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  • Articles  (793,603)
  • Elsevier  (438,041)
  • Springer  (259,378)
  • American Chemical Society  (91,768)
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  • Articles  (793,603)
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  • 1
    Publication Date: 2014-12-31
    Print ISSN: 1936-0851
    Electronic ISSN: 1936-086X
    Topics: Chemistry and Pharmacology , Physics
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  • 2
    Publication Date: 2014-12-31
    Print ISSN: 1936-0851
    Electronic ISSN: 1936-086X
    Topics: Chemistry and Pharmacology , Physics
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  • 3
    Publication Date: 2014-12-31
    Print ISSN: 1936-0851
    Electronic ISSN: 1936-086X
    Topics: Chemistry and Pharmacology , Physics
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  • 4
    Publication Date: 2014-12-31
    Description: We report on the realization of a quartz-enhanced photoacoustic (QEPAS) sensor for measurement of H 2 S gas traces. A distributed feedback diode laser working at 2.64 µm wavelength has been coupled to an acoustic detection module composed of a quartz tuning fork and a micro-resonator system, and the QEPAS signal has been optimized in terms of gas sample pressure and laser frequency modulation depth. The sensor shows a very good linearity with respect to the H 2 S concentration. We performed an Allan–Werle variance analysis to investigate the sensor long-term stability, and we reached a detection limit of four parts per million for 1-s integration time and 500 parts per billion in 60-s integration time. The realized QEPAS sensor represents a good compromise between performance and handiness, in view of a fully portable device.
    Print ISSN: 0946-2171
    Electronic ISSN: 1432-0649
    Topics: Physics
    Published by Springer
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  • 5
    Publication Date: 2014-12-31
    Description: We present a detailed design principle and propagation characteristics of a channel plasmon-photonic–crystal-coupled-waveguide (PPCCW) for realizing terahertz (THz) waveguides and waveguide-based devices. The avoided-crossing behavior exhibited by dispersion curves of the supermodes due to modal interference leads to a sharp change in group velocity close to the phase-matching wavelength. As a consequence, the group-velocity dispersion (GVD) peaks to a maxima (~1.40 × 10 5  ps/km·μm) and dips to a minima (~−1.60 × 10 5  ps/km·μm), thus exhibiting extremely large GVD. The propagation length is obtained in the order of a few centimeters. The analysis is substantiated by the frequency dependence of mode field distribution and propagation loss suffered by the supermodes of PPCCW geometry. Also, the obtained result is in good agreement with FEM-based study. The proposed waveguide is aimed at facilitating enhanced performance THz-waveguide sensors and GVD compensation modules.
    Print ISSN: 0946-2171
    Electronic ISSN: 1432-0649
    Topics: Physics
    Published by Springer
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  • 6
    Publication Date: 2014-12-31
    Description: By experiments and theory, we investigate the influence of heat transfer across a gas–solid interface on the nodule height of microstructured silicon fabricated under femtosecond laser pulses. By changing the pressure of the vacuum system, a fast-changing spread in height is found. This is determined by the different heat-transfer flux across the gas–solid interface for different Knudsen-number regimes. Heat transfer affects the energy remaining in the bulk silicon, which determines nodule formation and corresponding height. The rate of change in the heat-transfer flux induces a negative rate of change in the nodule height. These results are important when optimizing the surface microstructure for silicon-based photoelectron devices.
    Print ISSN: 0946-2171
    Electronic ISSN: 1432-0649
    Topics: Physics
    Published by Springer
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  • 7
    Publication Date: 2014-12-31
    Description: Two-line atomic fluorescence (TLAF) thermometry is based on the consecutive excitation of two nearby atomic ground states to a common excited state, and ratioing the ensuing fluorescence yields. TLAF is one of the few methods that hold promise for thermometry in sooting environments. We extend the method to the regime of fully saturated excitation and introduce a new seeding system that also allows the method to be used in lean flames. We compare results for saturated TLAF to those of linear TLAF and to thermocouple measurements, and find good correspondence. The saturated version introduced here maximizes fluorescence yields while simultaneously suppressing the dependence on excitation laser irradiance.
    Print ISSN: 0946-2171
    Electronic ISSN: 1432-0649
    Topics: Physics
    Published by Springer
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  • 8
    Publication Date: 2014-12-31
    Description: Restoration efforts in Florida’s Everglades focus on preserving and restoring this unique wetland’s natural landscape. Because most of the Everglades is a freshwater peatland, it requires surplus rainfall to remain a peatland. Restoration plans generally assume a stable climate, yet projections of altered climate over a 50-year time horizon suggest that this assumption may be inappropriate. Using a legacy regional hydrological model, we simulated combinations of a temperature rise of 1.5 °C, a ± 10 % change in rainfall, and a 0.46 m sea level rise relative to base conditions. The scenario of increased evapotranspiration and increased rainfall produced a slight increase in available water. In contrast, the more likely scenario of increased evapotranspiration and decreased rainfall lowered median water depths by 5–114 cm and shortened inundation duration periods by 5–45 %. Sea level rise increased stages and inundation duration in southern Everglades National Park. These ecologically significant decreases in water depths and inundation duration periods would greatly alter current ecosystems through severe droughts, peat loss and carbon emissions, wildfires, loss of the unique ridge and slough patterns, large shifts in plant and animal communities, and increased exotic species invasions. These results suggest using adaptive restoration planning, a method that explicitly incorporates large climatic and environmental uncertainties into long-term ecosystem restoration plans, structural design, and management. Anticipated water constraints necessitate alternative approaches to restoration, including maintaining critical landscapes and facilitating transitions in others. Accommodating these uncertainties may improve the likelihood of restoration success.
    Print ISSN: 0364-152X
    Electronic ISSN: 1432-1009
    Topics: Biology , Energy, Environment Protection, Nuclear Power Engineering
    Published by Springer
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  • 9
    Publication Date: 2014-12-31
    Description: Heat transfer and friction factor characteristics in a circular tube fitted with core rod at high temperature have been investigated experimentally. In the experiments, ambient air with Reynolds numbers in a range of 9,000–26,000 is passed through a circular tube with uniform wall temperature and convection and radiation heat transfer phenomena are studied. Experiments have been performed on the tube with core rod insert considering four values of uniform wall temperature. For each wall temperature considered, convection and radiation heat transfer coefficients have been determined. The experimental results show that at uniform wall temperature of 373, 473, 553 and 633 K the average share of the radiation heat transfer coefficient to the total heat transfer coefficient is 10.7, 14.6, 20.5 and 22.3 % respectively. In addition it was noted that for the mentioned temperatures, the heat transfer coefficient increased by 234, 275, 304 and 334 % respectively when using tube containing the core insert in comparison to the plain tube. It was also noted that increasing the wall temperature also resulted in increase of friction factor.
    Print ISSN: 0947-7411
    Electronic ISSN: 1432-1181
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Published by Springer
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  • 10
    Publication Date: 2014-12-31
    Description: The present paper deals with the stationary solution of the planar restricted three body problem when both the primaries are heterogeneous oblate spheroid with three layers of different densities and sources of radiation as well. It derives equations of motion and examines the existence and the linear stability of libration points. It is seen that there are five libration points, two triangular points and three collinear ones. It is further observed that the collinear points are unstable, while the triangular points are stable for the mass parameter 0 ≤ μ 〈 μ c r i t . Here μ c r i t (the critical mass parameter) depends upon the combined effects of radiation and that due to the three different layers in the primaries. It is further seen that long or short periodic elliptical orbits emanate from the triangular points in the aforementioned range of μ .
    Print ISSN: 0021-9142
    Electronic ISSN: 2195-0571
    Topics: Physics
    Published by Springer
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