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  • Articles  (7,870)
  • Articles: DFG German National Licenses  (7,870)
  • Springer  (7,870)
  • 2020-2024
  • 1985-1989  (7,870)
  • 1980-1984
  • 1988  (7,870)
  • Physics  (7,870)
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  • Articles  (7,870)
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  • 2020-2024
  • 1985-1989  (7,870)
  • 1980-1984
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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Meteorology and atmospheric physics 39 (1988), S. 169-183 
    ISSN: 1436-5065
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geography , Physics
    Notes: Summary The observed daily pressure fields over the Arctic are compared with those obtained from a control run of the Goddard Institute for Space Studies (GISS) General Circulation Model using a classification typing procedure developed by Kirchhofer (1973) and a rotated principal components analysis for both data sets. The simulated patterns appear quite realistic in both frequency and geographical characteristics, although the model data show greater extremes and more closed cells. The procedure described provides a potentially useful method for evaluating the synoptic representativeness of GCM simulations.
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Meteorology and atmospheric physics 39 (1988), S. 132-168 
    ISSN: 1436-5065
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geography , Physics
    Notes: Summary An analysis of mesoscale gravity wave events during the severe weather outbreak in the Red River Valley on 10–11 April 1979 is presented utilizing surface pressure data and the 3 h rawinsonde data from the AVE-SESAMEI special network. The unique data set provided by the SESAME field experiment makes it possible to relate the wavelike characteristics observed at the surface to the variability of the temperature, humidity, and wind fields over a deep tropospheric layer that act to initiate and sustain the waves over long distances and time periods. Three different wave events (A, B, and C) were identified via spectral analysis and cross-correlation techniques. They all have similar periods, approximately 3 h, but different phase velocities. All three wave events are generated and propagate in the exit region or anticyclonic side of upperlevel jet streaks. Convection and wind shear are shown to be unlikely contributors to the generation of event A, which is probably related to the development of a strong divergent field in association with an upper-tropospheric jet streak and to the ensuing mass adjustment process. Events B and C also appear in a region of strong ageostrophic motion associated with an upper-level jet streak. However, the low values of the Richardson number (Ri) at the critical levels of these two waves suggest vertical wind shear as a likely contributor to their generation and/or maintenance. A linear stability analysis confirms, with unprecedent spatial and temporal resolution, that a modal structure is present in the atmosphere whose characteristics are consistent with those of waves B and C. Three-hourly rawinsonde data show strong temporal and spatial variability throughout the troposphere in the wind, temperature, and humidity fields when the waves are present. Convective systems, as detected by radar, are closely linked to the waves, although not in a consistent manner: cells intensify or develop at the passage of a wave trough in event A, at the passage of a wave ridge in event C, and at the passage of a wave trough or ridge in event B, depending on the geographic location of the cells. For all three events, maximum rainfall recorded at the surface is associated with a wave ridge with a time lag of approximately 1 h.
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Meteorology and atmospheric physics 39 (1988), S. 184-196 
    ISSN: 1436-5065
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geography , Physics
    Notes: Summary In this paper, analytic solutions of the nonhydrostatic and hydrostatic forms of Long's model were obtained under two different sets of vertical boundary conditions: The first uses a sumusoidal obstacle at the lower boundary and a rigid-lid top for the upper boundary. The second set applies an isolated obstacle of the “Witch of Agnesi” type at the lower boundary, while still using a rigid lid at the top. Following the solution evaluations, comparisons between the nonhydrostatic and hydrostatic solutions were processed in order to describe several influences introduced by using the hydrostatic assumption in this model. Through comparisons we have found that, in the case of a sinusoidal lower boundary condition, the hydrostatic solution is obtained as the zero mode of the nonhydrostatic solution. The influence of the hydrostatic assumption on the model solution is trivial in this case. When an isolated lower boundary condition is applied, however, the solutions illustrate dramatic differences, showing the significance of the effect of hydrostatic assumption on this model's solutions. These effects vary considerably with the model parameters as well. The comparison results also reveal that the realization of the hydrostatic assumption in this model's solutions is accomplished through the vertical boundary conditions used in the model evaluations.
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  • 4
    ISSN: 1436-5065
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geography , Physics
    Notes: Summary To investigate the effect of atmospheric turbulence on microwave communication links, temperature and water vapor pressure have been measured and radio refractivity has been computed, during different meteorological conditions, in the atmospheric boundary layer of an urban site. The cospectra between temperature (T) and water vapor pressure (e) have been found to be either negative over the whole range of frequencies, or the low-frequency end of the cospectrum is of opposite sign relative to higher frequency end. In both cases cospectra follow a−5/3 law in the inertial subrange, in agreement with the theoretical predictions. The coherence spectra clearly show that the temperature and humidity fluctuations are highly coherent within the inertial subrange under both convective and stable conditions. The relative contribution ofC T 2 ,C eT andC e 2 to the real refractive index structure parameterC n 2 is examined and discussed.
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  • 5
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary Titanium has been successfully incorporated into polydimethylsiloxane and poly(tetramethylene oxide) modified TEOS based materials using sol-gel chemistry. Incorporation of titanium into the oligomer modified TEOS based materials altered the physical properties, however, the gross structural features remained the same.
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  • 6
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary Two-dimensional NMR and lanthanide shift reagents have been combined for the first time for NMR spectral assignments. The combined approach permitted very detailed interpretation to be made of the one-dimensional 1H and 13C spectra of ethylene-vinyl acetate copolymers.
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Polymer bulletin 19 (1988), S. 137-143 
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary The rates of urethane formation between linear and three-arm star hydroxyl-terminated polyisobutylenes (PIB-diols and -triols) and 4,4′-diphenylmethane diisocyanate (MDI) have been studied in the presence of triethylene diamine and stannous octoate catalysts in chlorebenzene at 25°C. The second order rate constants were determined and compared with those obtained with various polyether triols, hydroxyl-terminated polybutadiene and hydroxyl-terminated polyolefin. The rates of the normalized PIB-diol/MDI and PIB-triol/MDI reactions are essentially identical. In the presence of triethylene diamine, the rates of the PIB-diol and PIB-triol/MDI reactions are the same or much higher than that of the polyether-triol/MDI reaction. In contrast, in the presence of stannous octoate, the rates of the PIB-diol and PIB-triol/MDI reactions are much slower than that of the polyether-triol/MDI reaction. Differences in catalytic pathways are invoked to explain these observations. The reactivities of hydroxyl-terminated PIBs are similar to those of other hydroxyl-terminated polyhydrocarbons and sufficient for the synthesis of foams.
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  • 8
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary Suspension type PVC was reacted with sodium phenoxide in presence of different quaternary ammonium halides in THF or THF/water mixtures. The competition elimination vs. substitution of chlorine atoms depends on the homogeneity of the system, i.e. the more homogeneous the reaction mixture the less substituted the polymer.
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  • 9
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary Functionalized styrenes such as 4-(2-chloroethyl)styrene, 4-(2-chloroethyl)α-acetoxystyrene and 4-(3-bromopropyl)α-acetoxystyrene have been synthesized in two steps from commercial products and a preliminary study of their polymerization and copolymerization has been carried out.
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  • 10
    Electronic Resource
    Electronic Resource
    Springer
    Polymer bulletin 19 (1988), S. 123-128 
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary Copolymers of 2-ethyl-2-oxazoline (ETOX) and N-phenylmaleimide(PhMI) without initiator were prepared at different feed mole ratios, solvents, temperatures and times. The copolymers are almost statistical and rich in N-phenylmaleimide. The copolymer composition was determined by 1H NMR.
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