ALBERT

Notes: Matlab scripts that apply the Bence & Albee (1968) matrix correction algorithm to X-ray intensity data collected as element maps on a Cameca SX-50 microprobe are used to produce two-dimensional maps of oxide weight percent and cation proportions for SiO2, Al2O3, FeO, MnO, MgO, CaO, Na2O and K2O. Once generated, large data sets of mapped oxide weight percent values or cation numbers that retain spatial information can be used petrologically. The technique is used to evaluate the compositional range of barroisitic amphibole in an eclogite from New Caledonia, to examine aspects of equilibration during the partial hydration of the eclogite facies mineral assemblage.

Notes: The exceptional andalusite–kyanite–andalusite sequence occurs in Al-rich graphitic slates in a narrow pelite belt on the hangingwall of a ductile normal fault in NW Variscan Iberia. Early chiastolite is replaced by Ky–Ms–Pg aggregates, which are overgrown by pleochroic andalusite near granites intruded along the fault. Slates plot in AKFM above the chloritoid-chlorite tie-line. Their P–T grids are modelled with Thermocalc v2.7 and the 1998 databases in the NaKFMASH and KFMASH systems. The univariant reaction Ctd + And/Ky = St + Chl + Qtz + H2O ends at progressively lower pressure as F/FM increases and A/AFM decreases, shrinking the assemblage Cld–Ky–Chl, and opening a chlorite-free Cld–Ky trivariant field on the low temperature reaction side. This modelling matches the observed absence of chlorite in high F/FM rocks, which is restricted to low pressure in the andalusite stability field.The P–T path deduced from modelling shows a first prograde event in the andalusite field followed by retrogression into the kyanite field, most likely coupled with a slight pressure increase. The final prograde evolution into the andalusite field can be explained by two different prograde paths. Granite intrusion caused the first prograde part of the path with andalusite growth. The subsequent thermal relaxation, together with aH2O decrease, generated the retrograde andalusite–kyanite transformation, plus chlorite consumption and chloritoid growth. This transformation could have been related to folding in the beginning, and aided later by downthrowing due to normal faulting. Heat supplied by syntectonic granite intrusion explains the isobaric part of the path in the late stages of evolution, causing the prograde andalusite growth after the assemblage St–Ky–Chl. Near postectonic granites, a prograde path with pressure decrease originated the assemblage St–And–Chl.

Notes: Sm–Nd garnet-whole rock geochronology, phase equilibria, and thermobarometry results from Garnet Ledge, south-eastern Alaska, provide the first precisely constrained P–T–t path for garnet zone contact metamorphism. Garnet cores from two crystals and associated whole rocks yield a four point isochron age for initial garnet growth of 89.9 ± 3.6 Ma. Garnet rims and matrix minerals from the same samples yield a five point isochron age for final garnet growth of 89 ± 1 Ma. Six size fractions of zircon from the adjacent pluton yield a concordant U–Pb age of 91.6 ± 0.5 Ma. The garnet core and rim, and zircon ages are compatible with single-stage garnet growth during and/or after pluton emplacement. All garnet core–whole rock and garnet rim-matrix data from the two samples constrain garnet growth duration to ≤5.5 my. A garnet mid-point and the associated matrix from one of the two garnet crystals yield an age of 90.0 ± 1.0 Ma. This mid-point result is logically younger than the 90.7 ± 5.6 Ma core–whole rock age and older than the 88.4 ± 2.5 Ma rim-matrix age for this sample. A MnNaCaKFMASH phase diagram (P–T pseudosection) and the garnet core composition are used to predict that cores of garnet crystals grew at 610 ± 20 °C and 5 ± 1 kbar. This exceeds the temperature of the garnet-in reaction by c. 50 °C and is compatible with overstepping of the garnet growth reaction during contact metamorphism. Intersection of three reactions involving garnet-biotite-sillimanite-plagioclase-quartz calculated by THERMOCALC in average P–T mode, and exchange thermobarometry were used to estimate peak metamorphic conditions of 678 ± 58 °C at 6.1 ± 0.9 kbar and 685 ± 50 °C at 6.3 ± 1 kbar, respectively. Integration of pressure, temperature, and age estimates yields a pressure-temperature-time path compatible with near isobaric garnet growth over an interval of c. 70 °C and c. 2.3 my.

Notes: Metapelites and intercalated metapegmatites of the Saualpe crystalline basement, which forms part of the Austroalpine nappe complex in the Eastern Alps, display a polyphase tectonometamorphic history. Here, we focus on the evolution that these rocks underwent prior to Cretaceous (eo-Alpine) high-pressure metamorphism and related penetrative deformation. Geothermobarometry on coarse-grained porphyroclastic parageneses (garnet–biotite–muscovite–plagioclase–sillimanite–quartz), which occur as relics in kyanite–garnet, two-mica gneiss, yielded 600 °C/0.4 GPa. Results from a corundum-bearing lithology suggest that higher temperatures may have been reached in very restricted areas. The matrix of these rocks displays intense recrystallization during a pressure-dominated metamorphic overprint. Microstructures and mineral chemistry indicate that this low-pressure metamorphism was the first significant metamorphic imprint in these rocks. Mineral relics in all metapelitic rock types reflect low-pressure conditions for this interkinematic crystallization phase.The distribution, macroscopic and microscopic observations and the mineralogical composition of intercalated metapegmatites point to regionally elevated temperature conditions during their emplacement. Therefore, pegmatite formation is correlated with mineral formation in metapelites. Sm–Nd-dating of magmatic garnet from the pegmatite gneiss yielded 249 ± 3 Ma, which is interpreted to represent the age of pegmatite-emplacement and low-pressure metamorphism in the metapelites. Since the pegmatites are overprinted by mylonitisation and high-pressure metamorphism, this Permo–Triassic age also sets an upper age-limit to the eclogite facies metamorphic event, which affected considerable parts of the Saualpe crystalline basement.

Notes: A sequence of psammitic and pelitic metasedimentary rocks from the Mopunga Range region of the Arunta Inlier, central Australia, preserves evidence for unusually low pressure (c. 3 kbar), regional-scale, upper amphibolite and granulite facies metamorphism and partial melting. Upper amphibolite facies metapelites of the Cackleberry Metamorphics are characterised by cordierite-andalusite-K-feldspar assemblages and cordierite-bearing leucosomes with biotite-andalusite selvages, reflecting P–T conditions of c. 3 kbar and c. 650–680 °C. Late development of a sillimanite fabric is interpreted to reflect either an anticlockwise P–T evolution, or a later independent higher-P thermal event. Coexistence of andalusite with sillimanite in these rocks appears to reflect the sluggish kinematics of the Al2SiO5 polymorphic inversion. In the Deep Bore Metamorphics, 20 km to the east, dehydration melting reactions in granulite facies metapelites have produced migmatites with quartz-absent sillimanite-spinel-cordierite melanosomes, whilst in semipelitic migmatites, discontinuous leucosomes enclose cordierite-spinel intergrowths. Metapsammitic rocks are not migmatised, and contain garnet–orthopyroxene–cordierite–biotite–quartz assemblages. Reaction textures in the Deep Bore Metamorphics are consistent with a near-isobaric heating-cooling path, with peak metamorphism occurring at 2.6–4.0 kbar and c. 750–800 °C. SHRIMP U–Pb dating of metamorphic zircon rims in a cordierite-orthopyroxene migmatite from the Deep Bore Metamorphics yielded an age of 1730 ± 7 Ma, whilst detrital zircon cores define a homogeneous population at 1805 ± 7 Ma. The 1730 Ma age is interpreted to reflect the timing of high-T, low-P metamorphism, synchronous with the regional Late Strangways Event, whereas the 1805 Ma age provides a maximum age of deposition for the sedimentary precursor. The Mopunga Range region forms part of a more extensive low-pressure metamorphic terrane in which lateral temperature gradients are likely to have been induced by localised advection of heat by granitic and mafic intrusions. The near-isobaric Palaeoproterozoic P–T–t evolution of the Mopunga Range region is consistent with a relatively transient thermal event, due to advective processes that occurred synchronous with the regional Late Strangways tectonothermal event.

Notes: The Pinos terrane (Isle of Pines, W Cuba) is a coherent metamorphic complex that probably represents a portion of the continental margin of the Yucatan Block during the Mesozoic. Within the framework of other metamorphic terranes in the Greater Antilles, the Pinos terrane is characterized by the occurrence of high-grade kyanite-, sillimanite- and andalusite-bearing metapelites and migmatites. Assessment and modelling of phase relations in these high grade rocks indicate that they reached a peak temperature of c. 750 °C at 11–12 kbar, and then underwent strong decompression to c. 3 kbar at c. 600 °C. Decompression was contemporaneous with the main synmetamorphic deformation in the area (D2), and was accompanied by segregation of trondhjemitic partial melts formed by wet melting of metapelites. Metamorphism terminated in the Uppermost Cretaceous (68 ± 2 Ma; 40Ar/39Ar dates on biotite and muscovite). The P–T–t-deformation relations of the high-grade rocks suggest that crustal thickening (during collision of this portion of the Yucatan margin with the Great Volcanic Arc of the Caribbean?) was followed by decompression interpreted to reflect exhumation by extension, possibly related to the initial development of the Yucatan Basin in the uppermost Cretaceous.

Notes: Phengite occurring along with carpholite±lawsonite and/or chloritoid in HP–LT domains shows not only variable Si–(Mg+Fe) contents, but also variable interlayer contents (IC). To determine whether these chemical variations are coherently related to variation in P–T conditions on a regional scale, c. 100 rock samples were sampled in metapelites metamorphosed at conditions varying from 350 °C, 8 to 12 kbar to 450–500 °C, 18 to 20 kbar (Schistes Lustrés complex, franco-italian Western Alps). Based on microstructural and habit criteria, four types of phengite were differentiated that are related either to the rock mineralogy (carpholite vs chloritoid bearing samples) or correspond to various generations of phengite occurring in the same rock sample or thin section. Microprobe analyses reveal that each type of phengite is characterized by a specific composition and that phengite associated with carpholite has a lower interlayer content than phengite associated with chloritoid. The successive generations of retrograde phengite overgrowing carpholite point to a large decrease of interlayer content (c. 0.9–0.7 pfu) and (Fe+Mg) content (c. 0.25–0 pfu) with decreasing P–T conditions. This change is best accounted for by a gradual increase of the pyrophyllite component. In contrast, phengite from higher-temperature, chloritoid-bearing rock samples shows an almost constant interlayer content (c. 0.9–0.95 pfu) but a larger decrease of (Fe+Mg) content (c. 0.6–0.1 pfu). Hence, (1) the composition of the different phengite generations occurring (metastably) in the same rock sample may be used to retrieve points in P–T loops and (2) the pyrophyllitic substitution in phengite is large at low-temperature conditions and cannot be ignored. Thermobarometric estimates based on the Si-content alone will therefore result in pressure over-estimates. We propose a tentative location of the phengite Si and IC isopleths in P–T space which could allow a direct determination of the P–T conditions in carpholite-bearing rocks. Especially in some carpholite-bearing rocks, new thermodynamic models accounting for tschermak and pyrophyllitic substitution are also required prior to making reliable thermobarometric estimates in HP-LT metapelites.

Notes: High-MgAl rocks occur as xenoliths (up to 2 m in diameter) in mafic granulites at a newly discovered locality near Anakapalle. Following an early phase of deformation, ultrahigh-temperature (UHT) metamorphism and near-isothermal decompression, the rocks were intruded in a lit-par-lit manner by felsic melts (charnockite), which caused local-scale metasomatism. A subsequent deformation produced isoclinal folds and the distinct gneissic foliation of the charnockite still at granulite facies conditions.The sequence of multiphase reaction textures in the high-MgAl xenoliths reflects the changes of physico-chemical conditions during the polyphase evolution of the terrane; UHT metamorphism (stage 1, 〉 1000°C, c. 10 kbar) is documented by relics of extremely coarse grained domains with the assemblage orthopyroxene (opx)1 + garnet (grt)1 + sapphirine (spr)1 + spinel (spl)1 + rutile (rt). A subsequent phase of near-isothermal decompression in the order of 1–2 kbar (stage 2) resulted in extensive replacement of grt1 and opx1 megacrysts by lamellar (opx2 + spr2) symplectites. The intrusion of felsic melt (stage 3) led to the development of a narrow metasomatic black wall reaction zone (bt + sil + plg3 + opx2,3 + rt) at the immediate contact of the xenoliths and in melt infiltration zones to the partial replacement of (opx2 + spr2) symplectites by biotite and sillimanite and/or plg3, mainly at the expense of orthopyroxene, with concomitant coarsening of the intergrowth texture. The subsequent deformation (stage 4) further modified the symplectite textures through polygonization, recrystallization and grain-size coarsening. The deformation was followed by a period of cooling and decompression (stage 5, c. 800°C, 4–7 kbar) as indicated by local growth of late garnet (grt5) at the expense of (opx + spr + plg) domains at static conditions.Recently published isotope data suggest that the multistage evolution of the high-MgAl granulites at Anakapalle followed a discontinuous P–T trajectory that may be related to heating of the crust through magmatic accretion culminating in deep-crustal UHT metamorphism at 1.4 Ga (stage 1), fast uplift of the UHT granulites into mid-crustal levels as a consequence of extensional tectonics (stage 2), emplacement of felsic magmas in the Grenvillian (at c. 1 Ga, stage 3) resulting in reheating of the crust to high–T conditions followed by a phase of compressional tectonics (stage 4) and a period of cooling to the stable geotherm (stage 5) still in the Grenvillian.