and 2.1 ka BP, possibly associated with the late Holocene Thermal Maximum. Although surface waters on the Labrador Shelf cooled gradually after 3 ka BP in response to the Neoglaciation, Labrador Shelf subsurface/bottom waters show a shift to warmer temperatures after 2.1 ka BP. Although such an inverse stratification by cooling of surface and warming of subsurface waters on the Labrador Shelf would suggest a diminished convection during the last two millennia compared to the mid-Holocene, it remains difficult to assess whether hydrographic conditions in the LC have had a significant impact on Labrador Sea deep-water formation.

Description: We analysed: 1. TOC and CNS contents on sediment core PS69/274-1 and calculated the C/N-ratio and carbonate content of the individual sample depths. 2. a specific biomarker lipid called IPSO25 in sediment core PS69/274-1 from the western Amundsen Sea continental shelf, Antarctica, alongside a phytoplankton biomarker (dinosterol) for reconstructing palaeo-sea ice coverage. We further applied the PIPSO25 approach for semi-quantitative sea ice reconstructions. We analysed a specific biomarker lipid called IPSO25 in sediment core PS69/274-1 from the western Amundsen Sea continental shelf, Antarctica, alongside a phytoplankton biomarker (dinosterol) for reconstructing palaeo sea-ice coverage. We further applied the PIPSO25 approach for semi-quantitative sea-ice reconstructions.

Description: The Indian Monsoon and the westerlies strongly influence the sedimentation in the northeastern Arabian Sea by impacting rainfall and erosion on land and on biogeochemical processes in the ocean. To disentangle the terrestrial and oceanic processes, we analysed mineralogical and bulk geochemical components of a Holocene sediment core offshore Pakistan. Endmember modelling of grain sizes and principal component analyses (PCA) of major and trace elements identify the origin of sediments and their dominant mode of transport. Sedimentation processes during the early Holocene (10.8–8.2 ka BP) were influenced by the post-glacial sea level rise and orbitally forced strengthening of the Indian summer monsoon (ISM) and westerlies. This led to a shift from rather terrestrial-dominated towards a marine-dominated sedimentation, whereas the fluvial source shifted from the Makran rivers to the Hab River near Karachi. During the mid-Holocene (8.2–4.2 ka BP) a combination of weakening ISM and southward displacement of the ITCZ enhanced the influence of the westerlies, together decreasing river discharges and enhancing aeolian input (probably from the Sistan Basin region). This trend continued during the last ca. 4 ka when the increasing aridification of the Hab River catchment further increased the aeolian inputs. Solar and lunar driven short-term variations as well as Bond events known from the North Atlantic Ocean superpose these trends. They lead to a pronounced increase of fluvial inputs between 8.6–8.4 ka BP and at ca. 3 ka BP as well as to dry events around 4.2 ka and 1.2–1 ka BP. Our study highlights the increasing influence of the westerlies on the sedimentation processes in the northeastern Arabian Sea towards the late Holocene.

Description: The Benguela Upwelling System (BUS) is the most productive of all eastern boundary upwelling ecosystems and it hosts a well-developed oxygen minimum zone. As such, the BUS is a potential hotspot for production of N2O, a potent greenhouse gas derived from microbially driven decay of sinking organic matter. Yet, the extent at which near-surface waters emit N2O to the atmosphere in the BUS is highly uncertain. Here we present the first high-resolution surface measurements of N2O across the northern part of the BUS (nBUS).We found strong gradients with a threefold increase in N2O concentrations near the coast as compared with open ocean waters. Our observations show enhanced sea-to-air fluxes of N2O (up to 1.67 nmol m−2 s−1) in association with local upwelling cells. Based on our data we suggest that the nBUS can account for 13% of the total coastal upwelling source of N2O to the atmosphere