Abstract
THE formation and decomposition of a higher hydrogen peroxide H2O4 has been described in recent Russian literature. Much of this work dealt with the existence of condensed HO2 radicals or molecular H2O4 at low temperatures ; for example, Kobozev et al., Reznitskii et al., and Gorbanev1 investigated the reaction between atomic hydrogen and liquid ozone at −196°C. Calorimetric and electron spin resonance measurements are quoted as evidence for the existence of hydrogen superoxide H2O4 which decomposes spontaneously at −115°C. into hydrogen peroxide and oxygen.
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References
Kobozev, N. I., Nekrasov, L. I., and Yeremin, Ye. N., Zhur. Fiz. Khim., 30 (11), 2580 (1956). Kobozev, N. I., Skorokhodov, I. I., Nekrasov, L. I., and Makarova, E. I., Zhur. Fiz. Khim., 31 (8), 1843 (1957). C.T.S. Translation No. 564. Reznitskii, L. A., Khomykov, K. G., Nekrasov, L. I., and Skorokhodov, I. I., Zhur. Fiz. Khim., 32 (1), 87 (1958). Gorbanev, A. I., Zhur. Fiz. Khim., 31 (2), 515 (1957).
Astakhov, K. V., and Getzov, A. G., Doklady Akad. Nauk S.S.S.R., 81, 43 (1951).
Kruglyakova, K. E., and Emanuel, N. M., Doklady Akad. Nauk S.S.S.R., 83, 593 (1952).
Stadnik, P. M., Doklady Akad. Nauk S.S.S.R., 87, 445 (1952).
Purmal, A. P., Zhur. Fiz. Khim., 29 (5), 846 (1955).
Mckinley, J. D., Tech. Report No. 9, Jan. 1954. James Forrestal Res. Centre, Princeton, J. Chem. Phys., 22, 1258 (1954).
Mironov, K. E., and Danilova, M. S., Zhur. Neorg. Khim., 3 (12), 2807 (1958).
Metschl, J., J. Phys. Chem., 28, 417 (1924).
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MARSHALL, J., RUTLEDGE, P. A Higher Hydrogen Peroxide, H2O4?. Nature 184, 2013–2014 (1959). https://doi.org/10.1038/1842013a0
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DOI: https://doi.org/10.1038/1842013a0
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