Schwingungs- und NMR-spektroskopische Untersuchungen von Trivinylen und Trivinyldihalogeniden des Arsens und Antimons

https://doi.org/10.1016/0584-8539(82)80024-XGet rights and content

Abstract

The i.r. and Raman spectra of monomeric AsVi3, SbVi3, Vi3AsHal2 and Vi3SbHal2 (Vi = CH2 = CH-, Hal = F, Cl) have been recorded and assigned. According to these data the compounds have trigonal pyramidal and trigonal bipyramidal structures, respectively, probably with slightly twisted vinyl groups. The 1H- and 13C-NMR spectra of the products have been measured in different solvents and at different temperatures. For the quantum mechanical calculations of these NMR spectra a modified BASIC version of the known fortran programme LAOCOON III was used.

Literatur (14)

  • A.K. Holliday et al.

    J. Organomet. Chem.

    (1974)
    J.D. Odom et al.

    Inorg. Chem.

    (1974)
  • G. Masetti et al.

    Spectrochim. Acta

    (1970)
    G. Davidson

    Spectrochim. Acta

    (1971)
  • A. Foord et al.

    J. Mol. Struct.

    (1975)
    T. Fjelberg et al.

    Acta Chem. Scand. Ser. A.

    (1981)
  • G. Davidson et al.

    Spectrochim. Acta

    (1978)
  • L. Maier et al.

    J. Am. Chem. Soc.

    (1957)
    A.N. Nesmeyanov et al.

    Izvest. Akad. Nauk. S.S.S.R. Otdel. Khim. Nauk

    (1961)
  • H. Schrem et al.

    Z. Anorg. Allg. Chem.

    (1978)
  • A. Schmidt

    Chem. Ber.

    (1969)
There are more references available in the full text version of this article.

Cited by (0)

View full text