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  • Articles  (15,126)
  • Springer  (11,462)
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  • 2015-2019
  • 1990-1994  (15,126)
  • 1945-1949
  • 1994  (15,126)
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  • Articles  (15,126)
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  • 1
    Electronic Resource
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    Springer
    Mathematical programming 63 (1994), S. 109-125 
    ISSN: 1436-4646
    Keywords: Alternative theorems ; quasidifferentiable programming ; nonsmooth analysis ; optimality conditions ; difference convex programming
    Source: Springer Online Journal Archives 1860-2000
    Topics: Computer Science , Mathematics
    Notes: Abstract A new generalized Farkas theorem of the alternative is presented for systems involving functions which can be expressed as the difference of sublinear functions. Various other forms of theorems of the alternative are also given using quasidifferential calculus. Comprehensive optimality conditions are then developed for broad classes of infinite dimensional quasidifferentiable programming problems. Applications to difference convex programming and infinitely constrained concave minimization problems are also discussed.
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  • 2
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    Mathematical programming 63 (1994), S. 83-108 
    ISSN: 1436-4646
    Keywords: Convex programming ; deep cut ellipsoid algorithm ; rate of convergence ; location theory ; min—max programming
    Source: Springer Online Journal Archives 1860-2000
    Topics: Computer Science , Mathematics
    Notes: Abstract This paper proposes a deep cut version of the ellipsoid algorithm for solving a general class of continuous convex programming problems. In each step the algorithm does not require more computational effort to construct these deep cuts than its corresponding central cut version. Rules that prevent some of the numerical instabilities and theoretical drawbacks usually associated with the algorithm are also provided. Moreover, for a large class of convex programs a simple proof of its rate of convergence is given and the relation with previously known results is discussed. Finally some computational results of the deep and central cut version of the algorithm applied to a min—max stochastic queue location problem are reported.
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  • 3
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    Mathematical programming 63 (1994), S. 157-182 
    ISSN: 1436-4646
    Keywords: Steiner tree ; series—parallel graphs ; polyhedral characterization ; projection ; facets ; formulations
    Source: Springer Online Journal Archives 1860-2000
    Topics: Computer Science , Mathematics
    Notes: Abstract We consider the vertex-weighted version of the undirected Steiner tree problem. In this problem, a cost is incurred both for the vertices and the edges present in the Steiner tree. We completely describe the associated polytope by linear inequalities when the underlying graph is series—parallel. For general graphs, this formulation can be interpreted as a (partial) extended formulation for the Steiner tree problem. By projecting this formulation, we obtain some very large classes of facet-defining valid inequalities for the Steiner tree polytope.
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  • 4
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    Mathematical programming 63 (1994), S. 213-234 
    ISSN: 1436-4646
    Keywords: Max-flow problem ; min-cut problem ; duality gap
    Source: Springer Online Journal Archives 1860-2000
    Topics: Computer Science , Mathematics
    Notes: Abstract Strang (Mathematical Programming 26, 1983) gave a method to establish a max-flow min-cut theorem in a domain of a Euclidean space. The method can be applied also to max-flow min-cut problems defined by Iri (Survey of Mathematical Programming, North-Holland, 1979) whenever the capacity functions of max-flow problems are bounded and continuous. This paper deals with max-flow min-cut problems of Strang and Iri with unbounded or noncontinuous capacity functions. It is proved that, in such problems, max-flow min-cut theorems may fail to hold.
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  • 5
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    Mathematical programming 66 (1994), S. 273-281 
    ISSN: 1436-4646
    Keywords: Minimal test sets for integer programming ; Simplicial complexes ; Maximal lattice free bodies
    Source: Springer Online Journal Archives 1860-2000
    Topics: Computer Science , Mathematics
    Notes: Abstract The simplicial complexK(A) is defined to be the collection of simplices, and their proper subsimplices, representing maximal lattice free bodies of the form (x: Ax⩽b), withA a fixed generic (n + 1) ×n matrix. The topological space associated withK(A) is shown to be homeomorphic to ℝ n , and the space obtained by identifying lattice translates of these simplices is homeorphic to then-torus.
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  • 6
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    Mathematical programming 66 (1994), S. 313-325 
    ISSN: 1436-4646
    Keywords: Network ; Multicommodity flow ; Minimum cost flow ; Edge-disjoint paths
    Source: Springer Online Journal Archives 1860-2000
    Topics: Computer Science , Mathematics
    Notes: Abstract LetN = (G, T, c, a) be a network, whereG is an undirected graph,T is a distinguished subset of its vertices (calledterminals), and each edgee ofG has nonnegative integer-valuedcapacity c(e) andcost a(e). Theminimum cost maximum multi(commodity)flow problem (*) studied in this paper is to find ac-admissible multiflowf inG such that: (i)f is allowed to contain partial flows connecting any pairs of terminals, (ii) the total value off is as large as possible, and (iii) the total cost off is as small as possible, subject to (ii). This generalizes, on one hand, the undirected version of the classical minimum cost maximum flow problem (when |T| = 2), and, on the other hand, the problem of finding a maximum fractional packing ofT-paths (whena ≡ 0). Lovász and Cherkassky independently proved that the latter has a half-integral optimal solution. A pseudo-polynomial algorithm for solving (*) has been developed earlier and, as its consequence, the theorem on the existence of a half-integral optimal solution for (*) was obtained. In the present paper we give a direct, shorter, proof of this theorem. Then we prove the existence of a half-integral optimal solution for the dual problem. Finally, we show that half-integral optimal primal and dual solutions can be designed by a combinatorial strongly polynomial algorithm, provided that some optimal dual solution is known (the latter can be found, in strongly polynomial time, by use of a version of the ellipsoid method).
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  • 7
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    Mathematical programming 66 (1994), S. 379-402 
    ISSN: 1436-4646
    Keywords: Primary 49A52, 90C30 ; Secondary 26E15, 58C20 ; Nonsmooth analysis ; Second order necessary and sufficient conditions
    Source: Springer Online Journal Archives 1860-2000
    Topics: Computer Science , Mathematics
    Notes: Abstract In this paper we generalize and sharpen R.W. Chaney's results on unconstrained and constrained second-order necessary and sufficient optimality conditions [5–7] for general Lipschitz functions without the semismoothness assumption
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  • 8
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    Mathematical programming 67 (1994), S. 1-28 
    ISSN: 1436-4646
    Keywords: Error bound ; Analytic systems ; Karush—Kuhn—Tucker conditions ; Affine variational inequality ; Complementarity problem ; Integer feasibility problem
    Source: Springer Online Journal Archives 1860-2000
    Topics: Computer Science , Mathematics
    Notes: Abstract Using a 1958 result of Lojasiewicz, we establish an error bound for analytic systems consisting of equalities and inequalities defined by real analytic functions. In particular, we show that over any bounded region, the distance from any vectorx in the region to the solution set of an analytic system is bounded by a residual function, raised to a certain power, evaluated atx. For quadratic systems satisfying certain nonnegativity assumptions, we show that this exponent is equal to 1/2. We apply the error bounds to the Karush—Kuhn—Tucker system of a variational inequality, the affine variational inequality, the linear and nonlinear complementarity problem, and the 0–1 integer feasibility problem, and obtain new error bound results for these problems. The latter results extend previous work for polynomial systems and explain why a certain square-root term is needed in an error bound for the (monotone) linear complementarity problem.
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  • 9
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    Mathematical programming 67 (1994), S. 29-51 
    ISSN: 1436-4646
    Keywords: Infeasible-interior-point methods ; Linear complementarity problems ; Q-subquadratic convergence
    Source: Springer Online Journal Archives 1860-2000
    Topics: Computer Science , Mathematics
    Notes: Abstract We modify the algorithm of Zhang to obtain anO(n2L) infeasible-interior-point algorithm for monotone linear complementarity problems that has an asymptoticQ-subquadratic convergence rate. The algorithm requires the solution of at most two linear systems with the same coefficient matrix at each iteration.
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  • 10
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    Mathematical programming 67 (1994), S. 99-108 
    ISSN: 1436-4646
    Keywords: Stochastic programming with recourse ; Quantitative stability ; Lipschitz continuity ; Law of Iterated Logarithm ; Kolmogorov—Smirnov distance
    Source: Springer Online Journal Archives 1860-2000
    Topics: Computer Science , Mathematics
    Notes: Abstract In this paper we study stability of optimal solutions of stochastic programming problems with fixed recourse. An upper bound for the rate of convergence is given in terms of the objective functions of the associated deterministic problems. As an example it is shown how it can be applied to derivation of the Law of Iterated Logarithm for the optimal solutions. It is also shown that in the case of simple recourse this upper bound implies upper Lipschitz continuity of the optimal solutions with respect to the Kolmogorov—Smirnov distance between the corresponding cumulative probability distribution functions.
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  • 11
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    Mathematical programming 67 (1994), S. 109-119 
    ISSN: 1436-4646
    Keywords: Polynomial-time ; Linear programming ; Primal-dual ; Interior-point algorithm
    Source: Springer Online Journal Archives 1860-2000
    Topics: Computer Science , Mathematics
    Notes: Abstract Kojima, Megiddo, and Mizuno investigate an infeasible-interior-point algorithm for solving a primal—dual pair of linear programming problems and they demonstrate its global convergence. Their algorithm finds approximate optimal solutions of the pair if both problems have interior points, and they detect infeasibility when the sequence of iterates diverges. Zhang proves polynomial-time convergence of an infeasible-interior-point algorithm under the assumption that both primal and dual problems have feasible points. In this paper, we show that a modification of the Kojima—Megiddo—Mizuno algorithm “solves” the pair of problems in polynomial time without assuming the existence of the LP solution. Furthermore, we develop anO(nL)-iteration complexity result for a variant of the algorithm.
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  • 12
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    Mathematical programming 67 (1994), S. 325-341 
    ISSN: 1436-4646
    Keywords: Minimum capacity cut ; Network flow ; Polynomial algorithm
    Source: Springer Online Journal Archives 1860-2000
    Topics: Computer Science , Mathematics
    Notes: Abstract In this paper, we present an efficient implementation of theO(mn + n 2 logn) time algorithm originally proposed by Nagamochi and Ibaraki (1992) for computing the minimum capacity cut of an undirected network. To enhance computation, various ideas are added so that it can contract as many edges as possible in each iteration. To evaluate the performance of the resulting implementation, we conducted extensive computational experiments, and compared the results with that of Padberg and Rinaldi's algorithm (1990), which is currently known as one of the practically fastest programs for this problem. The results indicate that our program is considerably faster than Padberg and Rinaldi's program, and its running time is not significantly affected by the types of the networks being solved.
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  • 13
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    Mathematical programming 64 (1994), S. 81-101 
    ISSN: 1436-4646
    Keywords: 90C25 ; Convex programming ; Proximal methods ; Augmented Lagrangian ; Decomposition-splitting methods
    Source: Springer Online Journal Archives 1860-2000
    Topics: Computer Science , Mathematics
    Notes: Abstract This paper presents a decomposition method for solving convex minimization problems. At each iteration, the algorithm computes two proximal steps in the dual variables and one proximal step in the primal variables. We derive this algorithm from Rockafellar's proximal method of multipliers, which involves an augmented Lagrangian with an additional quadratic proximal term. The algorithm preserves the good features of the proximal method of multipliers, with the additional advantage that it leads to a decoupling of the constraints, and is thus suitable for parallel implementation. We allow for computing approximately the proximal minimization steps and we prove that under mild assumptions on the problem's data, the method is globally convergent and at a linear rate. The method is compared with alternating direction type methods and applied to the particular case of minimizing a convex function over a finite intersection of closed convex sets.
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  • 14
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    Mathematical programming 65 (1994), S. 73-91 
    ISSN: 1436-4646
    Keywords: Perturbation theory ; Sensitivity analysis ; Infinite linear programming
    Source: Springer Online Journal Archives 1860-2000
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  • 15
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    Computing 52 (1994), S. 17-30 
    ISSN: 1436-5057
    Keywords: 90B35 ; Optimization ; optimal makespan schedule ; optimal mean flow time schedule ; regular criterion ; polynomial time algorithm ; NP-hard problem
    Source: Springer Online Journal Archives 1860-2000
    Topics: Computer Science
    Description / Table of Contents: Zusammenfassung Es werden Reihenfolge-probleme mit zwei Aufträgen undm Maschinen untersucht, wobei die technologische Reihenfolge der Maschinen für den ersten Auftrag gegeben und für den zweiten Auftrag variabel ist. Es wird bewiesen, daß die Probleme “Minimierung der Gesamtbearbeitungszeit” und “Minimierung der mittleren Durchlaufzeit” NP-hard sind, wenn eine Unterbrechung der Operationen verboten ist. Für ein beliebiges reguläres Kriterium wird bei Zulassung von Unterbrechungen einO(n *) Algorithmus entwickelt, wobei mitn * die maximale Anzahl der Operationen für den ersten Auftrag bezeichnet wird.
    Notes: Abstract The shop-scheduling problem with two jobs andm machines is considered under the condition that the machine order is fixed in advance for the first job and nonfixed for the second job. The problems of makespan and mean flow time minimization are proved to be NP-hard if operation preemption is forbidden. In the case of preemption allowance for any given regular criterion theO(n *) algorithm is proposed. Here,n * is the maximum number of operations per job.
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  • 16
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    Computing 52 (1994), S. 89-96 
    ISSN: 1436-5057
    Keywords: 65C10 ; 68C25 ; Random number generation ; log-concave distributions ; rejection method ; simulation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Computer Science
    Description / Table of Contents: Zusammenfassung Wir erklären einen Algorithmus, der Stichproben von beliebigen log-konkaven Verteilungen (z.B. Binomial- und Hypergeometrische Verteilung) erzeugt. Er basiert auf Verwerfung von einer diskreten dominierenden Verteilung, die aus Teilen der geometrischen Verteilung zusammengesetzt wird. Der Algorithmus is gleichmäßig schnell für alle diskreten log-konkaven Verteilungen und nicht viel langsamer als Algorithmen, die nur für eine bestimmte Verteilung verwendet werden können.
    Notes: Abstract We give an algorithm that can be used to sample from any discrete log-concave distribution (e.g. the binomial and hypergeometric distributions). It is based on rejection from a discrete dominating distribution that consists of parts of the geometric distribution. The algorithm is uniformly fast for all discrete log-concave distributions and not much slower than algorithms designed for a single distribution.
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  • 17
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    Computing 52 (1994), S. 161-176 
    ISSN: 1436-5057
    Keywords: 65G05 ; 65K05 ; 90C20 ; Error analysis ; constrained optimization ; least squares problems ; null space method
    Source: Springer Online Journal Archives 1860-2000
    Topics: Computer Science
    Description / Table of Contents: Zusammenfassung Die numerische Stabilität des Nullraum-Verfahrens [2], [7] für lineare Ausgleichsprobleme mit linearen Gleichungs-Nebenbedingungen wird einer Rückwärtsanalyse unterzogen. An Hand einer Klasse von Testproblemen wird experimentell das Verhalten des Verfahrens dargestellt.
    Notes: Abstract The numerical stability of the null space method [2], [7] for linear least-squares problems with linear equality constraints is studied using a backward error analysis. A class of test problems is also considered in order to show experimentally the behaviour of the method.
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  • 18
    ISSN: 1436-5057
    Keywords: 34B30 ; 65L15 ; 39A10 ; 65G10 ; Hill's equation, cycle slip rate ; eigenvalues ; continued fractions ; verfication ; comparison theorem
    Source: Springer Online Journal Archives 1860-2000
    Topics: Computer Science
    Description / Table of Contents: Zusammenfassung Wir stellen eine Methode vor, die mit Hilfe von Matrix-Kettenbrüchen und dem Sturm'schen Vergleichssatz die Verifikation von Eigenwerten des Randwertproblems der Phase-Locked-Loop-Gleichung erster Ordnung $$pu'' + (\lambda + \tilde g)u = 0$$ ,p = 1/SNR, mit allgemeiner phasenvergleichender Charakteristik $$\tilde g(\phi )$$ erlaubt.
    Notes: Abstract We present a method depending on matrix continued fractions and Sturm's comparison theorem to obtain verified inclusions for eigenvalues of the underlying boundary value problem of the first-order phase locked loop equation $$pu'' + (\lambda + \tilde g)u = 0$$ ,p = 1/SNR with general phase detector characteristic $$\tilde g(\phi )$$ .
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  • 19
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    Computing 52 (1994), S. 281-297 
    ISSN: 1436-5057
    Keywords: 90B35 ; 90C27 ; Combinatorial problems ; on-line ; bin packing ; suboptimal algorithms
    Source: Springer Online Journal Archives 1860-2000
    Topics: Computer Science
    Description / Table of Contents: Zusammenfassung In dieser Arbeit untersuchen wir asymptotische untere Schranken von on-line Algorithmen für verschiedene Arten des Bin-Packungsproblems. Kürzlich haben Galambos und Frenk einen einfachen Beweis der unteren Schranke 1.536... für das eindimensionale Packungsproblem angegeben. Ausgehend von ihren Überlegungen präsentieren wir eine allgemeine Technik zur Herleitung unterer Schranken auch für andere Packungsprobleme. Wir verwenden diese Technik, um neue untere Schranken für das zweidimensionale (1,802...) und das dreidimensionale (1,974...) Packungsproblem zu beweisen.
    Notes: Abstract In this paper we discuss lower bounds for the asymptotic worst case ratio of on-line algorithms for different kind of bin packing problems. Recently, Galambos and Frenk gave a simple proof of the 1.536 ... lower bound for the 1-dimensional bin packing problem. Following their ideas, we present a general technique that can be used to derive lower bounds for other bin packing problems as well. We apply this technique to prove new lower bounds for the 2-dimensional (1.802...) and 3-dimensional (1.974...) bin packing problem.
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  • 20
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    Computing 52 (1994), S. 39-49 
    ISSN: 1436-5057
    Source: Springer Online Journal Archives 1860-2000
    Topics: Computer Science
    Description / Table of Contents: Zusammenfassung In dieser Arbeit untersuchen wir mehrer Methoden zur numerischen Berechnung von Transportphänomenen in Halbleitern, die auf kinetischen Gleichungen basieren. Insbesondere betrachten wir den Aufwand an Rechenzeit für die verschiedenen Algorithmen, der in einigen Fällen die Anwendung auf höherdimensionale Probleme unmöglich macht.
    Notes: Abstract In this paper we consider several methods for the numerical computation of carrier transport effects in semiconductors based on kinetic equations. We especially discuss the computational costs of the different algorithms, which in some cases prohibit their application to higher dimensional problems.
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  • 21
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    Computing 52 (1994), S. 51-63 
    ISSN: 1436-5057
    Keywords: 65F10 ; 65N20 ; 65N30 ; Preconditioning ; conjugate gradients ; local refinement ; elliptic problems
    Source: Springer Online Journal Archives 1860-2000
    Topics: Computer Science
    Description / Table of Contents: Zusammenfassung Präkonditionierte iterative Methoden von Typ der konjugierten Gradienten zur Lösung elliptischer und parabolischer Probleme werden auf lokal verfeinerten Gittern untersucht. Die Komponenten des während der Iteration berechneten Residuumsvektors werden betrachtet. Man erkennt, daß sie nur an den Knoten nahe dem Übergang zwischen feinem und grobem Gitter ungleich null sind. Diese Eigenschaft wird verwendet, um die präkonditionierte CG-Methode oder, wenn wie im parabolischen Fall die Matrix nicht symmetrisch ist, verallgemeinerte CG- oder GMRES-Methoden zu formulieren. Dadurch wird Speicherplatz und Rechenaufwand eingespart.
    Notes: Abstract Preconditioned iterative methods of conjugate gradient type for solving elliptic and parabolic problems discretized on grids wth local refinement are considered. The sparsity pattern of the residuals computed throughout the iterative process is investigated. It turns out that they are nonzero only near the interface nodes between the coarse-and fine-grids. This observation is used to formulate the preconditioned CG, and when the matrix is not symmetric as in the parabolic case—the generalized CG and GMRES methods, thus substantially saving storage and computation.
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  • 22
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    Computing 52 (1994), S. 139-159 
    ISSN: 1436-5057
    Keywords: 65N38 ; 45B05 ; 45E05 ; 45Z10 ; 65Y20 ; Boundary element method ; numerical quadrature ; collocation ; panel method ; cubature
    Source: Springer Online Journal Archives 1860-2000
    Topics: Computer Science
    Description / Table of Contents: Zusammenfassung Die Arbeit präsentiert effiziente Verfahren zur Bestimmung fast singulärer Integrale, wie sie in großer Anzahl bei der Diskretisierung von Integralgleichungen durch Kollokation auftreten. Die Methode basiert auf der Einführung von lokalen Polarkoordinaten um eine Dreiecksecke. Die innere Integration läßt sich analytisch durchführen, wobei man entweder entsprechende numerisch stabile Formeln oder Funktionsapproximationen verwenden kann. Die äußere Integration kann mit gewünschter Genauigkeit mittels Gauß-Legendre-Quadratur ermittelt werden. Numerische Tests unterstreichen die Effizienz unserer Methode.
    Notes: Abstract In this paper we present efficient methods to approximate nearly singular surface integrals arising massively when discretizing boundary integral equations via the collocation method. The idea is to introduce local polar coordinates centred at a corner of the triangle. Thus it is possible to perform the inner integration analytically, where either the corresponding formulae can be evaluated numerically stable or can be replaced by simple (rational) approximation quite efficiently. We show that the outer integration can be performed by simple Gauß-Legendre quadrature and how to adapt the order of the Gauß formulae to a required order of consistency. Numerical tests will emphasize the efficiency of our method.
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  • 23
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    Computing 52 (1994), S. 233-244 
    ISSN: 1436-5057
    Source: Springer Online Journal Archives 1860-2000
    Topics: Computer Science
    Description / Table of Contents: Zusammenfassung Es wird eine notwendige und hinreichende bedingung für die Existenz der Lösung der Intervall-Sylvester Gleichung angegeben. Dazu wird eine modifizierte Oettli Ungleichung abgeleitet, um die Lösung zu charakterisieren. Mehrere direkte Methoden für das Lösen der Gleichung werden vorgeschlagen und miteinander verglichen. Diese Methoden basieren auf verschiedenen Techniken wie Simulation, Lineare Programmierung, dem Zusammenhang zwischen einer Intervall-Sylvester Gleichung und einem Intervall-linearen System wie auch der Sensitivitätsanalyse. Weiters wird eine iterative Technik bereitgestellt, für die Konvergenz-Bedingungen verfügbar sind. Als Anwendung wird die Wurzel einer Intervall-Matrix berechnet.
    Notes: Abstract In this paper a necessary and sufficient condition for the existence of a solution for the interval Sylvester equation is given. A modified Oettli's inequality is derived to characterize the solution. Many direct methods for solving the equation are suggested and compared to each other. These methods are based on different techniques such as simulation, linear programming, correspondence between an interval Sylvester equation and an interval linear system as well as sensitivity analysis. An iterative technique for solving the interval Sylvester equation is provided with special conditions to guarantee the convergence. The square root of an interval matrix is calculated as an application to solving interval Sylvester equations.
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  • 24
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    Computing 52 (1994), S. 355-369 
    ISSN: 1436-5057
    Keywords: (Exact) computer arithmetic ; numerical algorithms ; dot-product computation ; summation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Computer Science
    Description / Table of Contents: Zusammenfassung Es wird ein Algorithmus vorgestellt, der ein Skalarprodukt beliebiger Länge auswertet. Bei der Berechnung tritt nur ein minimaler Rundungsfehler auf, der nicht von der Anzahl der Summanden abhängt. Der Algorithmus hat einen konstanten Speicherbedarf, einen linearen Rechenaufwand und es ist keine Erweiterung der arithmetischen Grundoperationen notwendig. Durch eine kleine Änderung erhält man einen Algorithmus, der das Ergebnis in Maschinengenauigkeit berechnet. Wegen seiner einfachen Struktur kann der Algorithmus leicht in Hardware realisiert werden.
    Notes: Abstract We present a new algorithm which computes dot-products of arbitrary length with minimal rounding errors, independent of the number of addends. The algorithm has anO(n) time andO(1) memory complexity and does not need extensions of the arithmetic kernel, i.e, usual floating-point operations. A slight modification yields an algorithm which computes the dot-product in machine precision. Due to its simplicity, the algorithm can easily be implemented in hardware.
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  • 25
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    Computing 52 (1994), S. 337-354 
    ISSN: 1436-5057
    Keywords: Primary 65D30 ; 41A55 ; Secondary 65R10 ; Cauchy principal value integrals ; Hadamard finite part integrals ; modified quadrature formula ; midpoint formula ; trapezoidal formula ; Simpson formula ; Peano constants
    Source: Springer Online Journal Archives 1860-2000
    Topics: Computer Science
    Description / Table of Contents: Zusammenfassung Wir zeigen, daß der Fehlerterm jedes modifizierten zusammengesetzten Quadraturverfahrens für Cauchy-Hauptwert-Integrale mit Exaktheitsgrads die bestmögliche Größenordnung in den KlassenC k [−1,1],k=1,2,...,s hat, aber nich inC s+1[−1,1]. Explizite obere Schranken für die Fehlerkonstanten der modifizierten Mittelpunkt-, Trapez- und Simpson-Verfahren werden angegeben. Des weiteren werden die Ergebnisse auf die entsprechenden Verfahren für Finite-Part-Integrale vom Hadamardschen Typ verallgemeinert.
    Notes: Abstract We show that the error term of every modified compound quadrature rule for Cauchy principal value integrals with degree of exactnesss is of optimal order of magnitude in the classesC k [−1,1],k=1,2,...,s, but not inC s+1[−1,1]. We give explicit upper bounds for the error constants of the modified midpoint rule, the modified trapezoidal rule and the modified Simpson rule. Furthermore, the results are generalized to analogous rules for Hadamard-type finite part integrals.
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    Computing 52 (1994), S. 389-405 
    ISSN: 1436-5057
    Keywords: 05C99 ; 68P20 ; 68R10 ; 90C27 ; Graph layout ; graph partitioning ; combinatorial optimization ; information retrieval
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    Topics: Computer Science
    Description / Table of Contents: Zusammenfassung Der Begriff eines Informationsgraphen wird als eine Repräsentation für objektorientierte Datenbanken vorgestellt. Das Wiederauffinden von Informationen ergibt sich als Optimierungsproblem bezüglich der so entstandenen Informationsgraphen. Das Layout stellt nicht nur den Raumbedarf der Datenbank sondern auch den Zeitbedarf des Wiederauffindens der Informationen dar. Heuristiken für das Wiederauffindungsproblem werden identifiziert und experimentell ausgewertet. Eine neue Heuristik-connectivity traversal-ergibt sowohl ein schnelles Wiederauffindungsverfahren wie auch qualitativ hochwertige Layouts.
    Notes: Abstract The concept of an information graph is introduced as a representation for object-oriented databases. The retrieval layout problem is an optimization problem defined over the class of information graphs. The layout abstracts the space efficiency of representing the database as well as the time efficiency of information retrieval. Heuristics for the retrieval layout problem are identified and evaluated experimentally. A new heuristic, connectivity traversal, is found to be fast and to produce high quality layouts.
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    Computing 53 (1994), S. 95-99 
    ISSN: 1436-5057
    Keywords: 65F35 ; 65L05 ; 65L07 ; Obrechkoff formula ; stiff differential equations
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    Topics: Computer Science
    Description / Table of Contents: Zusammenfassung Die Padé- oder Obrechkoff-Verfahren, die auf diagonalen oder subdiagonalen Padé-Approximationen der Exponentialfunktion beruhen, vereinen hohe Genauigkeit mit guter Stabilität; wegen des Auftretens höherer Ableitungen sind sie aber nur schwer effizient zu implementieren. Für das subdiagonale Verfahren dritter Ordnung mit zweiten Ableitungen haben wir eine Implementierung gefunden, die zu einem Code geführt hat, der für nicht besonders große, stark steife Systeme bei mäßigen Genauigkeitsforderungen konkurrenzfähig mit gängigen Codes ist.
    Notes: Abstract Padé or Obrechkoff methods based on diagonal or subdiagonal Padé approximations for the exponential function combine high accuracy and good stability; but the occurrence of higher derivatives makes their efficient implementation difficult. For the 3rd order subdiagonal 2nd derivative method, we have found an implementation which has resulted in a competitive code for moderately large, strongly stiff systems, under moderate accuracy requirements.
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    Computing 53 (1994), S. 119-136 
    ISSN: 1436-5057
    Keywords: 90C30 ; 65K05 ; Unconstrained optimization ; trust region method ; nonmonotone stabilization method
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    Topics: Computer Science
    Description / Table of Contents: Zusammenfassung Für das nichtrestringierte Optimierungsproblem wird eine neue Klasse von Trust-Region-Verfahren vorgestellt, die mit einer nichtmonotonen Stabilisierungsstrategie arbeiten. Die Konvergenzeigenschaften dieser Verfahren werden unter gewissen Regularitätsannahmen untersucht. Umfangreiche numerische Beispiele zeigen die hohe Effizienz dieser Verfahren.
    Notes: Abstract A class of trust region methods in unconstrained optimization is presented, by adopting a nonmonotone stabilization strategy. Under some regularity conditions, the convergence properties of these methods are discussed. Extensive numerical results which are reported show that these methods are very efficient.
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    Computing 53 (1994), S. 155-171 
    ISSN: 1436-5057
    Keywords: 65F10 ; 65N30 ; Wavelets ; wavelet packets ; robust multilevel methods ; V-cycle
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    Topics: Computer Science
    Description / Table of Contents: Zusammenfassung Wir betrachten den gedämpftenV-Zyklus für die Wavelet-Variante der “Frequenzzerlegungs-Multigridmethode” von Hackbusch [Numer. Math.56, 229–245 (1989)]. Es wird gezeigt, daß die Konvergenzgeschwindigkeit bei hinreichender Dämpfung durch Anisotropie nicht beeinflußt wird, aber noch von der Anzahl des Niveaus abhängt. Unsere Analyse beruht auf Eigenschaften von Wavelet-Paketen, die formuliert und bewiesen werden. Numerische Schätzungen der Konvergenzgeschwindigkeit erläutern die theoretischen Ergebnisse.
    Notes: Abstract The dampedV-cycle of the wavelet variation of the “Frequency decomposition multigrid method” of Hackbusch [Numer. Math.56, pp. 229–245 (1989)] is considered. It is shown that the convergence speed under sufficient damping is not affected by the presence of anisotropy but still depends on the number of levels. Our analysis is based on properties of wavelet packets which are supplied and proved. Numerical approximations to the speed of convergence illustrate the theoretical results.
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    Computing 53 (1994), S. 173-194 
    ISSN: 1436-5057
    Keywords: Primary: 65D30, 41A55 ; Secondary: 65D32 ; Singular integrals ; numerical integration ; exponential convergence
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    Topics: Computer Science
    Description / Table of Contents: Zusammenfassung Wir stellen eine Klasse von zusammengesetzten Quadraturformeln variabler Ordnung vor, die sich zur numerischen Integration von Funktionen mit einer Singularität im Inneren oder in der Nähe des Integrationsbereichs eignen. Für alle Integranden in dem abzählbar normierten RaumB β wird eine exponentielle Konvergenz des Verfahrens bewiesen. Numerische Beispiele zeigen, daß die ermittelten asymptotischen exponentiellen Konvergenzraten scharf sind und schon bei einer kleinen Zahl von Quadraturknoten erreicht werden.
    Notes: Abstract A class of variable order composite quadrature formulas for the numerical integration of functions with a singularity in or near to the region of integration is introduced. Exponential convergence of the method is shown for all integrands in the countably normed spaceB β. Numerical examples are presented which demonstrate that the asymptotic exponential convergence rates obtained here are sharp and already observed for a small number of quadrature points.
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    Computing 53 (1994), S. I 
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    Engineering with computers 10 (1994), S. 22-32 
    ISSN: 1435-5663
    Keywords: Conceptual design ; Database ; Frameworks ; Information management
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    Topics: Computer Science , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Technology
    Notes: Abstract An information modeling approach is used to gain an understanding of the information and decision content of conceptual engineering design. Information frameworks are presented that attempt to represent the key decisions made during conceptual design. Elements of the frameworks are derived from results from design theory and methodology and decision theory. Using a number of products, the frameworks are demonstrated in simulated design situations. The models provide an explicit, generic and consistent perspective for identifying the information content of conceptual designs.
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    Engineering with computers 10 (1994), S. 12-21 
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    Keywords: Aluminium electrolysis ; Expert systems ; Modelling ; Simulation
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    Topics: Computer Science , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Technology
    Notes: Abstract A workstation-based simulator of an aluminium electrolytic cell has been constructed. A mathematical model of the cell is integrated with a database and a knowledge base, and the simulator serves as a tool for the training of personnel and for research related to cell dynamics and cell control. When used in conjunction with an expert system, it provides a powerful decision-making tool or an efficient supervisory system. The mathematical model, the simulator itself, the user environment, the interactive simulation procedure as well as examples of the use of the simulator are presented in detail.
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    Engineering with computers 10 (1994), S. 63-80 
    ISSN: 1435-5663
    Keywords: Dimensioning ; Tolerancing ; Variational geometry
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    Topics: Computer Science , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Technology
    Notes: Abstract Dimensioning and tolerancing are very important issues in product design and manufacture. This paper gives a survey and review of the current state-of-the-art solutions to the problem of finding a meaning for dimensions and tolerances. Dimensioning and tolerancing in current engineering practices and researches in these topics are also discussed.
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    Engineering with computers 10 (1994), S. 95-111 
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    Keywords: Engineering design ; Formal ; Functional programming ; Object orientation ; Programming language
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    Topics: Computer Science , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Technology
    Notes: Abstract Currently available programming and database systems are insufficient for engineering applications. The authors contend that a logical progression from a formal conceptual model of the engineering domain to a computational model will lead to new programming paradigms capable of directly supporting engineering applications in a rigorous, concise manner. A formal domain model devised by the authors, theHybrid Model (HM) of design information, is briefly introduced. It is an extension of axiomatic set theory and is discussed in detail elsewhere. HM forms the basis ofDesigner, a prototype-based object-oriented programming language supporting a signature-based canonical message-passing mechanism and multiple inheritance. Designer is implemented using the Scheme programming language. Because Designer satisfies a formal conceptual model, and because it is based on a formally specified language, its robustness and logical validity are superior to those of other languages not founded on formal principles. Designer combines concepts of functional and object-oriented programming to provide the formal rigor and flexibility to capture the complex and strongly interrelated information that designers use. Examples demonstrate how Designer represents design information. The results of the authors' research indicate that Designer can capture design information (including aspects of functional requirements and design intent) effectively and efficiently.
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    Engineering with computers 10 (1994), S. 81-94 
    ISSN: 1435-5663
    Keywords: Design ; Expert system ; Extension ; Material processing
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    Topics: Computer Science , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Technology
    Notes: Abstract The main thrust of this research is in developing aknowledge-based system for the design of components for a material processing system. In particular, this paper concentrates on developing methodologies forinitial design andredesign in a quantitative and qualitative format. A die for plastic extrusion has been selected as the subject material processing component. A design algorithm using best first heuristic search and expert knowledge, both in procedural and declarative form, is the core of the scheme. Apart from this expert, the suggestedselection procedure for candidate design is also seen to accelerate the design scheme. The methodologies presented enableefficient design of the component. Some generality has been accomplished by the implementation of the techniques to dies of different cross-sectional shapes. The software is written inLisp within an object-oriented software package using analysis modules written in C.
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    Engineering with computers 10 (1994), S. 124-124 
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    Topics: Computer Science , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Technology
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    Engineering with computers 10 (1994), S. 112-123 
    ISSN: 1435-5663
    Keywords: Agent-based framework ; Architecture ; Concurrent engineering ; Cooperating expert systems ; Tandem integration
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    Topics: Computer Science , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Technology
    Notes: Abstract This paper proposes a tandem architecture for cooperating heterogeneous expert systems. Two levels of meta and working expert systems are involved. The working-level expert systems (W-ES), which may be implemented in their own computational environments and in private proof languages, are mainly for application computations. The meta-level expert systems (M-ES), using a common argument language, are mainly responsible for cooperation. The prototype AGENTS system is described for constructing M-ES. Interaction among W-ES has been transformed into two forms: communication between M-ES through ordinary AGENTS messages and communication between M-ES and the corresponding W-ES using the Deductive Inference Language (DIL). DIL predicates are provided for defining DIL: messages, actuators and converters for interpreting DIL queries and instantiating variables. By this approach, stand-alone capability of infividual systems is retained at the working-level and cooperation is achieved effectively with minimum embellishment at the meta-level.
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    Engineering with computers 10 (1994), S. 155-161 
    ISSN: 1435-5663
    Keywords: Constrains ; Geometric ; Parametric ; Product form
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    Topics: Computer Science , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Technology
    Notes: Abstract Much work has been carried out on the creation of protocols for the exchange of data between CAD systems, but very little on the transfer of knowledge. The knowledge behind the development of a product is vital if modifications and adaptations are to be made within a concurrent development environment. Current CAD systems only contain a limited level of product knowledge through user-defined parametric structures. It is the underlying relationships in these programs that need to be communicated between systems, rather than the form of their individual programming languages. A generic structure is proposed that is able to handle both the current level of parametric programming and is suited to the resolution of conflict through the use of constraint modelling procedures. The structure of a parametric description is described and decomposed into its fundamental components. These components are then re-formed within a truth maintenance structure to allow a transfer protocol to be created. The derived protocol structure is then demonstrated on a number of simple examples.
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    Engineering with computers 10 (1994), S. 245-257 
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    Keywords: Design methodology ; Iterative design ; Concurrent design ; Features ; Form templates ; Finite element analysis
    Source: Springer Online Journal Archives 1860-2000
    Topics: Computer Science , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Technology
    Notes: Abstract To help foster concurrency in engineering design, methodologies are needed to support the interpretation and abstraction of numerical simulation results for design modification purposes. A methodology is presented in this paper for the integration of continuum-based numerical simulations into a computational system for concurrent design of mechanical components. The technique involves conversion of low-level numerical data, such as that obtained by finite element analysis, into high-level symbolic representations calledform templates. The form templates are based onrudimentary features which carry meaningful qualitative descriptions abstracted from either manufacturing and/or functional numerical simulations. The form templates are superimposed on the design's primary representation in the solid modeler to facilitate the cognitive mapping of concurrent destructive or constructive solid modeling features for design modifications. Examples are presented to demonstrate the methodology.
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    AI & society 8 (1994), S. 1-16 
    ISSN: 1435-5655
    Keywords: History of computing ; Data processing ; Artificial intelligence ; Virtual reality ; Modernism ; Postmodernism
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    Topics: Computer Science
    Notes: Abstract The term ‘the artificial’ can only be given a precise meaning in the context of the evolution of computational technology and this in turn can only be fully understood within a cultural setting that includes an epistemological perspective. The argument is illustrated in two case studies from the history of computational machinery: the first calculating machines and the first programmable computers. In the early years of electronic computers, the dominant form of computing was data processing which was a reflection of the dominant philosophy of logical positivism. By contrast, artificial intelligence (AI) adopted an anti-positivist position which left it marginalised until the 1980s when two camps emerged: technical AI which reverted to positivism, and strong AI which reified intelligence. Strong AI's commitment to the computer as a symbol processing machine and its use of models links it to late-modernism. The more directly experiential Virtual Reality (VR) more closely reflects the contemporary cultural climate of postmodernism. It is VR, rather than AI, that is more likely to form the basis of a culture of the artificial.
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    AI & society 8 (1994), S. 60-70 
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    Keywords: Computer concepts ; Computer supported collaborative work ; Human-centred computing ; System design methodology
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    Topics: Computer Science
    Notes: Abstract Current usage of the expression “human-centred” in computing contexts suffers from a lack of clarity, and involves internal contradictions. It is not enough to base the concept of human-centredness on ideas of social utility, collaborative working or human controllability. However, the concept of human action (which embodies reference to human freedom) provides a theoretical underpinning to human-centredness by combining, from a human standpoint, concern with process and concern with goals. This has consequences for the design process, prompting us to include new concerns in our system specifications and providing some pointers towards human-centred design methodology.
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    AI & society 8 (1994), S. 45-59 
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    Keywords: Computerisation ; Design ; Metaphors ; Tacit knowledge ; Thinking ; Unthinkables
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    Topics: Computer Science
    Notes: Abstract Design can be thought of as a model for such endeavours as are intended to result in industrially manufactured products by means of thinking and other intellectual activity. Familiarity with the thinking involved in the designing process is important, not only for those engaged in training designers, but for anyone desirous of systemizing the endeavour. One procedure for approaching an understanding of the way designers think is to describe it with the help of different metaphors. There are some metaphors for thinking about complicated and interrelated phenomena that should lend themselves to illustrating the thinking involved in design, albeit with reservations — e.g. the difficulty of allowing due consideration for what is unthinkable and indescribable in this context.
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    AI & society 8 (1994), S. 95-96 
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    AI & society 8 (1994), S. 97-106 
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    AI & society 8 (1994), S. 123-130 
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    Keywords: Cohesion ; Diversity ; Regional development ; Technology policy ; Integration ; Development ; Scenario
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    Notes: Abstract In its broadest sense, cohesion is an ultimate goal for Europe. In a study about long term future scenarios for Europe it appears that deepening of the integration process may induce decreasing cohesion, unless measures are taken to promote regional diversity as a vector of development. The widening of Europe also raises threats to cohesion, but a well prepared scenario for a Development Belt surrounding the EC may positively enhance the cohesion process.
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    AI & society 8 (1994), S. 107-122 
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    Keywords: Diversity ; Coherence ; Cohesion ; Network ; Learning ; Local systems of innovation
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    Notes: Abstract A clear understanding of the concept and consequences of diversity in science and technology is a key issue for Europe, when considering the current debate on cohesion Put forward within the Single European Act. According to Article 130B of the Single Act, all European policies, including technological policies must contribute to the achievement of a greater cohesion throughout the EC. The European market is generally presented as mainly a patchwork of national or even regional characteristics, with compartmentalized niches, and specific regulations. But does cohesion mean decreasing disparities between regions, which in such case signifies a passive policy of reallocation of resources within the EC, at the risk of generating uniformity? Or, does cohesion mean integration of all innovative and creative efforts, which implies a more complex policy of stimulation, under the condition to maintain a certain diversity? Must the governments systematically reduce diversity, or on the contrary must they enlarge diversity? How can they distinguish between negative and positive aspects of diversity? How do they operate a trade off between economies of scale and economies of diversity? To try to answer these political issues and to set up a coherent industrial policy at the EC level, a careful analysis of the sources of diversity, of the mechanisms that generate or reduce diversity, of the ways to valorize diversity are discussed in this paper
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    AI & society 8 (1994), S. 151-163 
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    Keywords: Cohesion ; Central and Eastern Europe ; Interdisciplinary approach ; Post-socialist societies ; Transition
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    Notes: Abstract After the collapse of the command structures of the party-state in society and economy, it appeared that the integrative mechanisms as they are developing now in the post-socialist countries have a very limited cohesiveness in the sense that they can not easily support disequilibria and resist disruptions. The asynchronous collapse of old and developing of new integrative mechanisms created integrational vacuums at various levels. The dynamics of this process of conflicting time scales created additional problems of cohesion in each of the domains. It appeared that (dis)integration processes in politics and economics are closely interrelated. Marketization in itself offered enforced fragmentation rather than furthering cohesíon. The link between cohesion within Central and Eastern Europe and Europe at large is also discussed here.
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    AI & society 8 (1994), S. 164-185 
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    Keywords: Baltic states ; Bazaar economy ; Flexible specialisation ; Globalisation ; Industrial estates ; Innovation ; Institutionalism ; Interfirm co-operation ; Low policy ; Negotiation ; New institutions ; Regional co-operation ; Relevant social groups ; Routines ; Selection mechanisms
    Source: Springer Online Journal Archives 1860-2000
    Topics: Computer Science
    Notes: Abstract This article seeks to explain and conceptualise certain aspects of industrial and technological change at the regional level, using the Baltic region as a case. The concept of “new institutions” is applied to understand recent attempts to stimulate organised behaviour, trustrelations and co-operation at the level of low policy. New regional institutions deal with competing pressure groups, but their strength lies mostly in the ability to orchestrate and influence pressure groups in a formative way. The article identifies potential starting points for this regional involvement. It is divided into three parts. First, some of the economic problems and potentials of the Baltic states are scrutinised. Second, some features of new institutions are explored at the theoretical level. Third, some aspects of international policy-making are briefly discussed, especially the concept of low policies and bottom-up approaches.
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    AI & society 8 (1994), S. 197-206 
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    Keywords: Europe ; Labour ; New technologies ; Research ; Science ; Trade unions
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    Topics: Computer Science
    Notes: Abstract A series of decisions covering agriculture as well as industrial and regional policy fundamentally affect the very own interests of the dependently employed. For some years, the trade unions of all European countries have been on the defensive, undergoing a legitimation crisis. The improvement of the social charter and of the rights of the European Parliament are not sufficient to overcome this crisis and to secure a human, social, ecological and democratic future. For this reason, the order of the day must not only be a socially and ecologically compatible design for technology, but a socially and ecologically oriented one. There is certainly an enormous quantity of accompanying research within the European Community, but it is doubtful in how far this research takes into account the requirements of the majority of the population.
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    AI & society 8 (1994), S. 245-269 
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    Keywords: National change programmes ; Participative action research ; Research strategy ; Worklife development ; Workplace reform
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    Topics: Computer Science
    Notes: Abstract With increasing flexibility of technology and a shift towards competence being the core of competitive edge in worklife, the need for new organizational concepts or models which givejoint optimization across human and technological dimensions has been acknowledged in leading, innovative enterprises. National crossdisciplinary research based productivity programmes are appearing in several countries. Due to internationalization and the general shortcomings of bureaucratic organizational forms, regional networks of enterprises in cooperation with public R&D institutions seem to provide answers to needs of regions to remain competitive. The paper discusses the possible role of social science in a multilevel, participative strategy for developing new, democratic and productive organizational forms in worklife. Aspects of national productivity programmes in Scandinavia, Germany and Australia are discussed in connection with the situation in Italy as analyzed through some recent research projects.
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    AI & society 8 (1994), S. 285-291 
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    AI & society 8 (1994), S. 298-303 
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    Notes: Conclusions As my paper draws to a close, it may seem quite clear that by posing such questions about the organisation of work and labour, one opens up more problems than are actually solved. There is one question in particular that has to be answered. I shall ask that question rhetorically: Can there be a world in which group activities are not started up?
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    AI & society 8 (1994), S. 305-314 
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    Keywords: Consciousness ; Selfhood ; Science of Mind
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    Notes: Abstract For a variety of reasons, consciousness and selfhood are beginning once again to be intensively studied in a scientific frame of reference. The notions of each which are emerging are extremely varied: in the case of selfhood, the lack of an adequate vocabulary to capture various aspects of subjectivity has led to deep confusion. The task of the first part of this article is to clear up this terminological confusion, while salvaging whatever is valuable from the contemporary discussion. The more important task of the second part is to discuss the moral issues inevitably involved in any treatment, scientific or otherwise, of the modern identity.
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    AI & society 8 (1994), S. 315-325 
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    Keywords: Artificial intelligence technology ; International technology transfer
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    Topics: Computer Science
    Notes: Abstract One of the central factors influencing the process and the outcome of technology transfer is the nature of the technology being transferred. This paper identifies and discusses the main characteristics of Artificial Intelligence (AI) technology from the point of view of international technology transfer. It attempts to indicate the peculiarities of AI in this context and move towards a framework to assist recipient decision makers in optimising the formulation of their policies on AI technology transfer. The five AI characteristics identified here relate to complexity, localisation, uncertainty, capital intensiveness and awareness. Some of these features are in principle common with other high technologies, but still bear some aspects specific to AI, albeit only the intensity with which they characterise the technology. The complexity of AI technology partially stems from its multi-disciplinary nature. Certain sub-areas of AI are locally bound and therefore need local innovative capabilities to develop on the fundamental concepts. The uncertainty in AI projects stems mainly from the two factors of high rate of change and the difficulties of quantifying the gains of transferring cognitive load from human to machine. Expensive human skill and enabling technologies are required to develop, maintain and use AI systems efficiently, making such projects highly capital intensive. Finally, AI is a young field and is not always completely open about itself which makes the decision makers' awareness an important issue to be addressed in the growth of AI applications.
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    AI & society 8 (1994), S. 357-359 
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    AI & society 8 (1994), S. 359-363 
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    AI & society 8 (1994), S. 341-356 
    ISSN: 1435-5655
    Keywords: Knowledge discovery ; Database mining ; User intention ; Database security ; “Adversarial partnership”
    Source: Springer Online Journal Archives 1860-2000
    Topics: Computer Science
    Notes: Abstract We examine the relationship between systems and their users from the knowledge discovery perspective. Recently knowledge discovery in databases has made important progress, but it may also bring some potential problems to database design, such as issues related to database security, because an unauthorised user may derive highly sensitive knowledge from unclassified data. In this paper we point out that there is a need for a comprehensive study on knowledge discovery in human-computer symbiosis. Borrowing terms from algorithm design and artificial intelligence literature, we propose a notion called database-user adversarial partnership. We point out that this notion is general enough to cover various knowledge discovery and security of issues related to databases and their users. Furthermore, we point out the notion of database-user adversarial partnership can be further generalised into system-user adversarial partnership. Opportunities provided by knowledge discovery techniques and potential social implications are also discussed.
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    Research in engineering design 6 (1994), S. 25-37 
    ISSN: 1435-6066
    Keywords: Optimization ; Robust design ; Tolerances ; Variation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Technology
    Notes: Abstract In this paper we present a general, quantitative method for developing designs that are robust to variation in design variables and parameters. Variation is defined in terms of tolerances which bracket the expected deviation of uncertain quantities about nominal values. We specifically address the case where input variations are assumed to be random variables that are normally distributed. The method incorporates a second-order tolerance model as part of a nonlinear optimization process. The second-order tolerance model makes it possible to estimate the skewness of function distributions, which are modeled with a three-parameter gamma distribution. We apply the method to determine robust designs for 11 test cases that span a variety of problems; robustness is verified with Monte Carlo simulation. The method enables a designer to understand and account for the effects of tolerances, making it possible to build robustness into an engineering design.
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    Research in engineering design 6 (1994), S. 1-13 
    ISSN: 1435-6066
    Keywords: Concurrent engineering ; Design management ; Design process improvement
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Technology
    Notes: Abstract This research is aimed at structuring complex design projects in order to develop better products more quickly. We use a matrix representation to capture both the sequence of and the technical relationships among the many design tasks to be performed. These relationships define the “technical structure” of a project, which is then analyzed in order to find alternative sequences and/or definitions of the tasks. Such improved design procedures offer opportunities to speed development progress by streamlining the inter-task coordination. After using this technique to model design processes in several organizations, we have developed a design management strategy which focuses attention on the essential information transfer requirements of a technical project.
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    Research in engineering design 6 (1994), S. 38-57 
    ISSN: 1435-6066
    Keywords: Britannia Bridge ; Design laws ; Design process ; Design reasoning ; Hypotheses
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Technology
    Notes: Abstract In a recent paper, Dasgupta[6] has claimed to have identified two universal, qualitativelaws of design. Of these, one is called thehypothesis law, which states that: “A design process that reaches termination does so through one or more cycles of hypothesis creation, testing and (if necessary) modification.” This law was arrived at from arguments based on a model of the design process at the “knowledge level”[9] and on the concept of “bounded rationality”[15]. In the present article we describe an extensiveempirical test of the hypothesis law using an important historical case study. The case in question is the design, conducted between 1844 and 1847, of the Britannia Bridge which spanned the Menai Straits in Wales. Using published records of the project as the basis for our evidence, we shall show that the design process followed in this project strongly corroborates the hypothesis law.
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    Research in engineering design 6 (1994), S. 61-72 
    ISSN: 1435-6066
    Keywords: Inference strategy ; Qualitative reasoning ; Structural engineering
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Technology
    Notes: Abstract Qualitative reasoning is a methodology for deriving the behavior of a device from a declarative representation of relevant fundamental principles and a high-level description of the device. This article and its companion present a qualitative reasoning framework, named the space-centered framework, for reasoning about the behavior of structural systems subjected to loads. The framework includes a representation of the topology and geometry of a structure, and the fundamental principles of equilibrium, compatibility and force-deformation relationships. A parameter, such as a displacement or an internal force, is represented qualitatively by its algebraic sign and its relationship in magnitude with other parameters in the model. Component qualitative states incorporate the fundamental principles for a class of components, such as frame members or supports. The conjugate analogy between the equilibrium and compatibility laws is recognized in the representation. Processes acting between components represent fundamental principles of equilibrium and compatibility at the connections. A companion paper presents the inference strategy for the space-centered framework and its application to qualitative analysis of conceptual designs of structures.
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    Research in engineering design 6 (1994), S. 142-168 
    ISSN: 1435-6066
    Keywords: Geometric modeling ; AEC ; CAD/CAE ; Facility
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Technology
    Notes: Abstract This paper presents a referential scheme for representing and identifying the spatial extent of physical entities of constructed facilities, such as buildings and offshore structures. Using the basic operations of a non-manifold geometric modeler, a set of high-level algebraic operations is defined. The scheme and its algebra are used for modeling the spatial attributes of a facility entity at two levels: primary and secondary. The primary representation uniquely captures an entity's spatial attributes at the “skeletal” level and is used mainly for identifying discipline-independent topological relationships of that entity with others. Secondary representations, on the other hand, are used to provide an entity's discipline-specific geometric attributes. The topological relationships and geometric attributes of facility entities thus need not be explicitly stored, but can be computed on demand by the underlying non-manifold modeler.
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    Research in engineering design 6 (1994), S. 85-102 
    ISSN: 1435-6066
    Keywords: Analysis ; Behavior derivation ; Constraints
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Technology
    Notes: Abstract Generation of the behavioral constraint equations needed for analysis in the mechanical design synthesis-analysis iteration loop is currently based on approaches that model the behavior of an entire system or subsystem of the design. This paper presents a general approach to constraint derivation that is localized around design performance variables. The approach consists of an amenable design configuration representation, a standard format for representing behavior knowledge, and an algorithm that builds a constraint network that can be used to solve for the performance variables by applying behavioral knowledge to the configuration. The algorithm works outward from the initial performance variables, creating new performance variables as required, and processing only those behavior laws and components of the design needed to obtain a solution. It can take design variables (known conditions or variable parameters) into account, takes advantage of the part-subpart hierarchy in the configuration, can exploit previous solutions, and can detect indeterminacy that is sometimes caused by simplifying assumptions.
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    Research in engineering design 6 (1994), S. 211-222 
    ISSN: 1435-6066
    Keywords: Engineering design ; Simultaneous engineering ; Concurrent engineering ; Robust design ; Distributed optimization
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Technology
    Notes: Abstract Simultaneous engineering processes involve multifunctional teams; team members simultaneously make decisions about many parts of the product-production system and aspects of the product life cycle. This paper argues that such simultaneous distributed decisions should be based on communications about sets of possibilities rather than single solutions. By extending Taguchi's parameter design concepts, we develop a robust and distributed decision-making procedure based on such communications. The procedure shows how a member of a design team can make appropriate decisions based on incomplete information from the other members of the team. More specifically, it (1) treats variations among the designs considered by other members of the design team asconceptual noise; (2) shows how to incorporate such noises into decisions that are robust against these variations; (3) describes a method for using the same data to provide preference information back to the other team members; and (4) provides a procedure for determining whether to release theconceptually robust design or to wait for further decisions by others. The method is demonstrated by part of a distributed design process for a rotary CNC milling machine. While Taguchi's approach is used as a starting point because it is widely known, these results can be generalized to use other robust decision techniques.
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    Polymer bulletin 32 (1994), S. A3 
    ISSN: 1436-2449
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    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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    Polymer bulletin 32 (1994), S. 361-365 
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    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary Organosolv lignin was used as organic filler for polypropylene (PP) and poly(ethene-co-vinylacetate) (EVA) containing 13wt-% vinylacetate. As a function of the lignin content, which was varied between 0 and 30wt-%, mechanical properties such as Young's modulus, yield stress, fracture stress, and elongation at break of the thermoplastic lignin-based compounds were measured. Both lignin-filled thermoplastics exhibit pronounced matrix reinforcement with increasing lignin content. Due to better interfacial adhesion between lignin and EVA, 30wt-% lignin addition to EVA doubles Young's modulus without sacrificing high elongation at break.
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    Polymer bulletin 32 (1994), S. 373-380 
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    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary 4-Vinylphthalic anhydride can be prepared from phthalic acid via bromination and subsequent olefination (Heck-reaction). Homo- and copolymerization with styrene was accomplished using AIBN as initiator. The copolymer compositions were determined by infrared-spectroscopy. The copolymerization parameters are rs=0,15 and rVPA=3,09, the corresponding Q, e values of 4-vinylphthalic anhydride are estimated as Q=3,34 and e=0.09. Despite the fact that the molecular weights were rather low as a consequence of the reaction contions, the glass transition temperatures rise with increasing VPA content. The homopolymer has a glass transition temperature in the order of 226°C.
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    Polymer bulletin 32 (1994), S. 471-477 
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    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary Immiscible melt mixed blends of a crystallisable polyolefin (isotactic polypropylene, PP) and atactic polystyrene (PS) were prepared in a wide composition range. It was found that when PP is the major component in the blend its crystallisation behaviour is not affected by blending it with PS. However if PP is the minor component, it will be dispersed in the immiscible PS matrix, hence the nucleation mechanism changes from predominantly heterogeneous to predominantly homogeneous as long as the size of the dispersed PP droplets is below a critical value (of the order of 1–2 μm).
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    Polymer bulletin 32 (1994), S. 529-536 
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    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary New types of epoxy compounds containing biphenyl and azophenyl groups were synthesized. Model glycidyl ethers with one epoxy group were prepared to study the first reaction steps during the curing process. Diglycidyl ethers with or without a hexamethylene spacer were made to obtain epoxy networks. The structures of some intermediates and of the epoxy compounds synthesized were confirmed by Proton and Carbon-13 NMR spectroscopy.
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    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary A novel initiator, i.e. trimethylsilylmethyllithium has been successfully used for the ring opening polymerization of cyclosiloxanes, in toluene or in the bulk, in the presence of the cryptand [211] or DMSO. Suitable conditions have been found in which monomodal distributions of molecular weights are observed for homopolymers of 1,3,5,7-tetramethyl-1,3,5,7-tetravinylcyclotetrasiloxane (V4) as well as for copolymers of V4 with D3 or D4.
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    Polymer bulletin 32 (1994), S. 1-2 
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    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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    Notes: Summary Methylalumoxane (MAO)-activated rac-[1,2-bis(η5-(9-fluorenyl))-1-phenylethane]zirconium dichloride (1) was used for propene polymerization at 30, 50, and 70°C and constant monomer concentration. The polypropene products are isotactic with stereoregularities depending on the polymerization temperature. The pentad distributions follow “enantiomorphic site statistics”, indicating stereocontrol being conducted by the chiral catalyst site.
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    Polymer bulletin 32 (1994), S. 125-126 
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    Polymer bulletin 33 (1994), S. 389-395 
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    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary A satisfactory synthesis route to a new monomer, the 3-chloro-4-nitrostyrene (3-CNS) is described. The results of free radical polymerisation experiments (limit of conversion, global kinetics) are reported by comparison with those of the isomer 4-chloro-3-nitrostyrene (4-CNS). They show the great influence of the nitro group position which markedly increases the reactivity of 3-CNS.
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    Polymer bulletin 33 (1994), S. 431-438 
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    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary Poly(β-hydroxy nonanoate)-polystyrene graft copolymers were prepared by the reaction of active polystyrene containing peroxide group with poly(β-hydroxy nonanoate) at 80°C. Graft copolymers with a wide graft composition range depending on the amount of active polystyrene in the original mixture were produced and separated from the grafting product by fractional precipitation. NMR and IR spectra of the graft copolymers were containing the characteristic bands of the corresponding blocks. DSC curves of the graft copolymers had a large endotherm between 50 and 110°C.
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    Notes: Summary The isothermal crystallization kinetics of the isotactic content of three poly(1-hexadecene) samples with different tacticity has been studied by real-time small-angle X-ray scattering using synchrotron radiation. The process was analyzed in terms of the Avrami equation. The value of the Avrami exponent was found to be approximately 1, suggesting instantaneous nucleation followed by rod-like growth. The results are compared with those previously obtained by differential scanning calorimetry.
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    Polymer bulletin 32 (1994), S. 367-371 
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    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary In the present work we report the results of the polymerization of styrene using diphenylzinc-butanone, Ph2Zn-MeCOEt. Our results indicate that these systems induce the polymerization of styrene reaching a larger conversion when the molar ratio MeCOEt/Ph2Zn=1,0. According to size exclusion chromatography, SEC, studies of the polystyrene obtained using the Ph2Zn-MeCOEt showed unimodal curves and have molecular weight distribution narrower than those obtained using the Ph2Zn-H2O system, suggesting a more simple reaction system.
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    Notes: Summary Fast atom bombardment mass spectrometry (FAB-MS) has been used to identify oligomers with different end groups obtained by the carbonate interchange reaction of bisphenol-A with dimethyl carbonate and the partial methanolysis of poly(bisphenol-A carbonate)s. Based on the FAB-MS data, a reaction pathway for the formation of compounds in the synthesized oligomers is proposed.
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  • 81
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    Notes: Abstract A series of semi-interpenetrating polymer networks (semi-IPN's) based on different compositions of an acyclic polyethylene terephthalate oligomer and unsaturated polyester resin (UP) were prepared. The oligomer was dissolved in the resin containing styrene crosslinker. Later this mixture was crosslinked at room temperature using methyl ethyl ketone peroxide catalyst and cobalt naphtanate as promoter. The tensile strength of the IPN's decreases as the concentration of oligomer increases, whereas, elongation to break increases. A characterization of the oligomer used is also presented.
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    Polymer bulletin 32 (1994), S. 479-485 
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    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary The impact properties of 1:1 polyolefin-polystyrene blends compatibilised with a series of hydrogenated styrene-butadiene block copolymers of various structures have been studied with a view to establishing a structure-property realationship. The most effective compatibiliser in this context appears to be a low molecular weight triblock (Kraton G1652). Addition of only 5% Kraton G1652 affords a ca. three-fold improvement in the impact strength for a 1:1 PP/PS blend over the uncompatibilised blend and leads to near HIPS impact strength for a 1:1 LDPE/PS blend. This compatibiliser is as effective as a high molecular weight tapered diblock and appears to be substantially more effective than either low molecular weight diblocks or a higher molecular weight triblock.
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  • 83
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    Notes: Summary In the copolymerizations of 1-chloro-1-octyne (ClOc) and 1-chloro-2-phenylacetylene (ClPA) with norbornene (NBE) by MoCl5-n-Bu4Sn in toluene at-20°C, both comonomers were consumed simultaneously. The GPC curves of the copolymerization products were unimodal and identical irrespective of the RI and UV (290 nm) detectors. The13C NMR spectra of the products exhibited the presence of cross-propagating sequences. From these results, it is concluded that the copolymerization products are copolymers and not mixtures of homopolymers. The monomer reactivity ratios were: rClOc=0.69, rNBE=6.4; rClPA=1.0, rNBE=3.1. The more electron-donating the ring substituent of CiPA, the more reactive the ClPA in copolymerization with NBE.
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    Polymer bulletin 32 (1994), S. A5 
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    Notes: Summary Polymerization of 1-phenyl-2-(p-phenoxyphenyl)acetylene (p-PhODPA), 1-phenyl-2-(p-methoxyphenyl)acetylene, and 1-phenyl-2-(p-n-butoxyphenyl)acetylene was examined. These monomers polymerized with TaCl5-n-Bu4Sn to give methanol-insoluble polymers in over 60% yields. Poly(p-PhODPA) was a yellow solid completely soluble in toluene, CHCl3, etc., and its weight-average molecular weight was about 1.0x106 or higher. This polymer was thermally very stable (the onset temperature of weight loss in TGA in air was 420 °C). Its oxygen permeability coefficient (P o 2) was 37 barrers (P o 2/P n 2 2.2) and similar to that of natural rubber. In contrast, the other two polymers did not completely dissolve in any organic solvent, and their thermal stability was lower.
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    Polymer bulletin 32 (1994), S. 141-147 
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    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary Chelating polymers obtained by copolymerization of methacryl-oylmalodiethylester (MMDEt) with styrene, methylmethacrylate (MMA), N-vinylpyrrolidone (VPD) and N,N-dimethylacrylamide (DMAM) as well as the homopolymer of methacryloylmalodiethylester (MMDEt) have been investigated. Watersoluble chelating polymers derived from copolymerization with DMAM offer not only the possibility of a very fast removal of metal ions from aqueous solution, but are also insoluble after complexing certain metal ions and can therefore be separated by filtration. As additional investigations on the model acetyloylmalodiethylester (AMDEt) show, preferably hard metal ions such as Mg2+, Ca2+, Al3+ and Cu2+ with an ionic radius up to 1 Å are chelated by the enolic form of the β-ketodiester. The number of ligands for a metal ion corresponds to its valence.
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    Polymer bulletin 32 (1994), S. 207-214 
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    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary The 300 MHz 1H-NMR spectrum of free radical initiated poly(3-bromostyrene) is similar to the 1H-NMR spectra of certain poly(vinyl heterocycles) and can be interpreted in a like manner. The 13C-NMR is typical of spectra for meta-substituted polystyrenes, with some of the carbon resonances showing a sensitivity to polymer stereochemistry. The spectra indicate that poly(3-bromostyrene) synthesized by free radical initiation is an atactic polymer.
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    Notes: Summary Thermal molecular motion of a series of comb-shaped polymers with heptadecafluorodecyl side chains (CF 8C2-) has been studied based on dynamic viscoelastic measurement. The main chain of comb-shaped polymers was poly(fumarate), poly(methacrylate), and poly(acrylate). Poly(fluoroalkylfumarate) with heptadecafluorodecyl group, P(CF 8C2-iPF) was amorphous polymer, whereas poly(acrylate) and poly(methacrylate) with CF 8C2-, P(CF 8C2-Acr) and P(CF 8C2-MAcr) showed mesomorphic behavior. The pervaporation behavior of water/organic mixtures through amorphous polymer, P(CF 8C2-iPF), and mesomorphic one, P(CF 8C2-Acr), were investigated. The distinct increase in permselectivity has been observed at the mesomorphic transition of P(CF 8C2-Acr).
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    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Sammary New donor-acceptor substituted diarylacetylene hyperpolarizable chromophores bearing an amino group as donor and a methylsulfonyl group as acceptor at each extremities of an azatolane conjugated path have been designed to get a good nonlinearity-transparency trade-off, and synthesized. Corresponding methacrylate esters have been obtained then submitted to free radical polymerization, leading to novel side-chain nonlinear optical polymers and copolymers.
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  • 90
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    Polymer bulletin 32 (1994), S. 241-248 
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary An attempt is made to extend the model of Leibler for the emulsifying activity and interfacial properties of A-b-B diblock copolymers in incompatible blends of the homopolymers A and B-which are identical with the respective copolymer components- to enthalpically interacting C-b-D diblock copolymers, the block C being thermodynamically compatible with A and D with B. Due to the attractive enthalpic interaction the A/C-b-D/B compatibilized blends are promising for optimum phase adhesion (bold types for thermodynamically compatible partners). Thus, the extended model for a plane interfacial layer includes the enthalpic interaction of the compatible polymer pairs beside the entropic effects. The approach starts with the equillibrium supposition, not taking into consideration enthalpy driven migration effects of the block copolymer from the bulk to the interface, The model confirms a dominant role of the enthalpic interaction between blocks of the diblock copolymer and the respective homopolymers to the compatibilization of incompatible blend components. It is applicable also for blends compatibilized with block copolymers of unfavourable repulsive type interaction, A/C-b-D/B, and for blend systems with mixed type interactions, e. g. A/C-b-B/B or A/C-b-D/B.
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  • 91
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary Poly(2-thienyl vinyl ketone) was synthesized via free radical initiation and its 300 H-NMR and 75.5 MHz 13C-NMR spectra were recorded and analyzed. The analysis showed that poly(2-thienyl vinyl ketone) is an atactic polymer.
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  • 92
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary Poly(2-fluoro-1,4-phenylenevinylene), PFPV, and its copolymers have been synthesized via water soluble precursor route and their electrical and optical propreties were measured. It seems that electron-withdrawing fluorine substituent on phenylene ring increases the band-gap of PFPV and it affects electrical and optical properties. The conductivity values of FeCl3-doped drawn polymer films ranged from 10-1 to 101 Scm-1 depending on their composition, and were 10 times larger than those of undrawn ones. The χ(3) value for undrawn PFPV, using THG technique at 1907nm fundamental wavelength, was 4.76x10-12 esu.
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  • 93
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary A simple method for using differential scanning calorimeters to determine the crystallinity of syndiotactic polystyrene has been developed. Its validity was confirmed by use of infrared and x-ray analysis, as well as comparison to data from the literature. This method will be used to determine the effect of nucleating agents, shear stress, and temperature on the crystallization kinetics of syndiotactic polystyrene.
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  • 94
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    Polymer bulletin 33 (1994), S. 175-182 
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary Polyether-modified fullerenes have been prepared under mild conditions by reacting C60 or C70 in toluene with a precursor poly(oxyethylene) or poly(oxypropylene) polymer possessing amino end-groups. In the early stages of the interaction, soluble products are formed. Later, cross-linking proceeds between the polyfunctional fullerenes and the bifunctional polyethers. The non-crosslinked fullerene derivatives are soluble both in toluene and water; by evaporation of toluene, very adhesive films are formed.
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  • 95
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary Poly(sodium alkyl 2-hydroxy-3-methacryloyloxypropyl phosphate)s as polysoap induced the radical polymerization of methyl methacrylate and styrene in the absence of an added radical initiator in water at 80°C. The polysoap having a C14 alkyl group showed the highest activity of all tested groups. The generalized initiation mechanism of the spontaneous polymerization in which the micellar aggregation state participates is discussed.
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  • 96
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary Racemic ((3S,4R)-(3R,4S))-3-methyl-4-benzyloxycarbonyl-2-oxetanone has been prepared by a simple and reproductible method starting from a racemic mixture of threo-((2S,3S)-(2R,3R))-3-methylaspartic acid as chiral precursor. This α, β substituted β-lactone has been polymerized anionically, using tetraethylammonium benzoate as initiator, to yield high molecular weight and amorphous racemic threo-poly(β-benzyl-3-methylmalate). The catalytic cleavage of protecting benzyl ester groups has been conducted in different solvents and racemic threo-poly(β-3-methylmalic acid) has been obtained in N-methylpyrrolidone at room temperature. Racemic threo-poly(β-3-methylmalic acid-co-benzyl-β-3-methylmalate) has been prepared by heterogeneous H2/Pd charchoal catalyzed partial hydrogenolysis of the polymer precursor. Solubility of these different materials has been considered. Hydrolysis of threo-poly(β-3-methylmalic acid) has conducted to racemic threo-3-methylmalic acid. High resolution 13C NMR and selective INEPT NMR have been used for resonances assignment of polymers and copolymers. This new poly(β-hydroxy acid) type polyester expands the family of poly(β-malic acid) derivatives by opening the route for tailor making functional polystereoisomers with two stereogenic centers in the main chain and with the presence of an hydrophobic alkyl group and an hydrophilic carboxylic acid group in the macromolecule.
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  • 97
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    Polymer bulletin 33 (1994), S. 229-235 
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary The dependence of intensity of surface enhanced Raman scattering on the concentration of poly (4-vinyl pyridine) solutions was investigated. The spectral quality and the Raman scattering intensities of the enhanced spectra of poly (4-vinyl pyridine) adsorbed on nitric acid-roughened silver foil were inversely proportional to the concentration when it changed from semi-dilute to very dilute. The band intensity-concentration plot displays a turning point corresponding to the critical concentration for coil shrinkage. The observed phenomena are in accordance with Qian's proposal for the existence of C s for coil shrinkage in dilute solution.
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  • 98
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    Polymer bulletin 33 (1994), S. 257-257 
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 99
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    Polymer bulletin 32 (1994), S. 629-635 
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary The unconventional liquid chromatography of polymers under limiting conditions of their solubility was applied to poly(methyl methacrylate)s differing in their tacticity. The polymers were dissolved in thermodynamically good solvents and injected into an appropriate size exclusion chromatographic (SEC) column flushed with matched, moderately strong nonsolvents. The set of (limiting) conditions was found under which less soluble syndiotactic poly(methyl, methacrylate) moved along the column together with the zone of its initial solvent while better soluble isotactic poly(methyl methacrylate) was eluted according to the SEC mechanism. This indicates the potential of liquid chromatography under limiting conditions to characterize the tacticity of poly(methyl methacrylate)s.
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  • 100
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    Polymer bulletin 32 (1994), S. 675-678 
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary Dynamic mechanical properties of poly(dimethylphenyl methacrylátes) were studied considering the different positions of the methyl groups on the phenyl ring. In all cases a clear α relaxation can be observed which is associated to the polymer glass transition temperature (Tg). Nevertheless, at lower temperatures, viscoelastic activity is negligible. A correlation between the steric hindrance due to the methyl groups and the temperature at which the relaxation is detected, was established.
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