ALBERT

Description: The Argentine margin contains important sedimentological, paleontological and chemical records of regional and local tectonic evolution, sea level, climate evolution and ocean circulation since the opening of the South Atlantic in the Late Jurassic–Early Cretaceous as well as the present-day results of post-depositional chemical and biological alteration. Despite its important location, which underlies the exchange of southern- and northern-sourced water masses, the Argentine margin has not been investigated in detail using scientific drilling techniques, perhaps because the margin has the reputation of being erosional. However, a number of papers published since 2009 have reported new high-resolution and/or multichannel seismic surveys, often combined with multi-beam bathymetric data, which show the common occurrence of layered sediments and prominent sediment drifts on the Argentine and adjacent Uruguayan margins. There has also been significant progress in studying the climatic records in surficial and near-surface sediments recovered in sediment cores from the Argentine margin. Encouraged by these recent results, our 3.5-day IODP (International Ocean Discovery Program) workshop in Buenos Aires (8–11 September 2015) focused on opportunities for scientific drilling on the Atlantic margin of Argentina, which lies beneath a key portion of the global ocean conveyor belt of thermohaline circulation. Significant opportunities exist to study the tectonic evolution, paleoceanography and stratigraphy, sedimentology, and biosphere and geochemistry of this margin.

Description: The current generation of marine biogeochemical modules in Earth system models (ESMs) considers mainly the effect of marine biota on the carbon cycle. We propose to also implement other biologically driven mechanisms in ESMs so that more climate-relevant feedbacks are captured. We classify these mechanisms in three categories according to their functional role in the Earth system: (1) "biogeochemical pumps", which affect the carbon cycling; (2) "biological gas and particle shuttles", which affect the atmospheric composition; and (3) "biogeophysical mechanisms", which affect the thermal, optical, and mechanical properties of the ocean. To resolve mechanisms from all three classes, we find it sufficient to include five functional groups: bulk phyto- and zooplankton, calcifiers, and coastal gas and surface mat producers. We strongly suggest to account for a larger mechanism diversity in ESMs in the future to improve the quality of climate projections.

Description: EGU2010-13373 The frequency of volcanic activity varies on a wide rangeof spatial and temporal scales, from 〈1 yr. periodicities in single volcanic systems to periodicities of 106 yrs. in global volcanism. The causes of these periodicities are poorly understood although the long-term global variations are likely linked to plate-tectonic processes. Here we present evidence for temporal changes in eruption frequencies at an intermediate time scale (104 yrs.) using the Pleistocene to recent records of widespread tephras of sub-Plinian to Plinian, and occasionally co-ignimbrite origin, along the Pacific Ring of Fire, which accounts for about half of the global length of 44,000 km of active subduction. Eruptions at arc volcanoes tend to be highly explosive and the well-preserved tephra records from the ocean floor can be assumed to be representative of how eruption frequencies varied with time. Volcanic activity along the Pacific Ring of Fire evolved through alternating phases of high and low frequency; although there is modulation by local and regional geologic conditions, these variations have a statistically significant periodicity of 43 ka that overlaps with the temporal variation in the obliquity of the Earth’s rotation axis, an orbital parameter that also exerts a strong control on global climate changes. This may suggest that the frequency of volcanic activity is controlled by effects of global climate changes. However, the strongest physical effects of climate change occur at 100 ka periods which are not seen in the volcanic record. We therefore propose that the frequency of volcanic activity is directly influenced by minute changes in the tidal forces induced by the varying obliquity resulting in long-period gravitational disturbances acting on the upper mantle.

Description: EGU2010-10518 Seafloor compliance is the transfer function between pressure and vertical displacement at the seafloor Infragravity waves in the oceanic layer have long periods in the range of 30 – 500 s and obey a simple frequencywavenumber relation. Seafloor compliance from infragravity waves can be analyzed with single station recordings to determinate sub-seafloor shear wave velocities. Previous studies in the Pacific Ocean have demonstrated that reliable near-surface shear wave profiles can be derived from infragravity wave compliance. However, these studies indicate that, beside the water depth the compliance measurements are limited by instrument sensitivity, calibration uncertainties and possibly other effects. In this work seafloor compliance and infragravity waves are observed at two different locations in the Atlantic Ocean: the Logatchev hydrothermal field at the Mid Atlantic Ridge and the Azores (Sao Miguel Island). The data was acquired with the broadband ocean compliance station developed at the University of Hamburg as well as ocean station from the German instrument pool for amphibian seismology (DEPAS) equipped with broadband seismometers and pressure sensors. Vertical velocity and pressure data were used to calculate power spectral densities and normalized compliance along two profiles (one in each location). Power spectral densities show a dominant peak at low frequencies (0.01-0.035Hz) limited by the expected cut-off frequency, which is dependent on the water depth at each station. The peak has been interpreted as a strong infragravity wave with values between 10-14 and 10-11 (m/s2)2/Hz and 104 and 106 (Pa2)2/Hz for acceleration and pressure respectively. The results show compliance values between 10-10 and 10-8 1/Pa and its estimations take into account the coherence between seismic and pressure signals in order to confirm that the seismic signals in the infragravity waves are caused by pressure sources. Shear wave velocity models, with depth resolution from 200 to 2500 m for the deep water stations, were derived from compliance. Preliminary results indicate shear wave velocity increasing from 200 to 3500 m/s.

Description: EGU2010-9841 Active mud volcanoes, where changing salinities of pore fluids, large temperature gradients and occurrences of free gas are frequently observed, should potentially exhibit significant variability in their internal resistivity structure. This is due to the fact that the bulk resistivity is mainly determined by the porosity of sediments and the electrical resistivity of the pore filling contained therein. The resistivity variations may be derived from controlled source electromagnetic (CSEM) measurements. CSEM systems consist of an electric dipole transmitter producing a time varying source field and electric dipole receivers, which measure the earth´s response to this signal. For a RWE Dea funded investigation of fluid and gas leakages at the North Alex Mud Volcano (NAMV) - a comparatively small target with an area of about 1km2 - we have developed a new high resolution CSEM system. The system consists of several autonomous electric dipole receivers and a lightweight electric dipole transmitter, which can be mounted on a small remotely operated underwater vehicle (ROV). The use of a ROV allows for a precise placement of the transmitter, which is a necessary prerequisite for the investigation of such a small target. Furthermore, electromagnetic signals may be transmitted from different directions with respect to the stationary receivers, allowing for a 3D-style tomographic experiment. In this experiment, ten receivers were deployed over the surface of NAMV at a total of 16 receiver locations. During three successful dives with a Cherokee ROV (Ghent University, Belgium), the transmitter was deployed at a total of 80 locations. Here we present first quantitative results consisting of apparent resistivity estimations from the CSEM time domain data for each transmitter-receiver pair. The apparent resistivity map shows that the NAMV indeed has a heterogeneous resistivity structure with apparent resistivities varying by at least a factor of two: low apparent resistivities (~ 0.8Ωm) are found towards the center of the MV, whereas higher apparent resistivities (~ 1.6Ωm) prevail away from the center. In a second step, we interpret the time-domain data based on 1D inversions. Good data fits can be achieved by models containing 2-3 layers. Generally, the models indicate low resistivities at the surface, which can be associated with penetrating salt water and/or high temperatures. Toward greater depths, increasing resistivities presumably are due to a combination of compaction of sediments (i.e. reduced pore space), an increased presence of fresh water and possible occurrences of free gas. For some 1D models, the increase in resistivity exceeds a factor of 10 or more and layer interfaces are indicated down to depths of up to 70m. The derived resistivity variations observed at the NAMV will be interpreted in conjunction with temperature (Feseker, this session), fluid flow (Brückmann et al., this session) and seismic data (Bialas et al., this session) acquired. Temperature variations measured in the upper few meters are related to fluid flow, where high temperatures are indicative of upwelling fluids of low salinity and low temperature of either a downward flow of saline fluids or no flow activity. This type of surface measurement constitutes an integrative fluid flow gauge, which we can resolve vertically with our resistivity models. Seismic data yield a background structure to our resistivity model. New analysis of seismic data shows that seismic activity may also be linked to fluid flow activity, which we aim to match with resistivity variations and oscillations, which were observed in the electric and magnetic fields (Lefeldt et al., this session).

Description: Recently Hathorne et al. (2009) documented large intratest trace element (TE) variations in planktonic foraminifera from a single sediment trap sample that could not be explained by variations in water column properties. The laser ablation ICP-MS depth profiles of trace elements through the test walls revealed strong positive correlations between Li, Mg, Mn and Ba resulting from the mixing of a lower TE outer calcite with a higher TE inner calcite. In contrast Sr/Ca ratios remained relatively constant throughout the test wall. These intratest TE variations likely result from biomineralization processes and therefore should be explained by any valid biomineralization model. However, changes in calcite precipitation rate, crystal structure, or the chemical composition of the internal calcification reservoir could not, by themselves, fully account for the pattern of cation intratest variability. Here I expand on this work and investigate if a model of coral biomineralization by Sinclair and Risk (2006) can be adapted to explain the pattern of intratest TE variability in foraminifera. It is clear that the low Mg calcite secreting foraminifera must reduce the Mg/Ca ratio of the calcifying solution by at least a factor of 10 (e.g. Hathorne et al., 2009) and it has been suggested this is achieved by active removal of Mg from the calcification reservoir, although the actual mechanisms remain debatable (e.g. Bentov and Erez, 2006). However, a recent study of the calcification of a low Mg calcite species in the laboratory found a large shortcoming in the amount of Ca potentially provided by seawater transported to the site of calcification in vacuoles compared to a conservative estimate of the amount required to form the new calcite wall (de Nooijer et al., 2009a). This suggests active Ca transport to the site of calcification is required to provide sufficient Ca. If Ca specific, this Ca addition would effectively dilute the TE content (including Mg) of the calcification reservoir to varying degrees and potentially cause the positive TE correlations seen across the test wall. Sinclair and Risk (2006) used this dilution model to successfully explain some TE correlations in coral skeletons. This model can be effectively adapted to foraminifera as it accounts for recent observations of foraminiferal calcification including the transport of seawater by liquid endocytosis to the calcification site and an elevated pH at the site of calcification (Bentov et al., 2009; de Nooijer et al., 2009a, 2009b). This model therefore provides a powerful tool with which to integrate constraints from experimental observation with those from micro-analytical measurements to improve the accuracy, precision and scale of the palaepalaeoceanographic application of foraminiferal geochemistry. Bentov and Erez (2006) Geochem. Geophys. Gepsyst. 7, Q01P08. Bentov et al. (2009) PNAS 106, 21500. de Nooijer et al. (2009a) Biogeosciences 6, 2669. de Nooijer et al. (2009b) PNAS 106, 15374. Hathorne et al. (2009) Paleoceanography 24, PA4204. Sinclair and Risk (2006) Geochim. Cosmochim. Acta 70, 3855.

Description: We present Mg/Ca analyses performed via a Flow Through sequential dissolution device connected to an ICP-OES on the planktonic foraminifer Globorotalia inflata. The aim of the study is to explore the possibility to reconstruct the thermal gradient in the water column by separating non-crusted and crusted calcite phases in the tests of G. inflata using the difference between their Mg/Ca ratios as a measure of the thermal gradient. An important assumption is that the non-crusted part of the tests is calcified in shallow, warmer water than the crusted part. For analyses a range of different preparation steps were used to determine the ideal way of separating the phases. Foraminifer tests were (not) cleaned, (not) crushed, and (not) pulverized before online analysis with the FT device. To analyze samples with a FT device the foraminifer tests are placed on a filter with a mesh of 0.45 μm preventing clay minerals to wash through. A sequential dissolution protocol first rinses the samples with buffered Seralpur water before QD HNO3 is added in small steps to create a ramp of increasing acid strength. As acid is kept constant at each concentration for several minutes, dissolution of a specific calcite phase can take place. Initial results show that it is most effective to slightly crush the tests without applying standard cleaning procedures, but rather analyze them without cleaning. Samples were selected from the South Atlantic (core tops and specific downcore samples) and the Mediteterranean (plankton tows). All samples were chosen based on previous work on them to provide comparison with routinely analysed Mg/Ca ratios. The South Atlantic samples have been analyzed extensively as bulk samples separated in difference size fractions and crusted vs. non-crusted (Groeneveld and Chiessi). The Mediterranean samples were not only analyzed as bulk samples but also by Laser Ablation ICP-MS (von Raden et al.). Results show that bulk analyses are reliably reproduced by the FT method, especially for samples which are dominated by crusted calcite. Samples which were uncrusted often gave much higher Mg/Ca ratios than the bulk analyses. These higher Mg/Ca ratios mainly occur in the plankton tow samples and were also identified with Laser Ablation ICP-MS. A possible reason for this could be the presence of a high Mg amorphous calcite layer on the outside of foraminifer tests which have not completed their calcification yet as was recently also pointed out in several other studies. Identification of the crusted and uncrusted phases, and therewith a thermal gradient, seems to give the expected differences but a more rigorous statistical treatment is needed to pinpoint singular dissolution phases.

Description: Earthquake history shows that the Sunda subduction zone of the Indonesian margin produces great earthquakes offshore Sumatra, whereas earthquakes of comparable magnitude are lacking offshore Java and the Lesser Sunda islands. Morphological structures from multibeam bathymetric data across the forearc relate with the extent of the seismogenic zone (SZ). Off Java and the Lesser Sunda islands the Indo-Australian plate subducts almost normal underneath the oceanic plate of the Indonesian archipelago. Landward of the trench, the outer wedge of the slope break is ~50 km uniformly wide with uniform bathymetric gradients. The slope of the outer wedge is locally cut by one/two steeper ridges of ~5 km extent. The sharp slope break corresponds to the updip limit of the SZ, which is also associated with the seawardmost part of the outer arc high. Landward of the slope break we find narrow, uniform outer arc ridges. The landward termination of these ridges coincides with the downdip limit of the SZ. The intersection of the shallow upper plate mantle with the subduction thrust fault marks the downdip limit of the SZ beneath the forearc. Off Sumatra the Indo-Australian plate subducts obliquely underneath the continental part of the Indonesian Sunda margin. Landward of the trench, the outer wedge varies, being mostly ~70 km wide, in some areas narrowing to 50 km width. The lower slope bathymetric gradients are steep. The outer wedge slope is made up of several steeper ridges of ~5 km extent. The slope break is only locally sharp, and corresponds to the updip limit of the SZ. The outer arc ridges off Sumatra are, in comparison with the forearc structures off Java and the Lesser Sunda islands, wider and partly elevated above sea level forming the Mentawai forearc islands. The downdip limit of the SZ coincides with the intersection of a deeper upper plate mantle with the subduction thrust fault beneath the forearc. Sunda Strait marks a transition zone between the Sumatra and Java margins. Seafloor morphology enables the identification of the seismogenic zone (SZ) across the entire Sunda margin. The SZ is uniformly wide for the Sumatra margin and narrows off Sunda Strait. Sunda Strait is the transition between the Sumatra margin and the uniformly narrow extent of the SZ of the Java/Lesser Sunda margin. Comparing the Java and Lesser Sunda islands with the Sumatra margin we find the differences along the Sunda margin, especially the wider extent of the SZ off Sumatra, producing larger earthquakes, to result from the combination of various causes: The sediment income on the oceanic incoming plate and the subduction direction; we attribute a major role to the continental/oceanic upper plate nature of Sumatra/Java influencing the composition and deformation style along the forearc and subduction fault. Off Sumatra the SZ is up to more than twice as wide as off Java/Lesser Sunda islands, enlarging the unstable regime off Sumatra and thus the risk of sudden stress release in a great earthquake.

Description: EGU2011-407 The spatial and temporal distribution of sea ice in the subpolar North Atlantic is mainly controlled by the advection of warm Atlantic Water via the Norwegian and West Spitsbergen Current in eastern Fram Strait. Simultaneously, polar water and sea ice from the Arctic Ocean is transported southward by the East Greenland Current. Hence, variations in the strength of this oceanic circulation regime may either stimulate or reduce the sea ice extent. Based on organic geochemical studies of a high-resolution sediment core from eastern Fram Strait we provide new evidence for the highly variable character of the sea ice conditions in this area. The combination of the sea ice proxy IP25 (Belt et al., 2007) with phytoplankton derived biomarkers (e.g. brassicasterol, dinosterol; Volkman 2006) enables a reliable reconstruction of sea surface and sea ice conditions, respectively (Müller et al., 2009; 2010). By means of these biomarkers, we trace gradually increasing sea ice occurrences from the Mid to the Late Holocene – consistent with the neoglacial cooling trend. Throughout the past ca. 3,000 years (BP) we observe a significant short-term variability in the biomarker records, which points to rapid advances and retreats of the sea ice cover at the continental margin of West Spitsbergen. The co-occurrence of IP25 and phytoplankton markers, however, suggests that the primary productivity benefits from these sea ice surges. As such, higher amounts of open-water phytoplankton biomarkers together with peak abundances of IP25 indicate recurring periods of enhanced ice-edge phytoplankton blooms at the core site. To what extent a seesawing of temperate Atlantic Water may account for these sea ice fluctuations requires further investigation. Concurrent variations in Siberian river discharge (Stein et al., 2004) or Norwegian glacier extents (Nesje et al., 2001), however, strengthen that these fluctuations may be assigned to variations in the North Atlantic/Arctic Oscillation (NAO/AO) and (hence) a weakened/accelerated Atlantic Water input and Arctic sea ice export.