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Photothermal spectroscopy with femtojoule sensitivity using a micromechanical device

Abstract

WHEN a material absorbs a photon, a fraction of the energy may be transformed into heat. A measurement of photothermal heating as a function of wavelength can provide an absorption spectrum of the material. We have recently1,2 developed a micromechanical sensor capable of detecting heat changes of the order of picojoules (10-12 J). The instrument incorporates a bilayer cantilever of micrometre dimensions which bends in response to heating. Here we show that this device can be used for photothermal spectroscopy with a power sensitivity of 100 pW—two orders of magnitude better than the sensitivity of conventional photothermal deflection spectroscopy3. The small size of the sensor allows picogram quanti-ties of material to be studied, opening up the possibility of spectro-scopic studies on individual cells and bacteria. Being based on silicon technology, the sensor should be compatible with micro-electronic circuitry.

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Barnes, J., Stephenson, R., Welland, M. et al. Photothermal spectroscopy with femtojoule sensitivity using a micromechanical device. Nature 372, 79–81 (1994). https://doi.org/10.1038/372079a0

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