ALBERT

Description: Santorini, Greece is a major explosive volcano. The Santorini volcanic complex is composed of two active volcanoes—Nea Kameni and Mt. Columbo. Holocene eruptions have generated a variety of processes and deposits and eruption mechanisms pose significant hazards of various types. It has been recognized that, for major European volcanoes, few studies have focused on the social aspects of volcanic activity and little work has been conducted on public perceptions of hazard, risk and vulnerability. Such assessments are an important element of establishing public education programmes and developing volcano disaster management plans. We investigate perceptions of volcanic hazards on Santorini. We find that most residents know that Nea Kameni is active, but only 60% know that Mt. Columbo is active. Forty percent of residents fear that negative impacts on tourism will have the greatest effect on their community. In the event of an eruption, 43% of residents would try to evacuate the island by plane/ferry. Residents aged N50 have retained a memory of the effects of the last eruption at the island, whereas younger residents have no such knowledge. We find that dignitaries and municipal officers (those responsible for planning and managing disaster response) are informed about the history, hazards and effects of the volcanoes. However, there is no bemergency planQ for the island and there is confusion between various departments (Civil Defense, Fire, Police, etc.) about the emergency decision-making process. The resident population of Santorini is at high risk from the hazards associated with a future eruption.

Description: Late glacial to post glacial sea-level changes provide direct evidence of the progress of melting of large ice sheets during the last deglaciation but, although the correlation between ice and ocean volumes is incontrovertible, the causal link is commonly obscured. Local effects including tectonics, isostatic and hydroisostatic responses and equatorial ocean-syphoning impose additional signals that hide the true picture. A detailed regional study of the Western Indian Ocean based on the analysis of drill cores carried out through modern reefs, in combination with observations and sampling of reef foreslopes, and investigations of outcrops provides a comprehensive data base. Sites from a range of tectonic settings include the microcontinental margins of Madagascar, the granitic Seychelles, and the isolated volcanic islands of Réunion, Mauritius and the Comoros in which the effects of subsidence can be shown to be small. These cover a range of latitudes, and comparisons with adjacent sites on continental margins allow the construction of sea-level curves that closely reflect the eustatic response and disengage this from the effects of other mechanisms. The Mayotte foreslope in the Comoro Islands provides the first coral reef record of sea-level change during the early deglaciation in the Indian Ocean (110–115 m below present sea level between 18,000 and 17,000 yr BP). Two distinctive reef terraces, at 90 and 60 m water depth are dated at 13,600 yr BP and partly attributed to the Younger Dryas period (12,700–11,600 cal yr BP). Reef drowning at around 13,500 yr BP may correspond to Meltwater Pulse 1A, and although there were surges in the rate of sea-level rise, most notably between 11,950 and 11,350 yr BP, there is little evidence to support a well-defined Meltwater Pulse 1B. Reconstructed Holocene sea-level curves are in good agreement and reflect a rapid sea-level rise of about 6 mm yr−1 between 10,000 and 7500 yr BP, followed by a clear inflection around 7500 yr BP when the rate fell to 1.1 mm yr−1. Modern reefs started to grow 8000–9000 years ago. In the post-glacial period the rate of sea-level rise was 1–1.5 mm yr−1 before stabilization at its present level 3000–2500 years ago. Curves for the 10,000–6000 yr−1 BP interval correspond closely with those predicted by theoretical models but lie below these in the subsequent period. In particular, and with the exception of the margins of the Madagascar microcontinent influenced by hydroisostatic processes, they do not reflect predicted higher sea-level stands during the late Holocene.

Description: New data obtained during re-mapping of the northern part of Syros (Cyclades, Greece) allow the refinement of existing concepts about the structural evolution of this island. A metabasite belt and its metasedimentary envelope near Kampos and San Michali were mapped at a 1:5000 scale, with special emphasis on the structural inventory. The HP/LT rocks (P , 1.5 GPa; T , 500 8C at ,50 Ma) exposed are intensely deformed by at least two isoclinal folding events. Relative age relations between deformation and peak metamorphism indicate that isoclinal folding took place before or during peak metamorphism. Later deformation stages include Miocene non-penetrative upright kink folding and crenulation, transpressional strike-slip faulting, and open upright cylindrical folding, followed by the development of steep normal faults. Taking into account recent zircon U–Pb geochronological constraints, lithostratigraphic observations, and published data on the Neogene structural evolution of the Aegean, we present a history for the rocks of Syros, beginning with the formation of the oceanic crust(represented by the metabasites) to the present.

Description: The decadal-scale variability in the tropical Pacific has been analyzed herein by means of observations and numerical model simulations. The two leading modes of the sea surface temperature (SST) variability in the central western Pacific are a decadal mode with a period of about 10 yr and the ENSO mode with a dominant period of about 4 yr. The SST anomaly pattern of the decadal mode is ENSO like. The decadal mode, however, explains most variance in the western equatorial Pacific and off the equator. A simulation with an ocean general circulation model (OGCM) forced by reanalysis data is used to explore the origin of the decadal mode. It is found that the variability of the shallow subtropical–tropical overturning cells is an important factor in driving the decadal mode. This is supported by results from a multicentury integration with a coupled ocean–atmosphere general circulation model (CGCM) that realistically simulates tropical Pacific decadal variability. Finally, the sensitivity of the shallow subtropical–tropical overturning cells to greenhouse warming is discussed by analyzing the results of a scenario integration with the same CGCM.

Description: The current system east of the Grand Banks was intensely observed by World Ocean Circulation Experiment (WOCE) array ACM-6 during 1993–95 with eight moorings, reaching about 500 km out from the shelf edge and covering the water column from about 400-m depth to the bottom. More recently, a reduced array by the Institut für Meerskunde (IfM) at Kiel, Germany, of four moorings was deployed during 1999–2001, focusing on the deep-water flow near the western continental slope. Both sets of moored time series, each about 22 months long, are combined here for a mean current boundary section, and both arrays are analyzed for the variability of currents and transports. A mean hydrographic section is derived from seven ship surveys and is used for geostrophic upper-layer extrapolation and isopycnal subdivision of the mean transports into deep-water classes. The offshore part of the combined section is dominated by the deep-reaching North Atlantic Current (NAC) with currents still at 10 cm s−1 near the bottom and a total northward transport of about 140 Sv (Sv ≡ 106 m3 s−1), with the details depending on the method of surface extrapolation used. The mean flow along the western boundary was southward with the section-mean North Atlantic Deep Water outflow determined to be 12 Sv below the σθ = 27.74 kg m−3 isopycnal. However, east of the deep western boundary current (DWBC), the deep NAC carries a transport of 51 Sv northward below σθ = 27.74 kg m−3, resulting in a large net northward flow in the western part of the basin. From watermass signatures it is concluded that the deep NAC is not a direct recirculation of DWBC water masses. Transport time series for the DWBC variability are derived for both arrays. The variance is concentrated in the period range from 2 weeks to 2 months, but there are also variations at interannual and longer periods, with much of the DWBC variability being related to fluctuations and meandering of the NAC. A significant annual cycle is not recognizable in the combined current and transport time series of both arrays. The moored array results are compared with other evidence on deep outflow and recirculation, including recent models of different types and complexity.

Description: Measurements of δ18O and δ13C isotopes in three benthic foraminiferal species from surface sediments of the eastern Laptev Sea are compared to water δ18O values and δ13C values of dissolved inorganic carbon (DIC). Samples investigated originate from two environmentally contrasting core locations, which are influenced by riverine freshwater runoff to a varying degree. At the river-distal site, located within relatively stable marine conditions on the outer shelf, Elphidiella groenlandica, Haynesina orbiculare and Elphidium excavatum forma clavata show a positive specific offset of 1.4‰, 1.5‰ and 1‰, respectively, in their δ18O values relative to the expected value for inorganic calcite precipitated under equilibrium conditions. At the site close to the Lena River confluence, with enhanced seasonal hydrographic contrasts, calculated δ18O offsets in E. groenlandica and in H. orbiculare remain about the same whereas E. e. clavata displays a distinctly negative offset of −1.8‰. The δ18O variation in E. e. clavata is interpreted as a vital effect, a finding which limits the potential of this species for reconstructing freshwater-influenced shelf paleoenvironments on the basis of oxygen isotopes. This interpretation gains support when comparing foraminiferal δ13C with the δ13CDIC of the water. While some of the difference in the carbonate δ13C seems to be controlled by a riverine-related admixture of DIC, clearly defined δ13C ranges in each of the three foraminifera at the river-proximal site shows that also the carbon isotopic signature in E. e. clavata is particularly affected by environmental factors.

Description: Extensive methane hydrate layers are formed in the near-surface sediments of the Cascadia margin. An undissociated section of such a layer was recovered at the base of a gravity core (i.e. at a sediment depth of 120 cm) at the southern summit of Hydrate Ridge. As a result of salt exclusion during methane hydrate formation, the associated pore waters show a highly elevated chloride concentration of 809 mM. In comparison, the average background value is 543 mM. A simple transport-reaction model was developed to reproduce the Cl- observations and quantify processes such as hydrate formation, methane demand, and fluid flow. From this first field observation of a positive Cl- anomaly, high hydrate formation rates (0.15–1.08 mol cm-2 a-1) were calculated. Our model results also suggest that the fluid flow rate at the Cascadia accretionary margin is constrained to 45–300 cm a-1. The amount of methane needed to build up enough methane hydrate to produce the observed chloride enrichment exceeds the methane solubility in pore water. Thus, most of the gas hydrate was most likely formed from ascending methane gas bubbles rather than solely from CH4 dissolved in the pore water.

Description: A composite record (LO09-14) of three sediment cores from the subpolar North Atlantic (Reykjanes Ridge) was investigated in order to assess surface ocean variability during the last 11 kyr. The core site is today partly under the influence of the Irminger Current (IC), a branch of the North Atlantic Drift continuing northwestward around Iceland. However, it is also proximal to the Sub-Arctic Front (SAF) that may cause extra dynamic hydrographic conditions. We used statistical methods applied to the fossil assemblages of diatoms to reconstruct quantitative sea surface temperatures (SSTs). Our investigations give evidence for different regional signatures of Holocene surface oceanographic changes in the North Atlantic. Core LO09-14 reveal relatively low and highly variable SSTs during the early Holocene, indicating a weak IC and increased advection of subpolar water over the site. A mid-Holocene thermal optimum with a strong IC occurs from 7.5 to 5 kyr and is followed by cooler and more stable late Holocene surface conditions. Several intervals throughout the Holocene are dominated by the diatom species Rhizosolenia borealis, which we suggest indicates proximity to a strongly defined convergence front, most likely the SAF. Several coolings, reflecting southeastward advection of cold and ice-bearing waters, occur at 10.4, 9.8, 8.3, 7.9, 6.4, 4.7, 4.3 and 2.8 kyr. The cooling events recorded in the LO09-14 SSTs correlate well with both other surface records from the area and the NADW reductions observed at ODP Site 980 indicating a surface-deepwater linkage through the Holocene.

Description: Variability in the chemical composition, textures and electrical properties of the major sulphide mineral pyrite may be one cause of variation in the flotation and leaching properties of different sulphide ores. This report summarises the results of a review that has been conducted to establish the range in variability of natural pyrite with regard to chemical composition, texture and electrical properties. The S/Fe ratio in pyrite is generally very close to 2, suggesting that stoichiometric variability is small in this mineral. However, minor deviations from the ideal are reported. Pyrite typically contains a host of minor and trace elements, including: Ag, As, Au, Bi, Cd, Co, Cu, Hg, Mo, Ni, Pb, Pd, Ru, Sb, Se, Sb, Sn, Te, Tl and Zn. Minor elements are often present within the mineral lattice at levels up to several percent, these include; As, Co, Ni, Sb and possibly Cu, Ag, Au and Sn. Arsenian pyrites may contain up to 10% As, and such specimens are typically rich in other minor and trace elements, particularly Au. As-rich pyrites typically appear to have formed at relatively low temperatures and often exhibit habits that suggest rapid precipitation; these As-rich pyrites may be metastable and, therefore, relatively reactive. Considerable variation has been reported in the semiconducting properties of pyrite. Natural pyrites are either n- or p-type semiconductors and reported conductivities vary by four orders of magnitude. The rates of galvanic processes in mineral pulps are likely to vary with the mineral conductivities. Typically p-type pyrites exhibit low conductivities and are As-rich and are suggested to have formed at relatively low temperature, whereas relatively highly conducting n-type pyrites are typically As-poor and suggested to have formed at high temperature. Based on comparative measurements of rest potential, iron pyrite is the most electrochemically inert of the common sulphide minerals, with a rest potential of the order of 0.6 (cf. sphalerite and galena with rest potentials of 0.46 and 0.40 V. vs. SHE, respectively). Variability in the rest potential of different samples of this mineral are generally small. However, based on the extent of pyrite reaction during a peroxide dissolution procedure, the chemical reactivity of pyrite samples may differ significantly.

Description: A continuous lacustrine sequence from the western part of Lama Lake (69°32′N, 90°12′E), complemented by a peat sequence from the lake catchment provides the first detailed environmental reconstruction for the Late Glacial and Holocene on the Taymyr Peninsula. Scarce steppe-like communities with Artemisia, Poaceae, and Cyperaceae dominated during the Late Glacial. Tundra-like communities with Betula nana, Dryas, and Salix grew on more mesic sites. There are distinct climatic signals, which may be correlated with the Bølling and Allerød warming and Middle and Younger Dryas cooling. The Late Glacial/Preboreal transition, at about 10,000 14C yr BP, was characterized by changes from predominantly open herb communities to shrub tundra ones. Larch forest might have been established as early as 9700–9600 14C yr BP, whilst shrub alder came to the area ca 9500–9400 14C yr BP, and spruce did not reach area before ca 9200 14C yr BP. Spruce-larch forests with shrub alder and tree birch dominated the vegetation around the Lama Lake from ca 9000 14C yr BP. Dwarf birch communities were also broadly distributed. The role of spruce in the forest gradually decreased after 4500 14C yr BP. The vegetation cover in the Lama Lake area became similar to the modern larch-spruce forest ca 2500 14C yr BP. A pollen-based biome reconstruction supports a quantitative interpretation of the pollen spectra. Climate reconstructions obtained with information-statistical and plan-functional-type methods show very similar trends in reconstructed July temperature since ca 12,300 14C yr BP, while precipitation anomalies are less coherent, especially during the Late Glacial–Holocene transition.