ALBERT

Note: Table of Contents Abstract Zusammenfassung List of Figures List of Tables 1. Introduction 1.1 Scientific Background 1.1.1 Arctic Climate Change 1.1.2 Permafrost Degradation 1.1.3 The Arctic Freshwater System and its Biogeochemistry 1.2 Objectives 1.3 Study Region and Methods 1.3.1 Study Area 1.3.2 Field Sampling and Measurements 1.3.3 Geochemical Analyses 1.3.4 Data Processing 1.4 Thesis Structure 1.5 Author Contributions 2. Spatial Variability of Dissolved Organic Carbon, Solutes and Suspended Sediment in Disturbed Low Arctic Coastal Watersheds 2.1 Abstract 2.2 Introduction 2.3 Study Site 2.4 Methods 2.4.1 Stream Monitoring 2.4.2 Mapping of Disturbances 2.4.3 Flux Estimates and Statistics 2.5 Results 2.5.1 Catchment Disturbance 2.5.2 Runoff and Hydrochemistry 2.5.3 Lateral Transport of Stream Water 2.5.4 Hydrochemical Composition and Fluxes in Nearby Streams 2.6 Discussion 2.6.1 Total Runoff and Water Quality 2.6.2 Water Quality Changes from Headwaters to Downstream 2.6.3 Changes in Hydrochemistry and Isotopic Composition over Time 2.6.4 Importance of Disturbances for Hydrochemistry 2.7 Conclusions 2.8 Supplementary Material 3. Terrestrial Colored Dissolved Organic Matter (cDOM) in Arctic Catchments - Characterizing Organic Matter Composition Across the Arctic 3.1 Introduction 3.2 Study Area 3.3 Methods 3.3.1 Field Methods and Hydrochemistry 3.3.2 Statistical Analyses 3.4 Results 3.4.1 Meteorological Conditions and General Hydrochemistry 3.4.2 DOC and cDOM Absorption Characteristics 3.4.3 Downstream Patterns of DOC and cDOM Along Longitudinal Transects 3.4.4 Temporal Trends ofDOC and cDOM with Changing Meteorological Conditions 3.5 Discussion 3.5.1 Limitations of cDOM Measurements from Terrestrial Sources 3.5.2 Catchment Processes and Biogeochemical Cycling 3.5.2.1 Regional Catchment Properties 3.5.2.2 Rainfall Events 3.5.2.3 Downstream Patterns and Impact of Permafrost Disturbance 3.5.3 Nature of cDOM-DOC Across the Terrestrial Arctic 3.6 Conclusion 3.7 Supplementary Material 4. Summer Rainfall DOC, Solute and Sediment Fluxes in a Small Arctic Coastal Catchment on Herschel Island (Yukon Territory, Canada) 4.1 Abstract 4.2 Introduction 4.3 Study Site 4.4 Methodology 4.4.1 Weather data 4.4.2 Hydrology 4.4.3 Suspended Sediment and Hydrochemistry 4.4.4 Flux Estimates and Statistics 4.5 Results 4.5.1 Meteorological Conditions 4.5.2 Streamflow and Electrical Conductivity 4.5.3 Transport of Suspended Sediment and Organic Matter 4.5.4 Solute Transport 4.5.5 Alluvial Fan Sampling 4.6 Discussion 4.6.1 Hydrological Response 4.6.2 Water Quality and Fluxes 4.6.3 Rainfall Response and Flow Pathways 4.7 Conclusions 4.8 Supplementary Material 5. Synthesis 5.1 Impacts of Permafrost Degradation on Stream Biogeochemistry 5.2 Controls on DOM Quality across the Arctic 5.3 Biogeochemical Fluxes from Small Coastal Catchments to the Arctic Ocean 5.4 Challenges 5.5 Outlook Acronyms Bibliography Acknowledgements Eidesstattliche Erklärung

Note: Dissertation, Universität Potsdam, 2019 , Table of contents Abstract Zusammenfassung Abbreviations 1 Introduction 1.1 Scientific background 1.1.1 Permafrost in the Northern Hemisphere 1.1.2 The permafrost carbon climate feedback 1.1.3 Rapidly changing, deep permafrost environments 1.2 Aims of this dissertation 1.3 Investigated study areas 1.4 Basic method overview 1.4.1 Field work in the Arctic 1.4.2 Laboratory procedure 1.4.3 Analysis ofl andscape-scale carbon and nitrogen stocks 1.5 Thesis organization 1.6 Overview of publications 1.6.1 Publication#1 - Yedoma landscape publication 1.6.2 Publication#2 - Thermokarst lake sequence publication 1.6.3 Publication#3 - North Alaska Arctic river delta publication 1.6.4 Extended Abstract - Western Alaska river delta study 1.6.5 Appendices - Supplementary material and paper in preparation II Carbon and nitrogen pools in thermokarst-affected permafrost landscapes in Arctic Siberia 2.1 Abstract 2.2 Introduction 2.3 Material and methods 2.3.1 Study area 2.3.2 Field Work 2.3.3 Laboratory analysis 2.3.4 Landform classification and upscaling C and N pools 2.4 Results 2.4.1 Sedimentological results 2.4.2 Sampling site SOC and N stocks 2.4.3 Upscaling: Landscape SOC and N stocks 2.4.4 Radiocarbon dates 2.5 Discussion 2.5.1 Site specific soil organic C and N stock characteristics 2.5.2 Upscaling of C and N pools 2.5.3 Sediment and organic C accumulation rates 2.5.4 Characterizing soil organic carbon 2.5.5 The fate of organic carbon in thermokarst-affected yedoma in Siberia 2.6 Conclusions III Impacts of successive thermokarst lake stages on soil organic matter, Arctic Alaska 3.1 Abstract 3.2 Plain language summary 3.3 Introduction 3.4 Study site 3.5 Methods 3.5.1 Core collection 3.5.2 Biogeochemical analyses 3.5.3 Study area OC and N calculation 3.6 Results 3.6.1 Biogeochemistry 3.6.2 Sediment organic carbon and nitrogen stocks 3.6.3 Radiocarbon dates and carbon accumulation rates 3.6.4 Landscape C and N budget 3.7 Discussion 3.7.1 Impact of thermokarst lake dynamics on organic matter storage 3.7.2 High organic C and N stocks on the ACP 3.7.3 Landscape chronology 3.7.4 Organic matter accumulation 3.7.5 Future development 3.8 Conclusions IV Sedimentary and geochemical characteristics of two small permafrost-dominated Arctic river deltas in northern Alaska 4.1 Abstract 4.2 Introduction 4.3 Study area 4.4 Material and Methods 4.4.1 Soil organic carbon and soil nitrogen storage 4.4.2 Radiocarbon dating and organic carbon accumulation rates 4.4.3 Grain size distribution 4.4.4 Scaling carbon and nitrogen contents to landscape level 4.5 Results 4.5.1 Carbon and nitrogen contents 4.5.2 Radiocarbon dates and accumulation rates 4.5.3 Grain size distribution 4.5.4 Arctic river delta carbon and nitrogen storage 4.6. Discussion 4.6.1 Significance of carbon and nitrogen stocks in Arctic river deltas 4.6.2 SOC and SN distribution with depth 4.6.3 Sedimentary characteristics 4.6.3.1 Accumulation rates 4.6.3.2 Sediment distribution 4.6.4 Impacts of future changes 4.6.5 Significance of remotely sensed upscaling results 4.7 Conclusions V Soil carbon and nitrogen stocks in Arctic river deltas - New data for three Western Alaskan deltas 5.1 Abstract 5.2 Introduction 5.3 Study sites 5.4 Methods 5.5 Results and discussion 5.5 Conclusions VI Discussion 6.1 Interregional comparison 6.2 Changing thermokarst landscapes and their global impact 6.3 A growing C and N data base 6.4 Outlook - potential follow-up projects VII Synthesis VIII References Appendix A Synthesis of SOC and N inventories Appendix B Supplementary material to Chapter II Appendix C Supplementary material to Chapter III Appendix D Supplementary material to Chapter IV Appendix E Supplementary material to Chapter V Appendix F Arctic river delta data set - Version 1.0 Acknowledgements - Danksagung

Note: Contents: 1 General introduction. - 1.1 Challenges of isotope-based temperature reconstructions. - 1.2 Thesis overview. - 1.3 Author contributions. - 2 Theoretical background. - 2.1 The isotopic composition of firn and ice. - 2.1.1 Fractionation of water isotopologues. - 2.1.2 Relationship with temperature. - 2.1.3 Measuring of the isotopic composition. - 2.2 Processes within the firn column. - 2.2.1 The firn column of polar ice sheets. - 2.2.2 The density of firn. - 2.2.3 The temperature profile of firn. - 2.2.4 Vapour diffusion in firn. - 2.3 Internal climate variability. - 3 Regional climate signal vs.local noise: a two-dimensional view of water isotopes. - 3.1 Introduction. - 3.2 Data and methods. - 3.3 Results. - 3.3.1 Trench isotope records. - 3.3.2 Single-profile representativity. - 3.3.3 Mean trench profiles. - 3.3.4 Spatial correlation structure. - 3.3.5 Statistical noise model. - 3.4 Discussion. - 3.4.1 Local noise vs. regional climate signal. - 3.4.2 Representativity of isotope signals. - 3.4.3 Implications. - 3.5 Conclusions. - 3.6 Appendix A: Derivation of noise model. - 3.6.1 Definitions. - 3.6.2 Derivation of model correlations. - 3.6.3 Estimation of parameters. - 3.7 Appendix B: Noise level after diffusion. - 4 Constraints on post-depositional isotope modifications in east antarctic firn. - 4.1 Introduction. - 4.2 Data and methods. - 4.2.1 Sampling and measurements. - 4.2.2 Trench depth scale. - 4.2.3 Spatial variability of trench profiles. - 4.2.4 Quantification of downward advection, densification and diffusion. - 4.2.5 Statistical tests. - 4.3 Results. - 4.3.1 Comparison of T15 and T13 isotope data. - 4.3.2 Expected isotope profile changes. - 4.3.3 Temporal vs. spatial variability. - 4.4 Discussion. - 4.4.1 Densification, diffusion and stratigraphic noise. - 4.4.2 Additional post-depositional modifications. - 4.5 Conclusions. - 5 On the similarity and apparent cycles of isotope variations. - 5.1 Introduction. - 5.2 Data and Methods. - 5.2.1 Data. - 5.2.2 Spectral analysis. - 5.2.3 Rice’s formula. - 5.2.4 Cycle length and amplitude estimation. - 5.2.5 Model for vertical isotope profiles. - 5.3 Results. - 5.3.1 Spectral analysis of isotope profiles. - 5.3.2 Theoretical and observed cycle length. - 5.3.3 Illustrative examples. - 5.3.4 Depth dependency of cycle length. - 5.3.5 Simulated vs. observed isotope variations. - 5.4 Discussion and summary. - 5.5 Conclusions. - 5.6 Appendix A: Input sensitivity. - 5.7 Appendix B: Additional results. - 5.8 Appendix C: Spectral significance testing. - 6 Timescale-dependency of antarctic isotope variations. - 6.1 Introduction. - 6.2 Data and methods. - 6.2.1 DML and WAIS isotope records. - 6.2.2 Spectral model. - 6.2.3 Timescale-dependent signal-to-noise ratio. - 6.2.4 Effects of diffusion and time uncertainty. - 6.2.5 Present-day temperature decorrelation. - 6.3 Results. - 6.3.1 Illustration of model approach. - 6.3.2 DML and WAIS isotope variability. - 6.4 Discussion. - 6.4.1 Interpretation of noise spectra. - 6.4.2 Interpretation of signal spectra. - 6.4.3 Signal-to-noise ratios. - 6.4.4 Differences between DML and WAIS. - 6.5 Conclusions. - 7 Declining temperature variability from LGM to holocene. - 8 General discussion and conclusions. - 8.1 Short-scale spatial and temporal isotope variability. - 8.1.1 Local spatial variability. - 8.1.2 Seasonal to interannual variability. - 8.1.3 Spatial vs. temporal variability. - 8.2 Extension to longer scales. - 8.2.1 Spatial vs. temporal variability on interannual timescales. - 8.2.2 Holocene and longer timescales. - 8.3 Concluding remarks and outlook. - Bibliography. - A Methods to: declining temperature variability from lgm to holocene. - A.1 Temperature proxy data. - A.2 Model-based temperature and variability change. - A.3 Temperature recalibration of proxy records. - A.3.1 Recalibration of ice-core records. - A.3.2 Recalibration of marine records. - A.4 Variance and variance ratio estimation. - A.5 Noise correction. - A.5.1 Testing effect of noise correction. - A.6 Effect of ecological adaption and bioturbation. - A.7 Effect of proxy sampling locations. - B Layering of surface snow and firn: noise or seasonal signal?. - B.1 Introduction. - B.2 Materials and methods. - B.2.1 Firn-core density profiles. - B.2.2 Trench density profiles. - B.2.3 Dielectric profiling and density estimates. - B.2.4 Comparison of DEP and CT density. - B.2.5 Ion measurements. - B.3 Results. - B.3.1 2-D trench density data. - B.3.2 Spatial correlation structure. - B.3.3 Comparison of mean density, isotope and impurity profiles. - B.3.4 Spectral analysis of vertical density data. - B.4 Discussion. - B.4.1 Spatial variability. - B.4.2 Representativeness of single profiles. - B.4.3 Seasonal cycle in snow density. - B.4.4 Density layering in firn and impurities. - B.5 Conclusions. - Acknowledgements - Danksagung.

Note: Inhaltsverzeichnis 1 Einleitung 1.1Wissenschaftliche Zielsetzung 2 Grundlagen 2.1 Grundgleichungen 2.2 Potentielle Vorticity 2.3 Planetare Wellen 2.4 Atmosphärische Instabilität 2.5 Grenzschicht 2.6 Kopplung von Tropo- und Stratosphäre 3 Daten und Methoden 3.1 N-ICE2015 3.1.1 Expeditionsbeschreibung 3.1.2 Ziele der Expedition 3.2 Daten 3.2.1 Beobachtungsdaten 3.2.2 ERA-Interim Reanalyse 3.2.3 Das HIRHAM5 Modell 3.3 Analysemethoden 3.3.1 Temperaturinversionen 3.3.2 Vertikale Stabilität 3.3.3 Grenzschichthöhe 3.3.4 Eady Growth Rate 3.3.5 2d-Skalenfilterung und -Pattern-Korrelation 3.3.6 Nudging Experiment 4 Analyse der N-ICE2015 Radiosonden 4.1 Blick auf die Troposphäre 4.2 Fallstudie zum M2-Sturm: A 4.3 Zyklonencharakteristika 4.4 Temperaturinversionen und Stabilität 4.5 Vergleich mit ERA-Interim, SHEBA und Ny-Ålesund 4.6 Résumé der Expeditionsdaten 5 Nudging Studien mit HIRHAM5 5.1 Vergleich mit ERA-Interim 5.2 Vergleich der Simulationen 5.3 Fallstudie zum M2-Sturm: B 5.3.1 Synoptische Aktivität 5.4 Statistischer Vergleich 6 Einfluss der Stratosphäre 6.1 Stratosphäre im Winter 2014/2015 6.2 Fallstudie zum M2-Sturm: C 6.3 PV als Ladung 6.4 Résumé der Beobachtungen 7 Zusammenfassung und Ausblick A Zusätztliche Abbildungen B Literaturverzeichnis