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  • Articles  (145)
  • Open Access-Papers  (145)
  • 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry  (141)
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  • GEOPHYSICS
  • 2010-2014  (145)
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  • Articles  (145)
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  • 1
    Publication Date: 2020-12-09
    Description: Climate change negotiations aim to reduce net greenhouse-gas emissions by encouraging direct reductions of emissions and crediting countries for their terrestrial greenhouse-gas sinks. Ecosystem carbon dioxide uptake has offset nearly 10% of Europe’s fossil fuel emissions, but not all of this may be creditable under the rules of the Kyoto Protocol. Although this treaty recognizes the importance of methane and nitrous oxide emissions, scientific research has largely focused on carbon dioxide. Here we review recent estimates of European carbon dioxide, methane and nitrous oxide fluxes between 2000 and 2005, using both top-down estimates based on atmospheric observations and bottom-up estimates derived from ground-based measurements. Both methods yield similar fluxes of greenhouse gases, suggesting that methane emissions from feedstock and nitrous oxide emissions from arable agriculture are fully compensated for by the carbon dioxide sink provided by forests and grasslands. As a result, the balance for all greenhouse gases across Europe’s terrestrial biosphere is near neutral, despite carbon sequestration in forests and grasslands. The trend towards more intensive agriculture and logging is likely to make Europe’s land surface a significant source of greenhouse gases. The development of land management policies which aim to reduce greenhouse-gas emissions should be a priority.
    Description: Published
    Description: 842-850
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: carbon budget ; carbon dioxide ; methane ; greenhouse gas emission ; 03. Hydrosphere::03.04. Chemical and biological::03.04.02. Carbon cycling ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2021-01-07
    Description: The elemental fluxes and heat flow associated with large aquifer systems can be significant both at local and at regional scales. In fact, large amounts of heat transported by regional groundwater flow can affect the subsurface thermal regime, and the amount of matter discharged towards the surface by large spring systems can be significant relative to the elemental fluxes of surface waters. The Narni-Amelia regional aquifer system (Central Italy) discharges more than 13 m3 sec)1 of groundwater characterised by a slight thermal anomaly, high salinity and high pCO2. During circulation in the regional aquifer, groundwater reacts with the host rocks (dolostones, limestones and evaporites) and mixes with deep CO2-rich fluids of mantle origin. These processes transfer large amounts of dissolved substances, in particular carbon dioxide, and a considerable amount of heat towards the surface. Because practically all the water circulating in the Narni-Amelia system is discharged by few large springs (Stifone-Montoro), the mass and energy balance of these springs can give a good estimation of the mass and heat transported from the entire system towards the surface. By means of a detailed mass and balance of the aquifer and considering the soil CO2 fluxes measured from the main gas emission of the region, we computed a total CO2 discharge of about 7.8 · 109 mol a)1 for the whole Narni-Amelia system. Finally, considering the enthalpy difference between infiltrating water and water discharged by the springs, we computed an advective heat transfer related to groundwater flow of 410 ± 50 MW.
    Description: Published
    Description: 182-196
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: carbon dioxide degassing ; heat flow ; regional aquifer ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
    Publication Date: 2021-01-07
    Description: The quaternary volcanic complex of Mount Amiata is located in southern Tuscany (Italy) and represents the most recent manifestation of the Tuscan Magmatic Province. The region is characterised by a large thermal anomaly and by the presence of numerous CO2-rich gas emissions and geothermal features, mainly located at the periphery of the volcanic complex. Two geothermal systems are located, at increasing depths, in the carbonate and metamorphic formations beneath the volcanic complex. The shallow volcanic aquifer is separated from the deep geothermal systems by a low permeability unit (Ligurian Unit). A measured CO2 discharge through soils of 1.8 109 mol a 1 shows that large amounts of CO2 move from the deep reservoir to the surface. A large range in d13CTDIC ( 21.07 to +3.65) characterises the waters circulating in the aquifers of the region and the mass and isotopic balance of TDIC allows distinguishing a discharge of 0.3 109 mol a 1 of deeply sourced CO2 in spring waters. The total natural CO2 discharge (2.1 109 mol a 1) is slightly less than minimum CO2 output estimated by an indirect method (2.8 109 mol a 1), but present-day release of 5.8 109 mol a 1 CO2 from deep geothermal wells may have reduced natural CO2 discharge. The heat transported by groundwater, computed considering the increase in temperature from the infiltration area to the discharge from springs, is of the same order of magnitude, or higher, than the regional conductive heat flow (〉200 mWm 2) and reaches extremely high values (up to 2700mWm 2) in the north-eastern part of the study area. Heat transfer occurs mainly by conductive heating in the volcanic aquifer and by uprising gas and vapor along fault zones and in those areas where low permeability cover is lacking. The comparison of CO2 flux, heat flow and geological setting shows that near surface geology and hydrogeological setting play a central role in determining CO2 degassing and heat transfer patterns.
    Description: Published
    Description: 860–875
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: Carbon dioxide degassing ; Monte Amiata ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 4
    Publication Date: 2021-01-11
    Description: Globally, terrestrial ecosystems have absorbed about 30% of anthropogenic greenhouse gas emissions over the period 2000–2007 and inter-hemispheric gradients indicate that a significant fraction of terrestrial carbon sequestration must be north of the Equator. We present a compilation of the CO2, CO, CH4 and N2O balances of Europe following a dual constraint approach in which (1) a landbased balance derived mainly from ecosystem carbon inventories and (2) a land-based balance derived from flux measurements are compared to (3) the atmospheric data-based balance derived from inversions constrained by measurements of atmospheric GHG (greenhouse gas) concentrations. Good agreement between the GHG balances based on fluxes (1294±545 Tg C in CO2-eq yr−1), inventories (1299±200 Tg C in CO2-eq yr−1) and inversions (1210±405 Tg C in CO2-eq yr−1) increases our confidence that the processes underlying the European GHG budget are well understood and reasonably sampled. However, the uncertainty remains large and largely lacks formal estimates. Given that European net land to atmosphere exchanges are determined by a few dominant fluxes, the uncertainty of these key components needs to be formally estimated before efforts could be made to reduce the overall uncertainty. The net land-to-atmosphere flux is a net source for CO2, CO, CH4 and N2O, because the anthropogenic emissions by far exceed the biogenic sink strength. The dual-constraint approach confirmed that the European biogenic sink removes as much as 205±72 Tg C yr−1 from fossil fuel burning from the atmosphere. However, This C is being sequestered in both terrestrial and inland aquatic ecosystems. If the C-cost for ecosystem management is taken into account, the net uptake of ecosystems is estimated to decrease by 45% but still indicates substantial C-sequestration. However, when the balance is extended from CO2 towards the main GHGs, C-uptake by terrestrial and aquatic ecosystems is offset by emissions of non-CO2 GHGs. As such, the European ecosystems are unlikely to contribute to mitigating the effects of climate change.
    Description: Published
    Description: 3357–3380
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: carbon dioxide ; methane ; soil ; ecosystems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 5
    Publication Date: 2021-05-17
    Description: This special issue is dedicated to Yuri Taran's outstanding contributions to gas geochemistry that began in the early 1980s with his work on deuterium and 18O compositions of geothermal waters in the Mutnovsky (Kamchatka) region and continues to this day with work on the Kamchatka volcanic volatile budget, carbon isotopes of hydrocarbons, and new insights into the geochemistry of El Chichón volcano, Chiapas. Yuri has contributed greatly to the field of volcanic gas geochemistry and was the first to recognize the distinct deuterium and oxygen isotopic composition of fumarole condensates from volcanoes in Kamchatka (Taran et al. 1987a). The shift in δD and δ18O to significantly heavier values compared to local meteoric water led Yuri to introduce the term “andesitic water” (Taran et al. 1989a, b) which has since been recognized at subduction zone volcanoes globally. This distinct isotopic composition is evidence that volcanoes release water that ultimately originates as subducted seawater and is recycled through the mantle wedge back to the earth's surface. Yuri's early work on the gas emissions from Kamchatka and Kurile Islands volcanoes also included the development and testing of gas geothermometers (Taran 1986) and investigating hydrothermal alteration using isotopic data (Taran et al. 1987b). His curiosity remained focused on the isotope systematics of volcanic gases discharging from Kamchatka and the Kuriles through the late 1980s and 1990s with publications on the gas compositions of Klyuchevskoi (Taran et al. 1991), Mutnovsky (Taran et al. 1992), Avachinsky and Koryaksky (Taran et al. 1997). Yuri was involved in the discovery of a pure and unique rhenium mineral on Kudryavy volcano (Korzhinsky et al. 1994) and provided one of the most detailed chemical studies of high temperature (up to 950°C) fumaroles to date of any volcano (Taran et al. 1995). His 1995 paper on Kudryavy remains highly cited and provides the highest quality volcanic gas data which also include trace elements from a subduction zone. Such data are crucial when we attempt to interpret lower temperature volcanic gas compositions or calculate rare metal fluxes from volcanoes worldwide. His most recent publication on Kamchatka-Kurile volcanic emissions provides a detailed analysis of the total gas flux from these volcanoes (Taran 2009).
    Description: Published
    Description: 369-371
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: JCR Journal
    Description: reserved
    Keywords: Fluids Geochemistry ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 6
    Publication Date: 2021-06-08
    Description: The occurrence of intense CO2 degassing processes generating hundreds of cold CO2- rich gas emissions is typical of the central Apennines. In 2009, significant anomalies were detected coinciding with the L’Aquila seismic sequence as a consequence of a wide degassing process. Over the same time-span, space-time anomalies in Thermal InfraRed (TIR) satellite imagery possibly related to the increase of green-house gas (such as CO2, CH4, etc.) emission rates were detected in central Italy during the seismic swarm by a Robust Satellite Technique (RST) data analysis. A gas geochemical survey carried out in the L’Aquila area confirms the deep crustal origin of the anomalous gas emission detected by ground measurements. Anomalous fluid related signals were recorded some days before the mainshock coinciding with the most marked TIR anomalies independently detected by the RST analysis over 3 different types of satellite data. Anomalous gas emissions detected by ground measurements lasted some weeks, putting in evidence relationships with crustal deformative processes associated with the seismic sequence. Together with previous ground observations in the Umbria-Marche area, present ground and satellite TIR observations, are compatible with the hypothesis that a central Apennines area, much wider than the L’Aquila (March-April 2009) epicentral one, was actually affected by anomalous increases in CO2 release thus providing new tools to better understand the processes occurring behind a seismic shock.
    Description: Published
    Description: 147-168
    Description: 3.2. Tettonica attiva
    Description: JCR Journal
    Description: restricted
    Keywords: gas emission ; L’Aquila earthquake ; TIR ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 7
    Publication Date: 2020-11-12
    Description: Accepted for publication in Journal of Geophysical Research. Copyright (2010) American Geophysical Union.
    Description: Carbon dioxide (CO2) diffuse degassing structures (DDS) at Furnas Volcano (São Miguel Island, Azores) are mostly associated with the main fumarolic fields, evidence that CO2 soil degassing is the surface expression of rising steam from the hydrothermal system. Locations with anomalous CO2 flux are mainly controlled by tectonic structures oriented WNW-ESE and NW-SE and by the geomorphology of the volcano, as evidenced by several DDS located in depressed areas associated with crater margins. Hydrothermal soil CO2 emissions in Furnas volcano are estimated to be ~ 968 t d-1. Discrimination between biogenic and hydrothermal CO2 was determined using a 1 statistical approach and the carbon isotope composition of the CO2 efflux. Different sampling densities were used to evaluate uncertainty in the estimation of the total CO2 flux, and showed that a low density of points may not be adequate to quantify soil emanations from a relatively small DDS. Thermal energy release associated to diffuse degassing at Furnas caldera is about 118 MW (from an area of ~ 4.8 km2) based on the H2O/CO2 ratio in fumarolic gas. The DDS affect also Furnas and Ribeira Quente villages, which are located inside the caldera and in the south flank of the volcano, respectively. At these sites, 58% and 98% of the houses are built over hydrothermal CO2 emanations, and the populations are at risk due to potential high concentrations of CO2 accumulating inside the dwellings. Keywords: Soil diffuse degassing; soil CO2 flux; emission rates; Azores archipelago 2
    Description: Published
    Description: B12208
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: JCR Journal
    Description: open
    Keywords: Soil CO2 emissions ; Furnas volcano ; volcano monitoring. ; 04. Solid Earth::04.04. Geology::04.04.11. Instruments and techniques ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 8
    Publication Date: 2020-11-20
    Description: Siwi caldera, in the Vanuatu arc (Tanna island), is a rare volcanic complex where both persistent eruptive activity (Yasur volcano)and rapid block resurgence (Yenkahe horst) can be investigated simultaneously during a post-caldera stage. Here we provide new constraints on the feeding system of this volcanic complex, based on a detailed study of the petrology, geochemistry and volatile content of Yasur^Siwi bulk-rocks and melt inclusions, combined with measurements of the chemical composition and mass fluxes of Yasur volcanic gases. Major and trace element analyses of Yasur^ Siwi volcanic rocks, together with literature data for other volcanic centers, point to a single magmatic series and possibly long-lived feeding of Tanna volcanism by a homogeneous arc basalt. Olivine-hosted melt inclusions show that the parental basaltic magma, which produces basaltic-trachyandesites to trachyandesites by 50^70% crystal fractionation, is moderately enriched in volatiles ( 1wt % H2O, 0·1wt % S and 0·055 wt % Cl). The basaltic-trachyandesite magma, emplaced at between 4^5 km depth and the surface, preserves a high temperature (1107 158C) and constant H2O content ( 1wt %) until very shallow depths, where it degasses extensively and crystallizes. These conditions, maintained over the past 1400 years of Yasur activity, require early water loss during basalt differentiation, prevalent open-system degassing, and a relatively high heat flow ( 109W). Yasur volcano releases on average 13·4 103 tons d 1 of H2O and 680 tons d 1 of SO2, but moderate amounts of CO2 (840 tons d 1), HCl (165 tons d 1), and HF (23 tons d 1). Combined with melt inclusion data, these gas outputs constrain a bulk magma degassing rate of 5 107 m3 a 1, about a half of which is due to degassing of the basaltic-trachyandesite. We compute that 25 km3 of this magma have degassed without erupting and have accumulated beneath Siwi caldera over the past 1000 years, which is one order of magnitude larger than the accumulated volume uplift of the Yenkahe resurgent block. Hence, basalt supply and gradual storage of unerupted degassed basaltictrachyandesite could easily account for (or contribute to) the Yenkahe block resurgence.
    Description: Published
    Description: 1077-1105
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: JCR Journal
    Description: restricted
    Keywords: Vanuatu arc ; Yasur ; gas fluxes ; volatiles ; melt inclusions ; resurgent block ; volcano thermal budget ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 9
    Publication Date: 2021-01-27
    Description: In this work we report new data on He abundances and isotope ratios (3He/4He) from gas associated to some thermal and CO2-rich mineral waters in N-Portugal. Collected gas samples are mainly CO2-dominant except two sites where gas is N2-rich. All the sampling sites are characterized by exceptionally high helium contents with 3He/4He ratios, corrected for air contamination, varying considerably from 0.09 to 2.68 Ra. In all sites, the 3He/4He ratios are higher than that typical for stable continental areas thus indicating a variable but not-negligible (up to 30%) contribution of mantle-derived primordial He. In all the CO2-rich waters, CO2/3He ratios and 13CCO2 are comparable with mantle values, thus suggesting a magmatic origin also for CO2. On the contrary, in the N2-rich waters He is mainly radiogenic, and CO2 is organic in origin. Since no recent volcanic activity is observed in NW Iberia, high 3He/4He values could be due, at least, to three processes: a) releasing of gas from the local upper mantle through deep extensional fault systems; b) releasing of magmatic volatiles from crustal reservoir(s) formed during past volcanic activity; c) degassing of a subsurface emplaced magma body. Mantle He flux in N-Portugal has been estimated to be up to 3 orders of magnitude higher than that typical for stable continental areas, thus suggesting, in this area, the presence of a tensional tectonic regime. This implies that mantle gases could migrate upward probably through inherited tectonic structures reactivated by neotectonic activity. The third possible scenario seems to be less plausible since seismic surveys carried out in NW Iberian did not find any significant evidence of mantle intrusion in the crust. The observed spatial variability in mantle-derived contribution could reflect the geometry of the granitic plutons in this area, thus supporting the hypotheses of an upper mantle degassing. Alternatively, it could be the result of a lateral migration of magmatic volatiles stored in a crustal reservoir.
    Description: Published
    Description: Budapest, Hungary
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: open
    Keywords: Helium isotopes ; NW Iberian peninsula ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.07. Radioactivity and isotopes ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Poster session
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  • 10
    Publication Date: 2021-06-03
    Description: In spite of the large extension of the Earth degassing process and of the correlations with geodynamic processes and large scale geochemical processes, the Earth degassing process in the world is still poorly known. Beside the scientific interest on studying gas emissions, a better knowledge of the degassing process is crucial for mitigate gas hazard correlated to the release of dangerous gases (e.g., CO2, H2S) from natural emissions, that, like in Italy, caused many lethal accidents to animals and humans. After years of data collection organized on a base of a single research group, institution, or project, there is clearly a need for common frameworks that allow to aggregate data in order to observe the phenomena at various scale. The development of Googas in 2007 (Chiodini et al., 2008), funded by the Italian Civil Defence and focused on the serialization of data and the publication of a web map of gas emissions, was the first attempt to create a collaborative database on gas emissions. Googas, that represented an important advance in the knowledge of the phenomenon at the national scale, is however a static representation of the results of the project. Starting from the Googas experience, we are now extending the capabilities of Googas on the user side, developing a new web environment for collecting and publishing data of gas natural emissions dynamically. The collaborative environment allows researchers from different institutions to collect data in the most seamless way, and data to be published directly from within the same system. The web interface allows to insert data interactively into a spatially referred relational database management system. Moreover, researchers are aware of the activity of the others and can access data, leave comments as soon as data is being inserted. This new system aims to excite, inspire, and encourage participation among researchers. As gas emissions are inherently referred to geographic locations, published digital data will be available in several formats, including the ones conformant to Open Gis Consortium (OGC) standards, for an easy access by using Geographical Information Systems (GIS). The publication of data on the website will be ruled by a licensing system that facilitates and encourages the scientific method processes. The license will allow to use and distribute the data, to produce works from the data and to build up new data from it, as long as these rules are maintained and the attribution to the original work is being referred. In this way, the efforts to publish the data are balanced by the guarantees that the data's access will remain open. This new database of Italian gas emissions is an interesting environment where researchers can insert data in a common interface asynchronously and the results are immediately tangible. The development of this project is undergoing and researchers and developers interact closely, introducing and testing new features during the development phase. We believe that the development of this new environment represent a starting point towards the foundation of a collaborative database of gas emissions at global scale.
    Description: Published
    Description: San Francisco California USA
    Description: 5.10. TTC - Sistema web
    Description: open
    Keywords: gas emissions ; Italy ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Conference paper
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