ALBERT

Note: Zugl.: Braunschweig, Univ., Diss., 1996

Note: TABLE OF CONTENTS: ACKNOWLEDGEMENTS. - PREFACE. - INTRODUCTION. - SYMBOLS AND NOTATION. - PART I. FUNDAMENTAL PHYSICS AND MATERIALS TECHNOLOGY OF ICE. - 1.General Concepts. - 1. Introduction. - 2. Equations of Balance. - 3. Material Response. - (a) General constitutive relations, simple materials. - (b) The rule of material objectivity. - (c) Material symmetry. - (d) Constitutive response for isotropie bodies. - (e) Materials with bounded memory-some constitutive representations. - (f) Incompressibility. - (g) Some representations of isotropic functions. - 4. The Entropy Principle. - (a) The viscous heat-conducting compressible fluid. - (b) The viscous heat-conducting incompressible fluid. - (c) Pressure and extra stress as independent variables. - (d) Thermoelastic solid. - (e) Final remarks. - 5. Phase Changes. - (a) Phase changes for a viscous compressible heat-conducting fluid. - (b) Phase changes for a viscous incompressible heat-conducting fluid. - References. - 2. A Brief Summary of Constitutive Relations for Ice. - 1. Preliminary Remarks. - 2. The Mechanical Properties of Hexagonal Ice. - (a) The crystal structure of ordinary ice. - (b) The elastic behavior of hexagonal ice. - (c) The inelastic behavior of single-crystal ice. - 3. The Mechanical Properties of Polycrystalline Ice. - (a) The elastic behavior of polycrystalline ice. - (b) Linear viscoelastic properties of polycrystalline ice. - (α) General theory. - (β) Experimental results. - (c) Non-linear viscous deformation and creep. - (α) Results of creep tests. - (β) Generalization to a three-dimensional flow law. - (γ) Other flow laws. - 4. The Mechanical Properties of Sea Ice. - (a) The phase diagram of standard sea ice and its brine conten. - (b) Elastic properties. - (c) Other material properties. - References. - PART II. THE DEFORMATION OF AN ICE MASS UNDER ITS OWN WEIGHT. - 3. A Mathematical Ice-flow Model and its Application to Parallel-sided Ice Slabs. - 1. Motivation and Physical Description. - 2. The Basic Model - Its Field Equations and Boundary Conditions. - (a) The field equations. - (α) Cold ice region. - (β) Temperate ice region. - (b) Boundary conditions. - (α) At the free surface. - (β) Along the ice-water interface. - (γ) Along the bedrock surface. - (δ) Along the melting surface. - 3. The Response of a Parallel-sided Ice Slab to Steady Conditions. - (a) Dimensionless forms of the field equations. - (b) Parallel-sided ice slab, a first approximation to glacier and ice-shelf flow dynamics. - (α) Velocity and temperature fields x-independent. - (β) Extending and compressing flow. - (γ) Floating ice shelves 4. Concluding Remark. - References. - 4. Thermo-mechanical Response of Nearly Parallel-sided Ice Slabs Sliding over their Bed. - 1. Motivation. - 2. The Basic Boundary-value Problem and its Reduction to Linear Form. - 3. The Solution of the Boundary-value Problems. - (a) Zeroth-order problem. - (b) First-order problem. - (α) Harmonic perturbation from uniform flow for a zero accumulation rate. - (β) Analytic solution for a Newtonian fluid. - (γ) Numerical solution for non-linear rheology. - (δ) Effect of a steady accumulation rate. - (ε) A historical note on a previous approach. - (η) The first-order temperature problem. - (c) Numerical results for steady state. - (α) Transfer of bottom protuberances to the surface. - (β) Basal stresses. - (γ) Surface velocities. - (δ) Effect of a steady accumulation rate. - 4. Remarks on Response to a Time-dependent Accumulation Rate. - 5. Surface-wave Stability Analysis. - (a) The eigenvalue problem. - (b) Discussion of results. - 6. Final Remarks. - References. - 5. The Application of the Shallow-ice Approximation. - 1. Background and Previous Work. - 2. Derivation of the Basal Shear-stress Formula by Integrating the Momentum Equations over Ice Thickness. - (a) Derivation. - (b) The use of the basal shear-stress formula in applied glaciology. - 3. Solution of the Ice-flow Problem using the Shallow-ice Approximation. - (a) Governing equations. - (b) Shallow-ice approximation. - (c) Construction of the perturbation solution. - (d) Results. - (e) Temperature field. - 4. Theoretical Steady-state Profiles. - (a) Earlier theories and their limitations. - (b) Surface profiles determined by using the shallow-ice approximation. - 5. An Alternative Scaling - a Proper Analysis of Dynamics of Ice Sheets with Ice Divides. - (a) Finite-bed inclination. - (b) Small-bed inclination. - (c) Illustrations. - References. - 6. The Response of a Glacier or an Ice Sheet to Seasonal and Climatic Changes. - 1. Statement of the Problem. - 2. Development of the Kinematic Wave Theory. - (a) Full non-linear theory. - (b) Perturbation expansion-linear theory. - (c) An estimate for the coefficients C and D. - (d) Boundary and initial conditions. - 3. Theoretical Solutions for a Model Glacier. - (a) Solutions neglecting diffusion. - (b) Theoretical solutions for a diffusive model. - (α) Coefficient functions for the special model. - (β) Solution for a step function. - (γ) General solution for uniform accumulation rate. - (δ) The inverse problem - calculation of climate from variations of the snout. - 4. General Treatment for an Arbitrary Valley Glacier. - (a) Fourier analysis in time. - (α) Low-frequency response. - (β) High-frequency response. - (γ) Use of the results. - (b) Direct integration methods. - 5. Derivation of the Surface-wave Equation from First Principles Non-linear Theory. - (a) Surface waves in the shallow-ice approximation. - (α) Integration by the methods of characteristics. - (β) An illustrative example. - (γ) A remark on linearization. - (δ) Effects of diffusion. - (b) Remarks regarding time-dependent surface profiles in ice sheets. - (c) Long waves in an infinite ice slab - Is accounting for diffusion enough?. - (α) Basic equations. - (β) Construction of perturbation solutions. - (γ) Numerical results. - 6. Concluding Remarks. - References. - 7. Three-dimensional and Local Flow Effects in Glaciers and Ice Sheets. - 1. Introduction. - 2. Effect of Valley Sides on the Motion of a Glacier. - (a) Solutions in special cases. - (α) Exact solutions for the limiting cases. - (β) Solution for a slightly off-circular channel. - (γ) A note on very deep and wide channels. - (b) A useful result for symmetrical channels with no boundary slip. - (c) Numerical solution - discussion of results. - 3. Three-dimensional Flow Effects in Ice Sheets. - (a) Basic equations. - (b) Decoupling of the stress-velocity problem from the problem of surface profile. - (c) The equation describing the surface geometry. - (d) The margin conditions. - 4. Variational Principles. - (a) Fundamental variational theorem. - (b) Variational principle for velocities. - (c) Reciprocal variational theorem. - (d) Maximum and minimum principles. - (e) Adoption of the variational principles to ice problems. - 5. Discussion of Some Finite-element Solutions. - References. - Appendix: Detailed Calculations Pertaining to Higher-order Stresses in the Shallow-ice Approximation. - AUTHOR INDEX. - SUBJECT INDEX.

Note: CONTENTS: Introduction. - Topography and hydrography. - Climate, glaciation, permafrost. - Notes on the scientific exploration of the area. - Sea level changes. - C-14 dates on shell material, corrections and errors. - Marine limits. - Emergence curves. - Marine faunas. - Glaciation history. - Pleistocene glaciation. - The Milne Land Moraines. - Glacial retreat, the Rødefjord stages. - Glacial readvance. - Climatic implications. - Comparison with other areas. - Pollen analytical investigations. - Field methods. - Lake sediments. - C-14 dates of lake sediments and rates of sedimentation. - Pollen preparation and calculation procedures. - Pollen identification. - Description of sites and pollen diagrams. - Notes on the present vegetation. - Discussion and reconstruction of vegetation types. - Plant immigration and climatic change. - Summary of the vegetation history. - Comparison with other areas. - General notes on the climatic development. - Acknowledgements. - References.

Note: Contents I Review of Current Concepts 1 Introduction 1.1 Sequence Stratigraphy: A New Paradigm? 1.2 From Sloss to Vail 1.3 Problems and Research Trends: The Current Status 1.4 Stratigraphic Terminology 2 Methods for Studying Sequence Stratigraphy 2.1 Introduction 2.2 Erecting a Sequence Framework 2.2.1 The Importance of Unconformities 2.2.2 Facies Cycles 2.2.3 Stratigraphic Architecture: The Seismic Method 2.3 Methods for Assessing Regional and Global Changes in Sea Level, Other Than Seismic Stratigraphy 2.3.1 Areas and Volumes of Stratigraphic Units 2.3.2 Hypsometric Curves 2.3.3 Backstripping 2.3.4 Sea-Level Estimation from Paleoshorelines and Other Fixed Points 2.3.5 Documentation of Meter-Scale Cycles 2.4 Integrated Tectonic-Stratigraphic Analysis 3 The Four Basic Types of Stratigraphic Cycle 3.1 Introduction 3.2 The Supercontinent Cycle 3.3 Cycles with Episodicities of Tens of Millions of Years 3.4 Cycles with Million-Year Episodicities 3.5 Cycles with Episodicities of Less Than One Million Years 4 The Basic Sequence Model 4.1 Introduction 4.2 Terminology 4.3 Depositional Systems and Systems Tracts 4.4 Sequence Boundaries 4.5 Other Sequence Concepts 5 The Global Cycle Chart II The Stratigraphic Framework 6 Cycles with Episodicities of Tens to Hundreds of Millions of Years 6.1 Climate, Sedimentation, and Biogenesis 6.2 The Supercontinent Cycle 6.2.1 The Tectonic-Stratigraphic Model 6.2.2 The Phanerozoic Record 6.3 Cycles with Episodicities of Tens of Millions of Years 6.3.1 Intercontinental Correlations 6.3.2 Tectonostratigraphic Sequences 6.4 Main Conclusions 7 Cycles with Million-Year Episodicities 7.1 Extensional and Rifted Clastic Continental Margins 7.2 Foreland Basin of the North American Western Interior 7.3 Other Foreland Basins 7.4 Forearc Basins 7.5 Backarc Basins 7.6 Cyclothems and Mesothems 7;7 Carbonate Cycles of Platforms and Craton Margins 7.8 Evidence of Cyclicity in the Deep Oceans 7.9 Main Conclusions 8 Cycles with Episodicities of Less Than One Million Years 8.1 Introduction 8.2 Neogene Clastic Cycles of Continental Margins 8.3 Pre-Neogene Marine Carbonate and Clastic Cycles 8.4 Late Paleozoic Cyclothems 8.5 Lacustrine elastic and Chemical Rhythms 8.6 Clastic Cycles of Foreland Basins 8.7 Main Conclusions III Mechanisms 9 Long-Term Eustasy and Epeirogeny 9.1 Mantle Processes and Dynamic Topography 9.2 Supercontinent Cycles 9.3 Cycles with Episodicities of Tens of Millions of Years 9.3.1 Eustasy 9.3.2 Dynamic Topography and Epeirogeny 9.4 Main Conclusions 10 Milankovitch Processes 10.1 Introduction 10.2 The Nature of Milankovitch Processes 10.2.1 Components of Orbital Forcing 10.2.2 Basic Climatology 10.2.3 Variations with Time in Orbital Periodicities 10.2.4 Isostasy and Geoid Changes 10.2.5 The Nature of the Cyclostratigraphic Data Base 10.2.6 The Sensitivity of the Earth to Glaciation 10.2.7 Glacioeustasy in the Mesozoic? 10.2.8 Nonglacial Milankovitch Cyclicity 10.3 The Cenozoic Record 10.4 Late Paleozoic Cyclothems 10.5 The End-Ordovician Glaciation 10.6 Main Conclusions 11 Tectonic Mechanisms 11.1 Introduction 11.2 Rifting and Thermal Evolution of Divergent Plate Margins 11.2.1 Basic Geophysical Models and Their Implications for Sea-Level Change 11.2.2 Some Results from the Analysis of Modern Data Sets 11.3 Tectonism on Convergent Plate Margins and in Collision Zones 11.3.1 Magmatic Arcs and Subduction 11.3.2 Tectonism Versus Eustasy in Foreland Basins 11.3.2.1 The North American Western Interior Basin 11.3.2.2 The Appalachian Foreland Basin 11.3.2.3 Pyrenean and Himalayan Basins 11.3.3 Rates of Uplift and Subsidence 11.3.4 Discussion 11.4 Intraplate Stress 11.4.1 The Pattern of Global Stress 11.4.2 In-Plane Stress as a Control of Sequence Architecture 11.4.3 In-Plane Stress and Regional Histories of Sea-Level Change 11.5 Basement Control 11.6 Other Speculative Tectonic Hypotheses 11.7 Sediment Supply and the Importance of Big Rivers 11.8 Environmental Change 11.9 Main Conclusions IV Chronostratigraphy and Correlation: Why the Global Cycle Chart Should Be Abandoned 12 Time in Sequence Stratigraphy 12.1 Introduction 12.2 Hierarchies of Time and the Completeness of the Stratigraphic Record 12.3 Main Conclusions 13 Correlation, and the Potential for Error 13.1 Introduction 13.2 The New Paradigm of Geological Time? 13.3 The Dating and Correlation of Stratigraphic Events: Potential Sources of Uncertainty 13.3.1 Identification of Sequence Boundaries 13.3.2 Chronostratigraphic Meaning of Unconformities 13.3.3 Determination of the Biostratigraphic Framework 13.3.3.1 The Problem of Incomplete Biostratigraphic Recovery 13.3.3.2 Diachroneity of the Biostratigraphic Record 13.3.4 The Value of Quantitative Biostratigraphic Methods 13.3.5 Assessment of Relative Biostratigraphic Precision 13.3.6 Correlation of Biozones with the Global Stage Framework 13.3.7 Assignment of Absolute Ages 13.3.8 Implications for the Exxon Global Cycle Chart 13.4 Correlating Regional Sequence Frameworks with the Global Cycle Chart 13.4.1 Circular Reasoning from Regional Data 13.4.2 A Rigorous Test of the Global Cycle Chart 13.4.3 A Correlation Experiment 13.4.4 Discussion 13.5 Main Conclusions 14 Sea-Level Curves Compared 14.1 Introduction 14.2 The Exxon Curves: Revisions, Errors, and Uncertainties 14.3 Other Sea-Level Curves 14.3.1 Cretaceous Sea-Level Curves 14.3.2 Jurassic Sea-Level Curves 14.3.3 Why Does the Exxon Global Cycle Chart Contain So Many More Events Than Other Sea-Level Curves? 14.4 Main Conclusions V Approaches to a Modern Sequence-Stratigraphic Framework 15 Elaboration of the Basic Sequence Model 15.1 Introduction 15.2 Definitions 15.2.1 The Hierarchy of Units and Bounding Surfaces 15.2.2 Systems Tracts and Sequence Boundaries 15.3 The Sequence Stratigraphy of Clastic Depositional Systems 15.3.1 Pluvial Deposits and Their Relationship to Sea-Level Change 15.3.2 The Concept of the Bayline 15.3.3 Deltas, Beach-Barrier Systems, and Estuaries 15.3.4 Shelf Systems: Sand Shoals and Condensed Sections 15.3.5 Slope and Rise Systems 15.4 The Sequence Stratigraphy of Carbonate Depositional Systems 15.4.1 Platform Carbonates: Catch-Up Versus Keep-Up 15.4.2 Carbonate Slopes 15.4.3 Pelagic Carbonate Environments 15.5 Main Conclusions 16 Numerical and Graphical Modeling of Sequences 16.1 Introduction 16.2 Model Design 16.3 Selected Examples of Model Results 16.4 Main Conclusions VI Discussion and Conclusions 17 Implications for Petroleum Geology 17.1 Introduction 17.2 Integrated Tectonic-Stratigraphic Analysis 17.2.1 The Basis of the Methodology 17.2.2 The Development of an Allostratigraphic Framework 17.2.3 Choice of Sequence-Stratigraphic Models 17.2.4 The Search for Mechanisms 17.2.5 Reservoir Characterization 17.3 Controversies in Practical Sequence Analysis 17.3.1 The Case of the Tocito Sandstone, New Mexico 17.3.2 The Case of Gippsland Basin, Australia 17.3.3 Conclusions: A Modified Approach to Sequence Analysis for Practicing Petroleum Geologists and Geophysicists 17.4 Main Conclusions 18 Conclusions and Recommendations 18.1 Sequences in the Stratigraphic Record 18.1.1 Long-Term Stratigraphic Cycles 18.1.2 Cycles with Million-Year Episodicities 18.1.3 Cycles with Episodicities of Less Than One Million Years 18.2 Mechanisms 18.2.1 Long-Term Eustasy and Epeirogeny 18.2.2 Milankovitch Processes 18.2.3 Tectonic Mechanisms 18.3 Chronostratigraphy and Correlation 18.3.1 Concepts of Time 18.3.2 Correlation Problems, and the Basis of the Global Cycle Chart 18.3.3 Comparison of Sea-Level Curves 18.4 Modern Sequence Analysis 18.4.1 Elaboration of the Basic Sequence Model 18.4.2 Numerical and Graphical Modeling of Stratigraphic Sequences 18.5 Implications for Petroleum Geology 18.6 The Global-Eustasy Paradigm: Working Backwards from the Answer? 18.6.1 The Exxon Factor 18.6.2 Conclusions . 18.7 Recommendations References Author Index Subject Index

Note: Table of Contents: CHAPTER 1: THE ENVIRONMENTAL ISOTOPES: Environmental Isotopes in Hydrogeology. - Stable Isotopes: Standards and Measurement. - Isotope Ratio Mass Spectrometry. - Radioisotopes. - Isotope Fractionation. - Isotope Fractionation (a), Enrichment (e), and Separation (D). - CHAPTER 2: TRACING THE HYDROLOGIGICAL CYCLE: Craig's Meteoric Relationship in Global Fresh Waters. - Partitioning of Isotopes Through the Hydrological Cycle. - Condensation, Precipitation, and the Meteoric Water Line. - A Closer Look at Rayleigh Distillation. - Effects of Extreme Evaporation. - CHAPTER 3: PRECIPITATION: The T - d18O Correlation in Precipitation. - Local Effects on T - d18O. - Ice Cores and Paleotemperature. - CHAPTER 4: GROUNDWATER: Recharge in Temperate Climates. - Recharge in Arid Regions. - Recharge from River-Connected Aquifers. - Hydrograph Separation in Catchment Studies. - Groundwater Mixing. - CHAPTER 5: TRACING THE CARBON CYCLE: Evolution of Carbon in Groundwaters. - Carbonate Geochemistry. - Carbon-13 in the Carbonate System. - Dissolved Organic Carbon. - Methane in Groundwaters. - Isotopic Composition of Carbonates. - CHAPTER 6: GROUNDWATER QUALITY: Sulphate, Sulphide and the Sulphur Cycle. - Nitrogen Cycles in Rural Watersheds. - The "Fuhrberger Feld" Study. - Source of Chloride Salinity. - Landfill Leachates. - Degredation of Chloro-organics and Hydrocarbon. - Sensitivity of Groundwater to Contamination. - Summary of Isotopes in Contaminant Hydrology. - CHAPTER 7: IDENTIYING AND DATING MODERN GROUNDWATERS: The "Age" of Groundwater. - Stable Isotopes. - Tritium in Precipitation. - Dating Groundwaters with Tritium. - Groundwater Dating with 3H -3He. - Chlorofluorocarbons (CFCs). - Thermonuclear 36Cl. - Detecting Modern Groundwaters with 85Kr . - Submodern Groundwater. - CHAPTER 8: AGE DATING OLD GROUNDWATERS: Stable Isotopes and Paleogroundwaters. - Groundwater Dating with Radiocarbon. - Correction for Carbonate Dissolution. - Some Additional Complications to 14C Dating. - 14C Dating with Dissolved Organic Carbon (DOC). - Case Studies for 14C dating with DOC and DIC. - Chlorine-36 and Very Old Groundwater. - The Uranium Decay Series. - CHAPTER 9: WATER-ROCK INTERACTION: Mechanisms of Isotope Exchange. - High Temperature Systems. - Low Temperature Water-Rock Interaction. - Strontium Isotopes in Water and Rock. - Isotope Exchange in Gas-Water Reactions. - High pH Groundwaters-The Effect of Cement Reactions. - CHAPTER 10: FIELD METHODS FOR SAMPLING: Groundwater. - Water in the Unsaturated Zone. - Precipitation. - Gases. - Geochemistry. - References. - Subject Index. - Each chapter has Problems sections.

Note: Contents: Preface to the Second Edition. - Preface to the First Edition. - Part 1. - 1 Preliminary Description of Error Analysis. - 1.1 Errors as Uncertainties. - 1.2 Inevitability of Uncertainty. - 1.3 Importance of Knowing the Uncertainties. - 1.4 More Examples. - 1.5 Estimating Uncertainties When Reading Scales. - 1.6 Estimating Uncertainties in Repeatable Measurements. - 2. How to Report and Use Uncertainties. - 2.1 Best Estimate ± Uncertainty. - 2.2 Significant Figures. - 2.3 Discrepancy. - 2.4 Comparison of Measured and Accepted Values. - 2.5 Comparison of Two Measured Numbers. - 2.6 Checking Relationships with a Graph. - 2.7 Fractional Uncertainties. - 2.8 Significant Figures and Fractional Uncertainties. - 2.9 Multiplying Two Measured Numbers. - Problems for Chapter 2. - 3. Propagation of Uncertainties. - 3.1 Uncertainties in Direct Measurements. - 3.2 The Square-Root Rule for a Counting Experiment. - 3.3 Sums and Differences; Products and Quotients. - 3.4 Two Important Special Cases. - 3.5 Independent Uncertainties in a Sum. - 3.6 More About Independent Uncertainties. - 3.7 Arbitrary Functions of One Variable. - 3.8 Propagation Step by Step. - 3.9 Examples. - 3.10 A More Complicated Example. - 3.11 General Formula for Error Propagation. - Problems for Chapter 3. - 4. Statistical Analysis of Random Uncertainties. - 4.1 Random and Systematic Errors. - 4.2 The Mean and Standard Deviation. - 4.3 The Standard Deviation as the Uncertainty in a Single Measurement. - 4.4 The Standard Deviation of the Mean. - 4.5 Examples. - 4.6 Systematic Errors. - Problems for Chapter. - 5. The Normal Distribution. - 5.1 Histograms and Distributions. - 5.2 Limiting Distributions. - 5.3 The Normal Distribution. - 5.4 The Standard Deviation as 68% Confidence Limit. - 5.5 Justification of the Mean as Best Estimate. - 5.6 Justification of Addition in Quadrature. - 5.7 Standard Deviation of the Mean. - 5.8 Acceptability of a Measured Answer . - Problems for Chapter 5. - Part II. - 6. Rejection of Data. - 6.1 The Problem of Rejecting Data. - 6.2 Chauvenet's Criterion. - 6.3 Discussion. - Problems for Chapter 6. - 7. Weighted Averages. - 7.1 The Problem of Combining Separate Measurements. - 7.2 The Weighted Average. - 7.3 An Example. - Problems for Chapter 7. - 8. Least-Squares Fitting. - 8.1 Data That Should Fit a Straight Line. - 8.2 Calculation of the Constants A and В. - 8.3 Uncertainty in the Measurements of у. - 8.4 Uncertainty in the Constants A and В. - 8.5 An Example. - 8.6 Least-Squares Fits to Other Curves. - Problems for Chapter 8. - 9. Covariance and Correlation. - 9.1 Review of Error Propagation. - 9.2 Covariance in Error Propagation. - 9.3 Coefficient of Linear Correlation. - 9.4 Quantitative Significance of r. - 9.5 Examples. - Problems for Chapter 9. - 10. The Binomial Distribution. - 10.1 Distributions. - 10.2 Probabilities in Dice Throwing. - 10.3 Definition of the Binomial Distribution. - 10.4 Properties of the Binomial Distribution. - 10.5 The Gauss Distribution for Random Errors. - 10.6 Applications; Testing of Hypotheses. - Problems for Chapter 10. - 11. The Poisson Distribution. - 11.1 Definition of the Poisson Distribution. - 11.2 Properties of the Poisson Distribution. - 11.3 Applications. - 11.4 Subtracting a Background. - Problems for Chapter 11. - 12. The Chi-Squared Test for a Distribution. - 12.1 Introduction to Chi Squared. - 12.2 General Definition of Chi Squared. - 12.3 Degrees of Freedom and Reduced Chi Squared. - 12.4 Probabilities for Chi Squared. - 12.5 Examples. - Problems for Chapter 12. - Appendixes. - Appendix A. Normal Error Integral, I. - Appendix B. Normal Error Integral, II. - Appendix C. Probabilities for Correlation Coefficients. - Appendix D. Probabilities for Chi Squared. - Appendix E. Two Proofs Concerning Sample Standard Deviations. - Bibliography. - Answers to Quick Checks and Odd-Numbered Problems. - Index.

Note: Contents: Preface to the Second Edition. - Preface to the First Edition. - 1. INTRODUCTION AND HISTORICAL BACKGROUND. - History. - The Discovery of X-Rays. - The Discovery of X-Ray Diffraction. - History of Clay Mineralogy. - The Importance of Clay Mineralogy. - Box 1.1 Clay Minerals as Catalysts. - The Literature of Clay Mineralogy. - Summary. - References. - 2. NATURE AND PRODUCTION OF X-RAYS. - Box 2.1 Other Methods. - Safety and Protection. - Box 2.2 Defining a Dose of Radiation. - The Nature or X-Rays. - Continuous or White Radiation. - Characteristic Radiation. - General Absorption of X-Rays. - Characteristic Absorption. - Equipment for Producing and Recording X-Rays. - Stabilizing the Voltage. - Generating X-Rays. - The Diffractometer. - Step-Scanning with Automated Diffractometers. - The Single-Crystal Monochromator. - The Detector. - Signal Processing Circuitry. - The Strip-Chart Recorder. - An Example of a Checklist for Operating XRD Equipment. - Summary. - References. - 3. X-RAY DIFFRACTION. - Scattering. - Interference. - Scattering from a Row of Atoms. - Scattering from a Three-Dimensional Array of Atoms. - Bragg's Law. - Box 3.1 Diffraction and Reflection. - The Arithmetic of Scattering. - The Summation of Scattering Amplitudes. - The Structure Factor F. - Information from Intensity. - The Reciprocal Lattice. - Real versus Idealized Peaks on XRD Tracings. - The Interference Function F: Diffraction from a Crystal. - Whose Unit Cell Has a Unitary Scattering Factor. - The Lorentz-Polarization Factors. - Putting It All Together—Building an 001 Diffraction Pattern. - Exercise: Calculation of the Intensity from d(001) for Illite. - Points to Remember. - References. - 4. STRUCTURE AND PROPERTIES: GENERAL TREATMENT. - General Structural Features. - Tetrahedral Sheets. - Octahedral Sheets. - Dioctahedral and Trioctahedral. - Joining the Sheets. - Stacking the Layers. - Properties. - Total Charge, Layer or Permanent Charge, and Variable Charge. - Electric Double Layer. - Exchangeable Ions or Cation-Exchange Capacity. - Interaction of Water with Clay Mineral Surfaces. - Interaction with Organic Compounds. - Classification. - Box 4.1 Nomenclature. - References. - 5. STRUCTURE, NOMENCLATURE, AND OCCURRENCES OF CLAY MINERALS. - The Individual Clay Minerals. - The 1:1 Layer Type. - Serpentine minerals. - Berthierine. - Odinite. - Kaolin minerals. - Box 5.1 Uses of Kaolinite. - Allophane and imogolite. - The 2:1 Layer Type, x = 0. - The 2:1 Layer Type, x ~ 1. - The trioctahedral subgroup. - The dioctahedral subgroup. - The 2:1 Layer Types with x 〈 1. - Illite. - Glauconite. - Smectite. - Box 5.2 Alteration of Ash-Fall Layers. - Vermiculite. - Chlorite. - Mixed-Layered Clay Minerals. - Mixed-layering, interlayering, and interstratification. - Illite/smectite (I/S). - Box 5.3 Reichweite or Ordering. - Models for smectite-to-illite transition. - MacEwan crystallite model. - Fundamental particle model. - Two-solid-solution model. - Chlorite/smectite (C/S). - Serpentine/chlorite. - Kaolinite/expandables (K/E). - Sepiolite and Palygorskite. - The Origin of Clay Minerals. - Summary. - Exercise: Calculating Structural Formulas. - Exercise: Making Structural Models of Layer Silicates. - References. - 6. SAMPLE PREPARATION TECHNIQUES FOR CLAY MINERALS. - Evaluating the Sample. - Disaggregating the Rock. - Separating Clay Minerals from Clastic Rocks. - Separating Clay Minerals from Carbonate Rocks. - Separating Clay Minerals from Sulfate Rocks. - Separating Clay Minerals from Unconsolidated Materials. - Box 6.1 Glacial Deposits, North American Interior. - Chemical Pretreatments. - Removal of Iron Oxides. - Removal of Organic Materials. - Saturating the Clay Minerals with Different Cations. - Particle-Size Separation. - Preparing the Oriented Clay Mineral Aggregates. - The Glass Slide Method. - The Smear Mount Method. - The Millipore® Filter Transfer Method. - The Centrifuged Porous Plate Method. - Dealing with Curlers or Peelers. - Making the Random Powder Mount. - Everyday random powder packs. - Freeze-dried random powder packs. - Ethylene Glycol Solvation. - Final Note. - References. - IDENTIFICATION OF CLAY MINERALS AND ASSOCIATED MINERALS. - Clay Mineral Identification—General Principles. - Illite and Glauconite. - Chlorite and Kaolinite. - Vermiculite. - Smectite. - Sepiolite, Palygorskite, and Halloysite. - 060 Reflections. - The Use of hkl Reflections for the Determination of Polytypes. - Chlorite Polytypes. - The Kaolin Polytypes. - The Micas, Illite, and Glauconite. - Nonclay Minerals. - Silica Minerals. - Feldspar. - Zeolites. - Carbonates. - Apatite, Pyrite, and Jarosite. - Gypsum, Anhydrite, Celestite, and Barite. - Lepidocrocite, Goethite, Gibbsite, and Anatase. - Summary. - References. - 8. IDENTIFICATION OF MIXED-LAYERED CLAY MINERALS. - Méring's Principles and Mixed-Layered Nomenclature. - The Q Rule, a Broadening Descriptor. - Mixed-Layered Clay Minerals. - Illite/Smectite. - Chlorite/Smectite and Chlorite/Vermiculite. - Kaolinite/Smectite. - Serpentine/Chlorite. - Mica/Vermiculite. - Summary. - References. - 9. QUANTITATIVE ANALYSIS. - Required Sample Characteristics. - Sample Length. - Sample Thickness. - Sample Position. - Homogeneity of the Sample. - Equations for Quantitative Analysis. - Basic Quantitative Diffraction Equation. - Derivation of a Working Form of the Equation for Analysis. - The Method of the Orienting Internal Standard. - Mineral Reference Intensities. - General Comments. - Calculated Mineral Reference Intensities. - Practical Examples of the Application of Reference. - Intensities. - Measurement of Peak Intensity. - Comments and Summary. - References. - 10. DISORDER IN SMECTITE, ILLITE/SMECTITE, AND ILLITE. - Small Crystals in Reciprocal Space. - Turbostratic Disorder. - Theory. - Smectite. - Illite/Smectite. - Rotational Disorder in Illite and Illite/Smectite. - Cis-Vacant Elite and Interstratified Cis- and Trans-Vacant. - Illite/Smectite. - Conclusions. - References. - APPENDIX: MODELING ONE-DIMENSIONAL X-RAY PATTERNS. - The Input Variables. - Simulating the Instrument. - Describing the Clay Mineral. - Theory. - Structures of the Component Layers. - Advanced Techniques. - Pure Minerals. - Compositional Superstructures. - Layer Types Not Specifically Included. - Atom Types Not Incorporated in the Model. - Defect Broadening. - References. - INDEX.