ALBERT

Description: The possibility of using the 15% excess U234 activity in oceanic uranium for dating pelagic sediments in the age range 100,000 years to more than 1 m.y. has been explored. Results from a series of analyses of bulk samples, mechanical separates, and acid leach fractions indicate that separation of authigenic uranium from detrital uranium by either mechanical or chemical means is impractical. Measurements on totally dissolved samples reveal that the sediments do not form a closed system; post-depositional migration of U234 in the sedimentary column takes place. Based on the experimental data obtained from three red-clay cores with sedimentation rates ranging from 2 to 6 mm/1000 yr, a model depicting diffusion of the U234 generated within the sediments is proposed. The diffusion equation includes three parameters: sedimentation rate, diffusion coefficient for U234, and fraction of the internally produced U234 subject to mobility. If the amount of U234 lost from these cores is typical, a sizeable part of the U234 excess in the sea must be from this source.

Description: Samples collected at hourly intervals on May 18–19, 1980, at three sites 200 km downwind from Mount St. Helens, have made possible a detailed reconstruction of the conditions that contribute to the compositional heterogeneity of mineral and glass components observed in distal tephra layers. The air fall tephra deposited at the sites during the first 7 hours of the May 18 eruption is mostly coarse grained, microlite-rich, nonjuvenile glass and feldspar. Grain-size maxima in this initial tephra can be related to the cataclysmic blast at 0832 and a subsequent pulse of the eruption at 1200. Juvenile, microlite-free glass increases in relative abundance at the sampling sites beginning at about 1900. Such a change between nonjuvenile and juvenile tephra can be related to a 5-km increase in column height associated with the last major pulse of the eruption which occurred at 1700 at the volcano. Electron microprobe study of both microlite-rich and microlite-free pumice in the time series samples reveals significant compositional differences. Interstitial glass in nonjuvenile pumice deposited during the first few hours at the sampling sites is enriched in SiO2 and K2O and depleted in TiO2, FeO*, and MgO relative to juvenile glass. By comparison, major element composition of the least evolved juvenile glass sampled during the last several hours of the eruption displays a slight trend toward less evolved composition. Least squares calculations suggest that the more evolved character of the nonjuvenile glass can be explained by greater fractional crystallization brought about by enhanced cooling in a cryptodome prior to eruption, whereas the temporal changes observed in juvenile glass composition during the last several hours of the eruption suggest the presence of a small, slightly zoned magma chamber at depth. Electron microprobe study of glass-coated ilmenites, magnetites, and plagioclases provides the following estimates of the physical conditions in this reservoir: 865°±50°C, PH2O = 2.2 kbar and -log ƒO2 = 11.7. Analyses of bulk pumice, glass and selected mineral phases from May 25, June 12, July 22, and October 16–18 pumices erupted from Mount St. Helens indicate that the bulk pumice (magma) compositions have become slightly more andesitic with time, while mineral and co-existing glass compositions have changed significantly in post-May 18 eruptions with both being more highly evolved than those associated with the May 18 eruption. An application of the magnetite-ilmenite geothermometer to June 12 and July 22 samples indicates temperatures of 919°±30°C and 930°±50°C, respectively. Least squares calculations suggest that such evolved post-May 18 glass and mineral phases can be derived by fractional crystallization of a magma composition like bulk May 18 pumice into approximately 50% crystals and 50% residual liquid. Such partitioning between crystals and residual liquid appears to have occurred on the scale of centimeters and is interpreted as a consequence of accelerated crystallization under reduced water pressure.

Description: The well-known caldera of Thira (Santorini), Greece, was not formed during a single eruption but is composed of two overlapping calderas superimposed upon a complex volcanic field that developed along a NE trending line of vents. Before the Minoan eruption of 1400 B.C., Thira consisted of three Java shields in the northern half of the island and a flooded depression surrounded by tuff deposits in the southern half. Andesitic lavas formed the overlapping shields of the north and were contemporaneous with and, in many places, interbedded with the southern tuff deposits. Although there appears to be little difference between the composition of magmas erupted, differences in eruption style indicate that most of the activity in the northern half of the volcanic field was subaerial, producing lava flows, whereas in the south, eruptions within a flooded depression produced a sequence of mostly phreatomagmatic tuffs. Many of these tuffs are plastered onto the walls of what appears to have been an older caldera, most probably associated with an eruption of rhyodacitic tephra 100,000 years ago. The Minoan eruption of about 1400 B.C. had four distinct phases, each reflecting a different vent geometry and eruption mechanism. The Minoan activity was preceded by minor eruptions of fine ash. (1) The eruption began with a Plinian phase, from subaerial vent(s) located on the easternmost of the lava shields. (2) Vent(s) grew toward the SW into the flooded depression. Subsequent activity deposited large-scale base surge deposits during vent widening by phreatomagmatic activity. (3) The third eruptive phase was also phreatomagmatic and produced 60% of the volume of the Minoan Tuff. This activity was nearly continuous and formed a large featureless tuff ring with poorly defined bedding. This deposit contains 5–40% lithic fragments that are typical of the westernmost lava shield and appears to have been erupted when caldera collapse began. (4) The last phase consisted of eruption of ignimbrites from vent(s) on the eastern shield, not yet involved in collapse. Collapse continued after eruption of the ignimbrites with foundering of the eastern half of the caldera. Total volume of the collapse was about 19 km3, overlapping the older caldera to form the caldera complex visible today. Intracaldera eruptions have formed the Kameni Islands along linear vents concomitant with vents that may have been sources for the Minoan Tuff.

Description: Pairs of individually recognizable male Octopus vulgaris were observed in a large seawater tank containing two suitable homes (brick pots or plastic buckets). None of the animals established exclusive occupancy of one home and for much of the time both animals were associated together at the same site. Usually one of the two homes was preferred and its occupant was most likely to be the larger animal, or the earlier resident if they were of equal size. Large animals were observed to take food forcefully from smaller octopus. An arm alignment interaction is described which, it is suggested, may be a means by which two octopuses establish their relative sizes.

Description: During a 10-year study more than 2,000 phytoplankton samples were collected from the entire coast of Peru and analyzed. In general, diatoms were the most abundant group of organisms in all seasons. Predominant species were Rhizosolenia delicatula, Skeletonema costatum Thalassiosira subtilis, Thalassionema nitzschioides and several species of the genus Chaetooeros. Dinoflagellates and flagellates were observed frequently during summer. The mean distribution of the phytoplankton concentration during the 10 years shows the existence of several centers with higher cell densities along the coast, coinciding with the areas of more intense and persistent upwelling. Four major centers have been identified: Pimentel (˜6°S), Chimbote (˜9°S), Callao (˜12°S), and Tambo de Mora-Pisco (˜15°S); and two minor centers, Talara (˜4°S) and Ilo (˜17°S). The relative importance of each center seems to change according to the season. The highest phytoplankton concentration tended to be in the northern part of the coast during fall and winter and in the south through spring and summer.

Description: A general method for simulating aerosol size distribution dynamics is developed. The method, based on dividing the particle size domain into sections and dealing only with one integral quantity in each section (e.g., number, surface area, or volume), has the advantages that the integral quantity is conserved within the computational domain and coagulations between all particle sizes are properly accounted for. To demonstrate the simplicity and accuracy of the method for a practical problem, the evolution of a power plant plume aerosol undergoing coagulation is simulated.

Description: Sedimentation rates (corrected for compaction) from along the passive continental margin of Africa between the Equatorial Fracture Zone and Somalia are used to compare the rates of subsidence of the continental crust since early Mesozoic time. Three distinctive subsidence histories can be identified which correspond with basinal areas that have different structural styles: rifted (west coast), sheared (Equatorial and Agulhas fracture zones) and sunk (zones of vertical tectonics in eastern Africa). A comparison of subsidence rates with other tensional margins (NE USA and the North Sea) and a consideration of the plate tectonic history of the African margins leads to the proposal of a geo and thermodynamic model that takes cognizance of the worldwide mid-Cretaceous rheological discontinuity between taphrogenic and epeirogenic basin formation recognized by Kent, and the more generally accepted, purely plate tectonic driven model of margin subsidence. The new suggestion involves a lower Mesozoic worldwide rise in the geothermal gradient in the lithosphere which produces metamorphism of the base of the continental crust and initiates taphrogenesis along lineaments throughout Gondwanaland. A lowering of the geothermal gradient in the lower Cretaceous produces a switch to epeirogenic subsidence, driven solely by sediment loading and thermal contraction, by Aptian/Albian times. The thermal event facilitated continental separation, and sea floor spreading commenced locally at various times along the active taphrogenic belts. Local thermal and tectonic aberrations associated with this phenomenon over print onto the worldwide pattern of marginal basin subsidence. A further rise in the geothermal gradient may have been responsible for renewed taphrogenesis in eastern Africa in Tertiary times.

Description: We have compiled both laboratory and worldwide field data on electrical conductivity to help understand the physical implications of deep crustal electrical profiles. Regional heat flow was used to assign temperatures to each layer in regional electrical conductivity models; we avoided those data where purely conductive heat flow suggested temperatures more than about 1000°C, substantially higher than solidus temperatures and outside the range of validity of heat flow models. The resulting plots of log conductivity σ versus 1/T demonstrate that even low-conductivity layers (LCL) have conductivities several orders of magnitude higher than dry laboratory samples and that the data can be represented by straight line fits. In addition, technically active regions show systematically higher conductivities than do shield areas. Because volatiles are usually lost in laboratory measurements and their absence is a principal difference between laboratory and field conditions, these materials probably account for the relatively higher conductivities of rocks in situ in the crust; free water in amounts of 0.01–0.1% in fracture porosity could explain crustal conductivities. Other possibilities are graphite, hydrated minerals in rare instances, and sulfur in combination with other volatiles. As most of the temperatures are less than 700°C, partial melting seems likely only in regions of highest heat flow where the conductive temperature profiles are inappropriate. Another result is that at a given temperature, crustal high-conductivity layers (HCL) are more conductive by another order of magnitude and show more scatter than do LCL's. Because the differences between HCL's and LCL's are independent of temperature, we must invoke more than temperature increases as a cause for large conductivity increases; increased fluid concentration in situ seems a probable cause for enhanced conductivities in HCL's. From the point of view of these observations, it does not matter whether the fluids are in communication with the surface or trapped at lithostatic pressures.

Description: The exchange of inorganic nutrients; ammonium, nitrate and reactive phosphate between burrows of the infaunal polychaete Nereis virens Sars and the overlying water was assessed using V-shaped sediment cores. Exchange was determined by monitoring ventilation current and nutrient concentration of in- and excurrent water. Ammonium supply appeared independent of overlying water concentrations, showing a constant release of 0.5 μmol·h−1 (for a 2-g individual + burrow system) at concentrations from 2 to 87 μM. Of this release ≈40% originated from worm excretion, and the rest from microbial mineralization. Nitrate and phosphate exchange appeared very sensitive to overlying water concentrations, having equilibrium (zero flux) at 10–15 and 3 μM, respectively. Below these concentrations nitrate showed a slight release (due to nitrification), whereas phosphate was released at a rate of 3.2 × 10−2 μmol·h−1 at 1 μM (mineralization and desorption). Above equilibrium they both were removed during water passage through worm burrows, reaching 0.4 μmol·h−1 for nitrate at 107 μM (nitrate reduction) and 3.7 × 10−2 μmol·h−1 for phosphate at 5.6 μM (adsorption processes). The burrow system apparently acted as a buffer for phosphate and, to some degree, nitrate in the overlying water. At the study site (Norsminde Fjord estuary) nereid burrows were estimated to increase the sediment-water interface 150%. About 17% of the water column was cycled through the sediment by Nereis each day. The worm + burrow system was estimated to release 95 μmol· m−2·h−1 ammonium to the overlying water, which was ≈76–90% of the total release of ammonium from the sediment (30–36% was worm excretion).

Description: Acoustic basement lies at an average of between 6.0 and 6.5 sec two-way time below sea level in the southern Rockall Trough and northern Porcupine Abyssal Plain. The overlying sedimentary succession reaches maximum thicknesses of at least 4.0 sec, and can be divided by 3 regionally-developed seismic reflecting horizons, which are used as a framework to establish an acoustic stratigraphy for the area by selecting three “type” seismic sections. These reflectors are named, in ascending order, Shackleton, Charcot and Challenger. The area is crossed by E—W basement high structures, the Clare Lineament (which may be an easterly extension of the Charlie Gibbs Fracture Zone), that separates the Porcupine Abyssal Plain from the eastern part of southern Rockall Trough. Under the latter, the post-Shackleton acoustic sequence is thickened, as if dammed to the north of the Clare Lineament, whilst a further thickening, above reflector Charcot, occurs along a NE—SW line somewhat farther north into the southern Rockall Trough. This can also be related to shallow-lying acoustic basement features. Pre-Shackleton sediments overlie a very irregular basement topography. The acoustic characters of the various sediment packages are described and it is speculated that major changes in the sedimentary environments took place across reflectors Shackleton and Challenger, the latter probably establishing the modern bottom current circulation patterns. No ages can be unequivocally assigned to the main reflectors, but previously published data suggest a late Eocene—Oligocene age for Challenger. Possible lavas or sills are identified in the succession between reflectors Shackleton and Charcot.