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  • 1
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Science Ltd.
    Fatigue & fracture of engineering materials & structures 21 (1998), S. 0 
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: In order to clarify the effect of the atmospheric conditions on fatigue damage, rotary bending fatigue tests were carried out on smooth specimens of a normalized 0.37% carbon steel in controlled laboratory air. The air conditions used in the tests were moist air at 20 °C, moist air at 35 °C and dry air at 35 °C. The influence of atmosphere on crack initiation and propagation behaviour was investigated in detail based on successive observations of the surface. Experimental results showed that the fatigue life was superior at 20 °C compared to 35 °C by a factor of 2, while the effect of moisture was small compared to that of temperature. The statistical investigation of crack initiation and propagation behaviour indicated that the temperature strongly affects the crack initiation process; conversely, moisture plays an important role in the propagation process of cracks smaller than 0.3 mm. Moreover, the distribution characteristics of crack initiation life, crack propagation life, fatigue life and crack growth rate were analysed by assuming either a Weibull distribution or a log-normal distribution.
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  • 2
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Science Ltd.
    Fatigue & fracture of engineering materials & structures 21 (1998), S. 0 
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: This paper deals with the effect of anisotropy on fracture processes of a directionally solidified superalloy, Mar-M247, under a push–pull creep-fatigue condition at high-temperature. Three kinds of specimen were cut from a cast plate such that their axes possess angles of 0°, 45° and 90° with respect to the 〈001〉 orientation that is aligned parallel to the solidification direction (also to the grain boundaries and primary dendrite axis); these specimens being denoted the 0° specimen, the 45° specimen, and the 90° specimen, respectively. The tests were conducted at 1273 K (1000 °C) in air under equal magnitudes of the range of a ΔJ-related parameter, ΔWc , which represents the driving force for crack growth in creep-fatigue. Although the grain boundaries are macroscopically parallel to the solidification direction, they are wavy or serrated microscopically. Small cracks nucleate along parts of the grain boundaries perpendicular to the stress axis in all specimens. The 90° specimen has the shortest crack initiation life and the 0° specimen has the longest. In the 90° and 45° specimens, intergranular cracks continue to nucleate and a main crack is formed along the grain boundary due to the frequent coalescence of small cracks. In the 0° specimen, cracks grow into the grain, and transgranular cracks coalesce along the primary dendrite or grain boundary. The 0° specimen exhibits the slowest crack growth rate and the 90° specimen the fastest. These differences in the initiation and growth behaviour of small cracks cause the longest failure life in the 0° specimen and the shortest in the 90° specimen.
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  • 3
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Science Ltd.
    Fatigue & fracture of engineering materials & structures 21 (1998), S. 0 
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: This paper presents the results of recent studies of the micromechanisms of room temperature fatigue damage elucidated in a metastable beta Ti–15V–3Cr–3Al–3Sn alloy. The fatigue damage mechanisms observed include: grain boundary sliding, crack initiation/propagation, and crack coalescence prior to the onset of catastrophic failure. Mechanistically based models are presented for the prediction of fatigue damage (plasticity and cracking). The models are based on fracture mechanics idealizations of the complex damage modes observed during fatigue experiments, in which acoustic emission signals were collected from deformed sections. Following appropriate noise filtration and careful analysis of the detected acoustic emission signals, the number of counts due to cracking is shown to represent a scalar measure of damage. A modified power law expression (modified Paris law) is also proposed to describe the relationship between the cracking count rate and the effective stress intensity factor. Estimates of the fatigue lives are obtained by integrating between appropriate limits, after the separation of variables in the modified Paris law expression. The measured and predicted fatigue lives were generally in good agreement.
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  • 4
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Science Ltd.
    Fatigue & fracture of engineering materials & structures 21 (1998), S. 0 
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A life prediction model that was originally developed for the axial loading of unidirectional metal matrix composites (MMCs) undergoing combined thermal and mechanical loading is extended to the axial loading of cross-ply MMCs by adding an internally initiated matrix fatigue damage term. This new term accounts for the growth of cracks that initiate at the location where fibre–matrix separation occurs in the transversely-oriented plies. A comparison of the model predictions to experimental data on SCS-6/Timetal 21S shows that the model reasonably accounts for the dependence of applied stress, temperature and environment, as well as cyclic frequency. The dominant damage accumulation process for cross-ply MMCs with weak fibre–matrix bonds is described by this internally initiated matrix fatigue damage process for most stress–temperature cycle combinations. However, the fibre-dominated damage accumulation process operates under in-phase TMF when both stress and temperature are high. Environment-enhanced matrix fatigue is the dominant damage accumulation process under isothermal fatigue when stress is low and temperature is high.
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  • 5
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Science Ltd.
    Fatigue & fracture of engineering materials & structures 21 (1998), S. 0 
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The continued airworthiness of ageing aircraft and long-term durability of new airframes depends, in part, on the integrity of adhesive bonds used for repairs and joining structural components. Additionally, the advent of composite materials and advanced repair techniques incorporating composites has increased the number of adhesively bonded joints specified for use in aerospace structures. Traditionally, adhesive bonds have been analysed and designed using a dependable and rigorous stress-based approach. However, the need to address the effect of bondline flaws and to understand the fatigue characteristics of bonded joints has led to the adoption of a discipline already common in the design of metallic components—fracture mechanics. To understand the durability of bonded structures, however, it is further necessary to examine the effect of environmental exposure on the performance of the adhesive bondline. Familiarity with the stress-based and fracture mechanics analytical approaches, as well as an understanding of environmentally induced trends in bond performance is paramount to quality design. This paper will briefly discuss the attributes of the two main forms of bonded joint analysis, and will broadly outline a design approach that uses fracture mechanics and accounts for environmental effects. Experiments discussed in this paper were performed specifically to use fracture mechanics in assessing the environmental effects on a toughened epoxy adhesive. Results indicate that the Mode I fracture toughness and fatigue crack growth threshold of this adhesive are significantly reduced upon exposure to a high temperature, high humidity aircraft service environment. These results will be used to illustrate the philosophical arguments supporting the design approach.
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  • 6
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Science Ltd.
    Fatigue & fracture of engineering materials & structures 21 (1998), S. 0 
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: This paper investigates the scatter inherent in the early stages of fatigue life. A probabilistic fatigue model is proposed which relates the microstructural heterogeneity to the scatter in crack nucleation life. The crack nucleation life is defined as the number of cycles necessary to develop a crack with a length equal to the grain size. The model assumes homogeneity at the level of the grain size. A fracture mechanics-based microstructural model is used to describe the response of the grains. The primitive random variables which drive crack nucleation are identified and recent developments recorded in the literature are used to describe their statistical characteristics. First order reliability methods are used to predict the statistical distribution of fatigue crack nucleation life. Comparisons are made with trends in experimental observations.
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  • 7
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Science Ltd.
    Fatigue & fracture of engineering materials & structures 21 (1998), S. 0 
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The aim of this paper is to present a high cycle multiaxial fatigue life prediction method for metallic materials based on Papadopoulos’ previous works and limited to constant amplitude loading. The initiation process of a crack is treated as a mesoscopic phenomenon taking place on a scale of the order of a grain or a few grains. The damage variable chosen is the accumulated plastic strain at this mesoscopic scale. Its estimation requires a macro-meso passage and the location of the plane subjected to maximum damage. Initiation is achieved as soon as a critical value of the accumulated plastic mesostrain is reached in these grains, so-orientated that their easy glide directions coincide with a particular direction of the critical plane. The detrimental effect of out-of-phase loading on damage accumulation is taken into account through a newly defined coefficient estimated from mechanical loading parameters; no adjustable parameter is required. A good agreement has been found between the predicted and experimental results for in-phase and out-of-phase sinusoidal constant amplitude loadings by examining a large amount of experimental data.
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  • 8
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Science Ltd.
    Fatigue & fracture of engineering materials & structures 21 (1998), S. 0 
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Critical plane approaches are useful methods when designing against long-term fatigue of machine components made from metals. Somewhat surprisingly, the very basic problem of the evaluation of the amplitude and mean value of the shear stress acting on the critical plane is still not resolved satisfactorily for non-proportional cyclic loading conditions. In the present paper, existing proposals for solving this problem are briefly reviewed and their weaknesses highlighted. Then it is shown, through particular examples, that application of these proposals can lead to ambiguous results. Therefore, new definitions of the amplitude and mean value of the shear stress acting on the critical plane are formulated here. These new definitions are free from any ambiguity because they are based on the construction of the unique minimum-circumscribed circle to the path described by the shear stress on the critical plane. The centre of this circle defines the mean shear stress, whereas its radius provides the corresponding shear stress amplitude. The algorithm yielding this minimum-circumscribed circle is presented in some detail.
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  • 9
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Science Ltd.
    Fatigue & fracture of engineering materials & structures 21 (1998), S. 0 
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Fatigue tests were carried out on a shipbuilding-grade rolled steel, prestrained to various degrees up to 85% of its static tensile fracture strain. It is observed that prestraining degrades the fatigue life in the domain of low-cycle fatigue, but this effect is not apparent in the medium-to-high cycle fatigue regime. A set of equations has been developed to assess the behaviour of tensile prestrained materials for the entire range from low-to-high cycle fatigue. The data acquired in this study validate the authenticity of these formulae sufficiently well.
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  • 10
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Science Ltd.
    Fatigue & fracture of engineering materials & structures 21 (1998), S. 0 
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Metal matrix composites are increasingly utilized in engineering applications because of their favourable strength/weight ratio. However, their applications are still limited because of their relatively poor fatigue resistance, which could be improved by using some appropriate surface treatment. In this paper, an Al/Al2 O3 (20%) composite material is considered. In particular its fatigue strength is examined to verify if, how and when shot peening can be used to improve the performances of MMC components that are cyclically loaded. Fatigue tests allow one to evaluate the influence of shot peening on the fatigue limit of both smooth and notched specimens. Residual stress measurements, fracture surface analyses and metallographic examinations allow one to evaluate the role of residual stresses, hardening and grain distortion on the improvement that can be achieved with this treatment. On the basis of these results, some guidelines are drawn on how to optimize the choice of peening parameters.
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  • 11
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Science Ltd.
    Fatigue & fracture of engineering materials & structures 21 (1998), S. 0 
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Detailed numerical analyses are conducted to examine the effect of material elasticity and non-linear shape changes on void growth in viscoplastic solids. Numerical simulations are carried out under constant stress as well as cyclic loading conditions. The material response is assumed to be elastic-non-linear viscous (power law creep). Analyses of void growth are conducted assuming creep-controlled mechanism. The role of finite geometry changes in understanding cavity growth under balanced strain-controlled cyclic loading is also explored. The results indicate that while elastic accommodation does not influence void growth, non-linear shape changes of the voids significantly affect their growth characteristics. It is also shown that while grain boundary voids can grow under balanced strain cyclic loading when the accompanying shape changes are accounted for, they can either shrink or grow under load-controlled cycling depending on the loading frequency.
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  • 12
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Science Ltd.
    Fatigue & fracture of engineering materials & structures 21 (1998), S. 0 
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The brittle nature of concrete is a reflection of its low toughness and the presence of defects. One effective way to enhance the toughness of concrete is by fibre reinforcement. Synthetic fibres, mostly polypropylene, have been widely used as a concrete additive at 1% or less volume fraction for toughness enhancement and shrinkage control. Pull-out of fibres bridging a concrete matrix crack absorbs a significant amount of energy. This paper reviews some of the fracture mechanics approaches to the prediction of failure of fibre-reinforced concrete structures, methods used to rank the toughness of fibre-reinforced concrete, toughness optimization, and the properties of concrete reinforced with selected synthetic and recycled fibres.
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  • 13
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Science Ltd.
    Fatigue & fracture of engineering materials & structures 21 (1998), S. 0 
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: This paper examines the use of a neural network to model the chaotic behaviour of the growth of short fatigue cracks which are characterized by a decreasing crack growth rate with increasing crack length. Fatigue crack growth is modelled in terms of the Hobson short fatigue crack growth law. The neural network is exclusively trained and tested on Hobson’s experimental data of short fatigue cracks propagating in a 0.4% carbon steel. The empirical constants d, α and C of Hobson’s growth law are determined from the neural network predictions and are found to be within the following approximate ranges 63 〈 d 〈 400 (μm), −0.27 〈 α 〈 0.08 and 1 × 10−4 〈 C 〈 509 × 10−4 with no proportional relationship observed between the constant C and the applied cyclic stress. It is shown that neural networks are a viable computational tool for modelling the chaotic behaviour of short fatigue crack growth.
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  • 14
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Science Ltd.
    Fatigue & fracture of engineering materials & structures 21 (1998), S. 0 
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The fatigue crack growth resistance of a [0/90°]2s cross-ply SCS6 fibre-reinforced Ti–6Al–4V alloy metal-matrix composite has been assessed under displacement range control (i.e. under load shedding conditions with crack extension) to investigate potential fibre degradation and the process of crack extension at room temperature, and at 450°C, in air and in vacuum. Attention is focused on initial conditions that will promote crack arrest at room temperature. Under the test conditions employed here, regions of crack growth can occur where the applied nominal stress intensity factor range (ΔK) is relatively constant. This ‘constant’ΔK range is the result of a fortuitous balance between the particular test-piece geometry, loading conditions utilized, matrix crack growth and the rate of fibre fracture. It allows the influence of environment, cyclic frequency and temperature on fatigue crack growth resistance to be analysed more easily than for tests carried out under load control.The crack growth rate remained almost constant but with some steep local retardations in growth rate in the constant ΔK region at a temperature of 450°C, while crack arrest occurred at room temperature for the same initial ΔK. The average crack propagation rate in this ‘constant ΔK region’ at a temperature of 450°C in air was much greater than that at a temperature of 450°C in vacuum. This indicates that environment plays an important role in the process of fibre degradation. The effect of cyclic frequency is saturated at a frequency of less than 1 Hz. The process of crack growth at various frequencies is also discussed.
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  • 15
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Science Ltd.
    Fatigue & fracture of engineering materials & structures 21 (1998), S. 0 
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The role of free-edge stresses in controlling the initiation of failure from the interface corner of a scarf joint subjected to a uniform change in temperature is examined. In general, the stress field can be expressed by σij = Hrλ−1 + σij0 , where r is the radial distance from the interface corner, λ − 1 is the order of the stress singularity, H is the intensity of the singularity, and σij0 is a non-singular constant stress. A combination of the finite element method and a path-independent integral is used to evaluate the magnitude of H for two joint configurations: (i) a scarf joint between two long bi-material strips; and (ii) a scarf joint consisting of a thin elastic layer sandwiched between two substrates. The magnitude of H is linearly dependent on a non-dimensional constant function a; the magnitude of a decreases with increasing level of mismatch in the elastic properties of the bonded materials. A comparison between the values of H evaluated by the path-independent integral method and the commonly used extrapolation method indicate that the extrapolation method could be in error by as much as 25%.
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  • 16
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Science Ltd.
    Fatigue & fracture of engineering materials & structures 21 (1998), S. 0 
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Tensile and low-cycle fatigue tests were performed on a 316LN austenitic stainless steel at 300 and 77 K. The tensile and low-cycle fatigue properties were obtained and analysed in terms of the influence of temperature on the plastic deformation process and the formation of strain-induced martensite. The martensite content was evaluated using measurements of magnetic saturation. No α′-martensite was detected at 300 K under either monotonic or cyclic straining. On the contrary, at 77 K, strain-induced martensitic transformation is responsible for the higher elongation in tension and the secondary hardening observed on hardening/softening curves in low-cycle fatigue. The induced martensite content in tensile tests is a function of strain which deviates from Angel’s model. In low-cycle fatigue, it is a function of the strain level and the accumulated plastic strain. At a given total strain amplitude, the decrease of temperature from 300 to 77 K results in the decrease of plastic strain amplitude and homogenization of plastic strain distribution, and thus in the prolongation of fatigue life. The cyclic over-stress at 77 K, due to an intermediate ageing at 300 K, is related to pinning of initially free dislocations resulting from nitrogen diffusion during isothermal holding at room temperature. This results in a reduced fatigue life.
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  • 17
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Science Ltd.
    Fatigue & fracture of engineering materials & structures 21 (1998), S. 0 
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Simulations of the nucleation of dislocations, glide and annihilation ahead of a fatigue crack growing along a localized slip band (a ‘long’ Stage I crack or a Stage II crack with a K value close to the threshold) are performed for the case of push–pull or reversed torsion loadings, ignoring, in a first approach, the effect of grain boundaries. The crack growth rates are deduced from the dislocation flux at the crack tip. An influence of the normal stress on the friction between the crack flanks as well as on the condition for dislocation emission is introduced. A slower Stage I growth rate is then predicted for reversed torsion, consistent with experimental data.
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  • 18
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Science Ltd.
    Fatigue & fracture of engineering materials & structures 21 (1998), S. 0 
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Fractographic features related to fatigue growth in a titanium alloy Ti–6Al–3Mo–2Cr were examined in compressor disks that had failed in service. In-flight block cyclic loading that included hold-time loading and variable amplitudes of vibrational loading produced fracture characteristics which mainly reflected the two-phase (α + β) lamellar structure of the titanium alloy and contained localized areas of fatigue striations.Blocks of cyclic loads which included cycles of hold-time loading during the testing of disks resulted mainly in the formation of fatigue striations with no evidence of the lamellar microstructure of the titanium alloy. An analytical equation Vi = [(1 − ν2 )/(16  π  E  σ0.2 )][Ke ]2i is suggested to describe the relationship between the crack propagation rate, V, and the equivalent stress intensity factor, Ke , as applied to the semi- and then to the quarter-elliptical-shaped cracks. Fractographic features are discussed and the disks’ fatigue crack growth behaviour over 50 flights is demonstrated.
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  • 19
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Science Ltd.
    Fatigue & fracture of engineering materials & structures 21 (1998), S. 0 
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: An expression for the cumulative failure probability of a structure is proposed for cyclic loading conditions. This expression is dependent on an initial flaw distribution and a microcrack propagation law. Two sets of experiments were carried out on specimens made of spheroidal graphite cast iron. These specimens are tested under cyclic tension with two different load ratios. The initial flaw distribution is experimentally identified from microscopic observations. The crack propagation law parameters are identified from experimental results obtained with a load ratio R = 0.1. The expression for the failure probability is then used to predict experimental data obtained with a load ratio R = −1.
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  • 20
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    Electronic Resource
    Oxford, UK : Blackwell Science Ltd.
    Fatigue & fracture of engineering materials & structures 21 (1998), S. 0 
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The usefulness of simple sheet and plate specimens is discussed for various experimental research purposes. Specimens should be representative, as much as possible, of the conditions of fatigue problems in practice, which is more difficult to achieve for the fatigue crack initiation phase than for macro-crack growth. In many cases, small specimens can not be recommended because of insufficient similarity to the conditions of the engineering structure. Larger specimens have advantages for measurements of crack length and crack closure. The compact tension specimen and a recently proposed derivative are asymmetric specimens, while the middle crack specimen, central notch specimen and double-edge notch specimen are symmetric. The latter specimens should be preferred for experimental reasons as well as for reasons of a better similarity to the conditions of practical fatigue problems. A significant disadvantage of the asymmetric specimens is the high gradient of the stress intensity factor (dK/da).
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  • 21
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    Oxford, UK : Blackwell Science Ltd.
    Fatigue & fracture of engineering materials & structures 21 (1998), S. 0 
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A new class of large, high-speed seagoing ferry-boat is under development for service around the world. The ships, which are built entirely of aluminium-alloy plate and stiffeners, show a propensity for fatigue cracking of the welded structure. Cracks may occur in both the hulls and the superstructure early in their 20-year service life. Early appearance of fatigue cracks is shown to result from the combined stress and strain fields set up in weld zones by the static residual stresses and cyclic loads, beyond the effects of weld and detail geometry. A numerical example demonstrates that conventional methods of fatigue analysis overestimate the lifetime of the welded aluminium structure, while damage tolerance analysis based on fracture mechanics leads to improved prediction.
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  • 22
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    Oxford, UK : Blackwell Science Ltd.
    Fatigue & fracture of engineering materials & structures 21 (1998), S. 0 
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: It is well known that the tearing resistance curve J–Δa is not a material property and that probably the energy dissipation rate is preferable to the integral J to characterize crack growth. The G parameter represents the energy dissipated in plasticity and fracture and, under certain conditions, this parameter could be used directly as a critical value for a criterion based on an energy release rate calculated near the crack tip to simulate propagation. Indeed, we see that a local energy release rate could be calculated near the crack tip to take account only of that portion of energy which participates in the fracture.We applied this approach to simulate the crack growth for CT specimens with and without side grooves in a 20 MnMoNi 55 ferritic steel, and compared the results with Rousselier’s model.
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  • 23
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    Oxford, UK : Blackwell Science Ltd.
    Fatigue & fracture of engineering materials & structures 21 (1998), S. 0 
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: .The fatigue crack growth (FCG) behaviour of the aluminium–lithium (Al–Li) alloy 2090-T84 has been investigated from a series of constant amplitude FCG tests. The influence of in-plane orientation (L–T, T–L, L–T + 45°) and sheet thickness (1.6 and 6 mm) on the FCG rates for the rolled product has been examined. In general, the T–L orientation possesses superior FCG resistance for both thicknesses and the 6 mm thick sheet material showed marginally improved FCG resistance when compared to the 1.6 mm thick material, for all orientations. Closure-corrected FCG data suggests that much of the difference between the L–T and T–L orientation for the 6 mm thick sheet arises from differences in crack closure levels. When comparing the crack closure levels for C(T) and M(T) specimens, a significant difference is shown as ΔK increases. Fatigue crack growth rates for ΔK less than 15 MPa m were significantly higher in the M(T) specimens compared to the C(T) specimens. Compared with other factors examined the influence of specimen geometry appears to be a dominant factor.
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  • 24
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    Oxford, UK : Blackwell Science Ltd.
    Fatigue & fracture of engineering materials & structures 21 (1998), S. 0 
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The effect of microstructure on the fatigue properties of Ti–6Al–2.5Mo–1.5Cr alloy was investigated. The experimental results for both the fatigue crack initiation and propagation behaviour, as well as the dynamic fracture toughness (KId ) showed clearly that a lamellar microstructure is superior to two other structures. It was found that, as in the case of steels, the initiation and subsequent growth of cracks in the titanium specimens with a sharp notch may also occur on loading levels below the threshold values of the K factor (ΔKth ) determined for long fatigue cracks. In addition, measurements by interferential-contrast of the plastic zone size on the surface of specimens revealed that the different rate of crack growth at identical values of ΔK in individual structural states can roughly be correlated with the size of the plastic zone. A general relationship between the fatigue crack growth rate and plastic zone size, the modulus of elasticity and the role of crack tip shielding is discussed.
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    Fatigue & fracture of engineering materials & structures 21 (1998), S. 0 
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Based upon experimental short fatigue crack growth data and adopting the Brown–Hobson model, new crack growth equations have been derived in an attempt to describe more precisely short fatigue crack growth behaviour that separates the physically small crack regime from the long crack regime. An empirical model for physically small crack growth was developed by employing elastic–plastic fracture mechanics parameters.By considering the proposed approach to short fatigue crack modelling, a new second ‘microstructural’ threshold condition has been established using only short fatigue crack growth data. In the case of fatigue in an aggressive environment it is suggested that three transition (threshold) conditions can be identified representing: (i) a stress-assisted pitting/pit-to-crack transition; (ii) a microstructurally short shear crack/physically small tensile crack transition; and (iii) a physically small crack/long crack transition.A comparison of this approach with that of existing models has been made, and predictions of total fatigue lifetime using the model have been presented. A reasonable agreement has been observed between predicted and experimental crack growth rates.
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  • 26
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    Fatigue & fracture of engineering materials & structures 21 (1998), S. 0 
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Stress-corrosion cracking (SCC) involves the interaction between stress and the environment to cause cracking in situations where if present independently their effect would be benign. SCC involves mechanics through the role of stress and the material through its interaction with the environment. SCC has occurred in many engineering structures, generally without expectation that a specific combination of material and environment would produce such cracking. This paper discusses SCC and the development of models to quantify its effect on the life of structures—outlining both the approach and inherent complications due to the coupled mechanics and materials issues. This development is illustrated with reference to characterizing the initiation and early growth of SCC as it occurs on gas-transmission pipelines. The discussion closes with consideration of failure criteria for use in this application, which involves the coalescence of several cracks with the rather complex patches of cracks that occur with SCC in this application. Areas needing further attention are identified.
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  • 27
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    Fatigue & fracture of engineering materials & structures 21 (1998), S. 0 
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    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Conditions for adaptation of isotropically damaged elastic–plastic bodies with isotropic strain hardening are investigated in the framework of the energy-based coupled elastic–plastic damage model by Ju. The yield function is assumed to be a homogeneous function of the first order in the stress tensor components. Due to this assumption, the notion of effective yield stress can be introduced. The loading program is supposed to be prescribed. Features of the stress path at the post-adaptation stage are considered, which lead to new necessary shakedown conditions expressed by a set of inequalities, and, in turn, to a problem of mathematical programming whose solution yields lower estimates for the damage and strain-hardening parameters. In the event, if the calculated value of the damage parameter is greater than its critical value, an adaptation to a given loading program is impossible. This condition is also necessary for adaptation in the case if only bounds for applied loads are prescribed. A correction of the constitutive material model is proposed which possibly could be good for ductile damage. The derived shakedown condition is not only necessary, but also sufficient for the plastic adaptation. The developed method is expounded in an example.
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    Fatigue & fracture of engineering materials & structures 21 (1998), S. 0 
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    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Interconnect lines are thin wires inside microelectronic circuits. The material in an interconnect line is subjected to severe mechanical and electrical loading, which causes voids to nucleate and propagate in the line: microelectronic circuits often fail because an interconnect is severed by a crack. Many of the mechanisms of failure are believed to be associated with diffusion of material through the line; driven by variations in elastic strain energy and stress in the solid, by the flow of electric current, and by variations in the free energy of the solid itself. With a view to modelling interconnect failures, we have developed a finite element method that may be used to compute the effects of diffusion and deformation in an electrically conducting, deformable solid. Our analysis accounts for large changes in the shape of the solid due to surface diffusion, grain boundary diffusion, and elastic or inelastic deformation within the grains. The methods of analysis is reviewed in this paper, and selected examples are used to illustrate the capabilities of the method. We compute the rate of growth of a void in an interconnect by coupled grain boundary diffusion and creep; we investigate void migration and evolution by electromigration-induced surface diffusion; we study the influence of electromigration and stress on hillock formation in unpassivated interconnects, and compute the distribution of stress and plastic strain induced by electromigration in a passivated, polycrystalline interconnect line.
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  • 29
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    Fatigue & fracture of engineering materials & structures 21 (1998), S. 0 
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: In the analysis of a multilayered composite laminate with an arbitrarily shaped delamination, accurate non-linear laminate analysis is required to obtain the kinematic and kinetic variables which characterize the local state of deformation at a generic point of the delamination front. These variables provide the strain/curvature parameters and the boundary tractions for the local analysis model of a multimaterial region containing an interfacial crack. The singular elasticity solution in the vicinity of the crack tip is obtained by an eigenfunction expansion, where the coefficients of the eigenfunctions are evaluated by boundary collocation. The accuracy of the present solution is indicated by the computed energy release rate, which is in close agreement with the result based on path-independent integrals.
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    Fatigue & fracture of engineering materials & structures 21 (1998), S. 0 
    ISSN: 1460-2695
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The Ct parameter has proven very useful in correlations of creep crack growth behaviour under both transient and steady state creep conditions. In this paper, we investigate the implications of adopting a different definition of the creep zone based on an absolute measure of creep strain rather than a measure that is relative to the elastic strain. The analytical equations for small-scale creep and transition times from small-scale creep to extensive creep conditions are derived for the Ct parameter using this alternative definition, considering both primary and secondary creep strain. It is shown that this alternative definition gives a reasonable starting point for the theory, approximately in accordance with the transient evolution of the Ct parameter based on the more conventional definition of the creep zone, and removes the somewhat artificial limit of applicability imparted by the classical creep zone definition used in creep fracture mechanics. Accordingly, diffusional creep processes with a power law exponent n ≤ 3 are admitted in the Ct description.
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    Fatigue & fracture of engineering materials & structures 21 (1998), S. 0 
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Ceramic (Si3 N4 /SiC) composites have been produced by sintering. From the sintered block, three point bend specimens were cut out. A semi-circular crack was made on the centre of the tension surface of the test specimen with the aid of a Vicker’s indenter. The diameter of the semi-circular crack was about 60–70 μm. The specimens were subsequently heat treated at 1300°C for 1 h in vacuum, nitrogen or air. The bending strength was measured at room temperature, 800 and 1000°C. The specimens heat treated in air recovered considerably their bending strength at 1000°C, several specimens failed at a location different from the healed crack and their average strength showed the same value of that for smooth specimens. From these results, it is concluded that the recovery in bending strength of a cracked specimen was caused by crack healing.
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    Fatigue & fracture of engineering materials & structures 21 (1998), S. 0 
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The fatigue strength of spot-welded stainless sheet steels has been investigated. The main part of the fatigue tests was performed on a cold rolled austenitic stainless sheet steel (AISI304) in air at ambient temperature. For comparison, a duplex stainless steel (SAF2304) of similar yield strength as AISI304 was also incorporated into the test programme. Since the fatigue strength of spot-welded joints depends on the mode of loading, both shear-loaded and peel-loaded joints were tested. The fatigue strength of the spot-welded stainless steels was found to decrease with decreasing sheet thickness. Furthermore, the fatigue strength for peel-loaded joints is lower than that of shear-loaded joint for sheets of equal thickness.The local loading conditions at the weld edge have been analysed in terms of finite element calculations and fracture mechanics. A design parameter derived from a fracture mechanics analysis was defined for spot-welded stainless sheet steels. It was shown to predict the fatigue life of the present steels and joint configurations in a satisfactory way.
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    Fatigue & fracture of engineering materials & structures 21 (1998), S. 0 
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A theoretical technique is developed for determining both KI and KII from influence functions for angled edge cracks subjected to arbitrary distributions of normal and tangential contact stresses. Numerical results are presented which indicate the effect of crack length and crack angle on four influence functions, from which KI and KII can be readily determined for specified distributions of tangential or normal contact stresses. In order to illustrate the use of the influence functions, a worked example is presented which shows the variation of KI and KII with crack length and crack angle calculated for an assumed parabolic distribution of tangential stress under a fretting pad. Corresponding values of KI and KII for other distributions of tangential and normal stresses may be determined by the same simple summation techniques used in this report.
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  • 34
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    Fatigue & fracture of engineering materials & structures 21 (1998), S. 0 
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    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: This paper deals with the initiation and growth of small cracks in a directionally solidified superalloy, Mar-M247.
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    Fatigue & fracture of engineering materials & structures 21 (1998), S. 0 
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A new multiparameter approach is proposed for the prediction of the combined effects of multiple variables on fatigue crack growth. The method, which is based on multiple linear regression analysis, involves the statistical formulation of mathematical expressions for the crack growth rate, da/dN, as a function of multiple variables, e.g. stress intensity factor range, ΔK, crack closure stress intensity factor, Kcl , and stress ratio, R. A general empirical approach is proposed for the estimation of the fatigue crack growth rate as a function of the above variables. The predictive capability of the empirical approach is then verified by comparing predicted and measured fatigue crack growth and crack growth rate data obtained from tests on a quenched and tempered Q1N (HY80) pressure vessel steel. Error ranges and reliability functions are presented within a probabilistic mechanics framework, and the implications of the results are discussed for the development of generalized fatigue life prediction methods.
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    Fatigue & fracture of engineering materials & structures 21 (1998), S. 0 
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: This paper discusses the fracture prevention aspects of lifetime prediction. Initially, it is pointed out that lifetime can be determined by factors such as obsolescence and consumer rejection. Lifetime is then related to acceptable risk in order to make it compatible with advances in design philosophy for large welded structures.Accident statistics are cited and the argument made that the major opportunities for lifetime improvement are revealed by failure analysis, and are shown to lie in design and production. However, there are some structures, e.g. boilers and pressure vessels, where the construction rules are so well established that failures occur mainly because of operational errors.Based on the results of the Battelle/NBS Cost of Fracture Study, attention is focused on the effect of material–property reproducibility in driving failure probability. Little evidence could be found regarding reproducibility improvements of fatigue lifetime and brittle fracture toughness in production lots of alloys over time.
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    Fatigue & fracture of engineering materials & structures 21 (1998), S. 0 
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Titanium Matrix Composites (TMCs) are envisioned for use in the next generation of advanced aircraft and their engines. To ensure a smooth transition to industry, fatigue life prediction methodologies, which can account for random variations in mechanical and thermal loads, must be developed. To facilitate the development of such a model, fatigue testing has been conducted at Georgia Tech. on [0/ ± 45/90]s and [90/ ± 45/0]s laminates of SCS-6/Timetal 21S. The tests were done at temperatures of 400, 500 and 650 °C, with hold times of 1, 10 and 100 s superimposed at the maximum stress. The purpose of the tests was to separate the effect of time-dependent deformation from the effect of environmental degradation. Using the results of these tests, and results generated at NASA–Lewis Research Center (LeRC) and the US Air Force’s Wright Laboratory, a model has been developed which is based on the stress in the load-carrying fibres. The stress is modified by an effective stress concentration factor that is due to matrix cracking and a factor that includes the effect of hold times. It is a single term model that is intended for treating any variations in mechanical and thermal loads. Verification of this model is achieved by predicting fatigue lives for specimens subjected to spectrum loads performed at NASA–Langley Research Center (LaRC) and vacuum tests completed at Georgia Tech. The model is compared to five methodologies previously developed for life prediction, and is shown to have significantly better predictive power while reducing the number of empirical constants and curve fitting parameters necessary to collapse the data.
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    Fatigue & fracture of engineering materials & structures 21 (1998), S. 0 
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The development of shear bands in a class of materials with inhomogeneous and composite microstructures is analysed using dynamic finite element calculations. The analysis is based on experimental studies of the deformation localization and constitutive behaviour of tungsten composites having two-phase microstructures consisting of hard tungsten grains and a soft alloy metal matrix. The calculations concern the effects of variations in microstructures on the resistance of the materials to shear banding. Specifically, three variations from the currently used microstructure are considered: (1) the alteration of the matrix phase to one that has a lower thermal conductivity; (2) the introduction of an interfacial layer between the grains and the matrix which limits microscopic heat exchange between the phases by having a low thermal conductivity; and (3) the modification of the matrix to one having a lower strength at high temperatures, but otherwise the same thermal and mechanical properties as the nickel–iron–tungsten matrix currently used in many tungsten composites. Numerical results show that the introduction of the low-conductivity interfacial layer significantly enhances the formation of shear bands and reduces the overall flow stress of the composite throughout the deformation. On the other hand, accelerated thermal softening of the matrix phase at high temperatures expedites localization in later stages of deformation while allowing the material to maintain a strong stress–strain response in the early part of the deformation. The results point out possible directions for the improvement of advanced composites in applications where the localization of deformation plays an important role.
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    Fatigue & fracture of engineering materials & structures 21 (1998), S. 0 
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: It was just 40 years ago that some of us became aware that the methods of Irwin’s ‘Fracture Mechanics’ could be applied to fatigue crack growth. After the first 10 years of establishing that approach, many things were known which impact this Symposium’s theme of prediction of structural life.In the subsequent 30 years to the present, the Fracture Mechanics approach applied to life prediction has often been misused, or has ignored obvious characteristics which effect the precision and relevance of the predictions. This paper will emphasize some of these areas for improvements, which have been too often overlooked in practical applications. Some of the overlooked areas are:(1) the misuse of crack propagation laws in life prediction;(2) the modelling of crack shape effects in life calculations;(3) the neglect of significant statistical effects and considerations for particular applications.In conclusion, it is argued that life prediction methodology should be tailored to the application, rather than vice versa, which has all too often been the case. Keywords—Crack growth; Fatigue; Fracture mechanics; Life prediction; Load interaction; Statistical effects.
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    Fatigue & fracture of engineering materials & structures 21 (1998), S. 0 
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Results of an experimental investigation of the fatigue growth of small corner cracks emanating from small flaws are presented. Growth-arrest behaviour was observed, and increases in crack length during growth periods were of the order of the transverse grain size. For the test material, the corner crack front intersects, on average, only three–six grains in the small crack regime monitored, so only a small number of constrained, interior grains is encountered. It is suggested that the presence of partially constrained surface grains may contribute to the ‘anomalous’ growth behaviour which has been observed by a number of investigators.The crack growth histories of the test data presented exhibit considerable scatter. It is shown that a Student’s t-test can be used to estimate confidence intervals in order to provide a measure of the observed scatter. The variation in confidence intervals in the transition from small to long fatigue crack growth is discussed.
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    Fatigue & fracture of engineering materials & structures 21 (1998), S. 0 
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Understanding the physical bases of a cracked sample’s macroscopic response to applied loading, e.g. fatigue crack closure, requires non-destructive, microscopic quantification of the crack face separations as a function of applied load. Ideally, these measurements should cover the entire crack face. Non-destructive sectioning with high resolution X-ray computed tomography has been used for in situ observations of the crack faces under applied load in samples of Al–Li 2090, and in this paper, the crack openings that were measured in the interior of the sample are related to crack face geometry and to changes in the slope of load–displacement curves. The implications of these results are discussed for physically based crack closure modelling.
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    Fatigue & fracture of engineering materials & structures 21 (1998), S. 0 
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The objective of this paper is to develop a micromechanics model for the onset and subsequent multiplication of transverse cracks in the 90° layers of a cross-ply laminate under uniaxial tension. The micromechanics study of transverse matrix cracking is performed by a combination of finite element and analytical analyses. Based on the Griffith fracture criterion, the evolution of transverse matrix crack density is predicted. The prediction compares well with existing experimental data in the literature. Analytical expressions of the non-linear effective stress–strain curves are also obtained for a wide range of material systems. In addition, an analytical expression of the effective stiffness is derived based on the differential self-consistent method. The analytical results agree very well with the finite element calculations.
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The effect of the load ratio, R, on fatigue crack growth behaviour is analysed on the basis of the recently proposed inelastic discrete asperities model. A wide range of load ratios, both positive and negative, are examined. Particular emphasis is placed on compressive excursions, i.e. negative R loadings. The inelastic discrete asperities model is a micro-mechanical analysis based on the plastic crushing of a single asperity (or multiple asperities) located on the crack face close to the crack tip and under dominantly plane strain conditions. Experimental data have indicated that the primary crack face contacts which obstruct closure are immediately adjacent to the crack tip, although segments of the crack face more distant from the crack tip are not neglected. However, the more distant asperities are a part of the past crack advance history which does not influence current behaviour. By use of this model, it is shown that the effect of the load ratio can be adequately predicted once some baseline information on mechanical material properties and surface roughness is provided. The model also provides useful trend information and explains many of the observed phenomena, e.g. the ‘saturation’ of the compressive underload effects. For a constant applied nominal stress intensity factor range, ΔKnom , it is shown that the effective stress intensity factor range, ΔKeff , initially decreases as the positive R decreases (corresponding to the increasing influence of closure), reaches a minimum around R = 0, and then starts increasing with negative R (corresponding to the plastic crushing of the asperities which reduces closure), eventually reaching a saturation level below ΔKnom . Conversely, for an assumption of a constant ΔKeff , the applied ΔKnom increases as the positive load ratio decreases, reaching a maximum around R = 0, and then decreases with more negative R values, eventually reaching again a saturation level (above ΔKeff ). It is also shown that the effect of material hardness can be directly analysed based on this model.
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: In order to ascertain the validity of creep strength reduction factors for welds in real components, creep tests were performed at 600 °C on large specimens made of welded 316 L (N) stainless steel plates. Manual Metal Arc (MMA) welds as well as Tungsten Inert Gas (TIG) welds were investigated. The overall, and in some cases, local deformations of the weld were recorded. The experimental results were compared with two-dimensional, and in some cases, three-dimensional finite elements computations using the creep behaviour of the materials as determined by testing small standard specimens. The times to rupture were compared with predictions from design codes and other simplified engineering methods.
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Stress intensity factors for semielliptical surface cracks emanating from a circular hole are reported in this paper. The three-dimensional weight function method with three-dimensional finite element solutions for the uncracked stress distribution is used for the analysis. Two different loading conditions, i.e. remote tension and wedge loading, are considered for a wide range of geometrical parameters. Both single and double surface cracks are studied and compared with other solutions available in the literature. Typical crack opening displacements are also provided.
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Fatigue tests were performed on a spheroidal graphite cast iron in four point plane bending under constant stress amplitude and block loading conditions. The microstructure of this material has a ll’s eyes’ appearance, i.e. the spheroids of graphite are surrounded by ferrite and these nodules and ferrite zones are included in a pearlitic matrix. Scanning electronic microscope observations were carried out at different fractions of life for constant stress amplitude loadings above and below the conventional endurance limit. Non-propagating micro-cracks were observed at a stress level equal to the conventional endurance limit. These observations showed that another limit can be defined below the conventional endurance one, i.e. one below which micro-cracks were not observed to initiate in the matrix. These cracks were found to arrest at the ferrite/pearlite interface when the material was tested below this new limit. This concept was used to rationalize fatigue results from tests with loading in blocks above and below the conventional endurance limit.
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A modelling procedure was developed which is applicable to crack growth in notched components subjected to multiaxial fatigue for materials with different microstructures. An algorithm for crack growth, in a microstructure that was modelled as hexagons, was established as a competition between growth by crack linkages during the crack initiation and propagation stages and the propagation of a dominant crack as a single crack. Analytical results simulated by using the developed model were compared with experimental results from fatigue tests which had been conducted using notched specimens of pure copper, carbon steel and two kinds of titanium alloy. Cracking morphology, which was experimentally observed to depend on the microstructure and the loading mode, was well simulated using the present model. The fatigue failure life of a notched specimen was statistically estimated by a Monte Carlo procedure based on the model. The simulated life with a statistical scatter-band almost coincided with the experimental data.
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Crack growth histories for creep-brittle aluminium alloy 2519-T87 are simulated by controlling the rate of release of finite element nodes along the crack growth path using a variable time-step, nodal release algorithm. While earlier experimental studies established little or no correlation between time-dependent fracture parameters and the crack growth rate, a˙, during creep-brittle fracture, the numerical results presented here indicate excellent correlation of the Ct parameter with a˙ during the quasi-steady state crack growth regime. Differences in the experimental and numerical determination of time-dependent fracture parameters are likely to be due to difficulties in experimental determination of the creep component of the load line deflection rate, V˙c , during creep-brittle crack growth. A new quantity, K/rqc, is derived from time-dependent fracture parameters to predict crack growth for transient, quasi-steady state and steady state crack growth. However, Ct and K/rqc should only be employed as parameters for predicting creep-brittle crack growth with an understanding of the couplings which exist between these parameters and the crack growth rate.
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    Fatigue & fracture of engineering materials & structures 21 (1998), S. 0 
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Interactive creep–fatigue behaviour of a nickel-base superalloy (IN 597) has been examined at 850 °C under various strain-limited, cyclic torsional loading conditions. In one test, forward creep deformation was reversed by creep under equal magnitude stress levels and strain limits. In other tests, forward creep strain was reversed by fast monotonic plasticity with and without a subsequent period of relaxation. These cycles were repeated within each test until fracture. This paper examines empirically the influence of a number of test variables upon cyclic creep curves, and demonstrates the usefulness of predictions based upon continuous low cycle fatigue and simple creep data when used in conjunction with a mechanical equation of state. A cyclic equilibrium condition was not achieved from these tests. Instead, a progressive softening occurred giving reductions to the amount of creep strain, creep time interval and reversed peak stress with each new cycle. Such reductions are expressed from derived formulae that embrace the range of inelastic strain, cycle number, creep dwell stress, reversed peak stress, and times expended in creep and relaxation.Observations made on accumulated creep strain reveal the contribution to a creep–fatigue fracture from cyclic creep. This has led to a modified form of the linear damage rule which can provide conservative life predictions for components operating in service under similar cyclic conditions.
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  • 50
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    Fatigue & fracture of engineering materials & structures 21 (1998), S. 0 
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Large marine structures can be subjected to extensive localized damage, with strains reaching 10 times the yield strain. Small defects might propagate, and accurate defect assessment is required for safe operation. To simulate this problem, J-integrals have been computed for semielliptical cracks in wide steel plates under tension. Three-dimensional (3D) elastic–plastic finite element analysis was used to model shallow crack geometries with 0.2 ≤ a/c ≤ 0.57 and 0.05 ≤ a/t ≤ 0.15. The material responses were linear elastic followed either by power hardening, or perfect plasticity and power hardening. It was found that, in contrast to previous studies on single edge notch geometries, the material law does not have a major influence on the J–strain behaviour. Results obtained from the 3D analyses form the basis for the development of a J-based estimation scheme.
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  • 51
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    Fatigue & fracture of engineering materials & structures 21 (1998), S. 0 
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A criterion has been formulated for transcrystalline and intercrystalline fracture caused by the evolution of voids located both in a grain and on grain boundaries. The criterion is based on the idea of plastic collapse for a unit cell that is a regular structural mezovolume of polycrystalline material. The criterion does not require the introduction of any empirical parameters, such as critical void size, critical size of ligament between voids and critical void volume fraction, which are used in most models.Modelling has been performed for void nucleation and growth in a grain and on grain boundaries for elastic–plastic deformation and under creep conditions. A scheme is proposed to describe the transition from transcrystalline to intercrystalline cavitation fracture as a function of strain rate and temperature.The effect of stress triaxiality on the critical strain and the lifetime for both transcrystalline and intercrystalline fracture has been investigated. A comparison of the results predicted by the suggested criterion with available empirical data has been performed.
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  • 52
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    Polymer bulletin 36 (1996), S. 745-752 
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary Acrylamide/itaconic acid (AAm/IA) hydrogels prepared by irradiating with γ radiation were used in experiments on the adsorption of some cationic dyes such as basic red 9 (BR 9), basic green 4 (BG 4), cresyl violet (CV), and basic blue 20 (BB 20). Adsorption of the cationic dyes onto AAm/IA hydrogels is studied by batch adsorption technique. In the experiments of the adsorption, Langmiur type adsorption in the Giles classification system was found. Monolayer coverages for AAm/IA hydrogel-dye systems were calculated by using B point method. Adsorption studies indicated that monolayer coverages of AAm/IA hydrogel by these dyes were increased with following order; BB 20〉CV〉BR9〉BG 4.
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  • 53
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    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary Styrene was polymerized using combined systems of diphenylzinc, Ph2Zn, and metallocene compounds activated by methylaluminoxane, MAO. From the various metallocenes employed bis (indenyl) zirconium dichloride, Ind2ZrCl2, [isopropyl (cyclopentadienyl) (1-fluorenyl)] zirconiumdichloride, i-Pr (Flu) (Cp) ZrCl2, and bis (cyclopentadienyl) titanium dichloride, Cp2TiCl2, produced the larger amounts of polymer. Ph2Zn-Cp2TiCl2-MAO system gave polystyrene, PSt, whose DSC analysis indicated a major endotherm peak at 256°C. A butanone insoluble fraction of the polymer was separated from the crude PSt. The proportion of insoluble polymer depends on the metallocene employed and on the conversion to polymer.
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  • 54
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    Polymer bulletin 37 (1996), S. 29-33 
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary Polymerization of propylene was carried out at 0°C in the presence of methyl methacrylate(MMA) or ethyl benzoate(EB) using rac-Et(Ind)2ZrMe2 or rac-Me2Si(Ind)2ZrMe2/Ph3CB(C6F5)4 as catalyst, which resulted in highly isotactic poly(propylene) with [mmmm]〉98%, Tm=160–161°C and very few 1,3- or 2,1 regioirregular units. With the use of an achiral zirconocene Cp2ZrMe2, a polymer with Tm=139°C was resulted as well. Base on these experimental fact that the zirconocene can form a C1-symmetrical complex with a Lewis base.
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  • 55
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    Polymer bulletin 37 (1996), S. 21-28 
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary By using γ-butyrolactone (γ-BL) as the reaction media, highly active catalysts--light rare earth chloride-epoxidy-γ--BL-for the solution polymerization of ε-caprolactone, have been obtained for the first time. With these catalyst, PCL with molecular weight as his as 40x104(Mv) can be prepared at 60°C for 1.5 hr. The amount of epoxide in catalyst solution, catalyst aging temperature and time affect the catalyst activity significantly. The mechanism study shows that in γ-BL, the weakening of Ln-Cl bonds by the donation of coordinated γ-BL with Ln3+ and the homogenous effect promote the reaction between light rare earth chloride and epoxide. The produced rare earth alkoxide initiates CL polymerization via a ‘coordination-insertion’ mechanism with Acyl-oxygen bond cleavage.
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  • 56
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    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary Triethoxysilane groups were covalently attached onto the surface of ethylene-vinyl alcohol (EVOH) copolymer film via a urethane linkage through reaction between the hydroxyl groups in EVOH and 3-isocyanatopropyltriethoxysilane in the presence of dibutyltin dilaurate as catalyst. This reaction was confirmed by ATR-IR and XPS analysis. XPS results also indicated that this reaction was not surface sensitive and the modified layer was at least 40 Å in depth. The modified film samples were further reacted with tetramethoxysilane (TMOS) for partial hydrolysis and condensation and XPS results showed a significant increase in the contents of oxygen and silicone on the surface which confirmed the above reaction.
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  • 57
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    Polymer bulletin 37 (1996), S. 59-65 
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary The title monomer was synthesized from the corresponding aldehyde via a Wittig reaction. The monomer was polymerized using free radical initiation and its high field 1H- and 13C-NMR spectra were recorded. When analyzed in terms of stereochemistry the spectra showed poly(6-vinyl-1,4-benzodioxane) is an atactic polymer when synthesized via free radical initiation.
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  • 58
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    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary A resin containing 4-vinylpyridine and 2-acrylamidoglycolic acid was synthesized by radical polymerization with subsequent crosslinking by N,N′-methylene-bis-acrylamide. The resin was characterized by elemental analyses and FT-IR spectroscopy. The ability of this resin as well as both crosslinked homopolymers to bind Cu(II), Fe(II), Fe(III) and U(VI) was studied at different pHs depending on the metal ion. From pH=2 U(VI) was sorbed above 96% from an aqueous solution of 1.0 g/L. A dual sorption mechanism to U(VI) depending on the pH is suggested. The elution of the metal ions from the loaded resins was assayed with H2SO4 and Na2CO3.
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  • 59
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    Polymer bulletin 37 (1996), S. 199-206 
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary The photopolymerization of four analogous monomers: 2,2′-thiobisethanol diacrylate and its dimethacrylate plus 2,2′-oxybisethanol diacrylate and its dimethacrylate has been studied by isothermal differential scanning calorimetry (DSC) over a range of incident light intensities. The results obtained prove that the sulfide group accelerates polymerization both in the presence and absence of oxygen and enhances the conversion. The light intensity exponents for each monomer were determined and the mechanism of termination was discussed. The intensity exponents of sulfur-containing monomers are lower than their corresponding oxygen analogues, pointing to a greater participation of the bimolecular termination during their polymerization.
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  • 60
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    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary Photoinitiated methyl methacrylate-ethylene glycol dimethacrylate (MMA/EGDM) copolymerization has been investigated in toluene at a monomer concentration of 35 w/v %. Diphenyl-2,4,6-trimethylbenzoylphosphine oxide (DPTPO) was used as a photoinitiator at 0.3 wt% concentration. Monomer conversions and the size distribution of the polymer molecules were measured as a function of the reaction time up to the onset of macrogelation. Compared to the photoinitiators benzoin or benzoin derivatives, gelation process proceeds at much higher rates in the presence of DPTPO. The size distribution curves obtained by size-exclusion chromatography (SEC) change from monomodal to bimodal distributions as the polymerization proceeds. Strongly bimodal SEC curves were obtained in the close vicinity of the gel point. This finding confirms the coagulation type gelation mechanism of compact primary particles. It also indicates that the present gelation theories cannot describe the structure dependent kinetics of free-radical crosslinking copolymerization.
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  • 61
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    Notes: Summary FT-Raman spectroscopy of commercial amorphous and crystalline nylon 6–12 filaments subjected to various γ-radiation doses are presented. The results show that a difference exists in the interaction of γ-radiation with these polyamides, depending on the crystallinity which can be evaluated by measuring the CH-stretching/CH-bending Raman band intensity ratio as a function of applied γ-dose.
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  • 62
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    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract Solid-state 13C NMR spectroscopy involving magic angle spinning (MAS) techniques with and without cross-polarization was employed for interaction studies in natural rubber (NR)/EVA and NR/mercapto-modified EVA (EVASH) blends. From arrayed of variable contact time spectra, the proton T1ϱ values were determined at short contact times to analyze the EVA or EVASH domains and longer contact times to investigate the interactions in the NR domains. Substantial changes have been observed when dicumyl peroxide was employed as curing agent in NR/EVASH and NR/EVA/EVASH blends.
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  • 63
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    Polymer bulletin 37 (1996), S. 229-235 
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary Thermogravimetric analysis (TGA) has been shown to be a useful technique to determine the content of starch and other components that are usually present in blends of starch with synthetic polymers. However, some of these blends are composed of elements with an important superposition in their temperature degradation range. In these cases interpretation of the TGA results becomes quite difficult and usually important errors are committed in the determination of blend composition. We present here a method to improve the accuracy of the interpretation of TGA data. The analysis was developed to study blends containing starch, an ethylene-vinyl alcohol copolymer, and water plus glycerin as plasticizers. Using this procedure it is possible to predict blend composition with an error less than 3%, even when there is an appreciable superposition between the temperature degradation range of starch and poly(ethylene-co-vinyl alcohol). As the proposed method of analysis is quite general it may be extended to be used with other types of blends that give thermograms with similar characteristics to those described in this paper.
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  • 64
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    Notes: Abstract The synthesis of polysulfone-polydimethylsiloxane (PSU-PDMS)linear block copolymers has been carried out in solution by condensation of chloro-terminated bisphenol A, diphenylsulfone and α, ω-di (hydrogensilyl)-polydimethylsiloxane with Si−C bond. 1H-NMR spectra of the block copolymers allow the estimation of siloxane and polysulfone ratio. The molecular weight of the polysulfone and polysiloxane oligomers and the block copolymers was determined by GPC. Thermogravimetric analysis indicates a thermal stability of block copolymers up to 400°C and allows estimation of the process activation energy. Microphase separation of the block copolymers was observed by differential scanning calorimetry (DSC).
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  • 65
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    Notes: Summary Aim of this work was to study the effectiveness of a novel oxazoline-functionalized polypropylene as a compatibilizer for PP/PBT and PP/PA6 blends. This polypropylene-based compatibilizer mixes well with the polypropylene and is capable of reacting with the carboxylic and amine end groups of PBT and PA6. Significant improvements in blend toughness were achieved without reduction in strength and stiffness. These effects were related to stabilized morphology of finely dispersed minor phase well attached to the matrix. The enhanced interfacial interactions between the two phases, in particular at high PBT content were evidenced by increased melt viscosity.
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  • 66
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    Polymer bulletin 37 (1996), S. 361-367 
    ISSN: 1436-2449
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    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary The polyamides with aromatic rings in the main chain were synthesized by the solution polymerization of 4,4′-diphenylmethane diisocyanate and aliphatic dicarboxylic acid in the presence of catalyst. The thermal properties and the miscibility behaviours with polyamide-6,6 of these aromatic polyamides were studied. The aromatic polyamides synthesized with one kind of dicarboxylic acid had typical thermal properties of crystalline polymers, whereas those synthesized with the mixtures of dicarboxylic acids were not easily crystallized. The observed miscibility behaviours showed some differences from those predicted by binary interaction model.
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    Polymer bulletin 37 (1996), S. 369-376 
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    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary A series of aryl-aliphatic polyamides, copoly(4,4′-diaminobenzanilide-adipamide/2,6-naphthalamide)s, with feed mole ratios of adipic acid/2,6-naphthalene dicarboxylic acid of 1/9, 3/7, and 5/5 were synthesized. A new family of molecular composites based on the synthesized aryl-aliphatic polyamides and nylon 6 has been discovered. The molecular composites were found to have at least partial miscibility between aryl-aliphatic polyamides and nylon 6. Well-defined aryl-aliphatic polyamide microfibrils a few nanometers in diameter were observed in the molecular composites. 10 wt% aryl-aliphatic polyamide clearly promoted the toughness of nylon 6.
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    Polymer bulletin 37 (1996), S. 377-383 
    ISSN: 1436-2449
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    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary A new type of coordination polyurethane was prepared by incorporating the transition metal ions into the pyridine containing thermoplastic polyurethane films. Then the metal ions dispersed in the polyurethane matrix were reduced by controlling the exposure of the metal sites to NaBH4 under mild condition. The reduction of the polyurethane metal complex films resulted in the production of amorphous ultrafine metal powders. The size of these powders was controlled by the content of the metal ions and the polarity of the polymer matrix. A polar polymer backbone and lower metal ion concentration favored to achieve a smaller particle. It was also found that the polymer chains prohibited the excessive aggregation of the metal atoms and have protective effect on the final metal powders.
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  • 69
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    Notes: Summary Crack-tip deformation has been investigated in pre-cracked samples of core-shell rubber particle modified epoxy resins with different degrees of crosslinking. Light cross linking resulted in cavitation of the modifier, the formation of croids and extensive crack-tip yielding, whereas these deformation mechanisms were suppressed at room T in highly crosslinked specimens. A zone of particle debonding was observed in these latter at high T, but this appeared detrimental to the toughness. Indeed it was possible to increase the toughness in this case by oxygen plasma treatment of the modifier particles.
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  • 70
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    Notes: Summary An initiator for living free radical polymerization may be prepared by trapping the benzylic ethylbenzene radical with the stable 2,2,6,6-tetramethylpiperidinyl-1-oxy (TEMPO) radical. The adduct, 2,2,6,6-tetramethyl-1-(1-phenethyloxy)piperidine (TMPEP), smoothly undergoes thermal fragmentation at temperatures approaching 140° C to afford an active carbon radical capable of initiating polymerization and a passive mediating nitroxyl radical to reversibly cap and preserve the propagating polymer chain.
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  • 71
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    Notes: Summary Association processes of D-fructose dehydrogenase (FDH) onto surfaces of liposomes which were composed of N-(5-dimethylamino-1-naphthalenesulfonyl)-L-α-dimyristoylphosphatidylethanolamide and L-α-dimyristoylphosphatidylcholine or L-α-dimyristoylphosphatidylglycerol (1:9) were investigated by the fluorescence stopped-flow technique. The association processes were divided into two relaxation processes: the faster process whose apparent rate constant monotonously increased with the concentration of FDH, and the slower process whose rate constant showed a saturation behavior. Taking the number of binding sites on the liposome surface into consideration, the corrected association rate constant of the faster process was 4.4% of the theoretical value for a binary collision, probably due to a disadvantageous surface-searching and dehydration processes on the liposome and protein surfaces. The Arrhenius plots of the rate constants both for the faster and slower steps showed a discontinuous change around the gel to liquid-crystal phase transition temperature of the liposomes. Strong influences of deformability of liposomes, and state of hydrating water molecules around polar heads, on the rate of association processes were suggested.
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    Polymer bulletin 37 (1996), S. 423-428 
    ISSN: 1436-2449
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    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary Copolymers with 2-aceto-1,3-phenanthrenylene units in the chain have been directly prepared by Ru catalyzed step-growth copolymerization of 2-acetyl phenanthrene and α,ω-dienes such as 1,3-divinyltetramethyldisiloxane. Copolymers which incorporate 2-aceto-1,3-phenanthrenylene units possess higher TgS and increased thermal stability compared to analogous copolymers which have 2-aceto-5-phenyl-1,3-phenylene(biphenyl) or 2-aceto-1,3-phenylene units. Fluorescence spectra of these copolymers have been obtained.
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  • 73
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    Notes: Summary A new methodology is described for the synthesis of reactive polymers bearing triphenylphosphine dichloride groups by the use of triphosgene. These materials show high reactivity for the room temperature conversion of benzyl alcohol to benzyl chloride. In one hour, yields higher than 90% were achieved using reactive copolymers with up to 25 w% divinylbenzene (DVB). The functional groups can be easily and efficiently regenerated using 1.0 mol of triphosgene for every 2.6 moles of phosphine in the polymer. Preliminary results showed up to 40% conversion of benzyl alcohol in column reactions using regenerated polymers at 5 to 10 min contact times.
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  • 74
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    Notes: Summary The biosynthesis of poly (β-hydroxybutyrate) (PHB) byBacillus circulans was carried out through cultivation in nutrient broth in a single step. $$\overline {\text{M}} {\text{v}}$$ of polymer fractions soluble in chloroform were close to 2 x 105. IR,1H and13C NMR spectra of the isolated PHB were in agreement with the assumed structure of this poly-β-hydroxyester. NMR spectroscopy pointed out a high percentage of isotactic polymer, while differential scanning calorimetry showed that the PHB was crystalline.
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    Polymer bulletin 37 (1996), S. 437-442 
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    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary Graft copolymers of polyacrylonitrile (PAN) and poly(ethylene oxide) (PEO) were synthesized by radical copolymerization of acrylonitrile and methacrylate-headed poly(ethylene oxide) macromonomer. The macromonomer was prepared by reaction of methacryloyl chloride with PEO. The effects of solution concentration, initiator concentration and acrylonitrile/macromonomer molar ratio on the conversion, molecular weight and PEO branch content in the graft copolymer were studied. The graft copolymers were characterized by GPC, FTIR,13C-NMR and Kjeldhal method.
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    Polymer bulletin 37 (1996), S. 457-462 
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    Notes: Summary The title vinyl thiophene monomer was synthesized by dehydration of the corresponding secondary alcohol. Free radical initiated copolymerizations with methyl methacrylate, styrene or isobutyl methacrylate were performed and the copolymer compositions were used in the calculation of reactivity ratios. The data was analyzed via a nonlinear least squares error-in-variables method. The 2,5-dimethyl-3-vinylthiophene was shown to have equal or slightly less reactivity than each of the monomers chosen as comonomers.
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  • 77
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    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary Alkylation of the methylene bridged tetrahydropyrimidine derivatives by chloromethylstyrene produces the bridged bis(4-vinylbenzyl)-1,4,5,6,-tetrahydropyrimidinium salts in high yields. Similar procedures are used to prepare 2-imidazolinium derivatives. The quaternary salts which support functional side groups of potential biomedical interest are characterized by means of spectroscopic methods. These monomers are readily polymerized free radically in solution of dimethyl formamide at moderate temperatures. The soluble and insoluble polymers containing 2-imidazolinium and 1,4,5,6-tetrahydropyrimidinium salts were found to exhibit antibacterial activites againstEscherichia coli.
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    Polymer bulletin 37 (1996), S. 463-468 
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary The parent polymer, poly(allylamine) as ligand polymer was employed to synthesize polychelates of heavy metal ions. The functional poly(allylamine) and its Ni(II), Co(II) and Cu(II) metal chelates were characterized by elemental analysis, FT-IR spectroscopy, TGA, and SEM. For the polychelates magnetic and conductivimetry studies were also carried out.
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  • 79
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    Polymer bulletin 37 (1996), S. 475-482 
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary A new chemically amplified polymeric imaging system based on polymers containingt-butylmalonate pendant groups has been demonstrated. Both the homopolymer of di-t-butyl (vinylbenzyl)benzylmalonate and its copolymer with styrene have been tested in coatings containing a photoacid generator. Imaging experiments confirm that the materials have very high sensitivities when exposed to UV radiation near 250nm.
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  • 80
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary New pseudoaffinity chromatography supports were prepared and characterized from poly(sucrose acrylate) crosslinked with MDI or TDI and Cibacron Blue dye as ligand. Blue gels were useful in the retention of albumin and the results are reported.
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  • 81
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary Copolymers of ethylene and 1-hexexe, 1-octene and 4-methyl-1-pentene were obtained using Et[In]2ZrCl2/MAO catalyst at various pressures. The increase of 1-hexene and 1-octene concentration in the feed increases catalyst activity(g/nZr.h.bar) and productivity(g/nZr.h). For 4-methyl-1-pentene the activity is independent on comonomer concentration. Increasing the ethylene pressure the productivity of the copolymerization increases and the activity shows a weak decay. Characterization of the copolymer shows that at higher pressure the cristallinity of the copolymers is higher due to lower comonomer incorporation. There is a good linear correlation of cristallinity with comonomer concentration in the feed for 1-hexene and 1-octene at a fixed pressure, but not for 4-methyl-1-pentene.
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  • 82
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract The present work deals with copolymerization of styrene (STY) and methyl methacrylate (MMA) catalysed by nickel acetylacetonate - Ni(acac) 2 , employing methylaluminoxane (MAO) as cocatalyst. This catalyst system presented low catalyst activities for STY homopolymerization and very high activities for MMA. It seems that the catalyst system based on Ni(acac) 2 /MAO is effective for the copolymerization of MMA and STY to give block copolymer but it also produced polystyrene and poly(methyl methacrylate) homopolymers. The polymers were characterized by 13 C NMR, GPC and FTIR. The polystyrene homopolymer was identified by IR and NMR analyses of the cyclohexane soluble fraction. The presence of absorption bands correspondent to carbonyl group and aromatic ring was observed in the IR spectrum of the acetic acid soluble part. This result is a clue that STY-MMA copolymer with low molecular weight was produced. The high molecular weight copolymer (acetic acid insoluble fraction) was also characterized by IR analysis which indicated the presence of characteristic absorption bands of carbonyl group and aromatic ring. These results were confirmed by 13 C NMR analysis.
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  • 83
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    Polymer bulletin 40 (1998), S. 555-562 
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary Four narrow-distribution samples of sodium hyaluronate with weight-average molecular weights M w of 3.8 × 103 to 1.1 × 104 in 0.02 and 0.1 M aqueous NaCl at 25°C have been studied by small-angle X-ray scattering. Data for their z-average radii of gyration 〈S2〉z 1/2 and particle scattering functions P(θ), together with previous 〈S2〉z data from light scattering for high molecular weights, are compared with relevant theories for the wormlike chain with or without excluded volume, using the parameters estimated previously from intrinsic viscosity ([η]) data. It is shown that for M w lower than 1.1 × 104, 〈S2〉z, P(θ), and [η] of the polysaccharide in the aqueous salts are all consistently explained by this model without excluded volume.
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  • 84
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary Three new side chain liquid crystalline polythiiranes were prepared with new substituants on the mesogenic groups. Their thermotropic liquid crystalline behaviour was studied by the usual techniques (DSC, X-ray diffraction and polarized optical microscopy). Unlike the polyoxiranes described in the literature, the size of the terminal group has no influence on the nature of the mesophases of polythiiranes ; only slight changes of the transition temperatures were observed. In this series of polymers, a phase, denoted X, appeared at temperatures below the smectic E phase, and could not be identified by usual characterization techniques. An isothermal kinetic study for the smectic E / X phase transition resulted in an Avrami exponent close to 1, suggesting a one-dimensional ordering occurred during the transformation from the smectic phase. This result, combined with other observations, helped us to assign the X phase to the crystalline phase.
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  • 85
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    Polymer bulletin 40 (1998), S. 583-590 
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract Hybrid materials from Polyvinyl chloride (PVC) and titania were prepared using sol-gel technique. In-situ generation of titania network in the PVC matrix was carried out by introducing required amounts of tetrapropylorthotitanate (TPOT) followed by hydrolysis/condensation of TPOT in the matrix. Homogeneous and semi-transparent films were obtained by casting and solvent evaporation. Mechanical properties of these films up to 15 wt. % titania contents were studied. The results showed an increase in the Young's modulus, length at rupture and toughness of the unplasticised PVC. However, the tensile strength and stress at break point decreased with the addition of titania contents. Thermal stability of the material was studied using dehydrochlorination (DHCl) technique and thermogravimetric analysis. The PVC samples with small amount of titania were found to be more stable as compared with the pure PVC.
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  • 86
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: SUMMARY The sorption characteristics of benzene and cyclohexane vapours in the poly(urethane-urea) (PUU) with well defined structure were measured using an improved version of the Mc Bain's microbalance. The diffusion coefficients were calculated for the different vapour activities from the kinetics of solvent uptake, i.e. the sorption isotherms over time. Sorption and diffusion coefficients measured, showed a strong dependence of the applied vapour activity. The obtained transport parameters were discussed with regard to the polymer structure. Based on the sorption and diffusion data, the pervaporation performance of the PUU-based membrane in separation of the benzene/cyclohexane mixtures was predicted and compared with the experimental pervaporation characteristic.
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  • 87
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary The polymerization of styrene with catalysts based on Ni(acac)2 supported on SiO2 and Al2O3 was investigated. Using catalysts based on MAO supported on silica, a highly isotactic polystyrene was obtained. Nevertheless, the Al2O3-supported catalyst can promote isospecific polymerization activated by common. alkyl aluminum compounds even by any prior support treatment with MAO.
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  • 88
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    Polymer bulletin 40 (1998), S. 701-706 
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary A novel polymer having β,β-triketone unit in the main chain was prepared by polycondensation of triethylene glycol bis(p-butoxycarbonylphenyl) ether (1) with triethylene glycol bis(p-acetylacetophenyl) ether (4). The obtained polymer was soluble in CHCl3, DMF, and DMSO. The structure of the polymer was confirmed by 1H-NMR. Insoluble brownish yellow copper (II) chelate was obtained by adding a methanol solution of copper (II) acetate to a chloroform solution of the polymer. The IR analysis and the measurement of copper content by iodometric titration showed the quantitative formation of binuclear copper (II) complex.
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  • 89
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    Polymer bulletin 40 (1998), S. 715-720 
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary Synthesis and polymerization behavior of 1-trimethylsiloxy- or 1-triphenylsiloxy-silacyclobutane derivatives were studied. These monomers gave polymers with reasonably high molecular weight by platinum catalyst like platinum 1,3-divinyl-1,1,3,3-tetramethyldisfloxane complex. Side-chain smectic, liquid crystalline polymer was obtained from 1-methyl-1-[3-{(4-cyanobiphenyl-4'-yl)oxy}propyl]dimethylsiloxysilacyclobutane. In the polymerization by butyllithium or phenyllithium, monomers corresponding to the amounts of the initiator were consumed, but no polymers were formed. Apparently, elimination of the trimethylsiloxy or triphenylsiloxy group occurred in the nucleophilic attack of the initiator or propagating species on the silicon atom of the monomer.
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  • 90
    ISSN: 1436-2449
    Keywords: (Keywords: lanthanocene; methylaluminoxane; polymerization; butadiene; isoprene; styrene.)
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary The polymerization of butadiene(Bd), isoprene(Ip) and styrene(St) has been examined using the six catalyst systems composed of lanthanocene, (C5H9Cp)2NdCl(I), (C5H9Cp)2SmCl(II), (MeCp)2Sm OAr'(III), (Ind)2NdCl(IV), Me2Si(Ind)2NdCl(V) and (Flu)2NdCl(VI), and methylaluminoxane(MAO) respectively. All of them can be used to form the polyisoprene with molecular weights of 1 to 10 thousand and cis-1,4-unit contents of 41 to 47%. (I), (II) and (III) of them can be also used to form the polybutadiene with molecular weights of 10 to 20 thousand and cis-1,4-unit contents of 62 to 78%. In addition, the catalysts from (II) to (V) are still active for St polymerization and (II) of them gives a syndio -rich random polystyrene. It is noteworthy that (II) and (III) are active for homopolymerization of Bd, Ip and St in the same polymerization condition.
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  • 91
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    Polymer bulletin 40 (1998), S. 741-747 
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary In this work, a series of 2,3-O-methylcellulose (MC) with different DS value were prepared. Its phase transition behavior in aqueous solution was studied in terms of DS value, concentration and molecular weight. The the following conclusions were obtained. (1) All the 2,3-O-MC samples show no sol-gel transition in aqueous solution despite the molecular weight. (2) No phase separation was observed for the 2,3-O-MCs with a DS value lower than 1.0, even when the temperature was raised to 95°C. (3) The precipitation temperature is surprisingly different between 2,3-O-MCs. and other MCs possessing comparable total DS value. (4) The precipitation temperature of 2,3-O-MCs depends on the molecular weight rather than on the concentration.
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  • 92
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary Ultrahigh molecular weight polyacrylamides (PAAM) were obtained by plasma-induced polymerization in water solutions. The influenceof monomer concentration, sealing pressure, initiation time and post polymerization period on polymer yield and molecular weight were investigated. The viscosity and “screen factor” measurements, as well as the thermally stimulated depolarization currents spectroscopic data of the synthesized polymers, indicate good properties as efficient viscosity modifiers in displacement of fluids for enhance oil recovery (EOR).
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  • 93
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary In this report, the relaxation behavior of amorphous poly(ethylene terephthalate) (PET) in global chain orientation but nearly random segmental orientation (GOLR) state is studied by infrared dichroism, optical birefringence and hot shrinkage measurements at temperatures below or up PET's glass transition temperature, Tg. The results indicate that the difference in the relaxing rate between global chains and segments is at least in ∼ 102 times order above PET's Tg (∼ 84°C), with a rough approximation; while the sudden decrease of small Δn of the sample (∼ 10−4) upon being treated at about 85 ∼ 90°C, implies us that the small Δn is closely related with the orientation of global chains.
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  • 94
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    Polymer bulletin 41 (1998), S. 129-130 
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 95
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary New biomedical polyurethanes and a polyurethane urea based on Ε-caprolactone and 1,4-butanediisocyanate have been developed. On degradation, only non-toxic products are produced. The polyurethane urea with poly(Ε-caprolactone) soft segments and butanediisocyanate/butanediamine hard segments shows a high tensile strength, a high modulus and a high resistance to tearing but as a result of the strong interactions between the solvent and the polymer processing is difficult. When butanediamine is replaced by butanediol in the chain extension step, a processible polyurethane is obtained but the polymer lacks the desired mechanical properties for biomedical applications. By chain extending with a longer urethane diol block, a processible polymer was obtained with mechanical properties comparable to the polyurethane urea. This polyurethane has been made porous and can be used as a meniscal prosthesis.
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  • 96
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary Catalytic 1,3-butadiene polymerization systems can be obtained with the new complex [NbO(C16H11O6 −)(C2O4 2−)] as a catalyst. When the catalysis occurs in a homogeneous medium (toluene as a solvent) in conjunction with AlEt2Cl, cis-1,4-polybutadiene is obtained. A remarkable inversion of stereoselectivity has been observed when the catalysis is carried out in a two phase system with the molten salt AlCl3.1-methyl-3-n-butyl-imidazolium chloride (MBIC) as a solvent and AlEt2Cl as a cocatalyst, giving the trans 1,4-polybutadiene.
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  • 97
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary Highly branched aliphatic molecules have been used for the first time as tethers in the preparation of polymeric chiral stationary phases. Attachment of a specifically designed chiral selector to organic porous polymer beads through a branched linker substantially increases the enantioselectivity compared to that of the equivalent separation medium with a traditional linear tether.
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  • 98
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary The EPR spectra of composite dextran and carboxymethyldextran gels were studied in order to identify the functional groups involved in copper(II) complexation depending on pH. The porous structure resulting from crosslinking of polymer chains of dextran, via epichlorohydrin, forces the immobilization of Cu2+ ions surrounded by different oxygen groups of the polymer gel matrix. The different polynuclear structures are postulated to be formed depending on the type of polysaccharide derivatives. The results indicate that carboxyl and deprotonated hydroxyl groups participate in the complex formation.
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  • 99
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary Individual polystyrene (PS) and polyacrylonitrile (PAN) solutions in N,N-dimethylformamide (DMF) were studied by electronic absorption spectroscopy. Upon increasing the polymer concentration in the PS-DMF binary system a bathochromic shift of the band at about 260 nm was found. This spectral effect could be explained by an association of PS phenyl groups and/or by a complex formation between DMF and PS. The UV spectrum of PAN in DMF solution was interpreted in terms of the variety of possible donor-acceptor complex formations. The specific intermolecular interactions in the investigated binary liquid systems were discussed on the basis of the spectral data.
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  • 100
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary Measurement of swelling is used to estimate the extent of cross-linking of latex particles prepared by emulsion polymerization. In this paper we report swelling data as a function of solvent activity for two latexes: (1) a poly(butylacrylate) (PBA) latex, and (2) a poly(isodecylacrylate) latex. In the latter case comparison is made between the swelling behavior of fully cross-linked, i.e., networks without free polymer chains, and partially cross-linked latexes. It is demonstrated that the equilibrium swelling properties are only slightly affected by the presence of uncross-linked chains. Swelling gives reliable results for the cross-link density only if the latex does not contain free chains.
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