ALBERT

Note: Zugl.: Greifswald, Univ., Diss., 2005

Note: Contents Acknowledgments Chapter 1. Introduction 1.1 Discovery 1.2 General Introduction 1.3 Just for Fun — An Isotope Biography of Mr. Polychaete Chapter 2. Isotope Notation and Measurement Overview 2.1 The Necessary Minimum for Ecologists 2.2 Why Use the 5 Notation? 2.3 Why Is 8 a Good Substitute for % Heavy Isotope? 2.4 8 and the Ratio-of-Ratios 2.5 Chapter Summary Chapter 3. Using Stable Isotope Tracers Overview 3.1 Isotope Circulation in the Biosphere 3.2 Landscape Ecology and Isotope Maps 3.3 Community Ecology and Invasive Species in Food Webs 3.4 Life History Ecology and Animal Migrations 3.5 Plants, Microbes, and Scaling Up 3.6 Chapter Summary Chapter 4. Isotope Chi ("I Chi") Overview 4.1 Chocolate Isotopes 4.2 Oxygen in the Sea 4.3 Equations for Isotope Chi ("I Chi") 4.4 Building an I Chi Gain-Loss Model, Step by Step 4.5 Errors in I Chi Models 4.6 Exact Equations for I Chi Models 4.7 Cows in a Pasture 4.8 Chapter Summary Chapter 5. Mixing Overview 5.1 Isotope Mixing in Food Webs 5.2 Isotope Sourcery 5.3 Mixing Mechanics 5.4 Advanced Mixing Mechanics 5.5 Mixing Assumptions and Errors or the Art and Wisdom of Using Isotope Mixing Models 5.6 River Sulfate and Mass-Weighted Mixing 5.7 A Special Muddy Case and Mixing Through Time 5.8 The Qualquan Chronicles and Mixing Across Landscapes 5.9 Dietary Mixing, Turnover, and a Stable Isotope Clock 5.10 Chapter Summary Chapter 6. Isotope Additions Overview 6.1 Addition Addiction 6.2 The Golden Spike Award for Isotopes 6.3 Chapter Summary Chapter 7. Fractionation Overview 7.1 Fractionation Fundamentals 7.2 Isotopium and Fractionation in Closed Systems 7.3 A Strange and Routine Case 7.4 A Genuine Puzzle — Fractionation or Mixing? 7.5 Cracking the Closed Systems 7.6 Equilibrium Fractionation, Subtle Drama in the Cold 7.7 A Supply/Demand Model for Open System Fractionation 7.8 Open System Fractionation and Evolution of the Earth's Sulfur Cycle 7.9 Open System Legacies 7.10 Conducting Fractionation Experiments 7.11 Chapter Summary Chapter 8. Scanning the Future Overview 8.1 The Isotope Scanner 8.2 Mangrove Maude 8.3 The Beginner's Advantage—Imagine! 8.4 Chapter Summary Appendix. Important Isotope Equations and Useful Conversions Index Supplemental Electronic Materials on the Accompanying CD A. Chapter 1 Color Figures and Cartoon Problems B. Chapter 2 Color Figures and Cartoon Problems Technical Supplement 2A: Measuring Spiked Samples Technical Supplement 2B: Ion Corrections Technical Supplement 2C: The Ratio Notation and The Power of 1 C. Chapter 3 Color Figures and Cartoons Problems D. Chapter 4 Color Figures and Cartoons Problems I Chi Spreadsheets E. Chapters 5 Color Figures and Cartoons Problems I Chi Spreadsheets F. Chapter 6 Color Figure and Cartoon Problems I Chi Spreadsheet Technical Supplement 6A: How Much Isotope Should I Add? Technical Supplement 6B: Noisy Data and Data Analysis with Enriched Samples G. Chapter 7 Color Figures and Cartoons Problems I Chi Spreadsheets Technical Supplement 7A: A Chemist's View of Isotope Effects Technical Supplement 7B: Derivations of Closed System Isotope Equations H. Chapter 8 Color Figures and Cartoons Problems I. All Problems for Chapters 1-8 J. All Answers to Problems for Chapters 1-8 K. All Figures and Cartoons L. All I Chi Spreadsheets M. A Reading List

Note: Table of Contents: Copyright; Additional copies. - Foreword and acknowledgements. - Chapter 1. Cosmochemistry of the Rare Earth Elements: Condensation and Evaporation Processes / by William V. Boynton. - Introduction. - Meteorites. - Astrophysical context for interpretation of cosmochemical data. - Solar nebula. - Solar abundances. - Cosmochemical properties of the REE. - REE condensation reactions. - Activity coefficients. - Partial pressures. - Solid / gas distribution coefficients. - Why are the REE volatilities so different?. - Calculated REE patterns. - Early condensates. - Removing REE in the gas. - Comparison with meteoritic data. - Ultra-refractory component. - Group II inclusions. - FUN inclusions. - REE condensation as a function of oxygen fugacity. - Rims on CAI. - What have we learned from the REE?. - High temperatures were achieved in the solar nebula. - A very efficient mechanism for gas/dust separation existed in the solar nebula. - The high nebular temperatures existed for a long time. - A very intense, very brief, heat source also existed. - The solar nebula was a chaotic environment. - Summary. - Acknowledgements. - References. - Chapter 2. Radiogenic Isotope Geochemistry of Rare Earth Elements / by P. Jonathan Patchett. - Introduction. - Long-lived radioactive isotopes of Rare Earth Elements. - 138La-138Ce decay. - 147Sm-143Nd decay. - 176Lu-176Hf decay. - Cemical variations of La/Ce, Sm/Nd and Lu/Hf ratios. - Geochronological studies. - La-Ce and Lu-Hf chronology. - Sm-Nd chronology. - Defining bulk planetary isotopic evolution. - Isotopic study of planetary interiors. - The Moon. - The Earth. - Nd isotopes in studies of terrestrial crustal evolution. - Model Nd ages of continental crust. - Growth curves for the continental crust. - Origin of granitoids. - Nd isotopes and the sedimentary system. - Characterization of whole crustal terranes. - Crustal Lu-Hf isotopic studies. - Major unsolved problems. - Continental crustal growth curve. - Abundance of Archean continental crust. - Origin of mantle isotopic variations. - References. - Chapter 3. Partitioning of Rare Earth Elements between Major Silicate Minerals and Basaltic Melts / by Gordon A. McKay. - Introduction. - Usefulness of the REE for petrogenetic modelling. - Scope of this chapter. - Caveat. - How partition coefficients are measured. - Phenocryst/matrix studies of natural samples. - Experimental measurement of partition coefficients. - Basic experimental approach. - Equilibrium. - Percent level doping technique. - Beta-track mapping technique. - Other experimental approaches. - Henry's law: The applicability of percent-level doping results. - Factors governing mineral/melt partitioning. - Ionic size and charge of trace element. - Crystal field effects. - Cristallographic versus defect sites: The Henry's law question. - Phase compositions. - Oxidation state. - Thermodynamic relationships: Dependence of partitioning on temperature and composition. - Other predictive approaches. - Special applications. - Eu as an oxygen fugacity indicator. - Origin of the Eu anomaly in lunar mare basalts. - REE partition coefficient patterns for the major minerals. - Plagioclase. - Olivine. - Pyroxene. - Low-Ca pyroxene. - High-Ca pyroxene. - Garnet. - Future directions. - Acknowledgements. - References. - Chapter 4. An Approach to Trace Element Modeling Using a Simple Igneous System as an Example / by Gilbert N. Hanson. - Introduction. - Review of trace element equations. - Melting. - Fractional crystallization. - Melting versus fractional crystallization. - Essential structural constituents. - Example of petrogenetic approach. - Discussion and summary. - Acknowledgements. - References. - Chapter 5. Rare Earth Elements in Upper Mantle Rocks / by W. F. McDonough and Fredrick A. Frey. - Introduction. - Massive peridotites. - Massive peridotites: dominantly lherzolite Western Alps - Lanzo. - Western Alps -Baldissero, Balmuccia. - Eastern Liguria, Italy. - Western Liguria, Italy. - Eastern Pyrenees - France. - Ronda, Spain Effects of late stage alteration on REE. - What can be inferred about the melting process and the segregated melts?. - Massive peridotites: pyroxenite layers and veins and their wall rocks. - Amphibole-bearing pyroxenite veins. - Anhydrous pyroxenite layers. - How were the pyroxenite layers created? Evidence for multistage processes. - Implications for mantle enrichment processes (metasomatism). - Massive peridotites: dominantly harzburgite. - Oceanic peridotites. - Ultramafic xenoliths. - Group I spinel peridotites. - Garnet peridotites. - Pyroxenite and related xenoliths. - Models for REE abundance trends in peridotite xenoliths. - Megacrysts, minerals in xenoliths and damong inclusions. - Megacrysts. - Minerals in peridotites and pyroxenites. - Inclusions in diamonds. - Summary: comparison of peridotites from massifs and xenoliths and implications of REE data for Upper Mantle composition. - Acknowledgements. - References. - Chapter 6. Rare Earth Elements in Metamorphic Rocks / by Richard I. Grauch. - Introduction. - REE residence in metamorphic rocks. - REE mobility during metamorphism. - REE content of metamorphic rocks. - Suggestions for future work. - Acknowledgements. - References. - Chapter 7. Rare Earth Elements in Sedimentary Rocks: Influence of Provenance and Sedimentary Processes / by Scott M. McLennan. - Introduction. - Rare earth element properties and sedimentary rocks. - Cosmochemical considerations. - Geochemical considerations. - Aqueous geochemistry. - Normalizing and notation. - Sedimentary processes. - Weathering. - Diagenesis. - Sedimentary sorting. - REE and provenance studies. - Sedimentary rocks and crustal abundances. - Sedimentation and plate tectonics. - Archean sedimentary rocks and the Archean crust. - Archean greenstone belts. - REE in sedimentary rocks and crustal evolution. - Acknowledgements. - References. - Chapter 8. Aqueous Geochemistry of Rare Earth Elements / by Douglas G. Brookins. - Introduction. - The trivalent lanthanides (Ln III). - Types of complexes in solution. - Hydrolysis products. - Phosphate complexes. - Carbonate complexes. - Halide complexes. - Complexes with total dissolved sulfur. - Gadolinium-Terbium fractionation?. - Scandium and Yttrium. - Europium (II). - Cerium (IV). - Eh-pH diagrams. - Cerium. - Europium. - Other lanthanides. - Lanthanides in ocean waters. - Lanthanides and actinides. - Concluding remarks. - Acknowledgements. - References. - Chapter 9. Rare Earth Elements in Lunar Materials / by Larry A. Haskin. - Introduction. - The nature of planet moon. - The magma ocean hypothesis and its presumed products. - Lunar REE patterns. - Highland plutonic rocks. - Anorthosites. - Durâtes, troctolites, norites, and gabbros. - Lunar felsite (granite). - Highland volcanic rocks: KREEP. - Mare basalts. - Mare basalt sources as magma ocean products. - Assimilation of crusted material during basalt petrogenesis. - Glassy spherules. - Soils and breccias. - Caveat. - Acknowledgements. - References. - Chapter 10. Compositional and Phase Relations among Rare Earth Element Minerals / by Donald M. Burt. - Introduction. - Geochemical background. - Minerals. - Coupled substitutions. - Vector treatment. - Application to selected mineral groups. - Fluorides. - Carbonates. - Fluorocarbonates. - Monazite, xenotime, zircon, and related phases. - Apatites. - Florencite and related phases. - A-B oxides (niobates, tantalates, titanates, ferrites). - Fergusonitelbetafergusonite, ABO4. - Perovskite, ABO3. - Aeschyniteleuxenite, AB2O6. - Pyrochlore, A1-2B2O6(O,F,OH). - Allanite. - Titanite. - Garnet. - Gadolinite. - Chevkinite/perrierite. - Element distributions: acid-base relations. - Summary. - Acknowledgemen

Note: Contents: Preface / Hans-Jürgen Paech. - Palaeomagnetic and geochronological study of late Pan-African and Mesozoic igneous and metamorphic rocks from Central Dronning Maud Land, East Antarctica / Christian Rolf & Friedhelm Henjes-Kunst. - Aeromagnetic survey in Central Dronning Maud Land, East Antarctica, during the 1995/1996 GeoMaud Expedition: layout, execution, and data processing / Detlef Damaske, Vera Marginkowski, & Heinz-Dieter Möller. - Magnetic susceptibility of rock samples from Central Dronning Maud Land, East Antarctica / Hans-Jürgen Paech & Vera Marginkowski. - 3-D Aeromagnetic modelling in the Grubergebirge Area, Central Dronning Maud Land, East Antarctica / Sunchan Choi. - Ice thickness and sub-ice topography in Central Dronning Maud Land deduced by Radio Echo Sounding / Volkmar Damm & Dieter Eisenburger. - Airborne Radio Echo Sounding Survey in Central Dronning Maud Land, East Antarctica / Uwe Meyer, Daniel Steinhage, Uwe Nixdorf & Heinz Miller. - Gravity survey in Central Dronning Maud Land, East Antarctica, during the 1995/96 GeoMaud Expedition / Gernot Reitmayr. - Gravimetric profiling in Central Dronning Maud Land, East Antarctica / Diedrich Fritzsche. - A compilation of geophysical data from the Lazarev Sea and the Riiser-Larsen Sea, off Central Dronning Maud Land, East Antarctica / Karl Hinz, Soenke Neben, Yulia B. Gouseva & G. A. Kudryavtsev. - Sub-ice topography of selected areas in Central Dronning Maud Land, East Antarctica (Ground-based RES survey) / Georg Delisle. - Observations of the temperature field of glaciers at the margin of the Polar Plateau, Central Dronning Maud Land, East Antarctica / Georg Delisle. - A short note on the thermal regime of Lake Untersee in the Grubergebirge of Central Dronning Maud Land, East Antarctica / Georg Delisle & Michael Zeibig. - Late quaternary ice level changes in Central Dronning Maud Land, East Antarctica, as inferred from 14C ages of Mumiyo Deposits in snow petrel colonies / Ulrich Wand & Wolf-Dieter Hermichen. - A mummified seal found far inland in Central Dronning Maud Land, East Antarctica / Ulrich Wand & Wolf-Dieter Hermichen & Norbert W. Roland. - Precise GPS measurements to infer vertical crustal deformation in Central Dronning Maud Land, East Antarctica / Mirko Scheinert, Reinhard Dietrich, Axel Rülke, James Perlt & E. C. Malaimani. - Photogrammetric survey in Central Dronning Maud Land, East Antarctica, during the 1996 GeoMaud Expedition / Heinz Bennat. - Logistics of the 1995/96 GeoMaud Expedition to Central Dronning Maud Land, East Antarctica / Hans-Jürgen Paech & Jürgen Kothe. - Geographic data (Names, elevations and topographic maps) of Central Dronning Maud Land, East Antarctica / Hans-Jürgen Paech. - Comparison of the geology of Central Dronning Maud Land, East Antarctica, with other areas of the Gondwana Supercontinent / Hans-Jürgen Paech, Wilfried Bauer, Sandra Piazolo, Joachim Jacobs & Gregor Markl. - Present knowledge of the Geology of Central Dronning Maud Land, East Antarctica: Main results of the 1995/96 GeoMaud Expedition / Hans-Jürgen Paech. - 1 : 500,000 Geological map of Central Dronning Maud Land with explanatory notes / Hans-Jürgen Paech, Joachim Jacobs, Wilfried Bauer, Evgueni Mikhalsky, Franco Talarico, Fabrizio Colombo, Norbert W. Roland & Friedhelm Henjes-Kunst. - Editorial note.

Note: Zugl.: Bremen, Univ., Diss., 2006

Note: Contents: List of contributors. - Preface. - 1 An Overview of Rates of Chemical Weathering / S. M. Colman and D. P. Dethier. - PART I KINETICS AND MECHANISMS OF WEATHERING REACTIONS. - 2 The Relations between Crystal Structure and Silicate Weathering Rates / R. A. Eggleton. - 3 The Dissolution Rate of Forsteritic Olivine from Hawaiian Beach Sand / D. E. Grandstaff. - 4 Stoichiometry of Alkali Feldspar Dissolution at Room Temperature and Various pH Values / G. R. Holdren, Jr. and P. M. Speyer. - 5 Rate Limitation and Dissolution of Highly Soluble Minerals / J. B. Laronne. - PART II RATES OF MINERAL ALTERATION IN SOIL ENVIRONMENTS. - 6 The Etching of Hornblende Grains in the Matrix of Alpine Tills and Periglacial Deposits / R .D. Hall and R. E. Martin. - 7 Rates of Hornblende Etching in Soils on Glacial Deposits, Baffin Island, Canada / W. W. Locke. - 8 Rates of Mineral Weathering in the Wind River Mountains, Western Wyoming / W. C. Mahaney and D. L. Halvorson. - 9 Evolution of Iron Crusts in Tropical Landscapes / D.B. Nahon. - 10 Processes and Rates of Weathering in Cold and Polar Desert Environments / F. C. Ugolini. - PART III WEATHERING OF VOLCANIC ASHES AND DEPOSITS. - 11 Weathering of Holocene Airfall Tephras in the Southern Canadian Rockies / R. H. King. - 12 Controls on the Rates of Weathering and Clay Mineral Genesis in Airfall Tephras: A Review and New Zealand Case Study / D. J. Lowe. - 13 Rates of Weathering of 14C-Dated Late Quaternary Volcaniclastic Deposits in the Western United States / V. E. Neall and I. K. Paintin. - 14 Chemical Weathering of the May 18, 1980, Mount St. Helens Ash Fall and the Effect on the Iron Creek Watershed, Washington / A. F. White and L. V. Benson and A. Yee. - PART IV RATES OF FORMATION OF ROCK-WEATHERING FEATURES. - 15 Levels of Time Information in Weathering Measurements, with Examples from Weathering Rinds on Volcanic Clasts in the Western United States / S. M. Colman. - 16 Weathering Rates in Granitic Boulders Measured by P-Wave Speeds / R. Crook, Jr. and A. R. Gillespie. - 17 Growth of Weathering Rinds on Torlesse Sandstone, Southern Alps, New Zealand / I. E. Whitehouse and M. J. McSaveney and P. L. K. Knuepfer and T. J. H. Chinn. - PART V HYDROCHEMICAL STUDIES OF RATES OF WEATHERING. - 18 The Mathematical Basis for Determining Rates of Geochemical and Geomorphic Processes in Small Forested Watersheds by Mass Balance: Examples and Implications / M. A. Velbel. - 19 An Estimate of Plagioclase Weathering Rate in the Idaho Batholith Based upon Geochemical Transport Rates / J. L. Clayton. - 20 The Use of Catchment Studies for Assessing Chemical Weathering Rates in Two Contrasting Upland Areas in Northeast Scotland / J. Creasey and A. C. Edwards and J. M. Reid and D. A. MacLeod and M. S. Cresser. - 21 Weathering Rates and the Chemical Flux from Catchments in the Pacific Northwest, U.S.A. / D. P. Dethier. - 22 Rates of Weathering and Erosion Derived from Mass Balance in Small Drainage Basins / T. Paces. - 23 Processes and Rates of Saprolite Production and Erosion on a Foliated Granitic Rock of the Virginia Piedmont / M. J. Pavich. - Index.