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  • Articles  (9)
  • Articles: DFG German National Licenses  (9)
  • sediment  (9)
  • 2000-2004  (9)
  • Energy, Environment Protection, Nuclear Power Engineering  (9)
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  • Articles  (9)
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  • Articles: DFG German National Licenses  (9)
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  • 1
    ISSN: 1573-3017
    Keywords: lead ; waterfawl ; sediment ; toxicity ; mining ; risk assessment ; swans ; ALAD ; protoporphyrin
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract For many years, waterfowl have been poisoned by lead after ingesting contaminated sediment in the Coeur d'Alene River Basin, in Idaho. Results of studies on waterfowl experimentally fed this sediment were combined with results from field studies conducted in the Basin to relate sediment lead concentration to injury to waterfowl. The first step in the model estimated exposure as the relation of sediment lead concentration to blood lead concentration in mute swans (Cygnus olor), ingesting 22% sediment in a rice diet. That rate corresponded to the 90th percentile of sediment ingestion estimated from analyses of feces of tundra swans (Olor columbianus) in the Basin. Then, with additional laboratory studies on Canada geese (Branta canadensis) and mallards (Anas platyrhynchos) fed the sediment, we developed the general relation of blood lead to injury in waterfowl. Injury was quantified by blood lead concentrations, ALAD (δ-aminolevulinic acid dehydratase) activity, protoporphyrin concentrations, hemoglobin concentrations, hepatic lead concentrations, and the prevalence of renal nuclear inclusion bodies. Putting the exposure and injury relations together provided a powerful tool for assessing hazards to wildlife in the Basin. The no effect concentration of sediment lead was estimated as 24 mg/kg and the lowest effect level as 530 mg/kg. By combining our exposure equation with data on blood lead concentrations measured in moribund tundra swans in the Basin, we estimated that some mortality would occur at a sediment lead concentration as low as 1800 mg/kg.
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Environmental monitoring and assessment 64 (2000), S. 409-419 
    ISSN: 1573-2959
    Keywords: monitoring ; assessment ; water ; sediment ; bioaccumulation ; toxicity ; pesticides ; mercury ; PCB
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The San Francisco Estuary Regional Monitoring Program for Trace Substances (RMP) began in 1993 and is sponsored by 74 local, state, and federal agencies and companies through their discharge or Bay use permits. The RMP monitors water, sediment, toxicity, and bivalve bioaccumulation at 25 sites in the Bay that are considered to represent "background" conditions. Several major environmental issues have been identified by the RMP. Polychlorinated biphenyls and mercury were often above water quality guidelines, and often occurred in fish tissues above U.S. Environmental Protection Agency (U.S. EPA) screening values. Concentrations do not appear to be decreasing, suggesting continuing inputs. Episodes of aquatic toxicity often occurred following runoff events that transport contaminants into the Bay from urbanized and agricultural portions of the watershed. Sediment toxicity occurred throughout the Bay, and has been correlated with concentrations of specific contaminants (chlordanes, polynuclear aromatic hydrocarbons) at some locations; mixtures of contaminants were probably also important. Since the RMP does not monitor all ecosystem components, assessments of the overall condition of the Bay cannot be made. However, in terms of contamination, the RMP samples suggest that the South Bay, and North Bay sites are moderately contaminated.
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Environmental monitoring and assessment 63 (2000), S. 329-339 
    ISSN: 1573-2959
    Keywords: bioavailable ; lead ; sediment ; soil
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract This study determined the spatial distribution of soiland of sediment-associated lead in Iqaluit, Nunavut.Samples were collected from the following areas:outside the built-up area of the town to reflectbackground concentrations; known or potential pointsources of lead, such as the Upper Base, the SylviaGrinnell Dump and the Metal Dump (North 40); andresidential and commercial areas of Iqaluit and Apex,a satellite community. In the laboratory, the 〈63 μm sample fraction was analyzed for total lead andbioavailable lead, estimated by non-residual acidextractable lead content. The research findings revealthat elevated levels of bioavailable lead are presentin the study area. Total lead concentrations generallydo not exceed environmental guidelines. However, leadconcentrations in the Sylvia Grinnell Dump, and Apexand Iqaluit grid areas exceed health-based guidelines.The research concludes that there is not a serioushealth hazard posed by lead levels in the soil andsediment in the study area. However, severalenvironmental (elevated lead levels, bioavailableforms of lead and bare soil surfaces) and behaviouralfactors (vigorous and unsupervised play outside) maycreate a risk of lead exposure.
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Water, air & soil pollution 118 (2000), S. 407-418 
    ISSN: 1573-2932
    Keywords: DOC ; release kinetics ; sediment ; Water Soluble Organic Carbon (WSOC) ; wetland soil
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Release kinetics of Water Soluble Organic Carbon (WSOC) from a wetlandsoil and a river bottom sediment were investigated under variousexperimental conditions in the laboratory. The laminar sublayerconcept was applied to model the release process. The resultsindicate that the release process can be characterized by atypical first order equation derived from the laminar sublayermodeling. The mass transfer rate constants of the releaseprocess increased with the increase in flow velocity following apower function. Due to texture difference, the transfer rateconstant of the wetland soil is about one order of magnitudelarger than that of the river bottom sediment. The influences oftemperature and pH on the release kinetics are discussed.
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  • 5
    ISSN: 1573-2932
    Keywords: eutrophication ; nitrogen ; phosphorus ; river ; sediment
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Nitrogen (N) and phosphorus (P) concentrations were determined in sediment samples along the bed of Catatumbo river in both Colombian and Venezuelan territories until the river outlet in Maracaibo lake. Total phosphorus was determined by digestion with HCl followed by analysis using the ascorbic acid method and total nitrogen was done using the standard microkjeldahl method plus nitrate-nitrite. Ammonium, orthophosphate and nitrate were determined using standard methods after extraction steps. The mean concentrations along the river bed were found in an interval of 0.035 and 1.492 mg g-1 dry sed. for nitrogen and 0.027 and 1.039 mg g-1 dry sed. for phosphorus at 95% confidence level. The mean molar ratio N/P in the river bed was 4.42 and 3.46 for river outlet zones in the lake, which indicates that nitrogen is the limiting nutrient. For comparison with previous results of lake sediments from sites near the river outlet it was concluded that Catatumbo river is a significant source of nutrients to the Maracaibo Lake system because sediment nutrients concentrations from Catatumbo river were higher than the ones in Maracaibo Lake. Statistic studies showed significant differences between countries, zones and similar behaviour in the river bed as related to the affluent rivers.
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Water, air & soil pollution 118 (2000), S. 27-33 
    ISSN: 1573-2932
    Keywords: algae ; Bosphorus ; sediment ; trace metals
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Concentration of As, Cr, Fe, Zn, Co, Sb, Pb, Cd and Cu weredetermined in sediment and algae samples collected from theBosphorus in Turkey. Certain algae species were chosen among thegreen, brown and red algae species at three sampling stations.Element analyses were carried out by atomic absorptionspectrophotometry and instrumental neutron activation analysis. The locations having the highest metal concentrations insediments were as follows: As at Poyraz; Cr, Zn, Sb at RumeliFeneri and Fe, Co at Garipçe. In genral, the accumulation ofmost of the metals showed no direct correlation with algaespecies. On the other hand, C. verticillatus and C. barbataspecies of brown algae showed ability to accumulate arsenic.
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Water, air & soil pollution 122 (2000), S. 121-138 
    ISSN: 1573-2932
    Keywords: Soil erosion ; sediment ; water pollution ; forestry ; logging ; buffer strips
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract A runoff plot experiment found that ten metre undisturbed forest buffers removed80–90% of runoff and over 95% of sediment produced by logging skid tracks. The study was carried out on 21º slopes in a native forest in eastern New South Wales, Australia. The experiment included three replicates of four treatments including undisturbed control, skid track, skid track + undisturbed buffer and skid track + disturbed buffer. Skid track and control plots were 20 m long by 5 m wide. Buffer plots consisted of a 20 m by 5 m skid track directing runoff to a 10 m by 5 m naturally vegetated buffer that was either undisturbed or lightly disturbed. Runoff and sediment yields from plots were monitored over two successive summers. Undisturbed buffers greatly reduced overland flow and decreased sediment yields from around 100 Mg ha1 to less than 0.5 Mg ha-1. Differences in both runoff and sediment yield between undisturbed buffer and control treatments were minimal and not statistically significant. Disturbed buffers achieved similarly large reductions in runoff and sediment yield in two out of three replicates. The third replicate yielded as much or more runoff and sediment than the skid track plots suggesting that disturbance increased the risk of buffer failure. The peak rate of outflow from buffer plots was generally not related to peak buffer inflow until a threshold inflow of 1.6 L s-1 was reached, after which peak outflow and peak inflow were linearly related.
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  • 8
    Electronic Resource
    Electronic Resource
    Springer
    Water, air & soil pollution 122 (2000), S. 317-326 
    ISSN: 1573-2932
    Keywords: arsenic ; distillation ; gold tailing ; neutron activation analysis ; sediment ; speciation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract As(III) and As(V) in goldtailings and river-bedsediments from Obuasi were determined by distillationof arsenic as AsCl3. Results yielded 3750±426 mg kg-1 (45.2%) for As(V) and 3050±66 mg kg-1 (36.7%) for As(III) in the tailings. In the river-bed sediments, one spot yielded: As(III) 0 mg kg-1 (0%) and As(V) 1447±51 mg kg-1 (100%), whilst a second spot yielded: As(III) 0 mg kg-1 (0%) and As(V) 2976±51 mg kg-1 (100%). Using arsenic oxide standards, the recovery of As(III) and As(V) in the trioxide were 94.8 and 0.6% respectively. In a mixture of the two oxides, the recovery of As(III) was 87.6% with practically no interference from As(V). Total As content of the tailings was determined by neutron activation analysis (NAA) to be 8305±75 mg kg-1.
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  • 9
    ISSN: 1573-2932
    Keywords: bioturbation ; freshwater systems ; methylation ; sediment
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The toxicological consequences of Hg releases to the environment are largely governed by the conversion ofinorganic Hg to the most toxic methylmercury (MeHg), that is biomagnified through aquatic food chains. To gain further insight on the biological and physico-chemical factors controlling MeHg production and distribution among freshwater sediments and water, we used a sensitive and specific radiochemical procedure, developed at the National Institute for Minamata Disease. Systems containing 203Hg2+-spiked sediment cores (0.7 μg total Hg g-1 d.w.) and overlying water, both from a pristine mountain stream in Southern Japan, were incubated for 21–38 days in different conditions. Inorganic Hg and MeHg in sediment and water were extracted in dithizone-benzene and measured after separation by thin-layer chromatography. The conversion of added Hg to MeHg was 3.0 to 13.7% in sediments, with a tendency for higher proportions in the top layers. Surprisingly, more MeHg was found in the sediment (11.3%) and water (66.5%) of a system bubbled with air than in one bubbled with nitrogen (4.2 and 44.1%). Artificially increased levels ofbioturbation reduced by half the MeHg concentrationsand % of added total Hg in sediment and water. In allsystems, 55–68% of total Hg and MeHg in water wereassociated to suspended particles 〉1μm. MeHgbioaccumulation factors (BFs) from water ranged270–8100 and from sediment, 0.2–5.7 (wet weight basis). BFs in relation to water where 3 times higher for MeHg than for total Hg.
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