Publication Date:
2011-06-10
Description:
Purpose The USEtox model was developed in a scientific consensus process involving comparison of and harmonization between existing environmental multimedia fate models. USEtox quantitatively models the continuum from chemical emission to freshwater ecosystem toxicity via chemical-specific characterization factors (CFs) for Life Cycle Impact Assessment (LCIA). This work provides understanding of the key mechanisms and chemical parameters influencing fate in the environment and impact on aquatic ecosystems. Materials and method USEtox incorporates a matrix framework for multimedia modeling, allowing separation of fate, exposure, and ecotoxicity effects in the determination of an overall CF. Current best practices, such as incorporation of intermittent rain and effect factors (EF) based on substance toxicity across species, are implemented in the model. The USEtox database provides a dataset of over 3,000 organic chemicals, of which approximately 2,500 have freshwater EFs. Freshwater characterization factors for these substances, with a special focus on a subset of chemicals with characteristic properties, were analyzed to understand the contributions of fate, exposure, and effect on the overall CFs. The approach was based on theoretical interpretation of the multimedia model components as well as multidimensional graphical analysis. Results and discussion For direct emission of a substance to water, the EF strongly controls freshwater ecotoxicity, with a range of up to 10 orders of magnitude. In this release scenario, chemical-specific differences in environmental fate influence the CF for freshwater emissions by less than 2 orders of magnitude. However, for an emission to air or soil, the influence of the fate is more pronounced. Chemical partitioning properties between water, air, and soil may drive intermedia transfer, which may be limited by the often uncertain, media-specific degradation half-life. Intermedia transfer may be a function of landscape parameters as well; for example, direct transfer from air to freshwater is limited by the surface area of freshwater. Overall, these altered fate factors may decrease the CF up to 8 orders of magnitude. Conclusions This work brings new clarity to the relative contributions of fate and freshwater ecotoxicity to the calculation of CFs. In concert with the USEtox database, which provides the most extensive compilation of CFs to date, these findings enable those undertaking LCIA to understand and contextualize existing and newly calculated CFs. Content Type Journal Article Pages 1-9 DOI 10.1007/s11367-011-0294-6 Authors Andrew D. Henderson, Department of Environmental Health Sciences, School of Public Health, University of Michigan, 109 South Observatory, Ann Arbor, MI 48109, USA Michael Z. Hauschild, Department of Management Engineering, Technical University of Denmark, Produktionstorvet, Building 424, 2800 Lyngby, Denmark Dik van de Meent, Department of Environmental Science, Radboud University Nijmegen, P.O. Box 9010, 6500 GL Nijmegen, The Netherlands Mark A. J. Huijbregts, Department of Environmental Science, Radboud University Nijmegen, P.O. Box 9010, 6500 GL Nijmegen, The Netherlands Henrik Fred Larsen, Department of Management Engineering, Technical University of Denmark, Produktionstorvet, Building 424, 2800 Lyngby, Denmark Manuele Margni, CIRAIG, École Polytechnique de Montréal, P.O. Box 6079, Stn. Centre-ville, Montreal, QC H3C 3A7, Canada Thomas E. McKone, University of California Berkeley, and Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, CA 94720, USA Jerome Payet, Cycleco, 1011 av. Leon Blum, 01500 Amberieu, France Ralph K. Rosenbaum, Department of Management Engineering, Technical University of Denmark, Produktionstorvet, Building 424, 2800 Lyngby, Denmark Olivier Jolliet, Department of Environmental Health Sciences, School of Public Health, University of Michigan, 109 South Observatory, Ann Arbor, MI 48109, USA Journal The International Journal of Life Cycle Assessment Online ISSN 1614-7502 Print ISSN 0948-3349
Print ISSN:
0948-3349
Electronic ISSN:
1614-7502
Topics:
Energy, Environment Protection, Nuclear Power Engineering
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Economics
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