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Extraterrestrial platinum group nuggets in deep-sea sediments

Abstract

Iron cosmic spheres, composed of iron oxides surrounding a FeNi metal core, were discovered more than a century ago during the voyage of the HMS Challenger1. That tbe spheres originated by atmospheric melting of meteoritic metal is supported by a variety of evidence, including elemental composition2, the presence of the metastable oxide wustite3, similarity to analogues produced in the laboratory4 and content of 53Mn produced by exposure to cosmic rays5. We report here a previously unrecognized property of the spheres. The most common spheres larger than 300 µm do not, in fact, contain FeNi metal cores, but instead contain a micrometre-sized nugget composed almost entirely of platinum group elements. These elements appear to have been concentrated by the oxidation of molten meteoritic metal during atmospheric entry. This process is critically dependent on the relative abundance of oxygen in the atmosphere, and the first appearance of the nuggets in the geological record may provide a marker indicating when the oxygen abundance attained half of its present level.

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References

  1. Murray, S. & Renard, A. F. Rep. Scientific Results Voyage HMS Challenger Vol. 3 (Neill, Edinburgh, 1891).

    Google Scholar 

  2. Castaing, R. & Fredricksson, K. Geochim. cosmochim. Acta 14, 114–117 (1958).

    Article  ADS  CAS  Google Scholar 

  3. Marvin, V. B. & Einaudi, M. T. Geochim. cosmochim. Acta 31, 1871–1884 (1967).

    Article  ADS  CAS  Google Scholar 

  4. Blanchard, M. B. & Davis, A. J. geophys. Res. 83, 1793–1808 (1978).

    Article  ADS  CAS  Google Scholar 

  5. Nishiizumi, K. Earth planet. Sci. Lett. 63, 223–228 (1983).

    Article  ADS  CAS  Google Scholar 

  6. Brownlee, D. E., Pilachowski, L. B. & Hodge, P. W. Lunar planet. Sci. 10, 157–158 (1979).

    ADS  CAS  Google Scholar 

  7. Schamber, F. in X-Ray Fluorescence Analyses of Environmental Samples (ed. Dzubay, T. G.) 241–257 (Ann Arbor Science, 1975).

    Google Scholar 

  8. Wark, D. A. Astrophys. Space Sci. 65, 275–295 (1979).

    Article  ADS  CAS  Google Scholar 

  9. Palme, H. & Wlotzka, F. Earth planet. Sci. Lett. 33, 45–60 (1976).

    Article  ADS  CAS  Google Scholar 

  10. Fechtig, H. & Uteck, K. Ann N.Y. Acad. Sci. 119, 243–249 (1964).

    Article  ADS  CAS  Google Scholar 

  11. Gibbons, R. V., Horz, F., Thompson, T. D. & Brownlee, D. E. Proc. 7th Lunar Sci Conf. 863–880 (1976).

  12. Brett, R. Am. Miner. 52, 721–733 (1967).

    CAS  Google Scholar 

  13. Brownlee, D. E. in The Sea Vol. 7 (ed. Emiliani, C.) 733–762 (Wiley Interscience, New York, 1981).

    Google Scholar 

  14. Reed, T. B. Free Energy of Formation—An Atlas of Charts for High Temperature Chemical Calculations (MIT Press, Cambridge, 1971).

    Google Scholar 

  15. St. Clair, H. W. in Vacuum Metallurgy (ed. Bunshah, R. F.) 295–305 (Reinhold, New York 1958).

    Google Scholar 

  16. Honig, R. E. in Characterization of High Temperature Vapors (ed. Margrave, J. L.) 475–494 (Wiley, New York, 1967).

    Google Scholar 

  17. Crockett, J. H. Geochim. cosmochim. Acta 36, 517–535 (1972).

    Article  ADS  Google Scholar 

  18. Brownlee, D. E., Bates, B. & Beauchamp, R. H. in Chondrules and their Origins (ed. King, E.) 10–25 (Lunar Planetary Institute, Houston, 1983).

    Google Scholar 

  19. Alvarez, L. W., Alvarez, W., Asaro, F. & Michel, H. V. Science 208, 1095–1108 (1980).

    Article  ADS  CAS  Google Scholar 

  20. Anders, E. & Ebihara, M. Geochim. cosmochim. Acta 46, 2363–2380 (1982).

    Article  ADS  CAS  Google Scholar 

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Brownlee, D., Bates, B. & Wheelock, M. Extraterrestrial platinum group nuggets in deep-sea sediments. Nature 309, 693–695 (1984). https://doi.org/10.1038/309693a0

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