ALBERT

Description: Four cores from the Antarctic continental margin located between 50 and 200 km from the present-day ice shelf edge, were selected for sedimentological and mass spectrometer analysis. The first stable isotope records of the Southern Polar Ocean can be correlated in detail with global isotope stratigraphy. Together with magnetostratigraphic, sedimentological and micropaleontological data, the record provides stratigraphic and paleoceanographic information back to the Jaramillo subchron (910 kyr). Although the isotope values have been altered by diagenetic processes in the sediments, which are poor in carbonate, an interpretation is possible via correlation with the sedimentological parameters. Oxygen isotope data give indications for a meltwater spike at the beginning of interglacials, when large scale melting of parts of the ice shelves took place. The synchronous record of the benthic and planktonic d13C-signals reflect continuous bottom water formation also during glacials. Primary productivity was strictly reduced during glacials due to continuous ice coverage in the Weddell Sea. The climatic improvement at the beginning of an interglacial is associated with peak values in biologic activity lasting for about 15 kyr. During one climatic cycle, mean sedimentation rates at the continental margin decrease with increasing distance from the continent from 5.2 to 1.3 cm/kyr. Maximum sedimentation rates of 25 cm/kyr at the beginning of an interglacial down to 0.6 cm/kyr during glacial periods have been calculated. The rate is mainly controlled by movements of the ice shelf edge and ice rafting.

Description: To reveal the late Quaternary paleoenvironmental changes at the Antarctic continental margin, we test a lithostratigraphy, adjusted to a stable isotope record from the eastern Weddell Sea. The stratigraphy is used to produce a stacked sedimentological data set of eleven sediment cores. We derive a general model of glacio marine sedimentation and paleoenvironmental changes at the East Antarctic continental margin during the last two climatic cycles (300 kyr). The sedimentary processes considered include biological productivity, ice-rafting, current transport, and gravitational downslope transport. These processes are controlled by a complex interaction of sea-level changes and paleoceanographic and paleoglacial conditions in response to changes of global climate and local insolation. Sedimentation rates are mainly controlled by ice-rafting which reflects mass balance and behaviour of the Antarctic ice sheet. The sedimentation rates decrease with distance from the continent and from interglacial to glacial. Highest rates occur at the very beginning of interglacials, i.e. of oxygen isotope events 7.5, 5.5, and 1.1, these being up to five times higher than during glacials. The sediments can be classified into five distinct facies and correlated to different paleoenvironments: at glacial terminations (isotope events 8.0, 6.0, and 2.0), the Antarctic cryosphere adjusts to new climatic conditions. The sedimentary processes are controlled by the rise of sea level, the destruction of ice shelves, the retreat of sea-ice and the recommenced feeding of warm North Atlantic Deep Water (NADW) to the Circumpolar Deep Water (CDW). During peak warm interglacial periods (at isotope events 7.5, 7.3, 5.5., and 1.1), the CDW promotes warmer surface waters and thus the retreat of sea-ice which in turn controls the availability of light in surface waters. At distinct climatic thresholds local insolation might also influence sea-ice distribution. Primary productivity and bioturbation increase, the CCD rises and carbonate dissolution occurs in slope sediments also in shallow depth. Ice shelves and coastal polynyas favour the formation of very cold and saline Ice Shelf Water (ISW) which contributes to bottom water formation. During the transition from a peak warm time to a glacial (isotope stages 7.2-7.0, and 5.4-5.0) the superimposition of both intense ice-rafting and reduced bottom currents produces a typical facies which occurs with a distinct lag in the time of response of specific sedimentary processes to climatic change. With the onset of a glacial (at isotope events 7.0 and 5.0) the Antarctic ice sheet expands due to the lowering of sea-level with the extensive glaciations in the northern Hemisphere. Gravitational sediment transport becomes the most active process, and sediment transfer to the deep sea is provided by turbidity currents through canyon systems. During Antarctic glacial maxima (isotope stages between 7.0-6.0, and 5.0-2.0) the strongly reduced input of NADW into the Southern Ocean favours further advances of the ice shelves far beyond the shelf break and the continous formation of sea ice. Below ice shelves and/or closed sea ice coverage contourites are deposited on the slope.

Description: Oxygen and carbon isotope measurements were carried out on tests of planktic foraminifers N. pachyderma (sin.) from eight sediment cores taken from the eastern Arctic Ocean, the Fram Strait, and the lceland Sea, in order to reconstruct Arctic Ocean and Norwegian-Greenland Sea circulation patterns and ice covers during the last 130,000 years. In addition, the influence of ice, temperature and salinity effects on the isotopic signal was quantified. Isotope measurements on foraminifers from sediment surface samples were used to elucidate the ecology of N. pachyderma (sin.). Changes in the oxygen and carbon isotope composition of N. pachyderma (sin.) from sediment surface samples document the horizontal and vertical changes of water mass boundaries controlled by water temperature and salinity, because N. pachyderma (sin.) shows drastic changes in depth habitats, depending on the water mass properties. It was able to be shown that in the investigated areas a regional and spatial apparent increase of the ice effect occurred. This happened especially during the termination I by direct advection of meltwaters from nearby continents or during the termination and in interglacials by supply of isotopically light water from rivers. A northwardly proceeding overprint of the 'global' ice effect, increasing from the Norwegian-Greenland Sea to the Arctic Ocean, was not able to be demonstrated. By means of a model the influence of temperature and salinity on the global ice volume signal during the last 130,000 years was recorded. In combination with the results of this study, the model was the basis for a reconstruction of the paleoceanographic development of the Arctic Ocean and the Norwegian-Greenland Sea during this time interval. The conception of a relatively thick and permanent sea ice cover in the Nordic Seas during glacial times should be replaced by the model of a seasonally and regionally highly variable ice cover. Only during isotope stage 5e may there have been a local deep water formation in the Fram Strait.

Description: Vertical profiles of dissolved and particulate 230Th and 231Pa were obtained across the Antarctic Circumpolar Current (ACC) in the southern Atlantic. North of the Polar Front, dissolved and total 230Th increase with depth in conformity with published scavenging models. There is no depletion of 230Th or 231Pa in the water column south of the Polar Front, thought to be an area of enhanced biological productivity. 230Th concentrations increase three-fold to the Weddell Sea across the ACC. Dissolved and total 231Pa concentrations are relatively constant below 500 m depth at about 0.3 dpm m**-3, and change little with depth or latitude. The results from the Weddell Gyre are explained by a mixing-scavenging model that takes into account the input of lower Circumpolar Deep Water through upwelling, which is the main source of water in the Weddell Gyre and is enriched in 230Th but not in 231Pa. 230Th accumulates in the Weddell Gyre as a result of a reduction in the scavenging rate and by ingrowth from 234U. Ingrowth is more significant for 230Th than for 231Pa because the residence time of water in the gyre (about 35 years) is similar to the scavenging residence time of Th in the south Atlantic (29 years) but shorter than that of Pa (120 years). It is argued that changes in 230Th accumulation in the past may reflect changes in water residence time and in the formation rate of Weddell Sea Deep Water.

Description: 228Ra and its granddaughter 228Th were measured on a N-S transect from 45's to the Antarctic continent across the Antarctic Circumpolar Current (ACC) and the Weddell Sea. The distributions of 230Th, 228Th and 228Ra show that southward transport across the ACC of Circumpolar Deep Water (CDW), the source of Warm Deep Water (WDW) in the Weddell Sea, occurs on a time scale between 8 and 30 years, in qualitative agreement with estimates of the upwelling rate of WDW. The distribution of 228Ra in deep waters is controlled by advection and isopycnal mixing rather than diapycnal mixing. In the Weddell Sea, deep-water 228Ra activities reach 15-20 dpm/m**3. Enrichment in deep water is controlled by the production in the deep-sea floor, favoured by low biogenic sediment accumulation rates and consequently high 232Th contents in the surface sediment (3 to 5 dpm/g). The highest 228Ra value (73 dpm/m**3) was observed near the sea floor in a channel where an eastern outflow of Weddell Sea Bottom Water (WSBW) is suspected. It is not yet known whether this value is produced in-situ by accumulation in the stratified bottom water, or contains a Signal of enrichment in shelf- and Ice Shelf Water. High 228Ra activities on the south-eastem shelf (22 dpm/m**3) and low activities offshore yield an estimated residente time of 1.5 years on this shelf and imply slow exchange with offshore waters.

Description: During four expeditions with RV "Polarstern" at the continental margin of the southern Weddell Sea, profiling and geological sampling were carried out. A detailed bathymetric map was constructed from echo-sounding data. Sub-bottom profiles, classified into nine echotypes, have been mapped and interpreted. Sedimentological analyses were carried out on 32 undisturbed box grab surface samples, as well as on sediment cores from 9 sites. Apart from the description of the sediments and the investigation of sedimentary structures on X-radiographs the following characteristics were determined: grain-size distributions; carbonate and Corg content; component distibutions in different grain-size fractions; stable oxygen and carbon isotopes in planktic and, partly, in benthic foraminifers; and physical properties. The stratigraphy is based On 14C-dating, oxygen isotope Stages and, at one site, On paleomagnetic measurements and 230Th-analyses The sediments represent the period of deposition from the last glacial maximum until recent time. They are composed predominantly of terrigenous components. The formation of the sediments was controlled by glaciological, hydrographical and gravitational processes. Variations in the sea-ice coverage influenced biogenic production. The ice sheet and icebergs were important media for sediment transport; their grounding caused compaction and erosion of glacial marine sediments on the outer continental shelf. The circulation and the physical and chemical properties of the water masses controlled the transport of fine-grained material, biogenic production and its preservation. Gravitational transport processes were the inain mode of sediment movements on the continental slope. The continental ice sheet advanced to the shelf edge and grounded On the sea-floor, presumably later than 31,000 y.B.P. This ice movement was linked with erosion of shelf sediments and a very high sediment supply to the upper continental slope from the adiacent southern shelf. The erosional surface On the shelf is documented in the sub-bottom profiles as a regular, acoustically hard reflector. Dense sea-ice coverage above the lower and middle continental slope resulted in the almost total breakdown of biogenic production. Immediately in front of the ice sheet, above the upper continental slope, a 〈50 km broad coastal polynya existed at least periodically. Biogenic production was much higher in this polynya than elsewhere. Intense sea-ice formation in the polynya probably led to the development of a high salinity and, consequently, dense water mass, which flowed as a stream near bottom across the continental slope into the deep sea, possibly contributing to bottom water formation. The current velocities of this water mass presumably had seasonal variations. The near-bottom flow of the dense water mass, in combination with the gravity transport processes that arose from the high rates of sediment accumulation, probably led to erosion that progressed laterally from east to West along a SW to NE-trending, 200 to 400 m high morphological step at the continental slope. During the period 14,000 to 13,000 y.B.P., during the postglacial temperature and sea-level rise, intense changes in the environmental conditions occured. Primarily, the ice masses on the outer continental shelf started to float. Intense calving processes resulted in a rapid retreat of the ice edge to the south. A consequence of this retreat was, that the source area of the ice-rafted debris changed from the adjacent southern shelf to the eastern Weddell Sea. As the ice retreated, the gravitational transport processes On the continental slope ceased. Soon after the beginning of the ice retreat, the sea-ice coverage in the whole research area decreased. Simultaneously, the formation of the high salinity dense bottom water ceased, and the sediment composition at the continental slope then became influenced by the water masses of the Weddell Gyre. The formation of very cold Ice Shelf Water (ISW) started beneath the southward retreating Filchner-Ronne Ice Shelf somewhat later than 12,000 y.B.P. The ISW streamed primarily with lower velocities than those of today across the continental slope, and was conducted along the erosional step on the slope into the deep sea. At 7,500 y.B.P., the grounding line of the ice masses had retreated 〉 400 km to the south. A progressive retreat by additional 200 to 300 km probably led to the development of an Open water column beneath the ice south of Berkner Island at about 4,000 y.B.P. This in turn may have led to an additional ISW, which had formed beneath the Ronne Ice Shelf, to flow towards the Filcher Ice Shelf. As a result, increased flow of ISW took place over the continental margin, possibly enabling the ISW to spill over the erosional step On the upper continental slope towards the West. Since that time, there is no longer any documentation of the ISW in the sedimentary Parameters on the lower continental slope. There, recent sediments reflect the lower water masses of the Weddell Gyre. The sea-ice coverage in early Holocene time was again so dense that biogenic production was significantly restricted.

Description: We have measured the carbon isotopic composition of dissolved inorganic carbon in bottom waters of the Ontong Java Plateau (western equatorial Pacific) and on the northern Emperor Seamounts (northwest Pacific). Each of these locations is several hundred miles from the nearest Geochemical Ocean Sections Study (GEOSECS) stations, and the observed delta13C values at each site differ substantially from regionally averaged GEOSECS delta13C profiles. We discuss the possible causes of these differences, including horizontal variability, near-bottom effects, and problems with the Pacific GEOSECS delta13C data. We also measured the isotopic composition (C and O) of core top C. wuellerstorfi from a depth transect of cores at each location. The delta18O data are used to verify that our samples are Holocene. Comparison of foraminiferal and bottom water delta13C values shows that this species faithfully records bottom water delta13C at both sites and demonstrates that there is no depth-related artifact in the dissolved inorganic carbon-C. wuellerstorfi delta13C relationship at these sites.

Description: Probable in-situ manganese deposits larger than 1 cm in diameter buried in ODP/DSDP cores were selected for study after examining previous descriptions of the manganese deposits in site reports and the ODP data base. Most of the selected samples from 11 cores occur at or just above sedimentary hiatuses or in slowly deposited sediments and are overlain by rapidly deposited sediments of biogenic, terrigenous or volcanogenic origin. The changes in sedimentation recorded in the lithostratigraphic sections around these deposits are closely related to changes in tectonic evolution, deep water circulation or biological productivity at the sites. The similarity in composition and structure of the buried deposits to those of the modern manganese nodules and crusts with no evidence of post-depositional change suggest that buried manganese deposits may be used as indicators of past sedimentary conditions during which they formed. Their major components are hydrogenetic and earlydiagenetic manganese minerals as well as detrital minerals. The characteristics of these manganese deposits suggests that similar processes of deposition have taken place since the Paleogene or older.

Description: The measurements were obtained during two North Sea wide STAR-shaped cruises during summer 1986 and winter 1987, which were performed to investigate the circulation induced transport and biologically induced pollutant transfer within the interdisciplinary research in the project "ZISCH - Zirkulation und Schadstoffumsatz in der Nordsee / Circulation and Contaminant Fluxes in the North Sea (1984-1989)". The inventory presents parameters measured on hydrodynamics, nutrient dynamics, ecosystem dynamics and pollutant dynamics in the pelagic and benthic realm. The research program had the objective of quantifying fluxes of major budgets, especially contaminants in the North Sea. In spring 1986, following the phytoplankton spring bloom, and in late winter 1987, at minimum primary production activity, the North Sea ecosystem was investigated on a station net covering the whole North Sea. The station net was shaped like a star. Sampling started in the centre, followed by the northwest section and moving counter clockwise around the North Sea following the residual currents. By this strategy, a time series was measured in the central North Sea and more synoptic data sets were obtained in the individual sections. Generally advection processes have to be considered when comparing the data from different stations. The entire sampling period lasted for more than six weeks in each cruise. Thus, a time-lag should be considered especially when comparing the data from the eastern and the western part of the central and northern North Sea, where samples were taken at the beginning and at the end of the campaign. The ZISCH investigations represented a qualitatively and quantitatively new approach to North Sea research in several respects. (1) The first simultaneous blanket coverage of all important biological, chemical and physical parameters in the entire North Sea ecosystem; (2) the first simultaneous measurements of major contaminants (metals and organohaline compounds) in the different ecosystem compartments; (3) simultaneous determinations of atmospheric inputs of momentum, energy and matter as important ecosystem boundary conditions; (4) performance of the complex measurement program during two seasons, namely the spring plankton bloom and the subsequent winter period of minimal biological activity; and (5) support of data analysis and interpretation by oceanographic and meteorological numerical models on the same scales.

Description: Radiocarbon ages on CaCO3 from deep-sea cores offer constraints on the nature of the CaCO3 dissolution process. The idea is that the toll taken by dissolution on grains within the core top bioturbation zone should be in proportion to their time of residence in this zone. If so, dissolution would shift the mass distribution in favor of younger grains, thereby reducing the mean radiocarbon age for the grain ensemble. We have searched in vain for evidence supporting the existence of such an age reduction. Instead, we find that for water depths of more than 4 km in the tropical Pacific the radiocarbon age increases with the extent of dissolution. We can find no satisfactory steady state explanation and are forced to conclude that this increase must be the result of chemical erosion. The idea is that during the Holocene the rate of dissolution of CaCO3 has exceeded the rain rate of CaCO3. In this circumstance, bioturbation exhumes CaCO3 from the underlying glacial sediment and mixes it with CaCO3 raining from the sea surface.