The photoelectkon spectra of several methylgermanium and perfluoromethylgermanium iodides

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Abstract

He(I) photoelectron spectra are reported for the series of compounds (CH3)3GeI, (CH3)2GeHI, CH3GeH2I and (CH3)2GeI2, as well as for (CF3)3GeI, (CF3)2GeI2 and CF3GeI3. He(II) photoelectron spectra are also reported for all of the perfluoromethyl compounds. Assignments are proposed on the basis of semi-empirical CNDO/2 calculations, band shapes and changes of relative intensities between the He(I) and He(II) spectra. Comparisons are drawn with the related bromides and chlorides.

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